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The Effective Hamiltonian and Electron Correlation Energy
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作者 Deng Conghao and Feng Dacheng (Theoretical Chemistry Division, Shandong University, Ji’ nan)Deng Lu (Department of Physics, Baylor University, Waco, Texas, U. S. A. )Li Dazhong (Department of Physics, University of British Columbia, Canada) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1989年第4期336-343,共8页
An effective,hermitian hamiltonian is derived in amodel space. Its perturbation expressions to third order approximation are given.The correlation energy is also given to the third order approximation.The effective ha... An effective,hermitian hamiltonian is derived in amodel space. Its perturbation expressions to third order approximation are given.The correlation energy is also given to the third order approximation.The effective hamiltonian deviates form the actual one by the presence of acorrelation operator.The cprrelation operatop is given in an explicit form. 展开更多
关键词 fective hamiltonian Model space Transition operatop expansion operator Correlation energy
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