The stochastic cracking and healing behaviors of reaction-diffusion growth of thin filmswere studied by means of Markov processes analysis. We chose the thermal growth ofoxide scales on metals as an example of reactio...The stochastic cracking and healing behaviors of reaction-diffusion growth of thin filmswere studied by means of Markov processes analysis. We chose the thermal growth ofoxide scales on metals as an example of reaction-diffusion growth. The thermal growthof oxide films follows power law when no cracking occurs. Our results showed that thegrowth kinetics under stochastic cracking and healing conditions was different fromthat without cracking. It might be altered to either pseudo-linear or pseudo-power lawsdependent upon the intensity and frequency of the cracking of the films. When thehoping items dominated, the growth followed pseudo-linear law; when the diffusionalitems dominated, it followed pseudo-power law with the exponentials lower than theintrinsical values. The numerical results were in good agreement with the meassuredkinetics of isothermal and cyclic oxidation of NiAl-0.1 Y (at. %) alloys in air at 1273K.展开更多
A Molecular Dynamics (MD) simulation with Tersoff empirical many-bodypotential has been employed to investigate the growth processes of diamond film with energeticspecies deposition. In the present study, we have stud...A Molecular Dynamics (MD) simulation with Tersoff empirical many-bodypotential has been employed to investigate the growth processes of diamond film with energeticspecies deposition. In the present study, we have studied the reaction probabilities of energeticspecies with energies of 0.1 e V to 10eV at the substrate temperature of 1100K. In the cases of thediamond growth on the surface with H passivation, the reaction probability of hydrocarbon speciesconsiderably increases when the species energy is higher than 2eV. This means that the diamond filmcan grow in the case of high incident species energy without the process of hydrogen abstraction,which is needed in the case of incident species with low energy. The reaction mechanism of energeticspecies on hydrogen passivated diamond surface is also discussed.展开更多
The reactive spread behaviour of Cu particles on the surJace of Al has been studied.The role of oxide film and the .formation mechanism of the joint during Al/Cu contacting reaction brazing have been discussed.
The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement an...The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement and infrared spectroscopy. The friction-reducing behavior of the prepared films was examined on a static-dynamic friction coefficient measurement apparatus and on an atomic force microscope. It was found that all the reacted films on the Si substrate showed good friction-reducing ability; especially, the film of the octadecene exhibited the best friction-reducing ability. This was attributed to the transfer of the reacted films onto the counter face with formation of a transfer film on the counterpart surface, which led to the transformation of the sliding between the reacted films and the hard ceramic to fiat between the reacted films and its transfer film on the counterpart surface. The macroscopic and microscopic friction behaviors of the prepared films were dependent on their molecular chain lengths. Thus the octadecene reacted film with the highest degree of ordering arrangement showed the best friction-reducing and antiwear abilities in sliding against Si3N4.展开更多
1.IntroductionRecently,progress of vapour phasegrowth of diamond fihn under non-equilib-rium reaction condition has shown theprospect of its commercial production in re-spect of effectiveness and economy.Theprocess pr...1.IntroductionRecently,progress of vapour phasegrowth of diamond fihn under non-equilib-rium reaction condition has shown theprospect of its commercial production in re-spect of effectiveness and economy.Theprocess proceeds in the thermodynamical展开更多
Hydrogen distribution and content in diamond films deposited by DC arcjetunder gas recycling mode was evaluated by nuclear reaction analysis (NRA). The films werecharacterized using scanning electron microscopy, X-ray...Hydrogen distribution and content in diamond films deposited by DC arcjetunder gas recycling mode was evaluated by nuclear reaction analysis (NRA). The films werecharacterized using scanning electron microscopy, X-ray diffraction and Raman spectrometry. The NRAresults show that the hydrogen content in diamond films was approximately 0.6% (substratetemperature 770℃), and strongly depended on the substrate temperature. It was that the hydrogencontent increased with the increase of the substrate temperature. The possibility of hydrogentrapping in the films was also discussed.展开更多
By a method of hybrid physical-chemical vapour deposition （HPCVD） on three metal substrates of stainless steel, copper and niobium, we deposit MgB2 superconducting films over 1 μm thickness. All of them have zero r...By a method of hybrid physical-chemical vapour deposition （HPCVD） on three metal substrates of stainless steel, copper and niobium, we deposit MgB2 superconducting films over 1 μm thickness. All of them have zero resistance temperatures To（O） 〉 36 K and critical current densities Jc （IOK, OT） 〉106 A/cm^2. Meanwhile, in the bending test, all the MgB2 superconducting films adhere strongly to the metal substrates without peeling off. Therefore, the MgB2 superconducting films supplied by the HPCVD method exhibit preferable electrical, magnetic and mechanical properties, and have potential applications in future.展开更多
Lanthanum-rhodamine (6G and B) complexes were synthesized by Rheological Phase Reaction Method. Lanthanum-rhodamine (6G and B) complexes doped polyethylene films which have a function of lights-conversion were prepare...Lanthanum-rhodamine (6G and B) complexes were synthesized by Rheological Phase Reaction Method. Lanthanum-rhodamine (6G and B) complexes doped polyethylene films which have a function of lights-conversion were prepared. The emission and excitation spectra were measured. The experiments of growing seedling and culture were carried out in the shed built with doped and undoped polyethylene films. Lanthanum-rhodamine doped polyethylene films which have a function of lights-conversion can efficiently convert the green light in the sunlight to the red light for photosynthesis of crops, to promote the maturing of crops and raise the yield of crops.展开更多
The positron annihilation lifetimes and the Doppler broadening by slow positron beam are measured in thin Fe films with thickness 500 nm, a thin Hf film with thickness 100 nm, and the bilayer Fe (50 nm)/Hf (50 nm) on ...The positron annihilation lifetimes and the Doppler broadening by slow positron beam are measured in thin Fe films with thickness 500 nm, a thin Hf film with thickness 100 nm, and the bilayer Fe (50 nm)/Hf (50 nm) on quartz glass substrate. We have analyzed the behavior in vacancy-type defects in each layer through some deposition temperatures and annealing. It is observed that the thin Fe film, the thin Hf film, and the bilayer Fe (50 nm)/Hf (50 nm) already contain many vacancy-type defects. We have investigated the change of densities of the vacancy-carbon complex and the small vacancy-cluster with carbons, through solid-state amorphization of Fe (50 nm)/Hf (50 nm) bilayer.展开更多
A new method has been studied to obtain TiN-Ti(C,N)composite film by laser-induced re- action in order to modify the surface properties of substrate.An apparatus for this new technology has been developed.The main rea...A new method has been studied to obtain TiN-Ti(C,N)composite film by laser-induced re- action in order to modify the surface properties of substrate.An apparatus for this new technology has been developed.The main reaction,the influence of main processing parameters on the formation, composition,microstructure and properties of the film have been researched.The average hardness of the film is up to HK 2700-2800.The wear resist- ance of the film is higher than that of the substrate by a factor of 9-11;and the film has good adhesive strength with the substrate.展开更多
基金supported by Hundred-Talent Project of Chinese Academy of Sciencesby the National Natural Science Foundation of China for Young Scientist
文摘The stochastic cracking and healing behaviors of reaction-diffusion growth of thin filmswere studied by means of Markov processes analysis. We chose the thermal growth ofoxide scales on metals as an example of reaction-diffusion growth. The thermal growthof oxide films follows power law when no cracking occurs. Our results showed that thegrowth kinetics under stochastic cracking and healing conditions was different fromthat without cracking. It might be altered to either pseudo-linear or pseudo-power lawsdependent upon the intensity and frequency of the cracking of the films. When thehoping items dominated, the growth followed pseudo-linear law; when the diffusionalitems dominated, it followed pseudo-power law with the exponentials lower than theintrinsical values. The numerical results were in good agreement with the meassuredkinetics of isothermal and cyclic oxidation of NiAl-0.1 Y (at. %) alloys in air at 1273K.
基金This work is supported by the National Natural Science Foundation (Grant No. 10075009) Sino-France Advance Research Program (PRA)
文摘A Molecular Dynamics (MD) simulation with Tersoff empirical many-bodypotential has been employed to investigate the growth processes of diamond film with energeticspecies deposition. In the present study, we have studied the reaction probabilities of energeticspecies with energies of 0.1 e V to 10eV at the substrate temperature of 1100K. In the cases of thediamond growth on the surface with H passivation, the reaction probability of hydrocarbon speciesconsiderably increases when the species energy is higher than 2eV. This means that the diamond filmcan grow in the case of high incident species energy without the process of hydrogen abstraction,which is needed in the case of incident species with low energy. The reaction mechanism of energeticspecies on hydrogen passivated diamond surface is also discussed.
文摘The reactive spread behaviour of Cu particles on the surJace of Al has been studied.The role of oxide film and the .formation mechanism of the joint during Al/Cu contacting reaction brazing have been discussed.
基金National Natural Science Foundation of China(Grant No.50023001).
文摘The films of octadecene, dodecene, and undecenoic acid were prepared on H-terminated Si surface in the presence of ultraviolet irradiation. The resulted films were characterized with water-contact angle measurement and infrared spectroscopy. The friction-reducing behavior of the prepared films was examined on a static-dynamic friction coefficient measurement apparatus and on an atomic force microscope. It was found that all the reacted films on the Si substrate showed good friction-reducing ability; especially, the film of the octadecene exhibited the best friction-reducing ability. This was attributed to the transfer of the reacted films onto the counter face with formation of a transfer film on the counterpart surface, which led to the transformation of the sliding between the reacted films and the hard ceramic to fiat between the reacted films and its transfer film on the counterpart surface. The macroscopic and microscopic friction behaviors of the prepared films were dependent on their molecular chain lengths. Thus the octadecene reacted film with the highest degree of ordering arrangement showed the best friction-reducing and antiwear abilities in sliding against Si3N4.
文摘1.IntroductionRecently,progress of vapour phasegrowth of diamond fihn under non-equilib-rium reaction condition has shown theprospect of its commercial production in re-spect of effectiveness and economy.Theprocess proceeds in the thermodynamical
文摘Hydrogen distribution and content in diamond films deposited by DC arcjetunder gas recycling mode was evaluated by nuclear reaction analysis (NRA). The films werecharacterized using scanning electron microscopy, X-ray diffraction and Raman spectrometry. The NRAresults show that the hydrogen content in diamond films was approximately 0.6% (substratetemperature 770℃), and strongly depended on the substrate temperature. It was that the hydrogencontent increased with the increase of the substrate temperature. The possibility of hydrogentrapping in the films was also discussed.
基金Supported by the National Natural Science Foundation of China under Grant No 50572001, and the National Basic Research Programme of China under Grant No 2006CD601004.
文摘By a method of hybrid physical-chemical vapour deposition （HPCVD） on three metal substrates of stainless steel, copper and niobium, we deposit MgB2 superconducting films over 1 μm thickness. All of them have zero resistance temperatures To（O） 〉 36 K and critical current densities Jc （IOK, OT） 〉106 A/cm^2. Meanwhile, in the bending test, all the MgB2 superconducting films adhere strongly to the metal substrates without peeling off. Therefore, the MgB2 superconducting films supplied by the HPCVD method exhibit preferable electrical, magnetic and mechanical properties, and have potential applications in future.
文摘Lanthanum-rhodamine (6G and B) complexes were synthesized by Rheological Phase Reaction Method. Lanthanum-rhodamine (6G and B) complexes doped polyethylene films which have a function of lights-conversion were prepared. The emission and excitation spectra were measured. The experiments of growing seedling and culture were carried out in the shed built with doped and undoped polyethylene films. Lanthanum-rhodamine doped polyethylene films which have a function of lights-conversion can efficiently convert the green light in the sunlight to the red light for photosynthesis of crops, to promote the maturing of crops and raise the yield of crops.
文摘The positron annihilation lifetimes and the Doppler broadening by slow positron beam are measured in thin Fe films with thickness 500 nm, a thin Hf film with thickness 100 nm, and the bilayer Fe (50 nm)/Hf (50 nm) on quartz glass substrate. We have analyzed the behavior in vacancy-type defects in each layer through some deposition temperatures and annealing. It is observed that the thin Fe film, the thin Hf film, and the bilayer Fe (50 nm)/Hf (50 nm) already contain many vacancy-type defects. We have investigated the change of densities of the vacancy-carbon complex and the small vacancy-cluster with carbons, through solid-state amorphization of Fe (50 nm)/Hf (50 nm) bilayer.
文摘A new method has been studied to obtain TiN-Ti(C,N)composite film by laser-induced re- action in order to modify the surface properties of substrate.An apparatus for this new technology has been developed.The main reaction,the influence of main processing parameters on the formation, composition,microstructure and properties of the film have been researched.The average hardness of the film is up to HK 2700-2800.The wear resist- ance of the film is higher than that of the substrate by a factor of 9-11;and the film has good adhesive strength with the substrate.
