With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in th...With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in the field of human reliability analysis(HRA)to evaluate human reliability and assess risk in large complex systems.However,the classical SPAR-H method does not consider the dependencies among performance shaping factors(PSFs),whichmay cause overestimation or underestimation of the risk of the actual situation.To address this issue,this paper proposes a new method to deal with the dependencies among PSFs in SPAR-H based on the Pearson correlation coefficient.First,the dependence between every two PSFs is measured by the Pearson correlation coefficient.Second,the weights of the PSFs are obtained by considering the total dependence degree.Finally,PSFs’multipliers are modified based on the weights of corresponding PSFs,and then used in the calculating of human error probability(HEP).A case study is used to illustrate the procedure and effectiveness of the proposed method.展开更多
With the advent of Industry 4.0, smart construction sites have seen significant development in China. However, accidents involving digitized tower cranes continue to be a persistent issue. Among the contributing facto...With the advent of Industry 4.0, smart construction sites have seen significant development in China. However, accidents involving digitized tower cranes continue to be a persistent issue. Among the contributing factors, human unsafe behavior stands out as a primary cause for these incidents. This study aims to assess the human reliability of tower crane operations on smart construction sites. To proactively enhance safety measures, the research employs text mining techniques (TF-IDF-Truncated SVD-Complement NB) to identify patterns of human errors among tower crane operators. Building upon the SHEL model, the study categorizes behavioral factors affecting human reliability in the man-machine interface, leading to the establishment of the Performance Shaping Factors (PSFs) system. Furthermore, the research constructs an error impact indicator system for the intelligent construction site tower crane operator interface. Using the DEMATEL method, it analyzes the significance of various factors influencing human errors in tower crane operations. Additionally, the ISM-MICMAC method is applied to unveil the hierarchical relationships and driving-dependent connections among these influencing factors. The findings indicate that personal state, operating procedures, and physical environment directly impact human errors, while personal capability, technological environment, and one fundamental organizational management factor contribute indirectly. .展开更多
In view of the practical importance of the heat transfer devices in various thermal engineering fields including chemical and nuclear engineering,this study aims at developing an effective method of heat transfer enha...In view of the practical importance of the heat transfer devices in various thermal engineering fields including chemical and nuclear engineering,this study aims at developing an effective method of heat transfer enhancement by using selfrotating twisted tapes(SRTTs)and Al_(2)O_(3) nanoparticles.The effect of the selfrotating twisted tapes and Al2O3 nanoparticles on the thermal performance was comprehensively investigated in a circular pipe.The experimental results indicated the heat transfer rate was effectively improved by SRTTs in comparison of plain tube.In addition,the heat transfer multiplier with SRTTs decreased from 1.38 to 1.08 with the Reynolds number increasing from 19,322 to 64,407,while the friction factor multiplier decreased from 1.61 to 1.32.Besides,the results indicated that the employment of Al_(2)O_(3) nanoparticles and SRTTs demonstrated superior thermal performance to the single SRTTs.As Reynolds number increases from 19,322 to 64,407,the heat transfer multiplier decreased from 2.08 to 1.18 in the mass concentration of 3.0%and from 1.38 to 1.08 in mass concentration of 0.0%.Finally,the new heat transfer and friction factor correlations considering the combined effect of Al2O3 nanoparticle and SRTTs were developed within 10%deviation of experimental values.展开更多
The paper presents an experimental investigation on enhanced heat transfer and pressure loss characteristics by using single, double, triple, and quadruple twisted-tape inserts in a round tube having a uniform heat-fl...The paper presents an experimental investigation on enhanced heat transfer and pressure loss characteristics by using single, double, triple, and quadruple twisted-tape inserts in a round tube having a uniform heat-fluxed wall. The investigation has been conducted in the heat exchanger tube inserted with various twisted-tape numbers for co- and counter-twist arrangements for the turbulent air flow, Reynolds number (Re) from 5300 to 24000. The typical single twisted-tape inserts at two twist ratios, y/w = 4 and 5, are used as the base case, while the other multiple twisted-tape inserts are aty/w = 4 only. The experimental results of heat transfer and pressure drop in terms of Nusselt number (Nu) and friction factor 00, respectively, reveal that Nu increases with the increment of Re and of twisted-tape number. The values of Nu for the inserted tube are in a range of 1.15-2.12 times that for the plain tube while f is 1.9-4.1 times. The thermal enhancement factor of the inserted tube under similar pumping power is evaluated and found to be above unity except for the single and the double co-twisted tapes. The quadruple counter-twisted tape insert provides the maximum thermal performance.展开更多
Since data services are penetrating into our daily life rapidly, the mobile network becomes more complicated, and the amount of data transmission is more and more increasing. In this case, the traditional statistical ...Since data services are penetrating into our daily life rapidly, the mobile network becomes more complicated, and the amount of data transmission is more and more increasing. In this case, the traditional statistical methods for anomalous cell detection cannot adapt to the evolution of networks, and data mining becomes the mainstream. In this paper, we propose a novel kernel density-based local outlier factor(KLOF) to assign a degree of being an outlier to each object. Firstly, the notion of KLOF is introduced, which captures exactly the relative degree of isolation. Then, by analyzing its properties, including the tightness of upper and lower bounds, sensitivity of density perturbation, we find that KLOF is much greater than 1 for outliers. Lastly, KLOFis applied on a real-world dataset to detect anomalous cells with abnormal key performance indicators(KPIs) to verify its reliability. The experiment shows that KLOF can find outliers efficiently. It can be a guideline for the operators to perform faster and more efficient trouble shooting.展开更多
A novel approach for engineering application to human error probability quantification is presented based on an overview of the existing human reliability analysis methods. The set of performance shaping factors is cl...A novel approach for engineering application to human error probability quantification is presented based on an overview of the existing human reliability analysis methods. The set of performance shaping factors is classified as two subsets of dominant factors and adjusting factors respectively. Firstly, the dominant factors are used to determine the probabilities of three behavior modes. The basic probability and its interval of human error for each behavior mode are given. Secondly, the basic probability and its interval are modified by the adjusting factors, and the total probability of human error is calculated by a total probability formula. Finally, a simple example is introduced, and the consistency and validity of the presented approach are illustrated.展开更多
The performances of a hybrid energy system for decentralized heating are investigated.The proposed energy system consists of a solar collector,an air-source heat pump,a gas-fired boiler and a hot water tank.A mathemat...The performances of a hybrid energy system for decentralized heating are investigated.The proposed energy system consists of a solar collector,an air-source heat pump,a gas-fired boiler and a hot water tank.A mathematical model is developed to predict the operating characteristics of the system.The simulation results are compared with experimental data.Such a comparison indicates that the model accuracy is sufficient.The influence of the flat plate solar collector area on the economic and energy efficiency of such system is also evaluated through numerical simulations.Finally,this system is optimized using the method of orthogonal design.The results clearly demonstrate that the solar-heat pump-gas combined system is more convenient and efficient than the simple gas system and the heat pump-gas combined system,whereas it is less convenient but more efficient than the solarassisted gas system.展开更多
The paper described experimental investigation of heat transfer and single-phase pressure drop through tubes with different rotor-assembled strands inserted in the Reynolds number range of 800-9000 with lubricant as w...The paper described experimental investigation of heat transfer and single-phase pressure drop through tubes with different rotor-assembled strands inserted in the Reynolds number range of 800-9000 with lubricant as working fluid. In the experiment, fixed mounts were employed to eliminate the entrance effect. The experimental results showed that the employment of fixed mounts led to a visible bias of friction factor in the laminar regime while it could not affect the Nusselt numbers significantly. Experiment for the tube inserted with rotors-assembled strand showed remarkable improvement for heat transfer with the Nusselt number increased by 200%-225% in the laminar regime and 125%-160% in the transitional regime. Meanwhile, the friction factor increased inevitably by 200%-300% within the same range of Reynolds number. The comparison of different rotor-assembled strands in-serted tubes and plain tube showed that the heat transfer benefited from the increase of the diameter of rotor-assembled strand with the same lead and the decrease of the lead of rotor-assembled strand, so does the friction factor. Based on experimental data and thorough multivariant linear normal regression method, the correlations of average Nusselt number and friction factor are established.展开更多
Quantitative security metrics are desirable for measuring the performance of information security controls. Security metrics help to make functional and business decisions for improving the performance and cost of the...Quantitative security metrics are desirable for measuring the performance of information security controls. Security metrics help to make functional and business decisions for improving the performance and cost of the security controls. However, defining enterprise-level security metrics has already been listed as one of the hard problems in the Info Sec Research Council's hard problems list. Almost all the efforts in defining absolute security metrics for the enterprise security have not been proved fruitful. At the same time, with the maturity of the security industry, there has been a continuous emphasis from the regulatory bodies on establishing measurable security metrics. This paper addresses this need and proposes a relative security metric model that derives three quantitative security metrics named Attack Resiliency Measure(ARM), Performance Improvement Factor(PIF), and Cost/Benefit Measure(CBM) for measuring the performance of the security controls. For the effectiveness evaluation of the proposed security metrics, we took the secure virtual machine(VM) migration protocol as the target of assessment. The virtual-ization technologies are rapidly changing the landscape of the computing world. Devising security metrics for virtualized environment is even more challenging. As secure virtual machine migration is an evolving area and no standard protocol is available specifically for secure VM migration. This paper took the secure virtual machine migration protocol as the target of assessment and applied the proposed relative security metric model for measuring the Attack Resiliency Measure, Performance Improvement Factor, and Cost/Benefit Measure of the secure VM migration protocol.展开更多
The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems(LSAS). The former researches have confirmed...The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems(LSAS). The former researches have confirmed that the cells groupings time-shift pilots scheme is effective to reduce inter-cell interference, especially pilot contamination, which results from the pilot reuse in adjacent cells. However, they have not specified reasonable cells groupings factor, which plays a critical role in the general performance of the LSAS. Therefore, this problem is researched in details. The time for reverse-link data transmission will be compressed, when the groupings factor surpasses a certain range. Thus it is not always beneficial to increase the cells groupings factor without limitation. Furthermore,a reasonable cells groupings factor is deduced from the perspective of optimization to enhance the system performance. Simulations verify the proposed cell grouping factor.展开更多
The application of unbonded post-tensioning (PT) in structural walls has led to the development of advanced self-centring (rocking) shear wall systems that has significant advantages, including accelerated constructio...The application of unbonded post-tensioning (PT) in structural walls has led to the development of advanced self-centring (rocking) shear wall systems that has significant advantages, including accelerated construction due to the incorporation of prefabricated elements and segmental construction for different materials (e.g., concrete, masonry, and timber), reduced residual drifts, and little damage upon extreme seismic and wind loads. Concrete, masonry, and timber are often used for the construction of unbonded PT structural wall systems. Despite extensive research since the 1980s, there are no well-established design guidelines available on the shear wall configuration with the required energy dissipation system, joint’s locations and acceptance criteria for shear sliding, confinement, seismic performance factors, PT loss, PT force range and residual drifts of shear walls subjected to lateral loads. In this research a comprehensive state-of-the-art literature review was performed on self-centring shear wall system. An extensive study was carried out to collect a database of 100 concrete, masonry, and self-centring shear wall tests from the literature. The established database was then used to review shear walls’ configurations, material, and components to benchmark requirements applicable for design purposes. The behaviour of concrete, masonry and timber shear walls were compared and critically analysed. The general behaviour, force-displacement performance of the walls, ductility, and seismic response factors, were critically reviewed and analysed for different self-centring wall systems to understand the effect of different parameters including configurations of the walls, material used for construction of the wall (concrete, masonry, timber) and axial stress ratio. The outcome of this research can be used to better understand the behaviour of self-centring wall system in order to develop design guidelines for such walls.展开更多
Sodium hypochlorite(NaClO)is a commonly applied cleaning agent for ultrafiltration membranes in water and wastewater treatment.Long-term exposure to NaClO might change the properties and performance of polymeric membr...Sodium hypochlorite(NaClO)is a commonly applied cleaning agent for ultrafiltration membranes in water and wastewater treatment.Long-term exposure to NaClO might change the properties and performance of polymeric membranes,and ultimately shorten membrane lifespan.Active species in NaClO solution vary with solution pH,and the aging effects can change depending on the membrane material.In this study,the aging of polyvinylidene fluoride(PVDF)and polyethersulfone(PES)membranes by NaClO at pH 3–11 was investigated by examining variations in chemical composition,surface charge,surface morphology,mechanical strength,permeability,and retention ability.Polyvinyl pyrrolidone(PVP),which was blended in both membranes,was oxidized and dislodged due to NaClO aging at all investigated pH values,but the oxidation products and dislodgement ratio of PVP varied with solution pH.For the PVDF membrane,NaClO aging at pH 3–11 caused a moderate increase in permeability and decreased retention due to the oxidation and release of PVP.The tensile strength decreased only at pH 11 because of the defluorination of PVDF molecules.For the PES membrane,NaClO aging at all investigated pH resulted in chain scission of PES molecules,which was favored at pH 7 and 9,potentially due to the formation of free radicals.Therefore,a decrease in tensile strength and retention ability,as well as an increase in permeability,occurred in the PES membrane for NaClO aging at pH 3–11.Overall,the results can provide a basis for selecting chemical cleaning conditions for PVDF and PES membranes.展开更多
基金Shanghai Rising-Star Program(Grant No.21QA1403400)Shanghai Sailing Program(Grant No.20YF1414800)Shanghai Key Laboratory of Power Station Automation Technology(Grant No.13DZ2273800).
文摘With the improvement of equipment reliability,human factors have become the most uncertain part in the system.The standardized Plant Analysis of Risk-Human Reliability Analysis(SPAR-H)method is a reliable method in the field of human reliability analysis(HRA)to evaluate human reliability and assess risk in large complex systems.However,the classical SPAR-H method does not consider the dependencies among performance shaping factors(PSFs),whichmay cause overestimation or underestimation of the risk of the actual situation.To address this issue,this paper proposes a new method to deal with the dependencies among PSFs in SPAR-H based on the Pearson correlation coefficient.First,the dependence between every two PSFs is measured by the Pearson correlation coefficient.Second,the weights of the PSFs are obtained by considering the total dependence degree.Finally,PSFs’multipliers are modified based on the weights of corresponding PSFs,and then used in the calculating of human error probability(HEP).A case study is used to illustrate the procedure and effectiveness of the proposed method.
文摘With the advent of Industry 4.0, smart construction sites have seen significant development in China. However, accidents involving digitized tower cranes continue to be a persistent issue. Among the contributing factors, human unsafe behavior stands out as a primary cause for these incidents. This study aims to assess the human reliability of tower crane operations on smart construction sites. To proactively enhance safety measures, the research employs text mining techniques (TF-IDF-Truncated SVD-Complement NB) to identify patterns of human errors among tower crane operators. Building upon the SHEL model, the study categorizes behavioral factors affecting human reliability in the man-machine interface, leading to the establishment of the Performance Shaping Factors (PSFs) system. Furthermore, the research constructs an error impact indicator system for the intelligent construction site tower crane operator interface. Using the DEMATEL method, it analyzes the significance of various factors influencing human errors in tower crane operations. Additionally, the ISM-MICMAC method is applied to unveil the hierarchical relationships and driving-dependent connections among these influencing factors. The findings indicate that personal state, operating procedures, and physical environment directly impact human errors, while personal capability, technological environment, and one fundamental organizational management factor contribute indirectly. .
文摘In view of the practical importance of the heat transfer devices in various thermal engineering fields including chemical and nuclear engineering,this study aims at developing an effective method of heat transfer enhancement by using selfrotating twisted tapes(SRTTs)and Al_(2)O_(3) nanoparticles.The effect of the selfrotating twisted tapes and Al2O3 nanoparticles on the thermal performance was comprehensively investigated in a circular pipe.The experimental results indicated the heat transfer rate was effectively improved by SRTTs in comparison of plain tube.In addition,the heat transfer multiplier with SRTTs decreased from 1.38 to 1.08 with the Reynolds number increasing from 19,322 to 64,407,while the friction factor multiplier decreased from 1.61 to 1.32.Besides,the results indicated that the employment of Al_(2)O_(3) nanoparticles and SRTTs demonstrated superior thermal performance to the single SRTTs.As Reynolds number increases from 19,322 to 64,407,the heat transfer multiplier decreased from 2.08 to 1.18 in the mass concentration of 3.0%and from 1.38 to 1.08 in mass concentration of 0.0%.Finally,the new heat transfer and friction factor correlations considering the combined effect of Al2O3 nanoparticle and SRTTs were developed within 10%deviation of experimental values.
基金the Thailand Research Fund(TRF)(Grant No.Ph D/0143/2552)
文摘The paper presents an experimental investigation on enhanced heat transfer and pressure loss characteristics by using single, double, triple, and quadruple twisted-tape inserts in a round tube having a uniform heat-fluxed wall. The investigation has been conducted in the heat exchanger tube inserted with various twisted-tape numbers for co- and counter-twist arrangements for the turbulent air flow, Reynolds number (Re) from 5300 to 24000. The typical single twisted-tape inserts at two twist ratios, y/w = 4 and 5, are used as the base case, while the other multiple twisted-tape inserts are aty/w = 4 only. The experimental results of heat transfer and pressure drop in terms of Nusselt number (Nu) and friction factor 00, respectively, reveal that Nu increases with the increment of Re and of twisted-tape number. The values of Nu for the inserted tube are in a range of 1.15-2.12 times that for the plain tube while f is 1.9-4.1 times. The thermal enhancement factor of the inserted tube under similar pumping power is evaluated and found to be above unity except for the single and the double co-twisted tapes. The quadruple counter-twisted tape insert provides the maximum thermal performance.
基金supported by the National Basic Research Program of China (973 Program: 2013CB329004)
文摘Since data services are penetrating into our daily life rapidly, the mobile network becomes more complicated, and the amount of data transmission is more and more increasing. In this case, the traditional statistical methods for anomalous cell detection cannot adapt to the evolution of networks, and data mining becomes the mainstream. In this paper, we propose a novel kernel density-based local outlier factor(KLOF) to assign a degree of being an outlier to each object. Firstly, the notion of KLOF is introduced, which captures exactly the relative degree of isolation. Then, by analyzing its properties, including the tightness of upper and lower bounds, sensitivity of density perturbation, we find that KLOF is much greater than 1 for outliers. Lastly, KLOFis applied on a real-world dataset to detect anomalous cells with abnormal key performance indicators(KPIs) to verify its reliability. The experiment shows that KLOF can find outliers efficiently. It can be a guideline for the operators to perform faster and more efficient trouble shooting.
文摘A novel approach for engineering application to human error probability quantification is presented based on an overview of the existing human reliability analysis methods. The set of performance shaping factors is classified as two subsets of dominant factors and adjusting factors respectively. Firstly, the dominant factors are used to determine the probabilities of three behavior modes. The basic probability and its interval of human error for each behavior mode are given. Secondly, the basic probability and its interval are modified by the adjusting factors, and the total probability of human error is calculated by a total probability formula. Finally, a simple example is introduced, and the consistency and validity of the presented approach are illustrated.
文摘The performances of a hybrid energy system for decentralized heating are investigated.The proposed energy system consists of a solar collector,an air-source heat pump,a gas-fired boiler and a hot water tank.A mathematical model is developed to predict the operating characteristics of the system.The simulation results are compared with experimental data.Such a comparison indicates that the model accuracy is sufficient.The influence of the flat plate solar collector area on the economic and energy efficiency of such system is also evaluated through numerical simulations.Finally,this system is optimized using the method of orthogonal design.The results clearly demonstrate that the solar-heat pump-gas combined system is more convenient and efficient than the simple gas system and the heat pump-gas combined system,whereas it is less convenient but more efficient than the solarassisted gas system.
基金Supported by the National Natural Science Foundation of Beijing (3102023) and the National Science and Technology Support Plan Project (2011BAA04B02).
文摘The paper described experimental investigation of heat transfer and single-phase pressure drop through tubes with different rotor-assembled strands inserted in the Reynolds number range of 800-9000 with lubricant as working fluid. In the experiment, fixed mounts were employed to eliminate the entrance effect. The experimental results showed that the employment of fixed mounts led to a visible bias of friction factor in the laminar regime while it could not affect the Nusselt numbers significantly. Experiment for the tube inserted with rotors-assembled strand showed remarkable improvement for heat transfer with the Nusselt number increased by 200%-225% in the laminar regime and 125%-160% in the transitional regime. Meanwhile, the friction factor increased inevitably by 200%-300% within the same range of Reynolds number. The comparison of different rotor-assembled strands in-serted tubes and plain tube showed that the heat transfer benefited from the increase of the diameter of rotor-assembled strand with the same lead and the decrease of the lead of rotor-assembled strand, so does the friction factor. Based on experimental data and thorough multivariant linear normal regression method, the correlations of average Nusselt number and friction factor are established.
文摘Quantitative security metrics are desirable for measuring the performance of information security controls. Security metrics help to make functional and business decisions for improving the performance and cost of the security controls. However, defining enterprise-level security metrics has already been listed as one of the hard problems in the Info Sec Research Council's hard problems list. Almost all the efforts in defining absolute security metrics for the enterprise security have not been proved fruitful. At the same time, with the maturity of the security industry, there has been a continuous emphasis from the regulatory bodies on establishing measurable security metrics. This paper addresses this need and proposes a relative security metric model that derives three quantitative security metrics named Attack Resiliency Measure(ARM), Performance Improvement Factor(PIF), and Cost/Benefit Measure(CBM) for measuring the performance of the security controls. For the effectiveness evaluation of the proposed security metrics, we took the secure virtual machine(VM) migration protocol as the target of assessment. The virtual-ization technologies are rapidly changing the landscape of the computing world. Devising security metrics for virtualized environment is even more challenging. As secure virtual machine migration is an evolving area and no standard protocol is available specifically for secure VM migration. This paper took the secure virtual machine migration protocol as the target of assessment and applied the proposed relative security metric model for measuring the Attack Resiliency Measure, Performance Improvement Factor, and Cost/Benefit Measure of the secure VM migration protocol.
基金supported by the National Natural Science Foundation of China(6110602261574013)
文摘The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems(LSAS). The former researches have confirmed that the cells groupings time-shift pilots scheme is effective to reduce inter-cell interference, especially pilot contamination, which results from the pilot reuse in adjacent cells. However, they have not specified reasonable cells groupings factor, which plays a critical role in the general performance of the LSAS. Therefore, this problem is researched in details. The time for reverse-link data transmission will be compressed, when the groupings factor surpasses a certain range. Thus it is not always beneficial to increase the cells groupings factor without limitation. Furthermore,a reasonable cells groupings factor is deduced from the perspective of optimization to enhance the system performance. Simulations verify the proposed cell grouping factor.
基金Open Access funding enabled and organized by CAUL and its Member Institutions.
文摘The application of unbonded post-tensioning (PT) in structural walls has led to the development of advanced self-centring (rocking) shear wall systems that has significant advantages, including accelerated construction due to the incorporation of prefabricated elements and segmental construction for different materials (e.g., concrete, masonry, and timber), reduced residual drifts, and little damage upon extreme seismic and wind loads. Concrete, masonry, and timber are often used for the construction of unbonded PT structural wall systems. Despite extensive research since the 1980s, there are no well-established design guidelines available on the shear wall configuration with the required energy dissipation system, joint’s locations and acceptance criteria for shear sliding, confinement, seismic performance factors, PT loss, PT force range and residual drifts of shear walls subjected to lateral loads. In this research a comprehensive state-of-the-art literature review was performed on self-centring shear wall system. An extensive study was carried out to collect a database of 100 concrete, masonry, and self-centring shear wall tests from the literature. The established database was then used to review shear walls’ configurations, material, and components to benchmark requirements applicable for design purposes. The behaviour of concrete, masonry and timber shear walls were compared and critically analysed. The general behaviour, force-displacement performance of the walls, ductility, and seismic response factors, were critically reviewed and analysed for different self-centring wall systems to understand the effect of different parameters including configurations of the walls, material used for construction of the wall (concrete, masonry, timber) and axial stress ratio. The outcome of this research can be used to better understand the behaviour of self-centring wall system in order to develop design guidelines for such walls.
基金supported by the National Natural Science Foundation of China(No.51608427)the Natural Science Foundation of Shaanxi Province(No.2020JQ-672)+1 种基金the Key Research and Development Program of Shaanxi province(No.2019ZDLSF06-01)the Youth Innovation Team of Shaanxi Universities Funded by Education Department of Shaanxi Province。
文摘Sodium hypochlorite(NaClO)is a commonly applied cleaning agent for ultrafiltration membranes in water and wastewater treatment.Long-term exposure to NaClO might change the properties and performance of polymeric membranes,and ultimately shorten membrane lifespan.Active species in NaClO solution vary with solution pH,and the aging effects can change depending on the membrane material.In this study,the aging of polyvinylidene fluoride(PVDF)and polyethersulfone(PES)membranes by NaClO at pH 3–11 was investigated by examining variations in chemical composition,surface charge,surface morphology,mechanical strength,permeability,and retention ability.Polyvinyl pyrrolidone(PVP),which was blended in both membranes,was oxidized and dislodged due to NaClO aging at all investigated pH values,but the oxidation products and dislodgement ratio of PVP varied with solution pH.For the PVDF membrane,NaClO aging at pH 3–11 caused a moderate increase in permeability and decreased retention due to the oxidation and release of PVP.The tensile strength decreased only at pH 11 because of the defluorination of PVDF molecules.For the PES membrane,NaClO aging at all investigated pH resulted in chain scission of PES molecules,which was favored at pH 7 and 9,potentially due to the formation of free radicals.Therefore,a decrease in tensile strength and retention ability,as well as an increase in permeability,occurred in the PES membrane for NaClO aging at pH 3–11.Overall,the results can provide a basis for selecting chemical cleaning conditions for PVDF and PES membranes.