Atmospheric particulate matter(PM2.5) seriously influences air quality. It is considered one of the main environmental triggers for lung and heart diseases. Air pollutants can be adsorbed by forest. In this study we i...Atmospheric particulate matter(PM2.5) seriously influences air quality. It is considered one of the main environmental triggers for lung and heart diseases. Air pollutants can be adsorbed by forest. In this study we investigated the effect of forest cover on urban PM2.5 concentrations in 12 cities in Heilongjiang Province,China. The forest cover in each city was constant throughout the study period. The average daily concentration of PM2.5 in 12 cities was below 75 lg/m^3 during the non-heating period but exceeded this level during heating period. Furthermore, there were more moderate pollution days in six cities. This indicated that forests had the ability to reduce the concentration of PM2.5 but the main cause of air pollution was excessive human interference and artificial heating in winter. We classified the 12 cities according to the average PM2.5 concentrations. The relationship between PM2.5 concentrations and forest cover was obtained by integrating forest cover, land area,heated areas and number of vehicles in cities. Finally,considering the complexity of PM2.5 formation and based on the theory of random forestry, we selected six cities and analyzed their meteorological and air pollutant data. The main factors affecting PM2.5 concentrations were PM10,NO_2, CO and SO_2 in air pollutants while meteorological factors were secondary.展开更多
In this research, the main purpose is to estimate the variation of PM2.5 mass concentration and study the influence of meteorological characteristics on major components of PM2.5 concentrations in urban Tokyo, Japan. ...In this research, the main purpose is to estimate the variation of PM2.5 mass concentration and study the influence of meteorological characteristics on major components of PM2.5 concentrations in urban Tokyo, Japan. The results shown that the annual mean mass concentration of PM2.5 in urban Tokyo was higher than JEQS （Japanese Environmental Quality Standard） of the MOEJ （Ministry of the Environment Japan） （15 μg/m^3）, and 41.1% of the daily PM2.5 mass concentration exceeded the annual JEQS concentration during observation period. The major components of PM2.5 including SO4^2-, NO3^-, NH4^＋, OC and EC were tightly related to the meteorological conditions, the correlations results shown that the wind speed and relative humidity had significant correlations with major components of PM2.5 than the other meteorological factors. Higher relative humidity, windless and less rainfall conditions were favorable for elimination of PM2.5 concentration. Higher temperature was beneficial to the formation of SO42＂, but higher temperature and stronger sunshine duration were not conducive to the formation of NO3^-.展开更多
Based on the real-time data released by 17 atmospheric automatic stations in Chongqing,the pollution characteristics and variation trends of PM 2.5 and PM 10 and their correlations with meteorological factors from Jan...Based on the real-time data released by 17 atmospheric automatic stations in Chongqing,the pollution characteristics and variation trends of PM 2.5 and PM 10 and their correlations with meteorological factors from January 2014 to December 2018 were analyzed.The results show that the annual average mass concentration of PM 2.5 in Chongqing reduced from 65μg/m 3 in 2014 to 40μg/m 3 in 2018,and the annual average mass concentration of PM 10 decreased from 98μg/m 3 in 2014 to 64μg/m 3 in 2018.However,the annual average mass concentration of PM 2.5 in Chongqing from 2014 to 2018 and the annual average mass concentration of PM 10 from 2014 to 2016 exceeded the national level II standard,and the maximum exceeding standard rate was up to 0.86 and 0.40 times respectively.The monthly average mass concentration of PM 2.5 and PM 10 changed obviously,and the overall distribution was"U"-shaped.The ratio of PM 2.5 to PM 10 mass concentration ranged from 47.4%to 80.7%,with an average of 62.4%.The Pearson correlation coefficient between the mass concentration of PM 2.5 and PM 10 varied from 0.961 to 0.989,and there was a significant correlation at the confidence level of 0.01(bilateral).The mass concentration of PM 2.5 and PM 10 was extremely significantly correlated with average temperature,precipitation,and average air pressure,while there was no significant correlation between the mass concentrations of PM 2.5 and PM 10 and average relative humidity.The mass concentration of PM 2.5 and PM 10 was significantly correlated with sunshine duration.展开更多
Since 1991, air pollution has gained special attention in Taiwan after a petrochemical complex was constructed in Mailiao Township, Yunlin County. We explored the association between the magnitude of PM2.5 and meteoro...Since 1991, air pollution has gained special attention in Taiwan after a petrochemical complex was constructed in Mailiao Township, Yunlin County. We explored the association between the magnitude of PM2.5 and meteorological factors during 2012-2016. Our findings revealed that 1) mean PM2.5 levels gradually decreased from 30.70 μg/m3 in 2013 to 25.36 μg/m3 in 2016;2) wind speed is the main determinant of air quality—air quality significantly improved when it was faster than 4 m/sec;and 3) wind direction is another determinant of air quality—when the wind direction was southerly, air quality improved. Elevated PM2.5 levels were defined as those hourly levels higher than the third quartile (36 μg/m3). The significantly negative predictive factors for elevated PM2.5 levels were the summer or autumn seasons, rainfall, increased wind speed, and wind direction from 150° to 230° from the north. The significantly positive predictive factors for elevated PM2.5 levels were working hours from 6 a.m. to 2 p.m., a temperature between 11°C and 25°C, relative humidity between 40% and 68%, and wind direction (e.g., northerly wind, northeasterly wind, and easterly wind). The predictive formula is attached in the Appendix. Therefore, people should protect themselves on these high-risk days.展开更多
Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ...Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H_(2)O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.展开更多
The pollution of particulate matter less than 2.5μm （PM2.5） is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that ...The pollution of particulate matter less than 2.5μm （PM2.5） is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that of the U,S, national ambient air quality standards proposed by U.S. EPA. The major contributors to mass of PM2.5 were organics, crustal elements and sulfate. The chemical composition of PM2.5 varied largely with season, but was similar at different monitor stations in the same season. The fine particles （PM2.5） cause atmospheric visibility deterioration through light extinction, The mass concentrations of PM2.5 were anti-correlated to the visibility, the best fits between atmospheric visibility and the mass concentrations of PM2.5 were somehow different： power in spring, exponential in summer, logarithmic in autumn, power or exponential in winter. As in each season the meteorological parameters such as air temperature and relative humidity change from day to day, probably the reason of above correlations between PM2.5 and visibility obtained at different seasons come from the differences in chemical compositions of PM2.5.展开更多
The dosage of environmental radon progeny is typically estimated according to the environmental radon exposure and the recommended radon-progeny equilibrium factor, F. To investigate the relationship between PM2.5 and...The dosage of environmental radon progeny is typically estimated according to the environmental radon exposure and the recommended radon-progeny equilibrium factor, F. To investigate the relationship between PM2.5 and the radon-progeny equilibrium factor, cigarettes are used to simulate the haze–fog in a multi-functional radon chamber to achieve a stable radon concentration environment. A radon detector and a portable laser aerosol spectrometer are used to obtain the values for C_(mean) PM2.5,C_(Rn), and C_p. The results show that the mean values of F conform with the typical value recommended by the United Nations Scientific Committee on the Effects of Atomic Radiation and are within the reasonable range of0.1–0.9. In this study, a positive correlation is observed between the F values and PM2.5 concentrations.展开更多
基金supported by the Natural Science Foundation of Heilongjiang Province,China(Grant No.G2016001)
文摘Atmospheric particulate matter(PM2.5) seriously influences air quality. It is considered one of the main environmental triggers for lung and heart diseases. Air pollutants can be adsorbed by forest. In this study we investigated the effect of forest cover on urban PM2.5 concentrations in 12 cities in Heilongjiang Province,China. The forest cover in each city was constant throughout the study period. The average daily concentration of PM2.5 in 12 cities was below 75 lg/m^3 during the non-heating period but exceeded this level during heating period. Furthermore, there were more moderate pollution days in six cities. This indicated that forests had the ability to reduce the concentration of PM2.5 but the main cause of air pollution was excessive human interference and artificial heating in winter. We classified the 12 cities according to the average PM2.5 concentrations. The relationship between PM2.5 concentrations and forest cover was obtained by integrating forest cover, land area,heated areas and number of vehicles in cities. Finally,considering the complexity of PM2.5 formation and based on the theory of random forestry, we selected six cities and analyzed their meteorological and air pollutant data. The main factors affecting PM2.5 concentrations were PM10,NO_2, CO and SO_2 in air pollutants while meteorological factors were secondary.
文摘In this research, the main purpose is to estimate the variation of PM2.5 mass concentration and study the influence of meteorological characteristics on major components of PM2.5 concentrations in urban Tokyo, Japan. The results shown that the annual mean mass concentration of PM2.5 in urban Tokyo was higher than JEQS （Japanese Environmental Quality Standard） of the MOEJ （Ministry of the Environment Japan） （15 μg/m^3）, and 41.1% of the daily PM2.5 mass concentration exceeded the annual JEQS concentration during observation period. The major components of PM2.5 including SO4^2-, NO3^-, NH4^＋, OC and EC were tightly related to the meteorological conditions, the correlations results shown that the wind speed and relative humidity had significant correlations with major components of PM2.5 than the other meteorological factors. Higher relative humidity, windless and less rainfall conditions were favorable for elimination of PM2.5 concentration. Higher temperature was beneficial to the formation of SO42＂, but higher temperature and stronger sunshine duration were not conducive to the formation of NO3^-.
文摘Based on the real-time data released by 17 atmospheric automatic stations in Chongqing,the pollution characteristics and variation trends of PM 2.5 and PM 10 and their correlations with meteorological factors from January 2014 to December 2018 were analyzed.The results show that the annual average mass concentration of PM 2.5 in Chongqing reduced from 65μg/m 3 in 2014 to 40μg/m 3 in 2018,and the annual average mass concentration of PM 10 decreased from 98μg/m 3 in 2014 to 64μg/m 3 in 2018.However,the annual average mass concentration of PM 2.5 in Chongqing from 2014 to 2018 and the annual average mass concentration of PM 10 from 2014 to 2016 exceeded the national level II standard,and the maximum exceeding standard rate was up to 0.86 and 0.40 times respectively.The monthly average mass concentration of PM 2.5 and PM 10 changed obviously,and the overall distribution was"U"-shaped.The ratio of PM 2.5 to PM 10 mass concentration ranged from 47.4%to 80.7%,with an average of 62.4%.The Pearson correlation coefficient between the mass concentration of PM 2.5 and PM 10 varied from 0.961 to 0.989,and there was a significant correlation at the confidence level of 0.01(bilateral).The mass concentration of PM 2.5 and PM 10 was extremely significantly correlated with average temperature,precipitation,and average air pressure,while there was no significant correlation between the mass concentrations of PM 2.5 and PM 10 and average relative humidity.The mass concentration of PM 2.5 and PM 10 was significantly correlated with sunshine duration.
文摘Since 1991, air pollution has gained special attention in Taiwan after a petrochemical complex was constructed in Mailiao Township, Yunlin County. We explored the association between the magnitude of PM2.5 and meteorological factors during 2012-2016. Our findings revealed that 1) mean PM2.5 levels gradually decreased from 30.70 μg/m3 in 2013 to 25.36 μg/m3 in 2016;2) wind speed is the main determinant of air quality—air quality significantly improved when it was faster than 4 m/sec;and 3) wind direction is another determinant of air quality—when the wind direction was southerly, air quality improved. Elevated PM2.5 levels were defined as those hourly levels higher than the third quartile (36 μg/m3). The significantly negative predictive factors for elevated PM2.5 levels were the summer or autumn seasons, rainfall, increased wind speed, and wind direction from 150° to 230° from the north. The significantly positive predictive factors for elevated PM2.5 levels were working hours from 6 a.m. to 2 p.m., a temperature between 11°C and 25°C, relative humidity between 40% and 68%, and wind direction (e.g., northerly wind, northeasterly wind, and easterly wind). The predictive formula is attached in the Appendix. Therefore, people should protect themselves on these high-risk days.
文摘Background,aim,and scope Environmentally persistent free radicals(EPFRs)have received significant attention due to their longer lifetime and stable existence in various environments.The strong environmental migration ability of particulate matter allows EPFRs to migrate over long-distance transport,thereby impacting the quality of the local atmospheric environment.Additionally,EPFRs can also adhere to atmospheric particles and interact with typical gaseous pollutants to affect atmospheric chemical reactions.EPFRs can produce some reactive organic species,promoting oxidative stress in the human body,damaging biological macromolecules and ultimately affecting the organism health.EPFRs are considered as a novel type of pollutant that affects human health.Despite their significance,there are few literatures available on the characteristics and fate behaviors of EPFRs up to date.Therefore,supplemental reviews are crucial for providing comprehensive understanding of EPFRs.Materials and methods This review summarizes the characteristics of EPFRs in particulate matter,outlines the generation mechanism and influencing factors of EPFRs,and the impacts of EPFRs on environmental quality and organism health.Results The content of EPFRs in particulate matter ranges from 1017 to 1020 spins∙g−1.Due to the strong mobility of atmospheric particulate matter,the long-term exposure to high levels of EPFRs may aggravate the impact of particulate matter on human health.The interaction between EPFRs and typical gaseous pollutants can alter their fate and influence atmospheric chemical reactions.EPFRs are mainly produced by transition metal elements and substituted aromatic hydrocarbons through electron transfer.Additionally,the chemical bond rupture of organic substances through heat treatment or ultraviolet radiation can also produce EPFRs,and heterogeneous reactions are capable producing them as well.The production of EPFRs is not only influenced by transition metal elements and precursors,but also by various environmental factors such as oxygen,temperature,light radiation,and relative humidity.Discussion EPFRs in atmospheric particulates matters are usually rich in fine particulates with obvious seasonal and regional variations.They can easily enter the human respiratory tract and lungs with inhalable particulates,thereby increasing the risk of exposure.Additionally,EPFRs in atmospheric particulates can interact with some typical gaseous pollutants,impacting the life and fate of EPFRs in the atmosphere,and alter atmospheric chemical reactions.Traditionally,EPFRs are generated by transition metal elements and substituted aromatic hydrocarbons undergoing electron transfer in the post-flame and cool-zone regions of combustion systems and other thermal processes to remove HCl,H_(2)O or CO groups,ultimately produce semiquinones,phenoxyls,and cyclopentadienyls.Recent studies have indicated that EPFRs can also be generated under the conditions of without transition metal elemental.Organics can also produce EPFRs through chemical bond rupture during heat treatment or light radiation conditions,as well as through some heterogeneous reactions and photochemical secondary generation of EPFRs.The presence or absence of oxygen has different effects on the type and yield of EPFRs.The concentration,type,and crystal type of transition metal elements will affect the type,content,and atmospheric lifetime of EPFRs.It is generally believed that the impact of transition metal element types on EPFRs is related to the oxidation-reduction potential.The combustion temperature or heat treatment process significantly affects the type and amount of EPFRs.Factors such as precursor loading content,pH conditions,light radiation and relative humidity also influence the generation of EPFRs.EPFRs can interact with pollutants in the environment during their migration and transformation process in environmental medium.This process accelerates the degradation of pollutants and plays a crucial role in the migration and transformation of organic pollutants in environmental media.The reaction process of EPFRs may lead to the production of reactive oxygen species(ROS)such as∙OH,which can induce oxidative stress,inflammation and immune response to biological lung cells and tissues,leading to chronic respiratory and cardiopulmonary dysfunction,cardiovascular damage and neurotoxic effects,ultimately impacting the health of organisms.Conclusions The interaction mechanism between EPFRs in particulate matter and gaseous pollutants remains unclear.Furthermore,research on the generation mechanism of EPFRs without the participation of transition metals is not comprehensive,and the detection of EPFRs is limited to simple qualitative categories and lack accurate qualitative analysis.Recommendations and perspectives Further research should be conducted on the generation mechanism,measurement techniques,migration pathways,and transformation process of EPFRs.It is also important to explore the interaction between EPFRs in atmospheric particulate matter and typical gaseous pollutants.
基金The General Project of the Beijing Municipal Natural Science Foundation (No. 8012009) and the Key Project of the BeijingMunicipal Sciences & Technology Commission (No. H020620190091-H020620250230)
文摘The pollution of particulate matter less than 2.5μm （PM2.5） is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that of the U,S, national ambient air quality standards proposed by U.S. EPA. The major contributors to mass of PM2.5 were organics, crustal elements and sulfate. The chemical composition of PM2.5 varied largely with season, but was similar at different monitor stations in the same season. The fine particles （PM2.5） cause atmospheric visibility deterioration through light extinction, The mass concentrations of PM2.5 were anti-correlated to the visibility, the best fits between atmospheric visibility and the mass concentrations of PM2.5 were somehow different： power in spring, exponential in summer, logarithmic in autumn, power or exponential in winter. As in each season the meteorological parameters such as air temperature and relative humidity change from day to day, probably the reason of above correlations between PM2.5 and visibility obtained at different seasons come from the differences in chemical compositions of PM2.5.
基金supported by the National Natural Science Foundation of China(No.11565002)the Jiang Xi Young Science Foundation Project(No.GJJ150558)Open Funds of Engineering Research Center of Nuclear Technology Application of Ministry of Education(No.HJSJYB2017-2)
文摘The dosage of environmental radon progeny is typically estimated according to the environmental radon exposure and the recommended radon-progeny equilibrium factor, F. To investigate the relationship between PM2.5 and the radon-progeny equilibrium factor, cigarettes are used to simulate the haze–fog in a multi-functional radon chamber to achieve a stable radon concentration environment. A radon detector and a portable laser aerosol spectrometer are used to obtain the values for C_(mean) PM2.5,C_(Rn), and C_p. The results show that the mean values of F conform with the typical value recommended by the United Nations Scientific Committee on the Effects of Atomic Radiation and are within the reasonable range of0.1–0.9. In this study, a positive correlation is observed between the F values and PM2.5 concentrations.
