Accelerating the thermal fading rate of photochromic naphthopyrans by pillar[5]arene-based conjugated macrocycle polymer

A new micro-spherical conjugated macrocycle polymer(P[5]-TFB-CMP)was prepared by the condensation reaction between dihydrazide functionalized pillar[5]arene and 1,3,5-triformylbenzene under ambient conditions.P[5]-TFB-CMP exhibits large surface area with excellent thermal stability and has been used as additive to prepare composite PMMA film of photochromic naphthopyrans.The results showed that the addition of P[5]-TFB-CMP could dramatically accelerate the thermal fading rate of the photochromic composite film by up to 12 times.This is a new strategy to overcome the drawback of the matrix effect.

Performance of M-QAM, M-DPSK and M-PSK with MRC diversity in a Nakagami-m fading channel

The nature of a wireless communication channel is very unpredictable. To design a good communication link, it is required to know the statistical model of the channel accurately. The average symbol error probability(ASER) was analyzed for different modulation schemes. A unified analytical framework was presented to obtain closed-form solutions for calculating the ASER of M-ary differential phase-shift keying(M-DPSK), coherent M-ary phase-shift keying(M-PSK), and quadrature amplitude modulation(QAM) over single or multiple Nakagami-m fading channels. Moreover, the ASER was estimated and evaluated by using the maximal ratio-combining(MRC) diversity technique. Simulation results show that an error rate of the fading channel typically depends on Nakagami parameters(m), space diversity(N), and symbol rate(M). A comparison between M-PSK, M-DPSK, and M-QAM modulation schemes was shown, and the results prove that M-ary QAM(M-QAM) demonstrates better performance compared to M-DPSK and M-PSK under all fading and non-fading conditions.

SYNTHESIS AND PHOTOCHROMISM OF ACRYLIC ESTER COPOLYMERS BEARING PENDANT VIOLOGEN GROUPS

A series of acrylic ester copolymers with viologen group as pendant were synthesizedthrough the reaction of MMA-EBA (Ethenyl bromoacetate) copolymer with 4-(4'-pyridyl)-N-alkyl (or arylalkyl) pyridiniums. These viologen copolymers can exchange their anionwith NH_4PF_6 in methanol to improve their solubility in organic solvents such as DMFand acetone. Compared with the corresponding low molecular viologens, these viologencopolymers have relatively lower color development rate under UV light and fade fasterin air due to less affinity to photo-reductant and deficiency of association between theircation radicals. Their photofatigue resistant ability is also slightly better than that of lowmolecular vinlogens.

An Anti-Eavesdrop Transmission Scheduling Scheme Based on Maximizing Secrecy Outage Probability in Ad Hoc Networks

In this paper,we consider a wireless ad hoc network consisting of multiple source nodes transmitting to their respective destinations,where an eavesdropper attempts to intercept their transmissions.We propose an optimal transmission scheduling scheme to defend against the eavesdropper,where a source node having the highest secrecy rate is scheduled to access the wireless medium for transmitting to its destination in an opportunistic manner.To be specific,the secrecy rate between a pair of the source and destination in the presence of an eavesdropper varies temporally due to the wireless fading effect.The proposed optimal transmission scheduling scheme opportunistically selects a source node with the highest secrecy rate to transmit its data for the sake of maximizing the security of the ad hoc network against eavesdropping attacks.For comparison purposes,we also consider the conventional round-robin scheduling as a benchmark,where multiple source nodes take turns in accessing their shared wireless medium for transmitting to their respective destinations.We derive closed-form secrecy outage probability expressions of both the round-robin scheduling and the proposed optimal scheduling schemes over Rayleigh fading environments.Numerical results show that the proposed transmission scheduling scheme outperforms the conventional round-robin method in terms of its secrecy outage probability.Additionally,upon increasing the number of source-destination pairs,the secrecy outage probability of the round-robin scheme keeps unchanged,whereas the secrecy outage performance of the proposed transmission scheduling significantly improves,showing the security benefits of exploiting transmission scheduling for protecting wireless ad hoc networks against eavesdropping.