The title compound （C22H22N2O2Fe·CH3OH） was synthesized via a one-pot procedure from ferrocenylaldehyde, malononitrile and 5,5-dimethyl-1,3-cyclohexanedione using room temperature ionic liquid and pyridine as t...The title compound （C22H22N2O2Fe·CH3OH） was synthesized via a one-pot procedure from ferrocenylaldehyde, malononitrile and 5,5-dimethyl-1,3-cyclohexanedione using room temperature ionic liquid and pyridine as the catalysts, and characterized by elemental analysis, IR and ^1H NMR. The structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic system, space group P21/n, with a = 9.7085（15）, b = 22.951（4）, c = 9.987（2） A, β = 112.494（3）°, V = 2055.9（6）A^3 Z = 4, Mr= 402.28, De= 1.403 g/cm^3, p = 0.759 mm^-1, F（000） = 868, the final R = 0.0536 and wR = 0.1449 for 4202 observed reflections with I 〉 2σ（I）. The supramolecular single-helix chain of the title compound is formed by linking the building units with the hydrogen bond between N1 and N2. The adjacent chains are connected to a 2D layer by the hydrogen bond between N1 and O1. The adjacent layers are further linked by van der waals＇ force. The CH3OH molecule is trapped in the interlayer.展开更多
基金the National Natural Science Foundation of China (No. 20572057) Natural Science Foundation of Shandong Province (Y2006B11)
文摘The title compound （C22H22N2O2Fe·CH3OH） was synthesized via a one-pot procedure from ferrocenylaldehyde, malononitrile and 5,5-dimethyl-1,3-cyclohexanedione using room temperature ionic liquid and pyridine as the catalysts, and characterized by elemental analysis, IR and ^1H NMR. The structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic system, space group P21/n, with a = 9.7085（15）, b = 22.951（4）, c = 9.987（2） A, β = 112.494（3）°, V = 2055.9（6）A^3 Z = 4, Mr= 402.28, De= 1.403 g/cm^3, p = 0.759 mm^-1, F（000） = 868, the final R = 0.0536 and wR = 0.1449 for 4202 observed reflections with I 〉 2σ（I）. The supramolecular single-helix chain of the title compound is formed by linking the building units with the hydrogen bond between N1 and N2. The adjacent chains are connected to a 2D layer by the hydrogen bond between N1 and O1. The adjacent layers are further linked by van der waals＇ force. The CH3OH molecule is trapped in the interlayer.
