The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite...The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite.The wall rocks are composed of Variscan porphyritic-like biotite granite and the Lower Ordovician Wubin'aobao Formation.LA-ICP-MS zircon U-Pb dating of the fine-grained granite reveals two stages of zircons,one were formed at 181.7±7.4 Ma and the other at 133.6±3.3 Ma.The latter age is believed to be the formation age of the fine-grained granite,while the former may reflect the age of inherited zircons,based on the morphological study of the zircon and regional geological setting.The Re-Os model age of molybdenite is 142.2±2.5 Ma,which is older than the diagenetic age of the fine-grained granite.Therefore the authors believe that the metallogenic age of the Wurinitu molybdenum deposit should be nearly 133.6±3.3 Ma or slightly later,i.e.,Early Cretaceous.Combined with regional geological background research,it is speculated that the molybdenum deposits were formed at the late Yanshanian orogenic cycle in the Hingganling-Mongolian orogenic belt,belonging to the relaxation epoch posterior to the compression and was associated with the closure of the Mongolia-Okhotsk Sea.展开更多
The Huangtuliang monzonitic granite outcrops on the northern side of the Huangtuliang gold mining district, Chicheng, North Hebei Province. Our predecessors only made isotopic age determination using the K-Ar method. ...The Huangtuliang monzonitic granite outcrops on the northern side of the Huangtuliang gold mining district, Chicheng, North Hebei Province. Our predecessors only made isotopic age determination using the K-Ar method. Through LA-MC-ICP-MS zircon U-Pb dating and zircon Hf isotopic composition determination, this study acquired the age of 244.8±2.0 Ma(MSWD=0.57) on the basis of the weighed mean 206Pb/238U ratio, indicating that the Huangtuliang monzonitic granite was formed during the Middle Triassic period, which is the product of Early Indosinian magmatic activities in the region of North Hebei. εHf(t) values vary relatively evenly, within the range of-10.65--14.03, with an average of-12.14. The two-stage evolution model ages, tDM2, vary between 1943 and 2144 Ma, implying that the rock-forming materials of the Huangtiliang monzonitic granite mainly came from the Paleoproterozoic recirculated crustal materials, though a small quantity of enriched-mantle materials would have been involved.展开更多
The geochemical features of the monzonitic granite in Qimantage Hutouya deposit area,Qinghai,in respect to the mineralization,suggest that this granite belongs to weak peraluminous and high-k calc alkaline rock series...The geochemical features of the monzonitic granite in Qimantage Hutouya deposit area,Qinghai,in respect to the mineralization,suggest that this granite belongs to weak peraluminous and high-k calc alkaline rock series. The REE of the samples show right slope with obvious LREE/HREE differentiation and negative Eu abnormity. The trace elements show enrichment of LILE( Rb,Th,U,La,Nd),and deleption of Ba,Sr,Nd,P,Ti. The Sr-Nb isotopic data indicate that the magma source is mainly aluminosilicate lower crust with a small amount of new crustal materials. The weighted mean zircon U-Pbage of the Hutouya monzonitic granite is 221±1.7 Ma,belonging to Late Triassic. The Hutouya monzonitic granite was formed in the tectonic setting of transition from compression to extension during Middle-Late Triassic.展开更多
Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microsc...Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microscopic observations and chemical analyses with the aim of understanding their chemical characteristics and estimating the crystallization pressure and oxygen fugacity of their host rocks. Plagioclases in these rocks are albite and oligoclase, while alkali feldspars are orthoclase. For the phlogopite-micas, Fe-biotite and Li-phengite are common for the Ibity and Antsahakely granites, Mg-biotite is common for the Ibity granite and the Tsarasaotra monzonitic and granite dykes, and siderophyllite and Zinnwaldite are specific to the Ibity granite. Phlogopite-micas in the studied rocks are mainly primary, accessorily re-equilibrated, and rarely secondary. Calcic amphiboles distributed in the Magnesio-and Ferro-hornblende are identified in the Tsarasaotra monzonitic, whereas amphibole is rare and absent in the other rocks. Igneous titanite is observed in the Ibity granite and in the Tsarasaotra monzonitic rocks, which have similar compositions to some REE oxide-rich titanites. Concerning the Fe-Ti oxide phases, the rhombohedral and spinel/trifer tetroxide phases are found in both the Tsarasaotra monzonitic and the Tsarasaotra granite dyke, the trifer tetroxide and spinel + wüstite phases are found only in the Ibity granite, and the pseudobrookite + rhombohedral phase is found only in the Tsarasaotra granite dyke. The epidote mineral, rarely found in the Antsahakely granite, could be an indicator of metamorphism or hydrothermal activity involved during the emplacement of this rock. Aluminum in hornblende geobarometer gave pressure ranges of around 5 kbar for the Tsarasaotra monzonitic rocks. The Titanite geobarometer gave pressures of 2.5 - 3.2 kbar for the Ibity granite, 2.9 kbar for the Tsarasaotra monzonitic, and 7.1 kbar for the Antsahakely granite. Both amphibole and Fe-Ti oxide-base oxygen fugacity reveal high oxygen fugacity conditions for the Tsarasaotra monzonitic and granite dyke emplacements, which might have a relationship with a porphyritic environment.展开更多
基金support by China Geological Survey (1212010911028)NSFC(40802020)+1 种基金Ministry of Land and Resources(1212010633902,1212010633903 and 121201 0711814)CUGB(GPMR 0735)
文摘The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite.The wall rocks are composed of Variscan porphyritic-like biotite granite and the Lower Ordovician Wubin'aobao Formation.LA-ICP-MS zircon U-Pb dating of the fine-grained granite reveals two stages of zircons,one were formed at 181.7±7.4 Ma and the other at 133.6±3.3 Ma.The latter age is believed to be the formation age of the fine-grained granite,while the former may reflect the age of inherited zircons,based on the morphological study of the zircon and regional geological setting.The Re-Os model age of molybdenite is 142.2±2.5 Ma,which is older than the diagenetic age of the fine-grained granite.Therefore the authors believe that the metallogenic age of the Wurinitu molybdenum deposit should be nearly 133.6±3.3 Ma or slightly later,i.e.,Early Cretaceous.Combined with regional geological background research,it is speculated that the molybdenum deposits were formed at the late Yanshanian orogenic cycle in the Hingganling-Mongolian orogenic belt,belonging to the relaxation epoch posterior to the compression and was associated with the closure of the Mongolia-Okhotsk Sea.
基金financially supported jointly by the Geological Investigation Item sponsored by the China Geological Survey (No. 1212011220492)the Scientific Research Base of China’s Typical Metallic Ores (No. 200911007)the National Natural Science Foundation of China (40872137)
文摘The Huangtuliang monzonitic granite outcrops on the northern side of the Huangtuliang gold mining district, Chicheng, North Hebei Province. Our predecessors only made isotopic age determination using the K-Ar method. Through LA-MC-ICP-MS zircon U-Pb dating and zircon Hf isotopic composition determination, this study acquired the age of 244.8±2.0 Ma(MSWD=0.57) on the basis of the weighed mean 206Pb/238U ratio, indicating that the Huangtuliang monzonitic granite was formed during the Middle Triassic period, which is the product of Early Indosinian magmatic activities in the region of North Hebei. εHf(t) values vary relatively evenly, within the range of-10.65--14.03, with an average of-12.14. The two-stage evolution model ages, tDM2, vary between 1943 and 2144 Ma, implying that the rock-forming materials of the Huangtiliang monzonitic granite mainly came from the Paleoproterozoic recirculated crustal materials, though a small quantity of enriched-mantle materials would have been involved.
基金Supported by Project of China Geological Survey(No.20150209-01-079)
文摘The geochemical features of the monzonitic granite in Qimantage Hutouya deposit area,Qinghai,in respect to the mineralization,suggest that this granite belongs to weak peraluminous and high-k calc alkaline rock series. The REE of the samples show right slope with obvious LREE/HREE differentiation and negative Eu abnormity. The trace elements show enrichment of LILE( Rb,Th,U,La,Nd),and deleption of Ba,Sr,Nd,P,Ti. The Sr-Nb isotopic data indicate that the magma source is mainly aluminosilicate lower crust with a small amount of new crustal materials. The weighted mean zircon U-Pbage of the Hutouya monzonitic granite is 221±1.7 Ma,belonging to Late Triassic. The Hutouya monzonitic granite was formed in the tectonic setting of transition from compression to extension during Middle-Late Triassic.
文摘Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microscopic observations and chemical analyses with the aim of understanding their chemical characteristics and estimating the crystallization pressure and oxygen fugacity of their host rocks. Plagioclases in these rocks are albite and oligoclase, while alkali feldspars are orthoclase. For the phlogopite-micas, Fe-biotite and Li-phengite are common for the Ibity and Antsahakely granites, Mg-biotite is common for the Ibity granite and the Tsarasaotra monzonitic and granite dykes, and siderophyllite and Zinnwaldite are specific to the Ibity granite. Phlogopite-micas in the studied rocks are mainly primary, accessorily re-equilibrated, and rarely secondary. Calcic amphiboles distributed in the Magnesio-and Ferro-hornblende are identified in the Tsarasaotra monzonitic, whereas amphibole is rare and absent in the other rocks. Igneous titanite is observed in the Ibity granite and in the Tsarasaotra monzonitic rocks, which have similar compositions to some REE oxide-rich titanites. Concerning the Fe-Ti oxide phases, the rhombohedral and spinel/trifer tetroxide phases are found in both the Tsarasaotra monzonitic and the Tsarasaotra granite dyke, the trifer tetroxide and spinel + wüstite phases are found only in the Ibity granite, and the pseudobrookite + rhombohedral phase is found only in the Tsarasaotra granite dyke. The epidote mineral, rarely found in the Antsahakely granite, could be an indicator of metamorphism or hydrothermal activity involved during the emplacement of this rock. Aluminum in hornblende geobarometer gave pressure ranges of around 5 kbar for the Tsarasaotra monzonitic rocks. The Titanite geobarometer gave pressures of 2.5 - 3.2 kbar for the Ibity granite, 2.9 kbar for the Tsarasaotra monzonitic, and 7.1 kbar for the Antsahakely granite. Both amphibole and Fe-Ti oxide-base oxygen fugacity reveal high oxygen fugacity conditions for the Tsarasaotra monzonitic and granite dyke emplacements, which might have a relationship with a porphyritic environment.