Heterojunctions between polyaniline (PANI) and n-type porous silicon (PS), Al/PS-PANI/Au cell, were fabricated, and the rectifying parameters of this heterojunction diode were measured as a function of the preparation...Heterojunctions between polyaniline (PANI) and n-type porous silicon (PS), Al/PS-PANI/Au cell, were fabricated, and the rectifying parameters of this heterojunction diode were measured as a function of the preparation conditions of PANI and PS, the electronic structure of PANI as well as cell structure. The rectifying parameters of Al/PS-PANI/Au cell were determined to be gamma = 1.8x10(1) similar to 1.0x10(5) for the rectifying ratio at 3V, n = 3 similar to 12 for the ideal factor, j(0) = 8.0x10(-5) similar to 5.6x10(-2) mA/cm(2) for the reversed saturated current density, and phi(0) = 0.67 similar to 0.83 V for the barrier height, respectively. The best rectifying heterojunction diode made between PANI and n-type PS with higher rectifying factor (gamma = 1.0x10(5) at 3V), output current (>1500 mA/cm(2) at 3V) and lower ideal factor (n = 3.3) was obtained by preventing the oxidation of PS before evaporating Al electrode.展开更多
Excellent antibacterial performance of polyaniline （PAni） against Escherichia coli and Gram-positive Staphylococcus aureus microorganisms has been demonstrated under both dark and visible light conditions. The elect...Excellent antibacterial performance of polyaniline （PAni） against Escherichia coli and Gram-positive Staphylococcus aureus microorganisms has been demonstrated under both dark and visible light conditions. The electrostatic adherence between the PAni molecules and the bacteria may play a very important role for the antibacterial reaction of the PAni. As a result of our investigation, conducting PAni and its composites/blends are believed to be useful as a new type of antibacterial agent, self-clean as well as multifunctional material for improving the human health and living environment.展开更多
Polyaniline/silver (PANI/Ag) nanocomposite was prepared by chemical oxidative polymerization of aniline monomer in the presence of nitric acid. The formation of PANI/Ag nanocomposite was characterized by XRD, FTIR, TE...Polyaniline/silver (PANI/Ag) nanocomposite was prepared by chemical oxidative polymerization of aniline monomer in the presence of nitric acid. The formation of PANI/Ag nanocomposite was characterized by XRD, FTIR, TEM, UV-vis spectroscopy. The XRD patterns indicated that the crystalline phase of Ag is cubic with crystallite size of 93 nm. The TEM image shows that the Ag nanoparticles are well dispersed in the polyaniline matrix. Optical measurements show that the value of optical band gap of nanocomposite is lower than that of pure PANI. The DC-, AC-conductivities, dielectric permittivity (ε') and dielectric loss (ε'') of (PANI/Ag) nanocomposite and pure PANI have been measured in the temperature range from 303 to 723 K and frequency range from 10 to 103 kHz. The electrical conductivity of the (PANI/Ag) nanocomposite is higher than pure PANI. Temperature variation of frequency exponents in this blend suggests that AC-conductivity is attributed to correlated barrier hopping mechanism. At all frequencies, the ε' value for (PANI/Ag) nanocomposite is higher than that for pure one. The higher dielectric constant of the PANI/Ag nanocomposite indicates their better ability to store electric potential energy under the influence of alternative electric field.展开更多
Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel ...Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel adsorbent exhibited a high adsorption capacity of 298.5 mg·g-1 for Cr(Ⅵ)(318 K,pH=2.0).Meanwhile,the adsorption process can be fitted well with the pseudo-second-order model and the Freundlich model.Moreover,the Cr(Ⅵ)removal efficiency of the adsorbent remained above 85%after ten recycling experiments,indicating that PANI/CNF aerogel had excellent stability and reusability.Therefore,PANI/CNF aerogel showed a potential application in the treatment of chromium-containing wastewater.展开更多
An insulate to metal transition was investigated based on the measurements of the dependence of the conductivity, activation energy on the protonation state of polyaniline (PANI). An isotropy in conductivity for stret...An insulate to metal transition was investigated based on the measurements of the dependence of the conductivity, activation energy on the protonation state of polyaniline (PANI). An isotropy in conductivity for stretched salt form of PANI was observed.For salt film of PANI, the Ⅰ-Ⅴ curve obeys Ohm's law, which shows a typical metal behavior, however, for base film or film with low protonation state, it can be explained by Space Charge Limited Current (SCLC). It is also found that the Ⅰ-Ⅴ curve of base film of PANI is independent of the work function of electrodes and the polymerization temperature.展开更多
基金The project was supported by the Foundation of Chinese Academy of Sciences.
文摘Heterojunctions between polyaniline (PANI) and n-type porous silicon (PS), Al/PS-PANI/Au cell, were fabricated, and the rectifying parameters of this heterojunction diode were measured as a function of the preparation conditions of PANI and PS, the electronic structure of PANI as well as cell structure. The rectifying parameters of Al/PS-PANI/Au cell were determined to be gamma = 1.8x10(1) similar to 1.0x10(5) for the rectifying ratio at 3V, n = 3 similar to 12 for the ideal factor, j(0) = 8.0x10(-5) similar to 5.6x10(-2) mA/cm(2) for the reversed saturated current density, and phi(0) = 0.67 similar to 0.83 V for the barrier height, respectively. The best rectifying heterojunction diode made between PANI and n-type PS with higher rectifying factor (gamma = 1.0x10(5) at 3V), output current (>1500 mA/cm(2) at 3V) and lower ideal factor (n = 3.3) was obtained by preventing the oxidation of PS before evaporating Al electrode.
文摘Excellent antibacterial performance of polyaniline （PAni） against Escherichia coli and Gram-positive Staphylococcus aureus microorganisms has been demonstrated under both dark and visible light conditions. The electrostatic adherence between the PAni molecules and the bacteria may play a very important role for the antibacterial reaction of the PAni. As a result of our investigation, conducting PAni and its composites/blends are believed to be useful as a new type of antibacterial agent, self-clean as well as multifunctional material for improving the human health and living environment.
文摘Polyaniline/silver (PANI/Ag) nanocomposite was prepared by chemical oxidative polymerization of aniline monomer in the presence of nitric acid. The formation of PANI/Ag nanocomposite was characterized by XRD, FTIR, TEM, UV-vis spectroscopy. The XRD patterns indicated that the crystalline phase of Ag is cubic with crystallite size of 93 nm. The TEM image shows that the Ag nanoparticles are well dispersed in the polyaniline matrix. Optical measurements show that the value of optical band gap of nanocomposite is lower than that of pure PANI. The DC-, AC-conductivities, dielectric permittivity (ε') and dielectric loss (ε'') of (PANI/Ag) nanocomposite and pure PANI have been measured in the temperature range from 303 to 723 K and frequency range from 10 to 103 kHz. The electrical conductivity of the (PANI/Ag) nanocomposite is higher than pure PANI. Temperature variation of frequency exponents in this blend suggests that AC-conductivity is attributed to correlated barrier hopping mechanism. At all frequencies, the ε' value for (PANI/Ag) nanocomposite is higher than that for pure one. The higher dielectric constant of the PANI/Ag nanocomposite indicates their better ability to store electric potential energy under the influence of alternative electric field.
基金National Natural Science Foundation of China(Nos.52073046,51873036,and 51673039)Fundamental Research Funds for the Central Universities,China(Nos.2232020D-08 and 2232019A3-01)+3 种基金Natural Science Foundation of Shanghai,China(No.19ZR1470900)Shanghai Shuguang Program,China(No.19SG28)International Joint Laboratory for Advanced Fiber and Low-Dimension Materials,China(No.18520750400)Initial Research Funds for Young Teachers of Donghua University,China(No.106-07-0053089)。
文摘Aerogel composed of polyaniline/cellulose nanofiber(PANI/CNF)was synthesized by a two-step method and used as an adsorbent to remove Cr(Ⅵ)from wastewater in this study.Adsorption results showed that PANI/CNF aerogel adsorbent exhibited a high adsorption capacity of 298.5 mg·g-1 for Cr(Ⅵ)(318 K,pH=2.0).Meanwhile,the adsorption process can be fitted well with the pseudo-second-order model and the Freundlich model.Moreover,the Cr(Ⅵ)removal efficiency of the adsorbent remained above 85%after ten recycling experiments,indicating that PANI/CNF aerogel had excellent stability and reusability.Therefore,PANI/CNF aerogel showed a potential application in the treatment of chromium-containing wastewater.
文摘An insulate to metal transition was investigated based on the measurements of the dependence of the conductivity, activation energy on the protonation state of polyaniline (PANI). An isotropy in conductivity for stretched salt form of PANI was observed.For salt film of PANI, the Ⅰ-Ⅴ curve obeys Ohm's law, which shows a typical metal behavior, however, for base film or film with low protonation state, it can be explained by Space Charge Limited Current (SCLC). It is also found that the Ⅰ-Ⅴ curve of base film of PANI is independent of the work function of electrodes and the polymerization temperature.
