Domain switching is the main source of nonlinear characteristics in ferroelectrics. According to crystal plasticity theory, the domains and domain switching systems for perovskite- type structure ferro...Domain switching is the main source of nonlinear characteristics in ferroelectrics. According to crystal plasticity theory, the domains and domain switching systems for perovskite- type structure ferroelectrics are de?ned. Considering the traverse motion performance of domain wall, a rather simpli?ed form of evolution law about incremental of volume fraction during domain switching has been developed. The main factors, which exert an in?uence on domain switching, such as material parameters, domain wall motion history, kind of domain switching (180? or 90?) and volume fraction, could be addressed. The hysteresis loops of spontaneous electric polarization as a function of electric ?eld, the butter?y shaped strain versus electric ?eld curve and the platform relations between spontaneous polarization and stress, as well as the longitudinal strain and stress, are well simulated and discussed.展开更多
A simple phenomenological model is developed for describing the macroscopic constitutive response of ferroelectric materials based on consideration of the fact that domain switching is a progressive evolution process ...A simple phenomenological model is developed for describing the macroscopic constitutive response of ferroelectric materials based on consideration of the fact that domain switching is a progressive evolution process with loading. The volume fraction of domain switching is taken as an internal variable, which is derived from the domain nucleation theory. The proposed theory can simulate the dielectric hysteresis, reversed butterfly hysteresis, nonlinear strain-stress hysteresis, as well as electric displacement-stress relation of ferroelectric materials. Its compaxison with experimental results and two other theoretical models reveals that the model presented can well predict the nonlinear hysteresis of ferroelectrics under electrical or mechanical loading.展开更多
文摘Domain switching is the main source of nonlinear characteristics in ferroelectrics. According to crystal plasticity theory, the domains and domain switching systems for perovskite- type structure ferroelectrics are de?ned. Considering the traverse motion performance of domain wall, a rather simpli?ed form of evolution law about incremental of volume fraction during domain switching has been developed. The main factors, which exert an in?uence on domain switching, such as material parameters, domain wall motion history, kind of domain switching (180? or 90?) and volume fraction, could be addressed. The hysteresis loops of spontaneous electric polarization as a function of electric ?eld, the butter?y shaped strain versus electric ?eld curve and the platform relations between spontaneous polarization and stress, as well as the longitudinal strain and stress, are well simulated and discussed.
基金Project supported by the National Natural Science Foundation of China (Nos.90205022 and 10572067)the Ministry of Education of China (No.SRFDP 20030003064)
文摘A simple phenomenological model is developed for describing the macroscopic constitutive response of ferroelectric materials based on consideration of the fact that domain switching is a progressive evolution process with loading. The volume fraction of domain switching is taken as an internal variable, which is derived from the domain nucleation theory. The proposed theory can simulate the dielectric hysteresis, reversed butterfly hysteresis, nonlinear strain-stress hysteresis, as well as electric displacement-stress relation of ferroelectric materials. Its compaxison with experimental results and two other theoretical models reveals that the model presented can well predict the nonlinear hysteresis of ferroelectrics under electrical or mechanical loading.
