In atmospheric conditions, CuⅠis easily oxidized to CuⅡdue to the coexistence of moisture and oxygen.The poor oxidation inhibition of CuⅠrestricts the practical application of CuⅠ-containing materials.Herein we in...In atmospheric conditions, CuⅠis easily oxidized to CuⅡdue to the coexistence of moisture and oxygen.The poor oxidation inhibition of CuⅠrestricts the practical application of CuⅠ-containing materials.Herein we introduce an approach to construct a superhydrophobic microenvironment in CuⅠfunctionalized metal–organic frameworks by coordinatedly grafting organic amine compounds onto open metal sites(OMSs), which can hinder the accessibility of moisture to pores thereby enhancing the stability of CuⅠ. As a proof of concept, MIL-101(Cr) with abundant OMSs and octadecylamine(OA)with long hydrophobic alkyl groups are used as carrier and surface coating. As superhydrophobic porous materials, the resultant CuⅠM-OA exhibits improved CuⅠstability in addition to retaining high crystallinity and intact porosity while almost all CuⅠis oxidized in hydrophilic CuⅠM upon exposure in a humid atmosphere for 30 h. CuⅠM-OA owns excellent adsorption desulfurization performance(ADS) with regard to thiophene, benzothiophene, and 4,6-dimethyl dibenzothiophene. Even from hydrated fuel, the adsorption performance of CuⅠM-OA maintains well while the adsorption capacity of CuⅠM decreases to 7% after4 cycles. The remarkable moisture resistance, CuⅠstability, and high porosity make the current adsorbent CuⅠM-OA highly promising for the practical ADS process.展开更多
新型城市化建设和管理过程中,借助建筑信息模型(building information modeling,BIM)与地理信息系统(geographic information system,GIS)的数据集成,不但能实现建筑物的精细化表达,而且室外信息得以兼顾,实现空间分析及室内外一体化表...新型城市化建设和管理过程中,借助建筑信息模型(building information modeling,BIM)与地理信息系统(geographic information system,GIS)的数据集成,不但能实现建筑物的精细化表达,而且室外信息得以兼顾,实现空间分析及室内外一体化表达。但BIM与GIS两种不同的数据格式无法直接实现数据的互通。为此,首先分析了模型IFC和CityGML在文档形式等方面的差异,并实现了多个简单建筑物IFC模型到CityGML3.0 LOD2、LOD3的转换。其次,针对上述数据集成实验中语义丢失问题,扩展GIS的CityGML3.0数据格式,提出CityGML B-Con扩展模型,完善IFC到CityGML3.0的一对一映射关系。最后,实现多个不同复杂程度建筑物IFC模型到CityGML B-Con扩展模型的转换。实验结果表明,利用CityGML B-Con模型能实现BIM与GIS的数据集成。宏观层面来说,能够增强转换后建筑物外观的细节程度,微观层面而言,BuildingConstructiveElement和BuildingInstallation的子类得以区分,IfcStair、IfcRamp和IfcBeam等建筑构件都能通过一对一映射的方式转换至CityGML中,克服了CityGML原有标准在建筑物构件表达方面的缺陷,有效减少了BIM源数据语义信息的丢失。展开更多
基金supported by the National Science Fund for Distinguished Young Scholars (22125804)the National Natural Science Foundation of China (22008112, 22078155, and 21878149)+1 种基金the China Postdoctoral Science Foundation (2019M661813)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘In atmospheric conditions, CuⅠis easily oxidized to CuⅡdue to the coexistence of moisture and oxygen.The poor oxidation inhibition of CuⅠrestricts the practical application of CuⅠ-containing materials.Herein we introduce an approach to construct a superhydrophobic microenvironment in CuⅠfunctionalized metal–organic frameworks by coordinatedly grafting organic amine compounds onto open metal sites(OMSs), which can hinder the accessibility of moisture to pores thereby enhancing the stability of CuⅠ. As a proof of concept, MIL-101(Cr) with abundant OMSs and octadecylamine(OA)with long hydrophobic alkyl groups are used as carrier and surface coating. As superhydrophobic porous materials, the resultant CuⅠM-OA exhibits improved CuⅠstability in addition to retaining high crystallinity and intact porosity while almost all CuⅠis oxidized in hydrophilic CuⅠM upon exposure in a humid atmosphere for 30 h. CuⅠM-OA owns excellent adsorption desulfurization performance(ADS) with regard to thiophene, benzothiophene, and 4,6-dimethyl dibenzothiophene. Even from hydrated fuel, the adsorption performance of CuⅠM-OA maintains well while the adsorption capacity of CuⅠM decreases to 7% after4 cycles. The remarkable moisture resistance, CuⅠstability, and high porosity make the current adsorbent CuⅠM-OA highly promising for the practical ADS process.
文摘新型城市化建设和管理过程中,借助建筑信息模型(building information modeling,BIM)与地理信息系统(geographic information system,GIS)的数据集成,不但能实现建筑物的精细化表达,而且室外信息得以兼顾,实现空间分析及室内外一体化表达。但BIM与GIS两种不同的数据格式无法直接实现数据的互通。为此,首先分析了模型IFC和CityGML在文档形式等方面的差异,并实现了多个简单建筑物IFC模型到CityGML3.0 LOD2、LOD3的转换。其次,针对上述数据集成实验中语义丢失问题,扩展GIS的CityGML3.0数据格式,提出CityGML B-Con扩展模型,完善IFC到CityGML3.0的一对一映射关系。最后,实现多个不同复杂程度建筑物IFC模型到CityGML B-Con扩展模型的转换。实验结果表明,利用CityGML B-Con模型能实现BIM与GIS的数据集成。宏观层面来说,能够增强转换后建筑物外观的细节程度,微观层面而言,BuildingConstructiveElement和BuildingInstallation的子类得以区分,IfcStair、IfcRamp和IfcBeam等建筑构件都能通过一对一映射的方式转换至CityGML中,克服了CityGML原有标准在建筑物构件表达方面的缺陷,有效减少了BIM源数据语义信息的丢失。
文摘星基广播式自动相关监视(ADS-B,automatic dependent surveillance-broadcast)系统是一种新型的航空器监视技术,在未来空中交通管理系统中具有广阔的应用前景。为了深入研究星基ADS-B系统中航空器到卫星的空天链路通信性能,将专业软件Matlab和STK(system tool kit)有效联合,构建符合国际标准的星基ADS-B空天链路完整模型;通过离散事件动态交互模拟ADS-B消息的发送与接收全过程,最后统计得出体现星基ADS-B空天链路通信性能的消息识别概率(POI,possibility of identify)、消息检测概率(POD,possibility of detective)、信号接收功率、信号冲突概率、卫星覆盖范围等指标。仿真结果表明,随着区域内航空器数量上升,POI、POD下降,消息冲突概率上升。
