The successful encapsulation of dysprosium(Dy) into fullerene cages by activating the Dy2O3, containing graphite rods in situ 'back-burning' carbonarc evaporation with a high-yield of pyridine extraction techn...The successful encapsulation of dysprosium(Dy) into fullerene cages by activating the Dy2O3, containing graphite rods in situ 'back-burning' carbonarc evaporation with a high-yield of pyridine extraction technique is reported.展开更多
Four peptides PSPP1,PSPP2,PSPP3 and PSPP4 were purified from the water-extract of Papaver somniferum pollen.Their sequences,with 21,17,13 and 16 amino acid residues respectively,have been determined by Edman degradati...Four peptides PSPP1,PSPP2,PSPP3 and PSPP4 were purified from the water-extract of Papaver somniferum pollen.Their sequences,with 21,17,13 and 16 amino acid residues respectively,have been determined by Edman degradation-N-terminal dansylation.PSPP2, PSPP3 and PSPP4 were synthesized using solid phase method.The immunopromotive activities of PSPP1,PSPP2,PSPP3,PSPP4 and the initially separated sample PSPP have been also observed by the methods of counting erythrocyte rosette forming cells(ERFC) and T-lymphocyte transformation test in vitro.展开更多
Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine,leucinol and hydrazine hydrate,respectively,three novel thiacalix [4]arene derivatives 4,5 ...Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine,leucinol and hydrazine hydrate,respectively,three novel thiacalix [4]arene derivatives 4,5 and 6 with triazolyl and hydrogen bonding groups(NH and OH) were synthesized in high yields.They exhibited excellent extraction capability for six anionic and cationic dyes.The flexible cavity,π-triazole rings and hydrogen bonding groups all play crucial roles in dye complexation.展开更多
ZnO nanoparticles(ZnO NPs) were synthesized by chemical method(coprecipitation) and biological method using aqueous extracts of garlic(Allium sativum),rosemary(Rosmarinus officinalis) and basil(Ocimum basili...ZnO nanoparticles(ZnO NPs) were synthesized by chemical method(coprecipitation) and biological method using aqueous extracts of garlic(Allium sativum),rosemary(Rosmarinus officinalis) and basil(Ocimum basilicum).The influence of plant extract on the antibacterial and antioxidant activities of green synthesized nanoparticles was investigated.The X-ray diffraction studies reveal that all ZnO samples have hexagonal wurtzite structure.The particle size of ZnO NPs estimated by transmission electron microscopy analysis(between 14 and 27 nm) varies depending on the synthesis method of nanoparticles and the type of extracts from the plants used.The functional groups involved in the biosynthetic procedure were evidenced by Fourier transform infrared spectroscopy.The presence of Mn^(2+)ions,Zn vacancy complexes and oxygen vacancies in ZnO samples was highlighted by electron paramagnetic resonance spectroscopy.The green synthesized ZnO NPs have shown a good bactericidal activity against Staphylococcus aureus,Bacillus subtilis,Listeria monocytogenes,Escherichia coli,Salmonella typhimurium and Pseudomonas aeruginosa bacterial strains.ZnO NPs synthesized using extracts of the selected plant species have been found to exhibit more enhanced antibacterial and antioxidant activities as compared to chemical ZnO NPs.展开更多
文摘The successful encapsulation of dysprosium(Dy) into fullerene cages by activating the Dy2O3, containing graphite rods in situ 'back-burning' carbonarc evaporation with a high-yield of pyridine extraction technique is reported.
文摘Four peptides PSPP1,PSPP2,PSPP3 and PSPP4 were purified from the water-extract of Papaver somniferum pollen.Their sequences,with 21,17,13 and 16 amino acid residues respectively,have been determined by Edman degradation-N-terminal dansylation.PSPP2, PSPP3 and PSPP4 were synthesized using solid phase method.The immunopromotive activities of PSPP1,PSPP2,PSPP3,PSPP4 and the initially separated sample PSPP have been also observed by the methods of counting erythrocyte rosette forming cells(ERFC) and T-lymphocyte transformation test in vitro.
基金Financial support from the National Natural Science Foundation of China(No.20402002)Fujian Natural Science Foundation of China(No.2011J01031)+1 种基金Project of Fujian Provincial Department of Education(No.JA11044)Program for Excellent Young Researchers in University of Fujian Province(No.JA10056)
文摘Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine,leucinol and hydrazine hydrate,respectively,three novel thiacalix [4]arene derivatives 4,5 and 6 with triazolyl and hydrogen bonding groups(NH and OH) were synthesized in high yields.They exhibited excellent extraction capability for six anionic and cationic dyes.The flexible cavity,π-triazole rings and hydrogen bonding groups all play crucial roles in dye complexation.
基金supported by the Romanian Ministry of Education and Research within the Nucleu Programme(Project PN 09-44)
文摘ZnO nanoparticles(ZnO NPs) were synthesized by chemical method(coprecipitation) and biological method using aqueous extracts of garlic(Allium sativum),rosemary(Rosmarinus officinalis) and basil(Ocimum basilicum).The influence of plant extract on the antibacterial and antioxidant activities of green synthesized nanoparticles was investigated.The X-ray diffraction studies reveal that all ZnO samples have hexagonal wurtzite structure.The particle size of ZnO NPs estimated by transmission electron microscopy analysis(between 14 and 27 nm) varies depending on the synthesis method of nanoparticles and the type of extracts from the plants used.The functional groups involved in the biosynthetic procedure were evidenced by Fourier transform infrared spectroscopy.The presence of Mn^(2+)ions,Zn vacancy complexes and oxygen vacancies in ZnO samples was highlighted by electron paramagnetic resonance spectroscopy.The green synthesized ZnO NPs have shown a good bactericidal activity against Staphylococcus aureus,Bacillus subtilis,Listeria monocytogenes,Escherichia coli,Salmonella typhimurium and Pseudomonas aeruginosa bacterial strains.ZnO NPs synthesized using extracts of the selected plant species have been found to exhibit more enhanced antibacterial and antioxidant activities as compared to chemical ZnO NPs.