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Fault-Tolerant Design Techniques in ACMP Architecture
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作者 YAOWen.bin WANGDong-sheng 《Wuhan University Journal of Natural Sciences》 CAS 2005年第1期5-8,共4页
Single-chip multiprocessor (CMP) combined with the fault-loleranl(FT)techniques offers an ideal architecture to achieve high availability on the basis of sustaining highcomputing performance FT design of a single-chip... Single-chip multiprocessor (CMP) combined with the fault-loleranl(FT)techniques offers an ideal architecture to achieve high availability on the basis of sustaining highcomputing performance FT design of a single-chip multiprocessor is described, including thetechniques from hard-wart redundancy to software support and firmware strategy. The design aims atmasking the influences of errors and automatically correcting the system states. 展开更多
关键词 computer architecture fault-tolerant design single-chip multiprocessor
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Fault-Tolerant Design of Spaceborne Mass Memory System
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作者 张宇宁 常亮 +1 位作者 杨根庆 李华旺 《Transactions of Tianjin University》 EI CAS 2010年第1期17-21,共5页
A fault-tolerant spaceborne mass memory architecture is presented based on entirely commercial-off-theshelf components.The highly modularized and scalable memory kernel supports the hierarchical design and is well sui... A fault-tolerant spaceborne mass memory architecture is presented based on entirely commercial-off-theshelf components.The highly modularized and scalable memory kernel supports the hierarchical design and is well suited to redundancy structure.Error correcting code(ECC) and periodical scrubbing are used to deal with bit errors induced by single event upset.For 8-bit wide devices, the parallel Reed Solomon(10, 8) can perform coder/decoder calculations in one clock cycle, achieving a data rate of several Gb/... 展开更多
关键词 fault-tolerant memory architecture data integrity parallel Reed-Solomon codec
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CRBFT:A Byzantine Fault-Tolerant Consensus Protocol Based on Collaborative Filtering Recommendation for Blockchains
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作者 Xiangyu Wu Xuehui Du +3 位作者 Qiantao Yang Aodi Liu Na Wang Wenjuan Wang 《Computers, Materials & Continua》 SCIE EI 2024年第7期1491-1519,共29页
Blockchain has been widely used in finance,the Internet of Things(IoT),supply chains,and other scenarios as a revolutionary technology.Consensus protocol plays a vital role in blockchain,which helps all participants t... Blockchain has been widely used in finance,the Internet of Things(IoT),supply chains,and other scenarios as a revolutionary technology.Consensus protocol plays a vital role in blockchain,which helps all participants to maintain the storage state consistently.However,with the improvement of network environment complexity and system scale,blockchain development is limited by the performance,security,and scalability of the consensus protocol.To address this problem,this paper introduces the collaborative filtering mechanism commonly used in the recommendation system into the Practical Byzantine Fault Tolerance(PBFT)and proposes a Byzantine fault-tolerant(BFT)consensus protocol based on collaborative filtering recommendation(CRBFT).Specifically,an improved collaborative filtering recommendation method is designed to use the similarity between a node’s recommendation opinions and those of the recommender as a basis for determining whether to adopt the recommendation opinions.This can amplify the recommendation voice of good nodes,weaken the impact of cunningmalicious nodes on the trust value calculation,andmake the calculated resultsmore accurate.In addition,the nodes are given voting power according to their trust value,and a weight randomelection algorithm is designed and implemented to reduce the risk of attack.The experimental results show that CRBFT can effectively eliminate various malicious nodes and improve the performance of blockchain systems in complex network environments,and the feasibility of CRBFT is also proven by theoretical analysis. 展开更多
关键词 Blockchain CONSENSUS byzantine fault-tolerant collaborative filtering TRUST
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Review of Fault-tolerant Control for Motor Inverter Failure with Operational Quality Considered
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作者 Yuxuan Du Wenxiang Zhao +2 位作者 Yihua Hu Jinghua Ji Tao Tao 《CES Transactions on Electrical Machines and Systems》 EI CSCD 2024年第2期202-215,共14页
In recent years,motor drive systems have garnered increasing attention due to their high efficiency and superior control performance.This is especially apparent in aerospace,marine propulsion,and electric vehicles,whe... In recent years,motor drive systems have garnered increasing attention due to their high efficiency and superior control performance.This is especially apparent in aerospace,marine propulsion,and electric vehicles,where high performance,efficiency,and reliability are crucial.The ability of the drive system to maintain long-term fault-tolerant control(FTC)operation after a failure is essential.The likelihood of inverter failures surpasses that of other components in the drive system,highlighting its critical importance.Long-term FTC operation ensures the system retains its fundamental functions until safe repairs or replacements can be made.The focus of developing a FTC strategy has shifted from basic FTC operations to enhancing the post-fault quality to accommodate the realities of prolonged operation post-failure.This paper primarily investigates FTC strategies for inverter failures in various motor drive systems over the past decade.These strategies are categorized into three types based on post-fault operational quality:rescue,remedy,and reestablishment.The paper discusses each typical control strategy and its research focus,the strengths and weaknesses of various algorithms,and recent advancements in FTC.Finally,this review summarizes effective FTC techniques for inverter failures in motor drive systems and suggests directions for future research. 展开更多
关键词 fault-tolerant Motor drive Operation quality Inverter failure
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A finite-time fuzzy adaptive output-feedback fault-tolerant control for underactuated wheeled mobile robots systems
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作者 Pingfan Liu Shaocheng Tong 《Journal of Automation and Intelligence》 2024年第2期111-118,共8页
This paper investigates the adaptive fuzzy finite-time output-feedback fault-tolerant control (FTC) problemfor a class of nonlinear underactuated wheeled mobile robots (UWMRs) system with intermittent actuatorfaults. ... This paper investigates the adaptive fuzzy finite-time output-feedback fault-tolerant control (FTC) problemfor a class of nonlinear underactuated wheeled mobile robots (UWMRs) system with intermittent actuatorfaults. The UWMR system includes unknown nonlinear dynamics and immeasurable states. Fuzzy logic systems(FLSs) are utilized to work out immeasurable functions. Furthermore, with the support of the backsteppingcontrol technique and adaptive fuzzy state observer, a fuzzy adaptive finite-time output-feedback FTC scheme isdeveloped under the intermittent actuator faults. It is testifying the scheme can ensure the controlled nonlinearUWMRs is stable and the estimation errors are convergent. Finally, the comparison results and simulationvalidate the effectiveness of the proposed fuzzy adaptive finite-time FTC approach. 展开更多
关键词 Underactuated wheeled mobile robots system FINITE-TIME Fuzzy adaptive fault-tolerant control OUTPUT-FEEDBACK Intermittent actuator faults
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水田动力底盘逆向建模与质心验证——基于Geomagic Design X
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作者 何剑飞 曾志浩 +5 位作者 郭梓游 李贵蓉 钟文能 钟顺 王在满 李庆 《农机化研究》 北大核心 2024年第10期248-253,共6页
针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动... 针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动力底盘为例,将测得的实际质心位置与所建的模型质心位置进行比较,并对提出的逆向建模方法进行了试验验证以及误差分析。结果表明:总质量、x坐标、y坐标、z坐标的误差值分别为4.55%、3.62%、2.23%、4.81%,误差值均在5%内。此方法可构建准确的三维模型,为后续仿真优化数据精确性奠定了基础,与传统的研发相比较,可缩短农业机械研发周期、降低设计成本。 展开更多
关键词 水田 动力底盘 逆向建模 质心验证 Geomagic design X 数字样机
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App Designer辅助教学方法探索与实践——以软件无线电课程为例
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作者 向新 刘宇峰 +2 位作者 梁源 王瑞 何林远 《中国现代教育装备》 2024年第19期148-151,共4页
软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer... 软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer辅助课程教学,从教学准备、课堂互动、自主实验、反馈提升四个方面开展课程教学改革。实践表明,该方法对于提升学员的工程思维、系统思维具有显著效果,同时可以增强学员理论联系实际的能力。 展开更多
关键词 软件无线电 MATLAB App designer 教学方法改革 理实结合
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Finite-time fault-tolerant control of teleoperating cyber physical system against faults 被引量:1
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作者 PAN Chengwei LIU Xia +1 位作者 CHEN Yong LI Meng 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2023年第2期469-478,共10页
This paper studies a finite-time adaptive fractionalorder fault-tolerant control(FTC)scheme for the slave position tracking of the teleoperating cyber physical system(TCPS)with external disturbances and actuator fault... This paper studies a finite-time adaptive fractionalorder fault-tolerant control(FTC)scheme for the slave position tracking of the teleoperating cyber physical system(TCPS)with external disturbances and actuator faults.Based on the fractional Lyapunov stability theory and the finite-time stability theory,a fractional-order nonsingular fast terminal sliding mode(FONFTSM)control law is proposed to promote the tracking and fault tolerance performance of the considered system.Meanwhile,the adaptive fractional-order update laws are designed to cope with the unknown upper bounds of the unknown actuator faults and external disturbances.Furthermore,the finite-time stability of the closed-loop system is proved.Finally,comparison simulation results are also provided to show the validity and the advantages of the proposed techniques. 展开更多
关键词 teleoperating cyber physical system(TCPS) fractional Lyapunov stability fault-tolerant control(FTC) finite-time stability
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Design and Optimization of Dual-Winding Fault-Tolerant Permanent Magnet Motor 被引量:5
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作者 Xuefeng Jiang Shaoshuai Wang +1 位作者 Qiang Li Yufei Gao 《CES Transactions on Electrical Machines and Systems》 CSCD 2019年第1期45-53,共9页
To improve the performance of the traditional fault-tolerant permanent magnet(PM)motor,the design and optimal schemes of dual-winding fault-tolerant permanent magnet motor(DWFT-PMM)are proposed and investigated.In ord... To improve the performance of the traditional fault-tolerant permanent magnet(PM)motor,the design and optimal schemes of dual-winding fault-tolerant permanent magnet motor(DWFT-PMM)are proposed and investigated.In order to obtain small cogging torque ripple and inhibiting the short-circuit current,the air gap surface shape of the PM and the anti short-circuits reactance parameters are designed and optimized.According to the actual design requirements of an aircraft electrical actuation system,the parameters,finite element analysis and experimental verification of the DWFT-PMM after optimal design are presented.The research results show that the optimized DWFT-PMM owns the merits of strong magnetic isolation,physics isolation,inhibiting the short circuit current,small cogging torque ripple and high fault tolerance. 展开更多
关键词 Dual-winding motor design and optimization fault-tolerANCE finite element analysis short-circuit fault
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Robust fault-tolerant controller design for linear time-invariant systems with actuator failures:an indirect adaptive method 被引量:7
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作者 Xiaozheng JIN Guanghong YANG Yanping LI 《控制理论与应用(英文版)》 EI 2010年第4期471-478,共8页
In this paper,indirect adaptive state feedback control schemes are developed to solve the robust fault-tolerant control (FTC) design problem of actuator fault and perturbation compensations for linear time-invariant... In this paper,indirect adaptive state feedback control schemes are developed to solve the robust fault-tolerant control (FTC) design problem of actuator fault and perturbation compensations for linear time-invariant systems.A more general and practical model of actuator faults is presented.While both eventual faults on actuators and perturbations are unknown,the adaptive schemes are addressed to estimate the lower and upper bounds of actuator-stuck faults and perturbations online,as well as to estimate control effectiveness on actuators.Thus,on the basis of the information from adaptive schemes,an adaptive robust state feed-back controller is designed to compensate the effects of faults and perturbations automatically.According to Lyapunov stability theory,it is shown that the robust adaptive closed-loop systems can be ensured to be asymptotically stable under the influence of actuator faults and bounded perturbations.An example is provided to further illustrate the fault compensation effectiveness. 展开更多
关键词 fault-tolerant control Actuator failures Adaptive robust control Asymptotic stability
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Adaptive fault-tolerant controller design for airbreathing hypersonic vehicle with input saturation 被引量:12
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作者 Haibin Sun Shihua Li Changyin Sun 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2013年第3期488-499,共12页
The problem of fault-tolerant control is discussed for the longitudinal model of an airbreathing hypersonic vehicle (AHV) with actuator faults and external disturbances. Firstly, a fault-tolerant control strategy is... The problem of fault-tolerant control is discussed for the longitudinal model of an airbreathing hypersonic vehicle (AHV) with actuator faults and external disturbances. Firstly, a fault-tolerant control strategy is presented for the longitudinal model of an AHV, which guarantees that velocity and altitude track their reference trajectories at an exponential convergence rate. However, this method needs to know the minimum value of the actuator efficiency factor and the upper bound of the external disturbances, which makes it not easy to implement. Then an improved adaptive fault-tolerant control scheme is proposed, where two adaptive laws are employed to estimate the upper bound of the external disturbances and the minimum value of the actuator efficiency factor, respectively. Secondly, the problem of designing a control scheme with control constraints is further considered, and a new adaptive fault-tolerant control strategy with input saturation is designed to guarantee that velocity and altitude track their reference trajectories. Finally, simulation results are given to show the effectiveness of the proposed methods. 展开更多
关键词 airbreathing hypersonic vehicle (AHV) fault-tolerant control (FTC) adaptive control input saturation.
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H_∞ Robust Fault-Tolerant Controller Design for an Autonomous Underwater Vehicle’s Navigation Control System 被引量:4
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作者 程相勤 曲镜圆 +1 位作者 严浙平 边信黔 《Journal of Marine Science and Application》 2010年第1期87-92,共6页
In order to improve the security and reliability for autonomous underwater vehicle (AUV) navigation, an H∞ robust fault-tolerant controller was designed after analyzing variations in state-feedback gain Operating c... In order to improve the security and reliability for autonomous underwater vehicle (AUV) navigation, an H∞ robust fault-tolerant controller was designed after analyzing variations in state-feedback gain Operating conditions and the design method were then analyzed so that the control problem could be expressed as a mathematical optimization problem. This permitted the use of linear matrix inequalities (LMI) to solve for the Hv controller for the system. When considering different actuator failures, these conditions were then also mathematically expressed, allowing the H∞ robust controller to solve for these events and thus be fault-tolerant. Finally, simulation results showed that the H∞ robust fault-tolerant controller could provide precise AUV navigation control with strong robustness. 展开更多
关键词 AUV navigation control robust H∞ fault-tolerant control gain variations LMI
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Web Layout Design of Large Cavity Structures Based on Topology Optimization 被引量:1
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作者 Xiaoqiao Yang Jialiang Sun Dongping Jin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期2665-2689,共25页
Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas... Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas become a focal point for contemporary researchers. Therefore, this paper aims to investigate the topologyoptimization of large cavity structures as a means to enhance their performance, safety, and efficiency. By usingthe variable density method, lightweight design is achieved without compromising structural strength. Theoptimization model considers both concentrated and distributed loads, and utilizes techniques like sensitivityfiltering and projection to obtain a robust optimized configuration. The mechanical properties are checked bycomparing the stress distribution and displacement of the unoptimized and optimized structures under the sameload. The results confirm that the optimized structures exhibit improved mechanical properties, thus offering keyinsights for engineering lightweight, high-strength large cavity structures. 展开更多
关键词 Topology optimization lightweight design web layout design cavity structure
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Disturbance observer-based fuzzy fault-tolerant control for high-speed trains with multiple disturbances
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作者 王千龄 马彩青 林雪 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期383-391,共9页
The fault-tolerant control problem is investigated for high-speed trains with actuator faults and multiple disturbances.Based on the novel train model resulting from the Takagi–Sugeno fuzzy theory, a sliding-mode fau... The fault-tolerant control problem is investigated for high-speed trains with actuator faults and multiple disturbances.Based on the novel train model resulting from the Takagi–Sugeno fuzzy theory, a sliding-mode fault-tolerant control strategy is proposed. The norm bounded disturbances which are composed of interactive forces among adjacent carriages and basis running resistances are rearranged by the fuzzy linearity technique. The modeled disturbances described as an exogenous system are compensated for by a disturbance observer. Moreover, a sliding mode surface is constructed, which can transform the stabilization problem of position and velocity into the stabilization problem of position errors and velocity errors, i.e., the tracking problem of position and velocity. Based on the parallel distributed compensation method and the disturbance observer, the fault-tolerant controller is solved. The Lyapunov theory is used to prove the stability of the closed-loop system. The feasibility and effectiveness of the proposed fault-tolerant control strategy are illustrated by simulation results. 展开更多
关键词 fault-tolerant control high-speed trains disturbance observer fuzzy logic
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Heterogeneous Fault-Tolerant Aggregate Signcryption with Equality Test for Vehicular Sensor Networks
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作者 Yang Zhao Jingmin An +1 位作者 Hao Li Saru Kumari 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第10期555-575,共21页
The vehicular sensor network (VSN) is an important part of intelligent transportation, which is used for real-timedetection and operation control of vehicles and real-time transmission of data and information. In the ... The vehicular sensor network (VSN) is an important part of intelligent transportation, which is used for real-timedetection and operation control of vehicles and real-time transmission of data and information. In the environmentofVSN, massive private data generated by vehicles are transmitted in open channels and used by other vehicle users,so it is crucial to maintain high transmission efficiency and high confidentiality of data. To deal with this problem, inthis paper, we propose a heterogeneous fault-tolerant aggregate signcryption scheme with an equality test (HFTASET).The scheme combines fault-tolerant and aggregate signcryption,whichnot onlymakes up for the deficiency oflow security of aggregate signature, but alsomakes up for the deficiency that aggregate signcryption cannot tolerateinvalid signature. The scheme supports one verification pass when all signcryptions are valid, and it supportsunbounded aggregation when the total number of signcryptions grows dynamically. In addition, this schemesupports heterogeneous equality test, and realizes the access control of private data in different cryptographicenvironments, so as to achieve flexibility in the application of our scheme and realize the function of quick searchof plaintext or ciphertext. Then, the security of HFTAS-ET is demonstrated by strict theoretical analysis. Finally, weconduct strict and standardized experimental operation and performance evaluation, which shows that the schemehas better performance. 展开更多
关键词 Aggregate signcryption fault-tolerant HETEROGENEOUS equality test vehicular sensor network
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Fault-Tolerant Design for Data Efficient Retransmission in WiNoC 被引量:2
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作者 Yiming Ouyang Qi Wang +2 位作者 Zhe Li Huaguo Liang Jianhua Li 《Tsinghua Science and Technology》 SCIE EI CAS CSCD 2021年第1期85-94,共10页
There is a sharp decline in the network performance when the wireless link fails as a data path in the Wireless Network-on-Chip(WiNoC).To counteract this problem,we propose a fault-tolerance mechanism for the efficien... There is a sharp decline in the network performance when the wireless link fails as a data path in the Wireless Network-on-Chip(WiNoC).To counteract this problem,we propose a fault-tolerance mechanism for the efficient retransmission of data in the WiNoC.When an error is detected in the data transmission process,this mechanism works to feed back the fault information to the source node in real time via fault signal lines.In the source node,the highest transmission priority is assigned to the backup retransmitted data,and the corresponding direct link is positioned to enable the data packet for its efficient retransmission to the destination node,thereby ensuring efficiency in fault tolerance.Additionally,we have improved the receiving port of the wireless router,added the corresponding redundant buffers and mux,and dynamically selected the retransmitted non-faulty data packets to be written to the local router in order to avoid the disorderly retransmission of the data packets.The evaluation results of this paper demonstrate that compared with the methods which are under different fault conditions,this fault-tolerant method drastically improves the data throughput rate,reduces the delay,effectively guarantees the reliability of the network,and improves the system performance. 展开更多
关键词 wireless network-on-chip RETRANSMISSION fault-tolerant RELIABILITY
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Inverse design of mechanical metamaterial achieving a prescribedconstitutive curve 被引量:1
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作者 Zongliang Du Tanghuai Bian +4 位作者 Xiaoqiang Ren Yibo Jia Shan Tang Tianchen Cui Xu Guo 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2024年第1期16-22,共7页
Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between di... Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between different patterns under deformation.However,the related inverse design problem is quite challenging,due to the lack of appropriate mathematical formulation and the convergence issue in the post-buckling analysis of intermediate designs.In this work,periodic unit cells are explicitly described by the moving morphable voids method and effectively analyzed by eliminating the degrees of freedom in void regions.Furthermore,by exploring the Pareto frontiers between error and cost,an inverse design formulation is proposed for unit cells.This formulation aims to achieve a prescribed constitutive curve and is validated through numerical examples and experimental results.The design approach presented here can be extended to the inverse design of other types of mechanical metamaterials with prescribed nonlinear effective properties. 展开更多
关键词 METAMATERIAL Pattern-transformation Constitutive curve Inverse design
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Fault-Tolerant Design and Testing of USB2.0 Peripheral Devices IP Core System 被引量:1
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作者 白晓平 韦援丰 《Tsinghua Science and Technology》 SCIE EI CAS 2007年第S1期197-201,共5页
Universal serial bus 2.0 (USB2.0) is a kind of mainstream interface technology. The traditional USB developing is only to develop USB peripheral devices. For the USB2.0 peripheral devices IP core system that has wide ... Universal serial bus 2.0 (USB2.0) is a kind of mainstream interface technology. The traditional USB developing is only to develop USB peripheral devices. For the USB2.0 peripheral devices IP core system that has wide application foreground, some interference inevitably exists in signal transmitting. Some fault-tolerant design and test methods must be adopted in order to correctly transmit and receive data. Combining with a project, this paper introduces in detail about measures, hardware implement, and test methods of fault-tolerant design about USB2.0 peripheral devices IP core system. Fault-tolerant design measures, noise reduction measures of signal processing, fault-tolerant methods about data encode and decode, package identification (ID) field fault-tolerant methods, and cyclic redundancy checks fault-tolerant methods are discussed. The paper also presents some hardware implement methods about fault-tolerant design of data decode and test methods about fault-tolerant design of USB2.0 IP core system. These methods can offer the reference for development of USB2.0 system in all kinds of electronics instrumentations. 展开更多
关键词 universal serial bus fault-tolerant DIAGNOSIS testing HARDWARE signal processing
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Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries 被引量:1
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作者 Yunnan Gao Ling Liu +10 位作者 Yi Jiang Dexin Yu Xiaomei Zheng Jiayi Wang Jingwei Liu Dan Luo Yongguang Zhang Zhenjia Shi Xin Wang Ya‑Ping Deng Zhongwei Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期13-48,共36页
Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-... Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs. 展开更多
关键词 Zinc-air batteries Bifunctional electrocatalysts design principles Mechanistic understandings
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Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes 被引量:1
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作者 Lu Yang Shuming Dong +6 位作者 Shili Gai Dan Yang He Ding Lili Feng Guixin Yang Ziaur Rehman Piaoping Yang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期165-217,共53页
Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction... Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities. 展开更多
关键词 Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics
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