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Surface Modification Mechanism of Fine Coal by Electrochemical Methods 被引量:1
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作者 ZHU Hong WANG Fang-hui +1 位作者 WANG Dian-zuo OU Ze-shen 《Journal of China University of Mining and Technology》 EI 2006年第2期180-183,共4页
In order to reveal the surface modification mechanism of fine coal by electrochemical methods, the structural changes of the coal surface before and after electrochemical modification were investigated by Fourier Tran... In order to reveal the surface modification mechanism of fine coal by electrochemical methods, the structural changes of the coal surface before and after electrochemical modification were investigated by Fourier Transform In- frared Spectra (FTIR) and Raman Spectra. The results show that under certain electrochemical conditions, the oxy- gen-containing functional group in the coal structure and the oxygen content of absorption could be reduced and the floatability of coal improved. At the same time, the sulfur in the coal was reduced to the hydrophilic S2– which could be separated easily from coal. Thus electrochemical modification methods could be used to change the structure and func- tional group on the coal surface and to enhance the floatability of coal. 展开更多
关键词 粉煤 电化学浮选 改性机制 FTIR 拉曼光谱 表面改性
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全天时绝对测温激光雷达的多通道纯转动拉曼分光系统
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作者 李仕春 王旭 +4 位作者 张鹏辉 辛文辉 华灯鑫 胡向龙 宋跃辉 《中国激光》 EI CAS CSCD 北大核心 2022年第13期125-134,共10页
为实现大气温度廓线的全天时绝对探测,基于N_(2)分子的精细纯转动拉曼谱线结构,本课题组提出并设计了多通道纯转动拉曼激光雷达分光系统。采用F-P干涉仪(FPI)作为频率梳滤波器,考虑FPI膜层损耗和镜面缺陷,精细匹配N_(2)分子anti-Stokes... 为实现大气温度廓线的全天时绝对探测,基于N_(2)分子的精细纯转动拉曼谱线结构,本课题组提出并设计了多通道纯转动拉曼激光雷达分光系统。采用F-P干涉仪(FPI)作为频率梳滤波器,考虑FPI膜层损耗和镜面缺陷,精细匹配N_(2)分子anti-Stokes分支的纯转动拉曼谱线,实现了FPI结构及性能参数的优化,并有效滤除了太阳背景噪声及邻近谱线信号;结合衍射光栅和光纤线阵列,通过两级光谱滤光对弹性散射信号实现了约60 dB的抑制率,有效提取了8通道偶转动量子数(J=6~20)的拉曼光谱信号,以直接反演大气温度;基于标准大气模型,对8通道纯转动拉曼分光系统的信号功率及信噪比进行了仿真,并分析了全天时绝对测温激光雷达的探测性能。结果表明,在累积时间为17 min时,该系统实现白天信噪比优于10的探测高度可达到1.8 km,反演温度1 K偏差对应的高度达0.8 km,可实现全天时大气温度廓线的无校正探测。 展开更多
关键词 遥感 激光雷达 纯转动拉曼绝对测温 F-P干涉仪 精细拉曼谱结构 无校正探测
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