An Efficient and Green Procedure for the Preparation of gem-Dicar- boxylates from Aldehydes Catalyzed by Fe_2(SO_4)_3·xH_2O

An efficient and environmentally benign conversion of aldehydes into the corresponding gem-dicarboxylates was realized by using hydrated ferric sulfate as a heterogeneous catalyst. In addition to its high efficiency, the catalyst can be recovered simply and reused efficiently for at least seven times.

Groundwater arsenic removal by coagulation using ferric(Ⅲ)sulfate and polyferric sulfate: A comparative and mechanistic study

Elevated arsenic（As） in groundwater poses a great threat to human health. Coagulation using mono- and poly-Fe salts is becoming one of the most cost-effective processes for groundwater As removal. However, a limitation comes from insufficient understanding of the As removal mechanism from groundwater matrices in the coagulation process, which is critical for groundwater treatment and residual solid disposal. Here, we overcame this hurdle by utilizing microscopic techniques to explore molecular As surface complexes on the freshly formed Fe flocs and compared ferric（III） sulfate（FS） and polyferric sulfate（PFS）performance, and finally provided a practical solution in As-geogenic areas. FS and PFS exhibited a similar As removal efficiency in coagulation and coagulation/filtration in a two-bucket system using 5 mg/L Ca（ClO）_2. By using the two-bucket system combining coagulation and sand filtration, 500 L of As-safe water（〈 10 μg/L） was achieved during five treatment cycles by washing the sand layer after each cycle. Fe k-edge X-ray absorption near-edge structure（XANES） and As k-edge extended X-ray absorption fine structure（EXAFS） analysis of the solid residue indicated that As formed a bidentate binuclear complex on ferrihydrite, with no observation of scorodite or poorly-crystalline ferric arsenate. Such a stable surface complex is beneficial for As immobilization in the solid residue, as confirmed by the achievement of much lower leachate As（0.9 μg/L-0.487 mg/L）than the US EPA regulatory limit（5 mg/L）. Finally, PFS is superior to FS because of its lower dose, much lower solid residue, and lower cost for As-safe drinking water.

The gangue preparation coagulant （PFASS） experiment research and application

In order to design a new technological process system to take the polymeric ferric aluminum silicate sulfate（PFASS） and to apply it in wastewater processing, the chemical composition analysis was carried on to the Fuxin gangue, adopted the orthogonal experiment method to obtain optimum response condition of with the acid pickling taking the aluminum in the gangue and with alkali extracting taking the silicon in the gangue, The experiments indicate that the sample chemistry content which tests elect completely conform to the preparation inorganic polymer water treatment coagulant request standard. Used the polymeric ferric aluminum silicate sulfate results in which with the system take as the coagulant of treatment wastewater, used the mercerizing degree, the wastewater pH value, the coagulation time, the coagulant throws increment factors and so on to test and verify its influence on the waste water processing. The result indicates that by using this craft production PFASS in waste water processing, after the processed waste water achieves the emission standard, the processing effect is good.

Synthesis of Z and E-(2',5'-dimethoxyphenyl)-methylene-butyrolactones

A pair of Z and E isomers of cyclization of γ-ketoacid 7, which was prepared in six steps from 2,5-dimethoxyphenyl acetic acid 1, gave a pair of Z(20%) and E (4%) isomers of (2,5-dimethoxyphenyl)-methylene-butyrolactones

Effects ofiron and temperature on solubility of light rare earth sulfates in multicomponent system of Fe2(SO4)3-H3PO4-H2SO4 synthetic solution

Numerous light rare earth elements(LREE)minerals containing Fe and P were processed by sulfuric acid roasting method,and the leaching solution mainly comprises LREE sulfate,Fe2(SO4)3,H3PO4,and H2SO4,however,the solubility data of LREE sulfates in this system is few.This work studies the solubility of LREE sulfates in independent LREE sulfate system RE2(SO4)3-Fe2(SO4)3-H3 PO4-H2SO4(RE=La,Ce,Pr or Nd)and mixed LREE sulfates system(La,Ce,Pr,Nd)2(SO4)3-Fe2(SO4)3-H3 PO4-H2SO4 at different temperature(25-65℃)and concentrations of Fe2(SO4)3(Fe2 O3,0-50.13 g/L),H2SO4(0.5 mol/L),and H3 PO4(P2 O5,20.34 g/L)based on the industrial operating condition at low liquid and solid ratio 2:1.The solubility of each LREE sulfate in the independent system(La2 O3,12.25-20.88 g/L;CeO2,41.93-62.35 g/L;Pr6 O11,37.34-56.69 g/L;Nd2 O3,26.60-37.63 g/L)is much higher than that of the mixed system(La2 O3,6.95-11.03 g/L;CeO2,10.63-21.51 g/L;Pr6 O11,11.56-20.36 g/L;Nd2 O3,12.36-19.79 g/L)under the same other conditions.The results also indicate that,in the two systems,both Fe and the temperature have negative effects on the solubility of LREE sulfates.That may occur due to the complication reactions between the complexes of RESO4+and Fe(SO4)2-.However,the influence degree of temperature and iron concentration on the LREE sulfates solubility varies in the two systems and among different LREE species.This research is of theoretical significance for optimizing the conditions of the sulfuric acid process for recovering the LREE from the mixed LREE bearing minerals as well as the single LREE containing secondary rare earth scraps.

Rice productivity and profitability with slow-release urea containing organic-inorganic matrix materials

Applying slow-release fertilizers is possible means for reducing nitrogen(N) loss in rice production. Matrix-based fertilizers represent novel slow-release fertilizers. To date, there is little consensus about the effect of combined addition of organic and inorganic matrix materials on rice production. We developed a slow-release urea fertilizer with selected organic and inorganic matrix materials. The study aimed to: i) determine the effect of the slow-release urea on rice yield, profit, and agronomic efficiency and ii) elucidate its possible mechanisms. A two-year field experiment was conducted during 2015–2016. Besides,laboratory experiments were conducted to determine the potential N loss risk. Three treatments were set up: control without N application(CK), regular urea treatment(RU, 150 kg N ha^(-1)), and slow-release urea treatment(SU, 150 kg N ha^(-1)). The results showed that rice biomass and grain yield were significantly higher in SU than in RU(P < 0.05). The higher panicle density in SU was largely responsible for the greater grain yield. Net profit in SU was US$450 ha^(-1), higher than in RU. Agronomic efficiency was significantly greater in SU than in RU(P < 0.05). Rice height, root area, leaf chlorophyll, leaf nitrate reductase activity, and leaf glutamine synthetase activity were larger in SU than in RU. Less N loss and greater soil N availability were partly responsible for the improvements in rice growth traits and physiological parameters in SU. Overall, the slow-release urea is a promising fertilizer for rice production.