With increasing demand on energy density of lithium-ion battery,wide electrochemical window and safety performance are the crucial request for next generation electrolyte.Gel-electrolyte as a pioneer for electrolyte s...With increasing demand on energy density of lithium-ion battery,wide electrochemical window and safety performance are the crucial request for next generation electrolyte.Gel-electrolyte as a pioneer for electrolyte solidization development aims to solve the safety and electrochemical window problems.However,low ionic conductivity and poor physical performance prohibit its further application.Herein,a fast-ionic conductor(Li_(2.64)(Sc_(0.9)Ti_(0.1))_(2)(PO_(4))_(3))(LSTP)was added into poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)base gel-electrolyte to enhance mechanical properties and ionic conductivity.Evidences reveal that LSTP was able to weaken interforce between polymer chains,which increased the ionic conductibility and decreased interface resistance during the cycling significantly.The obtained LiFePO_(4)/hybrid gel-electrolyte/Li-metal coin cell exhibited excellent rate capacity(145 mA·h/g at 1C,95 mA·h/g at 3C,28℃)which presented a potential that can be comparable with commercialized liquid electrolyte system.展开更多
2D fast-ion velocity-space distributions have been reconstructed from two-view fast-ion D-alpha(FIDA)measurements on experimental advanced superconducting tokamak(EAST).To make up for the sparse data and incomplete ve...2D fast-ion velocity-space distributions have been reconstructed from two-view fast-ion D-alpha(FIDA)measurements on experimental advanced superconducting tokamak(EAST).To make up for the sparse data and incomplete velocity-space coverage with the dual-view,we use nonnegativity and null-measurements as prior information to reconstruct the velocity distribution in experiments with co-and counter-current neutral beam injection.An improved reconstructed fast-ion distribution is achieved by combining the existing O-and B-port FIDA measurements with the proposed A-port FIDA view.To further improve the reliability of FIDA-based reconstructions on EAST,based on real multi-view FIDA measurements on EAST in the near future,various bases will be studied further.展开更多
基金Projects(51974368,51774333) supported by the National Natural Science Foundation of ChinaProject(2020JJ2048) supported by the Hunan Provincial Natural Science Foundation of China。
文摘With increasing demand on energy density of lithium-ion battery,wide electrochemical window and safety performance are the crucial request for next generation electrolyte.Gel-electrolyte as a pioneer for electrolyte solidization development aims to solve the safety and electrochemical window problems.However,low ionic conductivity and poor physical performance prohibit its further application.Herein,a fast-ionic conductor(Li_(2.64)(Sc_(0.9)Ti_(0.1))_(2)(PO_(4))_(3))(LSTP)was added into poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)base gel-electrolyte to enhance mechanical properties and ionic conductivity.Evidences reveal that LSTP was able to weaken interforce between polymer chains,which increased the ionic conductibility and decreased interface resistance during the cycling significantly.The obtained LiFePO_(4)/hybrid gel-electrolyte/Li-metal coin cell exhibited excellent rate capacity(145 mA·h/g at 1C,95 mA·h/g at 3C,28℃)which presented a potential that can be comparable with commercialized liquid electrolyte system.
基金supported by National Natural Science Foundation of China(No.11975276)Anhui Provincial Natural Science Foundation(No.2008085J04)+3 种基金Anhui Provincial Key R&D Programmes(No.202104b11020003)the National Key Research and Development Program of China(No.2019YFE03020004)the Excellence Program of Hefei Science Center CAS(No.2021HSC-UE015)。
文摘2D fast-ion velocity-space distributions have been reconstructed from two-view fast-ion D-alpha(FIDA)measurements on experimental advanced superconducting tokamak(EAST).To make up for the sparse data and incomplete velocity-space coverage with the dual-view,we use nonnegativity and null-measurements as prior information to reconstruct the velocity distribution in experiments with co-and counter-current neutral beam injection.An improved reconstructed fast-ion distribution is achieved by combining the existing O-and B-port FIDA measurements with the proposed A-port FIDA view.To further improve the reliability of FIDA-based reconstructions on EAST,based on real multi-view FIDA measurements on EAST in the near future,various bases will be studied further.
