ZnO nanorod arrays with tunable size and field emission properties on an ITO substrate achieved by an electrodeposition method

In the present work, vertically aligned ZnO nanorod arrays with tunable size are successfully synthesized on nonseeded ITO glass substrates by a simple electrodeposition method. The effect of growth conditions on the phase, morphology, and orientation of the products are studied in detail by X-ray diffraction （XRD）, scanning electron mi-croscopy （SEM）, and transmission electron microscopy （TEM）. It is observed that the as-prepared nanostructures exhibit a preferred orientation along c axis, and the size and density of the ZnO nanorod can be controlled by changing the concentration of ZnC12. Field emission properties of the as-synthesized samples with different diameters are also studied, and the results show that the nanorod arrays with a smaller diameter and appropriate rod density exhibit better emission properties. The ZnO nanorod arrays show a potential application in field emitters.

Phase Transformation and Enhancing Electron Field Emission Properties in Microcrystalline Diamond Films Induced by Cu Ion Implantation and Rapid Annealing

Cu ion implantation and subsequent rapid annealing at 500℃ in N2 result in low surface resistivity of 1.611 ohm/sq with high mobility of 290 cm2 V-1S-1 for microcrystalline diamond （MCD） films. Its electrical field emission behavior can be turned on at Eo = 2.6 V/μm, attaining a current density of 19.5μA/cm2 at an applied field of 3.5 V/#m. Field emission scanning electron microscopy combined with Raman and x-ray photoelectron mi- croscopy reveal that the formation of Cu nanoparticles in MCD films can catalytically convert the less conducting disorder/a-C phases into graphitic phases and can provoke the formation of nanographite in the films, forming conduction channels for electron transportation.

Comparison of corneal biomechanical properties in normal tension glaucoma patients with different visual field progression speed

AIM：To compare the corneal biomechanical properties difference by ocular response analyzer（ORA） in normal tension glaucoma（NTG） patients with different visual field（VF） progression speed. METHODS：NTG patients with well-controlled Goldmann applanation tonometer（GAT） who routinely consulted Kitasato University Hospital Glaucoma Department between January 2010 and February 2014 were enrolled.GAT and ORA parameters including corneal compensated intraocular pressure（lOPcc）,Goldmann estimated intraocular pressure（lOPg）,corneal hysteresis（CH）,corneal resistance factor（CRF） were recorded.VF was tested by Swedish interactive threshold algorithm（SITA）-standard 30-2 fields.All patients underwent VF measurement regularly and GAT did not exceed 15 mm Hg at any time during the 3y follow up.Patients were divided into four groups according to VF change over 3y,and ORA findings were compared between the upper 25th percentile group（slow progression group） and the lower 25th percentile group（rapid progression group）.RESULTS：Eighty-two eyes of 56 patients were studied.There were 21 eyes（21 patients） each in rapid and slow progression groups respectively.GAT,lOPcc,lOPg,CH,CRF were 12.1＋1.4 mm Hg,15.8±1.8 mm Hg,12.8±2.0 mm Hg,8.4±1.1 mm Hg,7.9±1.3 mm Hg respectively in rapid progression group and 11.5±1.3 mm Hg,13.5±2.1 mm Hg,11.2±1.6 mm Hg,9.3±1.1 mm Hg,8.2±0.9 mm Hg respectively in slow progression group（P=0.214,〈0.001,0.007,0.017,0.413,respectively）.In bivariate correlation analysis,lOPcc,lOPcc-GAT and CH were significant correlated with m△MD（r =-0.292,-0.312,0.228 respectively,P =0.008,0.004,0.039 respectively）.CONCLUSION：Relatively rapid VF progression occurred in NTG patients whose lOPcc are rather high,CH are rather low and the difference between lOPcc and GAT are relatively large.Higher lOPcc and lower CH are associated with VF progression in NTG patients.This study suggests that GAT measures might underestimate the IOP in such patients.

Tuning field emission properties of boron nanocones with catalyst concentration

Single crystalline boron nanocones are prepared by using a simple spin spread method in which Fe3O4 nanoparticles are pre-manipulated on Si（lll） to form catalyst patterns of different densities. The density of boron nanocones can be tuned by changing the concentration of catalyst nanoparticles. High-resolution transmission electron microscopy analysis shows that the boron nanocone has a β-tetragonal structure with good crystallization. The field emission behaviour is optimal when the spacing distance is close to the nanocone length, which indicates that this simple spin spread method has great potential applications in electron emission nanodevices.

Effect of metal nanoparticle doping concentration on surface morphology and field emission properties of nano-diamond films

Nano-diamond particles are co-deposited on Ti substrates with metal(Ti/Ni) nanoparticles(NPs) by the electrophoretic deposition(EPD) method combined with a furnace annealing at 800℃ under N_(2) atmosphere. Modifications of structural and electron field emission(EFE) properties of the metal-doped films are investigated with different metal NPs concentrations. Our results show that the surface characteristics and EFE performances of the samples are first enhanced and then reduced with metal NPs concentration increasing. Both the Ti-doped and Ni-doped nano-diamond composite films exhibit optimal EFE and microstructural performances when the doping quantity is 5 mg. Remarkably enhanced EFE properties with a low turn-on field of 1.38 V/μm and a high current density of 1.32 mA/cm^(2) at an applied field of 2.94 V/μm are achieved for Ni-doped nano-diamond films, and are superior to those for Ti-doped ones. The enhancement of the EFE properties for the Ti-doped films results from the formation of the TiC-network after annealing. However, the doping of electron-rich Ni NPs and formation of high conductive graphitic phase are considered to be the factor, which results in marvelous EFE properties for these Ni-doped nano-diamond films.

Preparation of patterned boron nanowire films with different widths of unit-cell and their field emission properties

Large-area patterned films of boron nanowires（BNWs） are fabricated at various densities by chemical vapor deposition（CVD）. Different widths of unit-cell of Mo masks are used as templates. The widths of unit-cell of Mo masks are100 μm, 150 μm, and 200 μm, respectively. The distance between unit cells is 50 μm. The BNWs have an average diameter of about 20 nm and lengths of 10 μm–20 μm. High-resolution transmission electron microscopy analysis shows that each nanowire has a β-tetragonal structure with good crystallization. Field emission measurements of the BNW films show that their turn-on electric fields decrease with width of unit-cell increasing.

Preparation of few-layer graphene-capped boron nanowires and their field emission properties

Large-area boron nanowire（BNW） films were fabricated on the Si（111） substrate by chemical vapor deposition（CVD）. The average diameter of the BNWs is about 20 nm, with lengths of 5–10 μm. Then, graphene-capped boron nanowires（GC-BNWs） were obtained by microwave plasma chemical vapor deposition（MPCVD）. Characterization by scanning electron microscopy indicates that few-layer graphene covers the surface of the boron nanowires. Field emission measurements of the BNWs and GC-BNW films show that the GC-BNW films have a lower turn-on electric field than the BNW films.

Field Emission Properties of Nano-DLC Films Prepared on Cu Substrates by Pulsed Laser Deposition

Nano-diamond like carbon（DLC） thin films were prepared on fused silica and Cu substrates by the pulsed-laser deposition technique with different laser intensities. Step-measurement, atomic force microscope（AFM）, UV-VIS-NIR transmittance spectroscopy and Raman spectroscopy were used to characterize the films. It was shown that the deposition rate increases with the laser intensity, and the films prepared under different laser intensities show different transparency. Raman measurement showed that the content of sp^3 of the Nano-DLC thin films decreases with the laser intensity. The field emission properties of the Nano-DLC thin films on Cu substrates were studied by the conventional diode method, which showed that the turn-on field increases and the current density decreases with sp^3 content in the films. A lower turn-on field of 6 V/um and a higher current density of 1 uA/cm^2 were obtained for Nano-DLC thin films on Cu substrate.

SOME PROPERTIES OF FAR FIELD PATTERNS OF ACOUSTIC WAVES IN AN INHOMOGENEOUS MEDIUM

In this paper, by using functional analysis and integral equation method, we obtain some results about the properties of far field of acoustic waves in an inhomogeneous medium. And we also discuss some ill-posed inverse scattering problems by Tikhonov regularization method.

Effective Field Theory Techniques Applied to the Properties of the Axion

We utilize the effective field theory approach to study the properties of the axion. In particular, with s as well as u and d quarks regarded to be relatively light we derive a formula for the mass of the axion; a rough estimate of the rate for its dominant decay mode at low energy is also carried out.

Influence of the gassing materials on the dielectric properties of air

Influence of the gassing materials, such as PA6, PMMA, and POM on the dielectric properties of air are investigated. In this work, the fundamental electron collision cross section data were carefully selected and validated. Then the species compositions of the air–organic vapor mixtures were calculated based on the Gibbs free energy minimization. Finally, the Townsend ionization coefficient, the Townsend electron attachment coefficient and the critical reduced electric field strength were derived from the calculated electron energy distribution function by solving the Boltzmann transport equation. The calculation results indicated that H;O with large attachment cross sections has a great impact on the critical reduced electric field strength of the air–organic vapor mixtures. On the other hand, the vaporization of gassing materials can help to increase the dielectric properties of air circuit breakers to some degree.

Effects of vertical electric field and compressive strain on electronic properties of bilayer ZrS2

Using first-principles calculations,including Grimme D2 method for van der Waals interactions,we investigate the tuning electronic properties of bilayer zirconium disulfides（ZrS_2/ subjected to vertical electric field and normal compressive strain.The band gap of ZrS_2 bilayer can be flexibly tuned by vertical external electric field.Due to the Stark effect,at critical electric fields about 1.4 V/？,semiconducting-metallic transition presents.In addition,our results also demonstrated that the compressive strain has an important impact on the electronic properties of ZrS_2 bilayer sheet.The widely tunable band gaps confirm possibilities for its applications in electronics and optoelectronics.

STATISTIC PROPERTIES OF NOISE FIELD OF MOVING SOURCE IN SHALLOW WATER AND ITS EFFECTS ON SIGNAL PROCESSING FOR THE NOISE RANGING SONAR

In this paper the properties of space- time correlation function of the noise field of moving source in layered statistic inhomogeneous medium are studied and the effects of random fluctuating boundary are considered as well.It has been shown, theoretically and experimentally, multi-path propergating effects cause the dispersion of the correlation function and fluctuations of the medium refraction index and the boundary cause the fluctuation of it.The effect of the movement of the noise source on the output of real- time correlator is equivalent to a low- pass filter added the drift of space- time correlation function.These properties of the correlation function cause grave degradation of the signal processing gain of noise ranging sonar system.The fluctuating and the distortion of conrrelation function made it difficult to realize the noise ranging.So in this paper, a method of space correlation ranging by a linear array of four points with short separation and long span and a technigue of dual- correlation signal processing are presented. By this, the influences of previously mentioned factors are greatly overcomed.Futhermore, for the long period and great delay fluctuation of the dual- correlation function output caused by internal wave, a method of limited memory Quasi- Kalman filtering is developed and the effective accurate ranging and tracing of noise ranging sonar are able to be tralized finally.

The Explanation for the Origin of the Higgs Scalar and for the Yukawa Couplings by the Spin-Charge-Family Theory

The spin-charge-family theory is a kind of the Kaluza-Klein theories, but with two kinds of the spin connection fields, which are the gauge fields of the two kinds of spins. The SO(13,1) representation of one kind of spins manifests in d = (3 + 1) all the properties of family members as assumed by the standard model;the second kind of spins explains the appearance of families. The gauge fields of the first kind, carrying the space index m = (0,...,3), manifest in d = (3 + 1) all the vector gauge fields assumed by the standard model. The gauge fields of both kinds of spins, which carry the space index (7, 8) gaining at the electroweak break nonzero vacuum expectation values, manifest in d = (3 + 1) as scalar fields with the properties of the Higgs scalar of the standard model with respect to the weak and the hyper charge ( and , respectively), while they carry additional quantum numbers in adjoint representations, offering correspondingly the explanation for the scalar Higgs and the Yukawa couplings, predicting the fourth family and the existence of several scalar fields. The paper 1) explains why in this theory the gauge fields are with the scalar index s = (5,6,7,8) doublets with respect to the weak and the hyper charge, while they are with respect to all the other charges in the adjoint representations;2) demonstrates that the spin connection fields manifest as the Kaluza-Klein vector gauge fields, which arise from the vielbeins;and 3) explains the role of the vielbeins and of both kinds of the spin connection fields.

The Spin-Charge-Family Theory Is Explaining the Origin of Families,of the Higgs and the Yukawa Couplings

The (extremely efficient) standard model of the elementary particles and fields makes several assumptions, which call for explanations. Any theory offering next step beyond the standard model must explain at least the existence and properties of families and their members and correspondingly the existence of the scalar Higgs and the Yukawa couplings, which in this model take care of masses of fermions and weak bosons and influence the decaying properties of families. The spin-charge-family theory [1-11] is offering a possible explanation for the assumptions of the standard model—for the appearance of families and their members (for the charges of a family members), for the gauge fields, for the scalar fields—interpreting the standard model as its low energy effective manifestation. The spin-charge-family theory predicts at the low energy regime two decoupled groups of four families of quarks and leptons. The predicted fourth family waits to be observed, while the stable fifth family is the candidate to form the dark matter. In this paper properties of families are analysed. The appearance of several scalar fields, all in the bosonic (adjoint) representations with respect to the family groups, while they are doublets with respect to the weak charge, is presented, their properties discussed, it is explained how these scalar fields can effectively be interpreted as the standard model Higgs and the Yukawa couplings. The spin-charge-family theory predicts that there are no supersymmetric partners of the observed fermions and bosons.

Solvent Property Induced Morphological Changes of ABA Amphiphilic Triblock Copolymer Micelles in Dilute Solution: A Self-consistent Field Simulation Study

The morphological changes of ABA amphiphilic triblock copolymer micelles in dilute solution were systematically studied by tuning the solvent property using self-consistent field simulation. The solvent property was tuned by changing the Flory-Huggins interaction parameters between each type of blocks and solvent, respectively. The simulation results show that by changing the solvent properties, a series of micelle morphologies such as vesicle, cage-like, ring-shaped, rod-like and spherical micelle morphologies can be obtained. Variations of the free energy of the solution system and the surface area of micelles with the Flory-Huggins interaction parameters were calculated to better understand the effect of solvent property on micelle morphologies. In addition, a phase diagram showing the morphological changes of micelles with the Flory-Huggins interaction parameters is provided.

Effect of niobium substitution on microstructures and thermal stability of TbCu7-type Sm-Fe-N magnets

This paper reports crystal structures, magnetic properties and thermal stability of TbCu7-type Sm（8.5）Fe（（85.8-x）Co（4.5）Zr（1.2）Nbx（x = 0-1.8） melt-spun compounds and their nitrides, investigated by means of X-ray diffraction, vibrating sample magnetometer, flux meter and transmission electron microscope. It is found that the lattice parameter ratio c/a of TbCu7-type crystal structure increases with Nb substitution, which indicates that the Nb can increase the stability of the metastable phase in the Sm-Fe ribbons. Nb substitution impedes the formation of magnetic soft phase a-Fe in which reversed domains initially form during the magnetization reversal process. Meanwhile, Nb substitution refines grains and leads to homogeneous micro structure with augmented grain boundaries. Thus the exchange coupling pining field is enhanced and irreversible domain wall propagation gets suppressed. As a result, the magnetic properties are improved and the irreversible flux loss of magnets is notably decreased. A maximum value 771.7 kA/m of the intrinsic coercivity H（cj） is achieved in the 1.2 at% substituted samples.The irreversible flux loss for 2 h exposure at 120 ℃ declines from 8.26% for Nb-free magnets to 6.32% for magnets with 1.2 at% Nb substitution.