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Filtration performance and modeling of granular bed for dust removal from coal pyrolytic vapors
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作者 Shuaiqiang Yang Lin Du +3 位作者 Guangchao Ding Runguo Liu Wenli Song Songgeng Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期35-42,共8页
Dust removal from pyrolytic vapors at high temperatures is an obstacle to the industrialization of the coal pyrolysis process.In this work,a granular bed with expanded perlites as filtration media was designed and int... Dust removal from pyrolytic vapors at high temperatures is an obstacle to the industrialization of the coal pyrolysis process.In this work,a granular bed with expanded perlites as filtration media was designed and integrated into a 10 t·d^(–1)coal pyrolysis facility.The testing results showed that around 97.56%dust collection efficiency was achieved.As a result,dust content in tar was significantly lowered.The pressure drop of the granular bed maintained in the range of 356 Pa to 489 Pa.The dust size in the effluent after filtration exhibited a bimodal distribution,which was attributed to the heterogeneity of the dust components.The effects of filtration bed on pyrolytic product yields were also discussed.A modified filtration model based on the macroscopic phenomenological theory was proposed to describe the performance of the granular bed.The computation results were well agreed with the experimental data. 展开更多
关键词 Granular bed filtration Dust removal PYROLYSIS FILTRATION FIXED-BED
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Deep bed filtration model for cake filtration and erosion
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作者 L.I.KUZMINA Y.V.OSIPOV A.R.PESTEREV 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期355-372,共18页
Many phenomena in nature and technology are associated with the filtration of suspensions and colloids in porous media. Two main types of particle deposition,namely, cake filtration at the inlet and deep bed filtratio... Many phenomena in nature and technology are associated with the filtration of suspensions and colloids in porous media. Two main types of particle deposition,namely, cake filtration at the inlet and deep bed filtration throughout the entire porous medium, are studied by different models. A unified approach for the transport and deposition of particles based on the deep bed filtration model is proposed. A variable suspension flow rate, proportional to the number of free pores at the inlet of the porous medium, is considered. To model cake filtration, this flow rate is introduced into the mass balance equation of deep bed filtration. For the cake filtration without deposit erosion,the suspension flow rate decreases to zero, and the suspension does not penetrate deep into the porous medium. In the case of the cake filtration with erosion, the suspension flow rate is nonzero, and the deposit is distributed throughout the entire porous medium. An exact solution is obtained for a constant filtration function. The method of characteristics is used to construct the asymptotics of the concentration front of suspended and retained particles for a filtration function in a general form. Explicit formulae are obtained for a linear filtration function. The properties of these solutions are studied in detail. 展开更多
关键词 deep bed filtration cake filtration porous medium particle deposition and erosion analytical solution concentration front
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Chemical modification of barite for improving the performance of weighting materials for water-based drilling fluids
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作者 Li-Li Yang Ze-Yu Liu +3 位作者 Shi-bo Wang Xian-Bo He Guan-Cheng Jiang Jie Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期551-566,共16页
With increasing drilling depth and large dosage of weighting materials,drilling fluids with high solid content are characterized by poor stability,high viscosity,large water loss,and thick mud cake,easier leading to r... With increasing drilling depth and large dosage of weighting materials,drilling fluids with high solid content are characterized by poor stability,high viscosity,large water loss,and thick mud cake,easier leading to reservoir damage and wellbore instability.In this paper,micronized barite(MB)was modified(mMB)by grafting with hydrophilic polymer onto the surface through the free radical polymerization to displace conventional API barite partly.The suspension stability of water-based drilling fluids(WBDFs)weighted with API barite:mMB=2:1 in 600 g was significantly enhanced compared with that with API barite/WBDFs,exhibiting the static sag factor within 0.54 and the whole stability index of 2.The viscosity and yield point reached the minimum,with a reduction of more than 40%compared with API barite only at the same density.Through multi-stage filling and dense accumulation of weighting materials and clays,filtration loss was decreased,mud cake quality was improved,and simultaneously it had great reservoir protection performance,and the permeability recovery rate reached 87%.In addition,it also effectively improved the lubricity of WBDFs.The sticking coefficient of mud cake was reduced by 53.4%,and the friction coefficient was 0.2603.Therefore,mMB can serve as a versatile additive to control the density,rheology,filtration,and stability of WBDFs weighted with API barite,thus regulating comprehensive performance and achieving reservoir protection capacity.This work opened up a new path for the productive drilling of extremely deep and intricate wells by providing an efficient method for managing the performance of high-density WBDFs. 展开更多
关键词 Drilling fluids Weighting materials Filtration control Reservoir protection Stability property
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Effects of early postnatal gastric and colonic microbiota transplantation on piglet gut health
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作者 Christina Larsen Simone Margaard Offersen +4 位作者 Anders Brunse Mattia Pirolo Soumya Kanti Kar Luca Guadabassi Thomas Thymann 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2024年第2期645-658,共14页
Background Diarrhea is a major cause of reduced growth and mortality in piglets during the suckling and weaning periods and poses a major threat to the global pig industry.Diarrhea and gut dysbiosis may in part be pre... Background Diarrhea is a major cause of reduced growth and mortality in piglets during the suckling and weaning periods and poses a major threat to the global pig industry.Diarrhea and gut dysbiosis may in part be prevented via improved early postnatal microbial colonization of the gut.To secure better postnatal gut colonization,we hypothesized that transplantation of colonic or gastric content from healthy donors to newborn recipients would prevent diarrhea in the recipients in the post-weaning period.Our objective was to examine the impact of transplanting colonic or gastric content on health and growth parameters and paraclinical parameters in recipient single-housed piglets exposed to a weaning transition and challenged with enterotoxigenic Escherichia coli(ETEC).Methods Seventy-two 1-day-old piglets were randomized to four groups:colonic microbiota transplantation(CMT,n=18),colonic content filtrate transplantation(CcFT,n=18),gastric microbiota transplantation(GMT,n=18),or saline(CON,n=18).Inoculations were given on d 2 and 3 of life,and all piglets were milk-fed until weaning(d 20)and shortly after challenged with ETEC(d 24).We assessed growth,diarrhea prevalence,ETEC concentration,organ weight,blood parameters,small intestinal morphology and histology,gut mucosal function,and microbiota composition and diversity.Results Episodes of diarrhea were seen in all groups during both the milk-and the solid-feeding phase,possibly due to stress associated with single housing.However,CcFT showed lower diarrhea prevalence on d 27,28,and 29 compared to CON(all P<0.05).CcFT also showed a lower ETEC prevalence on d 27(P<0.05).CMT showed a higher alpha diversity and a difference in beta diversity compared to CON(P<0.05).Growth and other paraclinical endpoints were similar across groups.Conclusion In conclusion,only CcFT reduced ETEC-related post-weaning diarrhea.However,the protective effect was marginal,suggesting that higher doses,more effective modalities of administration,longer treatment periods,and better donor quality should be explored by future research to optimize the protective effects of transplantation. 展开更多
关键词 Colonic content filtrate transplantation Colonic microbiota transplantation Gastric microbiota transplantation Gut microbiota MUCOSA Neonatal Post-weaning diarrhea
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Machine learning-based comparison of factors influencing estimated glomerular filtration rate in Chinese women with or without nonalcoholic fatty liver
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作者 I-Chien Chen Lin-Ju Chou +2 位作者 Shih-Chen Huang Ta-Wei Chu Shang-Sen Lee 《World Journal of Clinical Cases》 SCIE 2024年第15期2506-2521,共16页
BACKGROUND The prevalence of non-alcoholic fatty liver(NAFLD)has increased recently.Subjects with NAFLD are known to have higher chance for renal function impairment.Many past studies used traditional multiple linear ... BACKGROUND The prevalence of non-alcoholic fatty liver(NAFLD)has increased recently.Subjects with NAFLD are known to have higher chance for renal function impairment.Many past studies used traditional multiple linear regression(MLR)to identify risk factors for decreased estimated glomerular filtration rate(eGFR).However,medical research is increasingly relying on emerging machine learning(Mach-L)methods.The present study enrolled healthy women to identify factors affecting eGFR in subjects with and without NAFLD(NAFLD+,NAFLD-)and to rank their importance.AIM To uses three different Mach-L methods to identify key impact factors for eGFR in healthy women with and without NAFLD.METHODS A total of 65535 healthy female study participants were enrolled from the Taiwan MJ cohort,accounting for 32 independent variables including demographic,biochemistry and lifestyle parameters(independent variables),while eGFR was used as the dependent variable.Aside from MLR,three Mach-L methods were applied,including stochastic gradient boosting,eXtreme gradient boosting and elastic net.Errors of estimation were used to define method accuracy,where smaller degree of error indicated better model performance.RESULTS Income,albumin,eGFR,High density lipoprotein-Cholesterol,phosphorus,forced expiratory volume in one second(FEV1),and sleep time were all lower in the NAFLD+group,while other factors were all significantly higher except for smoking area.Mach-L had lower estimation errors,thus outperforming MLR.In Model 1,age,uric acid(UA),FEV1,plasma calcium level(Ca),plasma albumin level(Alb)and T-bilirubin were the most important factors in the NAFLD+group,as opposed to age,UA,FEV1,Alb,lactic dehydrogenase(LDH)and Ca for the NAFLD-group.Given the importance percentage was much higher than the 2nd important factor,we built Model 2 by removing age.CONCLUSION The eGFR were lower in the NAFLD+group compared to the NAFLD-group,with age being was the most important impact factor in both groups of healthy Chinese women,followed by LDH,UA,FEV1 and Alb.However,for the NAFLD-group,TSH and SBP were the 5th and 6th most important factors,as opposed to Ca and BF in the NAFLD+group. 展开更多
关键词 Non-alcoholic fatty liver Estimated glomerular filtration rate Machine learning Chinese women
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Purification of Produced Water from a Sour Oilfield in South Kuwait. 1. Oil-Water Separation and Industrial Salt Production
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作者 Feras Al Salem Hessa Al Shamsi +5 位作者 Mariam Mohammed Abdulla Alaryani Basmalah Abdelazim Mohamed Khalaf Omnia Elsheikh Vijo Poulose Yosef Al Jasem Thies Thiemann 《Journal of Water Resource and Protection》 CAS 2024年第2期156-180,共25页
Produced water from an oil extraction site in South Kuwait was sampled after primary oil – water separation had been carried out. The produced water was filtered through a mixture of activated charcoal and esterified... Produced water from an oil extraction site in South Kuwait was sampled after primary oil – water separation had been carried out. The produced water was filtered through a mixture of activated charcoal and esterified cellulosic material gained from spent coffee grounds as a tertiary adsorption treatment. The earth-alkaline metal ions and heavy metals were separated from the de-oiled produced water by addition of either sodium or potassium hydroxide in the presence of carbon dioxide or by direct addition of solid sodium carbonate. The resulting filtrate gave salt of industrial purity upon selective crystallization on evaporation. 展开更多
关键词 Produced Water Oil and Gas Adsorption Filtration CRYSTALLIZATION
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Quantification of In Vivo Epidermal Keratinocyte Architecture Associated with the Signs of Skin Aging and the Skin Benefit Evaluation by Application of Galactomyces Ferment Filtrate (Pitera)-Containing Skin Care Product
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作者 Kukizo Miyamoto Yoko Munakata +4 位作者 Keisuke Fujii Chenlu Lei Ley Yang Suda Sudarsana Masutaka Furue 《Journal of Cosmetics, Dermatological Sciences and Applications》 2024年第1期12-28,共17页
Background: Aged skin exhibits visual alterations such as wrinkles, rough texture, pore dilation, and dull skin tone, as well as physiological aging, namely, decreased hydration and increased transepidermal water loss... Background: Aged skin exhibits visual alterations such as wrinkles, rough texture, pore dilation, and dull skin tone, as well as physiological aging, namely, decreased hydration and increased transepidermal water loss (TEWL). Recent advances in coherence tomography have also revealed that skin aging affects in vivo epidermal keratinocyte architecture. However, the interconnectivity between spatial architectural aging and visual/physiological aging parameters remains largely unknown. Purpose: To elucidate whether the tomographic keratinocyte architectural aging is correlated with visual and physiological skin aging parameters and to quantitatively evaluate the improvements of the architectural, visual, and physiological aging parameters by the daily treatment of the skin care formula containing Galactomyces Ferment Filtrate (GFF, 8X Pitera<sup>TM</sup>). Method: We measured the in vivo keratinocyte cellular architecture with two-photon stereoscopic tomography obtaining by-layer epidermal section images in 78 Asian females of various ages. Visual aging parameters were analyzed using a portable image capture system. Hydration and TEWL were also assessed. The anti-aging effects of GFF-containing skin moisturizer (SK-II LXP Cream<sup>TM</sup>) were also examined in two studies after twice-daily application for 2 (N = 35) and 4 (N = 32) weeks. Results: As for the keratinocyte cellular architecture, skin aging was significantly associated with decreased cell density and increased cell uniformity. These architectural aging parameters were significantly correlated with visual and physiological aging parameters, namely, rough texture, wrinkles, pore dilation, dull skin tone, dehydration, and increased TEWL. The strong interconnectivity allowed us to develop formulae to estimate the keratinocyte architecture from visual aging parameters. Moreover, twice-daily application of SK-II significantly improved the keratinocyte architecture associated with multiple skin aging visual and physiological parameters. Conclusion: Skin aging is a process involving mutual interconnections among epidermal keratinocyte cellular architecture, visual, and physiological parameters. The GFF-containing moisturizer SK-II effectively improves spatial architecture of keratinocytes in epidermis and these evaluated skin aging parameters in a new trajectory over the course of treatment. . 展开更多
关键词 Facial Skin Aging In Vivo Keratinocyte Cellular Architecture Visual Aging Pa-rameter Dehydration INTERCONNECTIVITY New Trajectory Galactomyces Fer-ment Filtrate PiteraTM SK-II LXP CreamTM
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ad-NILPOTENT ELEMENTS, QUASI-NILPOTENT ELEMENTS AND INVARIANT FILTRATIONS OF INFINITE DIMENSIONAL LIE ALGEBRAS OF CARTAN TYPE 被引量:5
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作者 金宁 《Science China Chemistry》 SCIE EI CAS 1992年第10期1191-1200,共10页
Let F be an arbitrary field of characteristic p≠2, and L be an infinite Lie, algebra ofCartan type (graded or complete). When p】3 (or p is arbitrary), the set of ad-nilpotent(or quasi-nilpotent) elements of L is det... Let F be an arbitrary field of characteristic p≠2, and L be an infinite Lie, algebra ofCartan type (graded or complete). When p】3 (or p is arbitrary), the set of ad-nilpotent(or quasi-nilpotent) elements of L is determined. Consequently, it is proved that the naturalfiltration and the noncontractible filtration of L are invariant. 展开更多
关键词 Lie algebras of CARTAN TYPE ad-nilpotent ELEMENTS quasi-nilpotent ELEMENTS filtration
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Canonical Metrics on Holomorphic Filtrations over Compact Hermitian Manifolds 被引量:1
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作者 Zhenghan Shen Pan Zhang 《Communications in Mathematics and Statistics》 SCIE 2020年第2期219-237,共19页
The purpose of this paper is twofold.We first solve the Dirichlet problem forτ-Hermitian-Einstein equations on holomorphic filtrations over compact Hermitian manifolds.Secondly,by using Uhlenbeck-Yau’s continuity me... The purpose of this paper is twofold.We first solve the Dirichlet problem forτ-Hermitian-Einstein equations on holomorphic filtrations over compact Hermitian manifolds.Secondly,by using Uhlenbeck-Yau’s continuity method,we prove the existence of approximateτ-Hermitian-Einstein structure on holomorphic filtrations over closed Gauduchon manifolds. 展开更多
关键词 τ-Hermitian-Einstein equation Approximateτ-Hermitian-Einstein structure Semi-stability Holomorphic filtration Gauduchon manifold
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Invariant filtrations of Lie algebras of Cartan type over commutative rings
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作者 金宁 沈光宇 《Chinese Science Bulletin》 SCIE EI CAS 1995年第11期890-893,共4页
The work of the classification of the simple Lie algebras over algebraical closed fieldF of prime characteristc p began nearly 50 years ago and the problem has been solved just recentlyunder the condition p】7,and the... The work of the classification of the simple Lie algebras over algebraical closed fieldF of prime characteristc p began nearly 50 years ago and the problem has been solved just recentlyunder the condition p】7,and the generalized Kostrikin-Safarevic conjecture that these al-gebras are all of classical or Cartan type is verified.For the classification of simple Liealgebras over non-closed fields,it is necessary to consider the forms.A central simple 展开更多
关键词 ring LIE algebra of CARTAN TYPE INVARIANT filtration nilpotent.
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On C-Bases, Partition Pairs and Filtrations for Induced or Restricted Specht Modules
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作者 Christos A. Pallikaros 《Algebra Colloquium》 SCIE CSCD 2019年第1期161-180,共20页
We obtain alternative explicit Specht filtrations for the induced and the restricted Specht modules in the Hecke algebra of the symmetric group (defined over the ring A = Z[g^1/2, q^-1/2], where q is an indeterminate)... We obtain alternative explicit Specht filtrations for the induced and the restricted Specht modules in the Hecke algebra of the symmetric group (defined over the ring A = Z[g^1/2, q^-1/2], where q is an indeterminate) using C-bases for these modules. Moreover, we provide a link bet ween a certain C-basis for the induced Specht module and the notion of pairs of partitions. 展开更多
关键词 Kazhdan-Lusztig cell Specht FILTRATION induction and RESTRICTION pair of PARTITIONS
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ON THE INVARIANT OF THE FILTRATIONS OF CARTAN TYPE P-ALGEBRAS OF CHARACTERISTIC 2
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作者 薛连永 《Chinese Science Bulletin》 SCIE EI CAS 1986年第13期933-934,共2页
Let k be a field of characteristic 2, k[x1,x2,.., xn] a polynomial algebra and
关键词 ALGEBRA POLYNOMIAL filtered FILTRATION
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On Mixed Multiplicities of Good Filtrations
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作者 Duong Quoc Viet Le Van Dinh 《Algebra Colloquium》 SCIE CSCD 2015年第3期421-436,共16页
This paper interprets mixed multiplicities of good filtrations as Hilbert-Samuel multiplicities, and shows that (ε1,..., εm)-superficial sequences in [16] (2007) and superficial sequences in [15] (1973) are we... This paper interprets mixed multiplicities of good filtrations as Hilbert-Samuel multiplicities, and shows that (ε1,..., εm)-superficial sequences in [16] (2007) and superficial sequences in [15] (1973) are weak-(FC)-sequences in [19] (2000). As consequences, we not only obtain generalized results for mixed multiplicities of ideals in [15, 16, 19] but also get an improvement of [19, Theorem 3.4] that seems to account well for the essence of [16, Theorem 1.4]. 展开更多
关键词 mixed multiplicity filtration (FC)-sequence superficial sequence
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Purely Inseparable Extensions and Ramification Filtrations
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作者 Hao Yu HU 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2021年第1期35-58,共24页
In this article,we investigate the shift of Abbes and Saito’s ramification filtrations of the absolute Galois group of a complete discrete valuation field of positive characteristic under a purely inseparable extensi... In this article,we investigate the shift of Abbes and Saito’s ramification filtrations of the absolute Galois group of a complete discrete valuation field of positive characteristic under a purely inseparable extension.We also study a functoriality property for characteristic forms. 展开更多
关键词 Abbes and Saito’s ramification filtration purely inseparable extension characteristic form
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Advances in particulate matter filtration:Materials,performance,and application 被引量:1
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作者 Xuzheng Ji Jianying Huang +5 位作者 Lin Teng Shuhui Li Xiao Li Weilong Cai Zhong Chen Yuekun Lai 《Green Energy & Environment》 SCIE EI CAS CSCD 2023年第3期673-697,共25页
Air-borne pollutants in particulate matter(PM)form,produced either physically during industrial processes or certain biological routes,have posed a great threat to human health.Particularly during the current COVID-19... Air-borne pollutants in particulate matter(PM)form,produced either physically during industrial processes or certain biological routes,have posed a great threat to human health.Particularly during the current COVID-19 pandemic,effective filtration of the virus is an urgent matter worldwide.In this review,we first introduce some fundamentals about PM,including its source and classification,filtration mechanisms,and evaluation parameters.Advanced filtration materials and their functions are then summarized,among which polymers and MOFs are discussed in detail together with their antibacterial performance.The discussion on the application is divided into end-of-pipe treatment and source control.Finally,we conclude this review with our prospective view on future research in this area. 展开更多
关键词 Air filtration PM capture End-of-pipe treatment Source control COVID-19
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Fabrication of High-Efficiency Polyvinyl Alcohol Nanofiber Membranes for Air Filtration Based on Principle of Stable Electrospinning 被引量:1
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作者 高婷婷 郑军妹 王丹阳 《Journal of Donghua University(English Edition)》 CAS 2023年第2期142-148,共7页
A mass flow matching model(MFMM)was established for studying the stable status of solution electrospinning.The study of the solution droplet status at the needle tip focused on various combinations of applied voltages... A mass flow matching model(MFMM)was established for studying the stable status of solution electrospinning.The study of the solution droplet status at the needle tip focused on various combinations of applied voltages and injection rates to figure out their influence on steadily fabricating polyvinyl alcohol(PVA)nanofibers prepared from PVA spinning solutions with two different mass fractions(10%and 16%).The results revealed that during the stable electrospinning,the influence resulted from the change of the injection rate approximately canceled out the impact brought by adjusting the applied voltage,leading to almost the same morphology as that of the PVA nanofibers.And the mass fraction of PVA in the spinning solution dominated the structure and the diameter distribution of the electrospun nanofibers.Under stable electrospinning conditions,the composite membrane was produced by depositing PVA nanofibers on the polyethylene terephthalate(PET)nonwoven substrate for an air filtration test.Furthermore,the prepared composite membrane exhibited a high air filtration efficiency(99.97%)and a low pressure drop(120 Pa)for 300-500 nm neutralized polystyrene latex(PSL)aerosol particles,demonstrating its potential as an alternative for a variety of commercial applications in air filtration. 展开更多
关键词 polyvinyl alcohol(PVA) NANOFIBER stable electrospinning air filtration MEMBRANE
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Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO_(2) membrane
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作者 Tutuk Djoko Kusworo Monica Yulfarida +1 位作者 Andri Cahyo Kumoro Dani Puji Utomo 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第3期123-136,共14页
The presence of impurities in the bioethanol fermentation broth should be removed to mitigate any possible ineffective refining processes as well as to enhance bioethanol production. In this study, a prefiltration pro... The presence of impurities in the bioethanol fermentation broth should be removed to mitigate any possible ineffective refining processes as well as to enhance bioethanol production. In this study, a prefiltration process was carried out for separating fermentation yeast cells and residual substrates using a microfiltration membrane. Hydrophilic polyvinylidene fluoride-graphene oxide/titanium dioxide(PVDF-GO/TiO_(2)) membrane with polyvinyl alcohol(PVA) surface-coating modification was fabricated and characterized. Membrane modification attempts have succeeded in increasing the hydrophilicity as indicated by contact angle decline from 72.10° to 34.83° and affinity towards water leading to higher water permeability. The performance evaluation showed that 90.77% of unwanted by-products(yeast cells and residual substrate) can be removed. This high rejection is also followed by a high and stable flux performance at 40.20 L·m^(-2)·h^(-1) where the flux was increased by 13 times compared to that of the neat membrane. The PVA-coated PVDF-GO/TiO2showed the best anti-biofouling performance with a flux recovery ratio after 5 days incubation(FRR5d) of 93.55%. This membrane material has excellent prospects in future membrane development for either in-situ application or as a pre-filtration in the fermentation process to separate living cells and residual substrates before being further processed in the refining processes. 展开更多
关键词 BIOFUEL Membranes FERMENTATION Filtration Separation SELECTIVITY
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Tannic acid/Fe^(3+)interlayer for preparation of high-permeability polyetherimide organic solvent nanofiltration membranes for organic solvent separation
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作者 Haike Li Xindong Li +5 位作者 Guozai Ouyang Lang Li Zhaohuang Zhong Meng Cai Wenhao Li Wanfu Huang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第5期17-29,共13页
Organic solvent nanofiltration(OSN)membranes have a great application prospect in organic solvent separation,but the development of OSN membranes is mainly restricted by trade-off between permeability and rejection ra... Organic solvent nanofiltration(OSN)membranes have a great application prospect in organic solvent separation,but the development of OSN membranes is mainly restricted by trade-off between permeability and rejection rate.In this work,a TA/Fe^(3+)polymer was introduced into polyetherimide(PEI)ultrafiltration membranes crosslinked with hexamethylene diamine as the intermediate layer,and OSN membranes with high separation performance and solvent permeability were obtained through interfacial polymerization and solvent activation.The interlayer with high surface hydrophilicity and a fixed pore structure controlled the adsorption/diffusion of the amine monomer during interfacial polymerization,forming a smooth(average surface roughness<5.5 nm),ultra-thin(separation layer thickness reduced from 150 to 16 nm)and dense surface structure polyamide(PA)layer.The PA-Fe^(3+)_3-HDA/PEI membrane retained more than 94%of methyl blue(BS)in 0.1 g·L^(-1)BS ethanol solution at 0.6 MPa,and the ethanol permeation reached 28.56 L^(-1)·m^(-2)·h^(-1).The average flux recovery ratio(FRR)of PA-Fe^(3+)_(3)-HDA/PEI membrane was found to be 84%,which has better fouling resistance than PA-HDA/PEI membrane,and it was found to have better stability performance through different solvent immersion experiments and continuous operation in 0.1 g·L^(-1)BS ethanol solution.Compared with thin-film composite nanofiltration membranes,the PA-Fe^(3+)_(3)-HDA/PEI membrane can be manufactured from an economical and environment-friendly method and overcomes the trade-off between permeability and rejection rate,showing great application potential in organic solvent separation systems. 展开更多
关键词 Nanofiltration membrane Waste treatment SURFACE FILTRATION Tannic acid Interfacial polymerization
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Recent Progress of Fabrication,Characterization,and Applications of Anodic Aluminum Oxide(AAO)Membrane:A Review
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作者 Saher Manzoor Muhammad Waseem Ashraf +2 位作者 Shahzadi Tayyaba Muhammad Imran Tariq MKhalid Hossain 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第5期1007-1052,共46页
The progress of membrane technology with the development of membranes with controlled parameters led to porous membranes.These membranes can be formed using different methods and have numerous applications in science ... The progress of membrane technology with the development of membranes with controlled parameters led to porous membranes.These membranes can be formed using different methods and have numerous applications in science and technology.Anodization of aluminum in this aspect is an electro-synthetic process that changes the surface of the metal through oxidation to deliver an anodic oxide layer.This process results in a self-coordinated,exceptional cluster of round and hollow formed pores with controllable pore widths,periodicity,and thickness.Categorization in barrier type and porous type films,and different methods for the preparation of membranes,have been discussed.After the initial introduction,the paper proceeds with a brief overview of anodizing process.That engages anodic aluminum oxide(AAO)layers to be used as formats in various nanotechnology applications without the necessity for expensive lithographical systems.This review article surveys the current status of the investigation on AAO membranes.A comprehensive analysis is performed on AAO membranes in applications;filtration,sensors,drug delivery,template-assisted growth of various nanostructures.Their multiple usages in nanotechnology have also been discussed to gather nanomaterials and devices or unite theminto specific applications,such as nano-electronic gadgets,channel layers,and clinical platforms tissue designing.From this review,the fact that the specified enhancement of properties of AAO can be done by varying geometric parameters of AAO has been highlighted.No review paper focused on a detailed discussion of multiple applications of AAO with prospects and challenges.Also,it is a challenge for the research community to compare results reported in the literature.This paper provides tables for easy comparison of reported applications with membrane parameters.This review paper represents the formation,properties,applications with objective consideration of the prospects and challenges of AAO applications.The prospects may appeal to researchers to promote the development of unique membranes with functionalization and controlled geometric parameters and check the feasibility of the AAO membranes in nanotechnology and devices. 展开更多
关键词 AAO membranes anodization template assisted growth FILTRATION SENSORS drug delivery
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