Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocol...Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.展开更多
Fast phase-transferring was adopted in ethanol solution at the condition of n (oil-soluble tea pol-yphenol): N (As3﹢) = 2:1, 4:1, 6:1, pH = 4.0, temperature 40°C - 45°C, action period of 15 h to compo...Fast phase-transferring was adopted in ethanol solution at the condition of n (oil-soluble tea pol-yphenol): N (As3﹢) = 2:1, 4:1, 6:1, pH = 4.0, temperature 40°C - 45°C, action period of 15 h to compose the target, of which the productivity was 59%, UV was 267.50, 218.00, 220.50 nm, FTIR was 6291, 34158.6, 2850.2, 1708.2;1457.3;1370.4, 1224.2, 1144.0, 760.5 cm﹣1, fluorescence value λmax = 257, 591.1, 593.7, 590.3, 591.0, 591.5, XRD λ/nm is 3.6974, 4.186, 12.0762, 15.4747, 1H-NMRδ = 0.782, 1.193, 1.483 - 1.586, 1.959 - 2.184, 2.479, 3.116, 3.970 - 3.981, 5.231 - 5.753, 6.537 - 7.300. Finally it was ascertained through XRD as double-coordinated polycrystal compound.展开更多
Based on medium plate runout table ultra-fast cooling( UFC)-accelerated cooling equipment( ACC) system,a heat transfer coefficient model was constructed. Firstly,according to the measured data,heat transfer coefficien...Based on medium plate runout table ultra-fast cooling( UFC)-accelerated cooling equipment( ACC) system,a heat transfer coefficient model was constructed. Firstly,according to the measured data,heat transfer coefficients under different roll speed and water volume were calculated by using an inverse heat conduction method. Secondly,a monofactorial heat transfer coefficient calculation formula was obtained. Finally,the heat transfer coefficient model based on medium plate runout table UFC-ACC system was constructed by intercept function,slope function,interaction influence function and linear or nonlinear influencing factors. The precision of these models was validated by comparing model prediction value with measured data,and the results were in good agreement with practical needs,and the average deviation was less than 5%.展开更多
螺旋管蒸汽发生器是液态金属快堆中能量传递的核心设备,其运行的稳定性、安全性对核电站的运行有至关重要的影响。为此,本文构建了液态金属快堆螺旋管蒸汽发生器一次侧、二次侧耦合传热的三维数值模型,分别基于经济合作与发展组织核能署...螺旋管蒸汽发生器是液态金属快堆中能量传递的核心设备,其运行的稳定性、安全性对核电站的运行有至关重要的影响。为此,本文构建了液态金属快堆螺旋管蒸汽发生器一次侧、二次侧耦合传热的三维数值模型,分别基于经济合作与发展组织核能署(The Organisation for Economic Co-operation and Development,OECD/NEA)物性手册和美国国家标准与技术研究院(National Institute of Standards and Technology,NIST)数据库建立液态金属和水-水蒸气变物性计算关联式,采用Lee相变模型计算二次侧水-水蒸气蒸发过程中两相间的质量传递。基于实验数据,分别对本文模型一次侧传热以及二次侧传热的计算可靠性进行了验证。最后以铅铋快堆为例,研究了不同一次侧进口参数下蒸汽发生器一、二次侧之间的耦合传热特性,并与传统水冷堆进行了对比。结果表明:在同等条件下,相比于传统水冷堆,一次侧采用铅铋液态金属时,一、二次侧之间的壁面热流密度明显提升,热流密度峰值可达1439.97 kW·m^(-2),比水冷堆相应数值提升5~6倍,这导致二次侧管内气相蒸发过程明显加剧,体积含气率急剧上升;同时,一、二次侧之间的沿程热流密度分布更加不均匀,沿程热流密度分布相对偏差值比水冷堆相应数值增大3~4倍。随着一次侧进口铅铋温度从350℃增大到450℃,一、二次侧之间的壁面热流密度随之增大,对应的热流密度峰值从950.7 kW·m^(-2)增大到1439.97 kW·m^(-2),提升约1.5倍,同时一、二次侧之间的沿程热流密度分布更加不均匀,不均匀度增大20%。展开更多
Purpose: To increase the efficiency of densely encoded magnetization transfer imaging of the brain, we time-multiplex multiple slices within the same readout using simultaneous echo refocusing FLASH imaging with magne...Purpose: To increase the efficiency of densely encoded magnetization transfer imaging of the brain, we time-multiplex multiple slices within the same readout using simultaneous echo refocusing FLASH imaging with magnetization transfer (MT) preparation (MT-SER-FLASH). Materials and Methods: Inefficiency in total scan time results from the number of frequency samples needed for sufficient quality of quantitative parameter maps for a binary spin bath model. We present a highly efficient multiplexing method, simultaneous echo refocused magnetization transfer imaging (MT-SER-FLASH) for reducing the total scan time of MT imaging by one-third. The specific absorption rate (SAR) was also reduced by reducing the number of MT-pulses per volume. Results: 2D-MT-SER-FLASH is performed in 19 minutes rather than 1 hour, acceptable for routine clinical application. The SAR could be reduced to 69% instead of more than 100% with a standard 2D or 3D-FLASH with MT-preparation. Conclusion: The net reduction of scan time and SAR enables the use of quantitative model based magnetization transfer imaging within a clinical environment.展开更多
A cyanine dye, 2-[7-（1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene）-1,3,5-heptatrienyl]-1,3,3-trimethyl-3H-indolium iodide （NK-125）, is doped in 4-cyano-4＇-pentylbiphenyl （5 CB）, and the mixture is sandwiched ...A cyanine dye, 2-[7-（1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene）-1,3,5-heptatrienyl]-1,3,3-trimethyl-3H-indolium iodide （NK-125）, is doped in 4-cyano-4＇-pentylbiphenyl （5 CB）, and the mixture is sandwiched between two pieces of rubbed glass plates. The third-order nonlinear optical properties of the oriented NK-125-SCB layers are measured by the resonant femtosecond degenerate four-wave mixing （DFWM） technique at 760 nm. The third-order nonlinear optical susceptibility of one of the present samples is 5.5×10^-8 esu. The slow DFWM response of the NK-125-SCB layers due to a population grating is accelerated by the increasing laser power because of amplified spontaneous emission （ASE）. On the other hand, we do not observe a similar phenomenon for NK-125- polyethylene glycol （PEG-400）. Oriented NK-125 molecules in nematic liquid crystals must have very high ASE efficiency. Hence the population grating in a DFWM signal disappears within about 4 ps. It is expected that NK-125-SCB can be used as a material for very fast all-optical switching.展开更多
基金UK Engineering and Physical Sciences Research Council(EPSRC)New Investigator Award(2018,EP/R043272/1)Newton Advanced Fellowship(192097)for financial support+3 种基金the Royal Society,the Engineering and Physical Sciences Research Council(EPSRC,EP/R023980/1,EP/V027131/1)the European Research Council(ERC)under the European Union's Horizon 2020 research and innovation program(HYPERION,Grant Agreement Number 756962)the Royal Society and Tata Group(UF150033)EPSRC SPECIFIC IKC(EP/N020863/1)
文摘Metal oxide charge transport materials are preferable for realizing long-term stable and potentially low-cost perovskite solar cells(PSCs).However,due to some technical difficulties(e.g.,intricate fabrication protocols,high-temperature heating process,incompatible solvents,etc.),it is still challenging to achieve efficient and reliable all-metal-oxide-based devices.Here,we developed efficient inverted PSCs(IPSCs)based on solution-processed nickel oxide(NiO_(x))and tin oxide(SnO_(2))nanoparticles,working as hole and electron transport materials respectively,enabling a fast and balanced charge transfer for photogenerated charge carriers.Through further understanding and optimizing the perovskite/metal oxide interfaces,we have realized an outstanding power conversion efficiency(PCE)of 23.5%(the bandgap of the perovskite is 1.62 eV),which is the highest efficiency among IPSCs based on all-metal-oxide charge transport materials.Thanks to these stable metal oxides and improved interface properties,ambient stability(retaining 95%of initial PCE after 1 month),thermal stability(retaining 80%of initial PCE after 2 weeks)and light stability(retaining 90%of initial PCE after 1000 hours aging)of resultant devices are enhanced significantly.In addition,owing to the low-temperature fabrication procedures of the entire device,we have obtained a PCE of over 21%for flexible IPSCs with enhanced operational stability.
文摘Fast phase-transferring was adopted in ethanol solution at the condition of n (oil-soluble tea pol-yphenol): N (As3﹢) = 2:1, 4:1, 6:1, pH = 4.0, temperature 40°C - 45°C, action period of 15 h to compose the target, of which the productivity was 59%, UV was 267.50, 218.00, 220.50 nm, FTIR was 6291, 34158.6, 2850.2, 1708.2;1457.3;1370.4, 1224.2, 1144.0, 760.5 cm﹣1, fluorescence value λmax = 257, 591.1, 593.7, 590.3, 591.0, 591.5, XRD λ/nm is 3.6974, 4.186, 12.0762, 15.4747, 1H-NMRδ = 0.782, 1.193, 1.483 - 1.586, 1.959 - 2.184, 2.479, 3.116, 3.970 - 3.981, 5.231 - 5.753, 6.537 - 7.300. Finally it was ascertained through XRD as double-coordinated polycrystal compound.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51104045)
文摘Based on medium plate runout table ultra-fast cooling( UFC)-accelerated cooling equipment( ACC) system,a heat transfer coefficient model was constructed. Firstly,according to the measured data,heat transfer coefficients under different roll speed and water volume were calculated by using an inverse heat conduction method. Secondly,a monofactorial heat transfer coefficient calculation formula was obtained. Finally,the heat transfer coefficient model based on medium plate runout table UFC-ACC system was constructed by intercept function,slope function,interaction influence function and linear or nonlinear influencing factors. The precision of these models was validated by comparing model prediction value with measured data,and the results were in good agreement with practical needs,and the average deviation was less than 5%.
文摘螺旋管蒸汽发生器是液态金属快堆中能量传递的核心设备,其运行的稳定性、安全性对核电站的运行有至关重要的影响。为此,本文构建了液态金属快堆螺旋管蒸汽发生器一次侧、二次侧耦合传热的三维数值模型,分别基于经济合作与发展组织核能署(The Organisation for Economic Co-operation and Development,OECD/NEA)物性手册和美国国家标准与技术研究院(National Institute of Standards and Technology,NIST)数据库建立液态金属和水-水蒸气变物性计算关联式,采用Lee相变模型计算二次侧水-水蒸气蒸发过程中两相间的质量传递。基于实验数据,分别对本文模型一次侧传热以及二次侧传热的计算可靠性进行了验证。最后以铅铋快堆为例,研究了不同一次侧进口参数下蒸汽发生器一、二次侧之间的耦合传热特性,并与传统水冷堆进行了对比。结果表明:在同等条件下,相比于传统水冷堆,一次侧采用铅铋液态金属时,一、二次侧之间的壁面热流密度明显提升,热流密度峰值可达1439.97 kW·m^(-2),比水冷堆相应数值提升5~6倍,这导致二次侧管内气相蒸发过程明显加剧,体积含气率急剧上升;同时,一、二次侧之间的沿程热流密度分布更加不均匀,沿程热流密度分布相对偏差值比水冷堆相应数值增大3~4倍。随着一次侧进口铅铋温度从350℃增大到450℃,一、二次侧之间的壁面热流密度随之增大,对应的热流密度峰值从950.7 kW·m^(-2)增大到1439.97 kW·m^(-2),提升约1.5倍,同时一、二次侧之间的沿程热流密度分布更加不均匀,不均匀度增大20%。
文摘Purpose: To increase the efficiency of densely encoded magnetization transfer imaging of the brain, we time-multiplex multiple slices within the same readout using simultaneous echo refocusing FLASH imaging with magnetization transfer (MT) preparation (MT-SER-FLASH). Materials and Methods: Inefficiency in total scan time results from the number of frequency samples needed for sufficient quality of quantitative parameter maps for a binary spin bath model. We present a highly efficient multiplexing method, simultaneous echo refocused magnetization transfer imaging (MT-SER-FLASH) for reducing the total scan time of MT imaging by one-third. The specific absorption rate (SAR) was also reduced by reducing the number of MT-pulses per volume. Results: 2D-MT-SER-FLASH is performed in 19 minutes rather than 1 hour, acceptable for routine clinical application. The SAR could be reduced to 69% instead of more than 100% with a standard 2D or 3D-FLASH with MT-preparation. Conclusion: The net reduction of scan time and SAR enables the use of quantitative model based magnetization transfer imaging within a clinical environment.
文摘A cyanine dye, 2-[7-（1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene）-1,3,5-heptatrienyl]-1,3,3-trimethyl-3H-indolium iodide （NK-125）, is doped in 4-cyano-4＇-pentylbiphenyl （5 CB）, and the mixture is sandwiched between two pieces of rubbed glass plates. The third-order nonlinear optical properties of the oriented NK-125-SCB layers are measured by the resonant femtosecond degenerate four-wave mixing （DFWM） technique at 760 nm. The third-order nonlinear optical susceptibility of one of the present samples is 5.5×10^-8 esu. The slow DFWM response of the NK-125-SCB layers due to a population grating is accelerated by the increasing laser power because of amplified spontaneous emission （ASE）. On the other hand, we do not observe a similar phenomenon for NK-125- polyethylene glycol （PEG-400）. Oriented NK-125 molecules in nematic liquid crystals must have very high ASE efficiency. Hence the population grating in a DFWM signal disappears within about 4 ps. It is expected that NK-125-SCB can be used as a material for very fast all-optical switching.
