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OBJECTIVE MEASUREMENT:A STUDY OF SHIRTING FABRIC FINISHES
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作者 拱荣华 《Journal of China Textile University(English Edition)》 EI CAS 1993年第4期62-70,共9页
The results of an investigation into the effects of various finishing processes on the propertiesof cotton rich mans shirting fabrics are presented and discussed.The KES-FB system was used forthe testing of fabric mec... The results of an investigation into the effects of various finishing processes on the propertiesof cotton rich mans shirting fabrics are presented and discussed.The KES-FB system was used forthe testing of fabric mechanical properties.It is concluded that mercerising cotton rich fabrics is nota cost effective finish process while the optimisation of the bleaching process may bring more bene-fit.The investigation is part of a long term program aimed at the development of an expert systemfor total fabric engineering. 展开更多
关键词 fabric finishING fabric PERFORMANCE fabric HAND tailorability objective MEASUREMENT shirting fabric EXPERT system
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Wrinkle Resistant Finishing of Cotton Fabrics with the Complex System of PBTCA/CA 被引量:1
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作者 宋海涛 隋淑英 +2 位作者 朱平 董朝红 张林 《科技信息》 2011年第3期I0197-I0198,共2页
In this paper,the wrinkle resistant finishing of cotton fabric with the complex system of PBTCA and CA was mainly discussed.The influence of finishing conditions such as the amount of finishing agent and catalyst,curi... In this paper,the wrinkle resistant finishing of cotton fabric with the complex system of PBTCA and CA was mainly discussed.The influence of finishing conditions such as the amount of finishing agent and catalyst,curing temperature and curing time were studied.Wrinkle recovery angle(WRA),breaking strength(BS) and whiteness(Wh) of finished fabric were measured.The experimental data indicated that the best finishing conditions were PBTCA 120g/L,CA 50g/L,sodium hypophosphite 50g/L,triethanolamine 20g/L,cured 170℃ for 120s. 展开更多
关键词 PBTCA CA Cotton fabric WRINKLE RESISTANT finishING
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Preparation of HPMA and Its Application in Durable Press Finishing of Cotton Fabric
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作者 赵敏 周翔 《Journal of China Textile University(English Edition)》 EI CAS 2000年第3期32-34,共3页
A series of hydrolyzed poly(maleic anhydride)(HPMA) is synthesized by using maleic anhydride as the monomer and hydrogen peroxide as the initiator.The effects of reaction temperature,reaction time period and amount of... A series of hydrolyzed poly(maleic anhydride)(HPMA) is synthesized by using maleic anhydride as the monomer and hydrogen peroxide as the initiator.The effects of reaction temperature,reaction time period and amount of initiator on the double bond residue in the products are studied to decide a suitable synthesizing process.Thepreferable amount of the initiator is 50 wt%,and thepolymerization should be carried out at 105℃ for two hours.Cotton fabrics are finished with the synthesized products and several commercial HPMAs,respectively.And the performance properties of the finished fabrics are compared.The fabric finished with the synthetic HP-MA using the above-mentioned synthesizing process isimparted a high wrinkle recovery angle. 展开更多
关键词 cotton fabric CROSSLINK durable PRESS finishing.
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STUDY OF FLAME RETARDING FINISH OF POLYPROPYLENE / VISCOSE BLEND FABRICS
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作者 郑利民 杨志云 +1 位作者 赵曙辉 叶慧敏 《Journal of China Textile University(English Edition)》 EI CAS 1997年第4期37-41,共5页
The combustion mechanisms of PP / Viscose blend fabrics are briefly discussed, and the factors affecting flame retarding(FR) effect are analyzed. Apart from this, the choice of processes of FR finish is also discussed... The combustion mechanisms of PP / Viscose blend fabrics are briefly discussed, and the factors affecting flame retarding(FR) effect are analyzed. Apart from this, the choice of processes of FR finish is also discussed in this paper. Other factors such as coating add-on, curing temperature and time are studied too. The results show that the factors above all have different extent of influence upon FR effect. 展开更多
关键词 PP / VISCOSE BLEND fabricS FLAME RETARDING finish coating char length afterglowing time
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Impact of Different Water Repellent Finishes on Cotton Double Jersey Fabrics
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作者 Kawser Parveen Chowdhury 《Journal of Textile Science and Technology》 2018年第3期85-99,共15页
This study demonstrated that the variation in physical and chemical performance on cotton double jersey knit fabrics was decided by the knit structure, water repellent chemicals types and their concentration. Here, tw... This study demonstrated that the variation in physical and chemical performance on cotton double jersey knit fabrics was decided by the knit structure, water repellent chemicals types and their concentration. Here, two types of double jersey fabrics were treated with different types of water repellent chemicals at different formulations to evaluate the performance of water repellent finishes on knit fabrics properties. The levels of water repellency of the fabrics were assessed by AATCC 127 hydrostatic head test method and by ISO 4920:2012 spray rating test method. To evaluate the performance of water repellent finishes on knit fabric properties, GSM, bursting strength test according to ASTM (D 3786-87) method, air permeability, color fastness to wash, water, perspiration, chlorinated water and color fastness to rubbing with ISO method were done. The results showed that both physical and chemical properties of the finished cotton knits, depend to a great extent on knit structure, the water repellent finish type and concentration to obtain water repellent fabrics with desirable properties. 展开更多
关键词 WATER REPELLENCY WATER REPELLENT finish DOUBLE JERSEY fabric FLUOROCARBON
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Effect of Special Finishes on the Functional Properties of Cotton Fabrics
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作者 Kawser Parveen Chowdhury 《Journal of Textile Science and Technology》 2018年第2期49-66,共18页
This study demonstrated that the changes in functional properties of both woven and knit cotton fabrics were determined to evaluate the performance of different special finishes. Here, 100% cotton fabrics were treated... This study demonstrated that the changes in functional properties of both woven and knit cotton fabrics were determined to evaluate the performance of different special finishes. Here, 100% cotton fabrics were treated with different types of finishing chemicals at different formulations. To assess the performance of different finishes on fabric properties, GSM, bursting strength, tensile strength, dimensional stability, absorbency, crease recovery angle with ASTM and AATCC methods were done. The results showed that the functional properties of the finished cotton fabrics both woven and knit depend to a great extent on the type of finish. 展开更多
关键词 Water REPELLENT finish WRINKLE Free finish SOFT finish Paper TOUCH finish Knit fabric Woven fabric Performance
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The Effects of Dyeing and Finishing Pretreatment Process to the Sliver Fiber Shielding Fabric and the Reasons
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作者 ZHANG Tan MA Jian-wei +1 位作者 GUO Kun XU Hong-xing 《科技视界》 2014年第1期211-212,共2页
Through the silver fiber and cotton mixed silver fiber shielding fabric,not only soft and comfortable,it can wear personal,but also has excellent anti electromagnetic shielding effect. Fabric in dyeing and finishing p... Through the silver fiber and cotton mixed silver fiber shielding fabric,not only soft and comfortable,it can wear personal,but also has excellent anti electromagnetic shielding effect. Fabric in dyeing and finishing process,may cause some damage on the silver fiber,influence the shielding performance of shielding fabric. Therefore,in this paper,through the experimental and analysis,find dyeing and finishing process may affect silver fiber shielding fabric and the reasons. 展开更多
关键词 棉混纺织物 银纤维 产品介绍 染整工艺
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Anti-Bacterial and Flame Retardant for Cotton Fabric by One-Bath Finishing
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作者 朱平 隋淑英 +1 位作者 王炳 孙铠 《Journal of China Textile University(English Edition)》 EI CAS 1998年第2期82-84,共3页
A research on the process of cotton fabric flame-re-tarding,anti-bacterial finishing and one-bath finish-ing of anti-bacterial and flame-retarding is discussed.The flame retardant agent was phosphorous-contained,and t... A research on the process of cotton fabric flame-re-tarding,anti-bacterial finishing and one-bath finish-ing of anti-bacterial and flame-retarding is discussed.The flame retardant agent was phosphorous-contained,and the bacteriostatic finishing agent named SFR-1 wassynthesized.The flame retardancy of the fabric finishedcan meet the DOC FF3-71 Children Sleepwear Stan-dard.Its bacterial inhibiting capacity can meet and ex-ceed the requirements of similar products 展开更多
关键词 cotton fabric flame - RETARDING finishING anti - BACTERIAL finishING one - BATH
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Research on Properties of Woven Fabrics Treated by High Pressure Water Jet 被引量:3
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作者 Huang Gu(黄故) 《Journal of Donghua University(English Edition)》 EI CAS 2001年第4期94-96,共3页
The paper introduces a new technique for the treatment of the woven fabrics. Sprayed by high pressure water jet, the appearance, handle and stiffness of the fabric are improved. Other properties of the high pressure w... The paper introduces a new technique for the treatment of the woven fabrics. Sprayed by high pressure water jet, the appearance, handle and stiffness of the fabric are improved. Other properties of the high pressure water treated fabrics like drape coefficient, air permeability, tenacity are also presented. 展开更多
关键词 Woven fabric High PRESSURE AIR jet fabric finishING
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REDUCING HAIRFALLING AND PILLING STUDY IN RABBIT HAIR/WOOL WORSTED KNITWEAR——CHOOSING AND EVALUATING OF FINISHING AGENT
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作者 王璐 杨冠军 +2 位作者 王俦 曾泳春 陈霞明 《Journal of China Textile University(English Edition)》 EI CAS 1995年第2期8-13,共6页
In the paper, the effects of reducing hairfalling and pilling were compared in rabbit hair/woolworsted knitwear by adding various finishing agents. Reducing rates of hairfalling and pilling wereof 6.7%—66.7% and 9.... In the paper, the effects of reducing hairfalling and pilling were compared in rabbit hair/woolworsted knitwear by adding various finishing agents. Reducing rates of hairfalling and pilling wereof 6.7%—66.7% and 9.3%—73.5% respectively, while fabric handle changed from grade 1 to grade5 in 12 treating method groups. To evaluate the severity of hairfalling and pilling and the conditionof fabric handle of knitwear objectively, quantitatively and comprehensively, we advocated usingthe concept of "geueral evaluating value(GEV)". The results indicated that GEVs of acrylategroups were low, but GEVs of silicone resin groups were high, especially the group with finishingagent solution containing 7% silicone resin No.3 in which reducing rates of pilling and hairfallingwere of 53% (National standard: grade 4.5) and 62%, respectively, and washing stability was verygood, while knitwear’s fabric handle almost did not change. 展开更多
关键词 rabbit hair KNITTED fabric PILLING tendency hairfalling finishing agent fabric handle general EVALUATING value.
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抗熔滴型多元有机硅阻燃剂整理锦纶6织物的制备及其性能 被引量:2
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作者 范硕 杨鹏 +3 位作者 曾锦豪 宋潇迪 龚昱丹 肖遥 《纺织学报》 EI CAS CSCD 北大核心 2024年第1期152-160,共9页
为提升锦纶6织物阻燃性能,基于水解缩合反应原理,开发设计多元协效抗熔滴型含磷席夫碱基有机硅阻燃剂,并采用浸渍法对锦纶6织物进行阻燃整理。借助红外光谱、热重分析仪、微型燃烧量热仪、极限氧指数仪、扫描电镜、拉曼光谱及热裂解气... 为提升锦纶6织物阻燃性能,基于水解缩合反应原理,开发设计多元协效抗熔滴型含磷席夫碱基有机硅阻燃剂,并采用浸渍法对锦纶6织物进行阻燃整理。借助红外光谱、热重分析仪、微型燃烧量热仪、极限氧指数仪、扫描电镜、拉曼光谱及热裂解气质联用仪等技术分别对阻燃锦纶6织物的化学结构、热稳定性、燃烧行为及其燃烧后炭化层与气相热解产物系统研究。结果表明:阻燃锦纶6织物的炭化能力及阻燃性能有效提升,其残炭率可增加至33.9%,且在火焰移开后可快速实现自熄,并未有熔滴产生;相较于锦纶6织物,阻燃锦纶6织物的热释放速率峰值(PHRR)及总释热量(THR)分别下降23.8%及20.4%,火灾安全性有效提升;经水洗20次后,阻燃锦纶6织物仍可实现自熄,其PHRR及THR值相较于锦纶6织物,仍分别下降了14.1%及13.6%。 展开更多
关键词 锦纶6织物 阻燃整理 阻燃剂 功能纺织品 多元有机硅 抗熔滴
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Development of an Antibacterial Finishing Progress for Medical Compression Hosiery
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作者 MESA Loraine 毛俊峰 +2 位作者 陈晓洁 张倩 王璐 《Journal of Donghua University(English Edition)》 EI CAS 2016年第4期614-618,共5页
Medical compression hosiery based on polyurethane and polyamide covered yarns was treated with two antibacterial agents,SCJ-891 and SCJ-963, to investigate their antimicrobial performance. Various parameters of finish... Medical compression hosiery based on polyurethane and polyamide covered yarns was treated with two antibacterial agents,SCJ-891 and SCJ-963, to investigate their antimicrobial performance. Various parameters of finishing process, including concentration,temperature,pH and liquor ratio,were studied in the single factor and orthogonal experiments. ANOVA analysis indicated that all of these four variables played important roles in antimicrobial efficacy. Different combinations of finishing parameters gave different antimicrobial efficacies against both gram positive bacteria Staphylococcus aureus( S. aureus) and gram negative bacteria Escherichia coli( E. coli). SCJ-963 treated fabric had better antibacterial efficacy when compared with that of SCJ-963 treated yarn. Meanwhile both SCJ-963 treated fabric and yarn showed better antibacterial efficacy when compared with SCJ-891 treated fabric and yarn. The optimized parameters for SCJ-891 treated fabric against S. aureus( A: 86%) were a liquor ratio of 1: 20,a concentration of 10% of weight of fabric,pH of 4. 5 and a temperature of 99℃; the optimized parameters for SCJ-963 treated fabric against S. aureus( A: 83%) were a liquor ratio of 1: 15,a concentration of 10% of weight of fabric, a pH of 5 and a temperature of 99℃. Furthermore, two kinds of antimicrobial finishing of the fabric had good resistance to 50 times washing. This study concluded that SCJ-891 and SCJ-963 were compatible to be used in medical compression hosiery. 展开更多
关键词 fabric liquor antibacterial antimicrobial finishing polyurethane Compression washing ANOVA clothes
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PREPARATION AND APPLICATION OF A NEW ANTIFELTING RESIN FOR WOOL FABRICS
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作者 孙铠 王际平 《Journal of China Textile University(English Edition)》 EI CAS 1991年第3期22-29,共8页
In this paper,a new resin called Resin M for imparting antifelting properties to wool fabricshas been studied.Resin M may be used by aqueous oxidative/polymer technique.It is provedthat Oxidant A/Resin M treatment can... In this paper,a new resin called Resin M for imparting antifelting properties to wool fabricshas been studied.Resin M may be used by aqueous oxidative/polymer technique.It is provedthat Oxidant A/Resin M treatment can satisfy the machine washable requirement formulated byI.W.S..Resin M is a good agent for antifelting treatment of wool fabrics with proper pretreatment.Oxidant A/Resin M treatment has little influence on dyeing and moisture adsorption properties ofwool fibers.The pilling resistance of the treated fabrics is higher than that of the untreated ones.The strength and the handle of the treated fabrics have little been changed.According to thescanning electron microscope observations,it is recommended that the polymer encapsulation ofindividual fiber also plays an important role in the felting resistance of the treated fabrics though itis well known that the shrink resistance of the treated fabrics is believed to be due to the binding offibers. 展开更多
关键词 felting shrinkage wool fabric washing fastness resin finishing antifelting machine washable Resin M superwash
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微胶囊技术在功能纺织品领域的应用研究进展
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作者 要彬 李孟轩 《针织工业》 北大核心 2024年第5期85-89,共5页
利用微胶囊技术可以获得具有较好舒适性和耐久性,同时具有多种功能的功能纺织品,是提升纺织品科技含量、提高纺织品附加价值的有效手段。文章主要从功能微胶囊制备和微胶囊强化功能织物的开发两个方面,总结了近年来微胶囊技术在功能织... 利用微胶囊技术可以获得具有较好舒适性和耐久性,同时具有多种功能的功能纺织品,是提升纺织品科技含量、提高纺织品附加价值的有效手段。文章主要从功能微胶囊制备和微胶囊强化功能织物的开发两个方面,总结了近年来微胶囊技术在功能织物领域的应用成果,介绍了蓄热调温、芳香保健、变色指示3种常见的功能微胶囊以及微胶囊强化功能织物的研究成果。并根据其未来发展趋势,提出研究重点应放在集成型、复合型微胶囊功能纺织品开发方面的建议。 展开更多
关键词 微胶囊 功能纺织品 功能整理 研究进展
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Optimization of Finishing Process and Energy Savings in Denim Textile Facility
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作者 Md. Enamul Haque Kaisul Kabir +5 位作者 Md. Asib Khan Mohammad Abu Syed Nizami Rajib Kabiraj Mohammed Fakhruddin Md. Golam Arif Md. Abu Hanif 《Journal of Textile Science and Technology》 2023年第3期151-164,共14页
Denim is widely accepted among exported textile products due to its aesthetics, appearance, and fashion. Practitioners employed several physical or chemical treatments to improve denim qualities in denim finishing ope... Denim is widely accepted among exported textile products due to its aesthetics, appearance, and fashion. Practitioners employed several physical or chemical treatments to improve denim qualities in denim finishing operations. So, several treatment processes, including enzymatic, bleaching, singeing, heat set, and ozone finish, are used, which made this processing more energy consumption and time-consuming. Therefore, it is significant to investigate how changing the chemicals and raw ingredients could improve the finishing process, which is environmentally and economically beneficial for sustainable production practices in the denim finishing process. This study’s research design comprises an experimental investigation in a denim plant in Bangladesh. Two different fabrics were chosen to analyze, determining the potential savings of finishing on the denim fabrics’ performance characteristics. By deducting singeing and heat-set processes, the researchers ran an experimental process by maintaining the same length of fabric. Then, the impacts of finishing process optimization on the mechanical, thermal, and comfort parameters of drape, stiffness, and tear strength were examined. The study’s findings demonstrated that this experiment increased productivity and reduced the finishing unit’s energy consumption without compromising the denim fabrics’ quality. This study significantly impacts environmental sustainability by preserving limited energy resources and manufacturing denim finishing processes. 展开更多
关键词 finishing Process Energy Savings Denim fabrics Potential Savings Process Optimization Cotton-Elastane fabric
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涤纶织物分散荧光黄染色及易去污整理
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作者 杨宏林 郏奎宇 +1 位作者 项伟 陈慧媛 《印染》 北大核心 2024年第1期48-51,56,共5页
为了改善荧光黄染色涤纶织物的易去污性,以色度坐标和亮度因子β为指标,优化染色工艺和易去污整理工艺。结果表明,荧光黄10G对涤纶织物最佳染色工艺条件为:染料质量分数1.0%(omf),染浴pH为5,染色温度130℃,染色时间40 min;最佳易去污整... 为了改善荧光黄染色涤纶织物的易去污性,以色度坐标和亮度因子β为指标,优化染色工艺和易去污整理工艺。结果表明,荧光黄10G对涤纶织物最佳染色工艺条件为:染料质量分数1.0%(omf),染浴pH为5,染色温度130℃,染色时间40 min;最佳易去污整理工艺为:整理剂质量浓度40 g/L,焙烘温度150℃,焙烘时间60 s。整理后的涤纶织物经10次洗涤后易去污性仍达4级,经30次洗涤后其荧光性能仍可满足相关标准要求,且耐皂洗色牢度和耐摩擦色牢度均达到4级以上。 展开更多
关键词 染色 易去污整理 分散荧光染料 涤纶织物
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UV接枝聚硅氧烷-TiO_(2)复合棉织物的制备及性能
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作者 黄守磊 武凤艳 +2 位作者 田喜强 马阳 孙红梅 《印染》 CAS 北大核心 2024年第9期42-45,共4页
通过紫外辐射3-(异丁烯酰氧)丙基三甲氧基硅烷对棉织物进行接枝聚合改性,然后与钛酸四丁酯共水解,形成Si—O—Ti化学键,通过化学键合的形式引入TiO_(2)层。由于Si元素位于棉织物和二氧化钛之间,阻断TiO_(2)光催化降解棉织物。化学键合Ti... 通过紫外辐射3-(异丁烯酰氧)丙基三甲氧基硅烷对棉织物进行接枝聚合改性,然后与钛酸四丁酯共水解,形成Si—O—Ti化学键,通过化学键合的形式引入TiO_(2)层。由于Si元素位于棉织物和二氧化钛之间,阻断TiO_(2)光催化降解棉织物。化学键合TiO_(2)与棉织物的结合强度高,提高了耐久性。TiO_(2)对棉织物的整体结构未造成改变,但棉织物的抗紫外线能力显著提升,禁带宽度变小,光催化自清洁能力增强。 展开更多
关键词 功能整理 二氧化钛 紫外接枝 棉织物 聚硅氧烷 抗紫外 自清洁
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表面活性剂与纳米颗粒协同稳定Pickering有机硅乳液的制备及其应用性能 被引量:1
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作者 范奥运 沈军炎 +2 位作者 杨雷 李剑浩 张志坚 《纺织学报》 EI CAS CSCD 北大核心 2024年第1期136-145,共10页
针对目前有机硅平滑剂乳液往往存在分散稳定性差或高剂量表面活性剂引起的应用性能降低等问题,以聚丙烯酸异辛酯的共聚物胶乳(PEHA)为Pickering颗粒,协同表面活性剂,用于制备“油/水”Pickering有机硅乳液,并将其用于织物后整理。考察了... 针对目前有机硅平滑剂乳液往往存在分散稳定性差或高剂量表面活性剂引起的应用性能降低等问题,以聚丙烯酸异辛酯的共聚物胶乳(PEHA)为Pickering颗粒,协同表面活性剂,用于制备“油/水”Pickering有机硅乳液,并将其用于织物后整理。考察了PEHA粒径、表面亲水改性及PEHA质量分数对有机硅乳液分散稳定性的影响,通过对整理残液化学需氧量(COD)和整理织物表面摩擦因数的研究,考察了表面活性剂与Pickering纳米颗粒协同稳定对有机硅乳液应用性能的影响。结果表明:PEHA颗粒吸附在有机硅液滴的表面,形成机械阻隔,提升有机硅乳液的分散稳定性,180 nm的PEHA颗粒的稳定效率最佳,90 nm时的稳定效率最差;表面亲水改性能显著提高PEHA稳定乳液的效率,在质量分数仅为10%时,即可实现乳液稳定;最佳稳定方案可使表面活性剂质量分数降低60%以上;浸轧整理织物时,相比表面活性剂独自稳定的体系,Pickering体系吸附织物效率更高,整理后残液的COD值降低63%,整理织物表面静、动摩擦因数分别降低至0.51与0.49,即“Pickering/表面活性剂”协同稳定有机硅乳液具有良好的应用性能。 展开更多
关键词 有机硅乳液 Pickering乳液 化学需氧量 后整理剂 摩擦因数 织物整理
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常泰长江大桥主航道桥纵向约束索CFRP筋材及成品索试制试验研究
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作者 夏鹏飞 《桥梁建设》 EI CSCD 北大核心 2024年第5期1-6,共6页
常泰长江大桥主航道桥为主跨1208 m的公铁两用双塔钢桁梁斜拉桥,采用温度自适应塔梁约束体系实现对温度的完全自适应,该体系采用CFRP索作为纵向约束索。CFRP索采用127-∅7 mm扭绞型热挤聚乙烯平行CFRP筋材成品索。为保证CFRP索的质量,首... 常泰长江大桥主航道桥为主跨1208 m的公铁两用双塔钢桁梁斜拉桥,采用温度自适应塔梁约束体系实现对温度的完全自适应,该体系采用CFRP索作为纵向约束索。CFRP索采用127-∅7 mm扭绞型热挤聚乙烯平行CFRP筋材成品索。为保证CFRP索的质量,首先在工业化生产线上进行CFRP筋材试制及静载拉伸试验,然后在CFRP筋材试制基础上,进行CFRP成品索的试制及静载拉伸试验研究。结果表明:CFRP筋材试拉伸的强度为3099~3886 MPa,拉伸弹性模量为181~201 GPa;CFRP成品索加载至大于100%公称破断索力时,索体内的CFRP筋材未出现开裂、损伤、断丝等现象,锚固体(锚具及铸体)未见异常,拉伸弹性模量大于160 GPa,试验结果均满足相关要求。 展开更多
关键词 斜拉桥 温度自适应塔梁约束体系 纵向约束索 CFRP筋材 CFRP成品索 试制 静载拉伸试验
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壳聚糖基膨胀阻燃涤纶/棉混纺织物的制备及其性能
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作者 李平 朱平 刘云 《纺织学报》 EI CAS CSCD 北大核心 2024年第2期162-170,共9页
为得到阻燃且满足实际应用需求的涤纶/棉混纺织物(T/C),选用亚磷酸化壳聚糖(PCS)和γ-哌嗪基丙基甲基二甲氧基硅烷(GP-108)制备阻燃整理剂(PCS/GP),通过一步浸渍法对涤纶/棉混纺织物进行整理,并研究其微观表面形貌、热稳定性能、阻燃性... 为得到阻燃且满足实际应用需求的涤纶/棉混纺织物(T/C),选用亚磷酸化壳聚糖(PCS)和γ-哌嗪基丙基甲基二甲氧基硅烷(GP-108)制备阻燃整理剂(PCS/GP),通过一步浸渍法对涤纶/棉混纺织物进行整理,并研究其微观表面形貌、热稳定性能、阻燃性能、拉伸性能以及白度等。结果表明:PCS/GP成功在涤纶/棉混纺织物表面沉积成膜,包裹住涤纶/棉纤维;T/C-PCS/GP呈现典型的涤纶/棉混纺织物二步热降解过程,在700℃时保留有28.5%的残炭量,说明PCS/GP提高了阻燃涤纶/棉混纺织物在高温区的热稳定性能;T/C-PCS/GP的LOI值提升至26.5%,实现了垂直燃烧测试中的离火自熄,残炭扫描电镜照片表明,PCS/GP的沉积改善了涤纶/棉混纺织物燃烧时存在的“支架”效应;T/C-PCS/GP的热释放速率峰值和火灾蔓延指数较T/C分别降低了20%和40%,表明其火灾危险性大幅度降低;锥形量热测试后的残炭电镜照片表明,T/C-PCS/GP能够保留完整的织物编织结构,残炭表面存在明显的膨胀炭层,与垂直燃烧测试结果相符;热重红外测试结果表明,T/C-PCS/GP分解提前,主要影响棉组分热降解并促进其成炭,而高温区的红外谱图表明,在致密炭层的保护下,T/C-PCS/GP的热降解得到抑制。T/C-PCS/GP与T/C-PCS相比,断裂强力提升17%,其断裂强力与T/C的断裂强力相差不大;同时,GP-108的使用改善了T/C-PCS的黄变问题,提升了T/C-PCS/GP的白度。然而,阻燃样品耐久性较差,需要后续改进。 展开更多
关键词 涤纶/棉混纺织物 阻燃整理 壳聚糖 膨胀体系 硅烷偶联剂
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