Two-phase equilibria between the ferromagnetic fcc and the paramagnetic fcc phase from 800 ℃ to 900 ℃ in the Co-rich region have been detected by the diffusion couple technique. Two phase separation region of the fc...Two-phase equilibria between the ferromagnetic fcc and the paramagnetic fcc phase from 800 ℃ to 900 ℃ in the Co-rich region have been detected by the diffusion couple technique. Two phase separation region of the fcc has been confirmed along the Curie temperature.The phase equilibria including the present results and the thermodynamic data of the Co-Cr system reported in the literature were analyzed on the basis of the thermodynamic evaluation. A set of thermodynamic values for the liquid, fcc, hcp, bcc, sigma phases was obtained. The calculated phase equilibria were in good agreement with most of the experimental data.展开更多
研究Sn含量对Ti-13Ta-xSn(x=3,6,9,12,摩尔分数,%)合金中fcc相形成的影响。合金采用机械合金化方法制备,所用设备为行星式球磨机。通过Rietveld分析发现,fcc相的晶粒尺寸小于10 nm,微应变大于10-3,这两个条件是钛基合金中形成fcc相所必...研究Sn含量对Ti-13Ta-xSn(x=3,6,9,12,摩尔分数,%)合金中fcc相形成的影响。合金采用机械合金化方法制备,所用设备为行星式球磨机。通过Rietveld分析发现,fcc相的晶粒尺寸小于10 nm,微应变大于10-3,这两个条件是钛基合金中形成fcc相所必需的。对于所有的样品,fcc相的显微组织中均含有小于10 nm的等轴晶。当Sn含量为6%时,钛合金中fcc相的含量最大,因为该合金具有最大的微应变(1.5×10-2)和晶粒尺寸(6.5 nm)。实验数据表明,球磨过程中形成固溶体和非晶相。用扩展Miedema模型对促进固溶体和非晶相形成的必要条件进行热力学计算。结果表明,当Sn含量从3%增加到12%时,形成非晶相所需的能量从大约10 k J/mol变为-5 k J/mol左右。热力学计算结果与XRD分析和HRTEM结果一致。展开更多
文摘Two-phase equilibria between the ferromagnetic fcc and the paramagnetic fcc phase from 800 ℃ to 900 ℃ in the Co-rich region have been detected by the diffusion couple technique. Two phase separation region of the fcc has been confirmed along the Curie temperature.The phase equilibria including the present results and the thermodynamic data of the Co-Cr system reported in the literature were analyzed on the basis of the thermodynamic evaluation. A set of thermodynamic values for the liquid, fcc, hcp, bcc, sigma phases was obtained. The calculated phase equilibria were in good agreement with most of the experimental data.
基金financial support from FONDECYT Project No.1190797FONDEQUIP/EQM Project No.140095。
文摘研究Sn含量对Ti-13Ta-xSn(x=3,6,9,12,摩尔分数,%)合金中fcc相形成的影响。合金采用机械合金化方法制备,所用设备为行星式球磨机。通过Rietveld分析发现,fcc相的晶粒尺寸小于10 nm,微应变大于10-3,这两个条件是钛基合金中形成fcc相所必需的。对于所有的样品,fcc相的显微组织中均含有小于10 nm的等轴晶。当Sn含量为6%时,钛合金中fcc相的含量最大,因为该合金具有最大的微应变(1.5×10-2)和晶粒尺寸(6.5 nm)。实验数据表明,球磨过程中形成固溶体和非晶相。用扩展Miedema模型对促进固溶体和非晶相形成的必要条件进行热力学计算。结果表明,当Sn含量从3%增加到12%时,形成非晶相所需的能量从大约10 k J/mol变为-5 k J/mol左右。热力学计算结果与XRD分析和HRTEM结果一致。
