The analysis of hydrochemical characteristics and influencing factors of surface river on plateau is helpful to study water hydrological cycle and environmental evolution,which can scientifically guide rational develo...The analysis of hydrochemical characteristics and influencing factors of surface river on plateau is helpful to study water hydrological cycle and environmental evolution,which can scientifically guide rational development and utilization of water resources and planning of ecological environment protection.With the expansion and diversification of human activities,the quality of surface rivers will be more directly affected.Therefore,it is of great significance to pay attention to the hydrochemical characteristics of plateau surface rivers and the influence of human activities on their circulation and evolution.In this study,surface water in the Duoqu basin of Jinsha River located in Hengduan mountain region of Eastern Tibet was selected as the representative case.Twenty-three groups of surface water samples were collected to analyze the hydrochemical characteristics and ion sources based on correlation analysis,piper trigram,gibbs model,hydrogen and oxygen isotopic techniques.The results suggest the following:(1)The pH showed slight alkalinity with the value ranged from 7.25 to 8.62.Ca^(2+),Mg^(2+)and HCO_(3)^(–)were the main cations and anions.HCO_(3)^(-)Ca and HCO_(3)^(-)Ca·Mg were the primary hydrochemical types for the surface water of Duoqu River.The correlation analysis showed that TDS had the most significant correlation with Ca^(2+),Mg^(2+)and HCO_(3)^(–).Analysis on hydrogen and oxygen isotopes indicated that the surface rivers were mainly recharged by atmospheric precipitation and glacial melt water in this study area.(2)The surface water had a certain reverse cation alternating adsorption,and surface water ions were mainly derived from rock weathering,mainly controlled by weathering and dissolution of carbonates,and secondly by silicates and sodium rocks.(3)The influence of human activities was weak,while the development of cinnabar minerals had a certain impact on the hydrochemistry characteristics,which was the main factor for causing the increase of SO_(4)^(2–).The densely populated county towns and temples with frequent incense burning activities may cause some anomalies of surface water quality.At present,the Duoqu River watershed had gone through a certain influence of mineral exploitation,so the hydrological cycle and river eco-environment at watershed scale will still bound to be change.The results could provide basic support for better understanding water balance evolution as well as the ecological protection of Duoqu River watershed.展开更多
Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped ...Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped stretchable and tailorable triboelectric nanogenerator(FST-TENG)based on the geometric construction of a steel wire as electrode and ingenious selection of silicone rubber as triboelectric layer.Owing to the great robustness and continuous conductivity,the FST-TENGs demonstrate high stability,stretchability,and even tailorability.For a single device with ~6 cm in length and ~3 mm in diameter,the open-circuit voltage of ~59.7 V,transferred charge of ~23.7 nC,short-circuit current of ~2.67 μA and average power of ~2.13 μW can be obtained at 2.5 Hz.By knitting several FST-TENGs to be a fabric or a bracelet,it enables to harvest human motion energy and then to drive a wearable electronic device.Finally,it can also be woven on dorsum of glove to monitor the movements of gesture,which can recognize every single finger,different bending angle,and numbers of bent finger by analyzing voltage signals.展开更多
Long-term changes of composition, sources and burial fluxes of TOC (total organic carbon) in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, si...Long-term changes of composition, sources and burial fluxes of TOC (total organic carbon) in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, similarity analysis is employed to confirm that the carbon burial features resulted from two collected cores are typical in the central Yellow Sea mud area where YSWC (Yellow Sea Warm Current) is prevalent. On this basis, the burial flux of TOC here was considered to be 235.5-488.4 pmol/(cm^2.a) since the first industrial revolution, accounting for about 70%-90% among burial fluxes of TC (total carbon) in the sediments. Compared TOC/TC ratio in the two cores with that in other marine sediments worldwide, we suggest that the growth of calcareous/non-calcareous organisms and dissolution of IC (inorganic carbon) are important factors controlling the TOC/TC ratio in sediment. Results of two-end mixed model based on fi13C data indicate that marine-derived organic carbon (OCa) is the main part among total burial organic carbon which accounts for a ratio over 85%. Due to the high TOC/TC ratio in the two cores, TC in the sediments also mainly exists as OCa, and the proportion of OCa is about 60%-80%. Away from the shore and relatively high primary production in upper waters are the main reasons that OCa is predominant among all burial OC in sediments of the central Yellow Sea mud area. Burial of OC in this mud area is probably mainly influenced by the human activities. Although the economic development during the late 19th century caused by the first industrial revolution in China did not obviously increase the TOC burial fluxes in the sediments, the rise of industry and agriculture after the founding of new China has clearly increased the TOC burial flux since 1950s. Otherwise, we also realize that among TC burial fluxes, TIC account for about 10%-30% in sediments of the central Yellow Sea mud area, so its burial could not be simply ignored here. Distinct from TOC burial, long-term TIC burial fluxes variations relate with climate changes more closely: the East Asian summer monsoon may influence the strength of the Huanghe River (Yellow River) flood, which could further affect the transport of terrestrial IC from land to the central Yellow Sea as well as the burial of these IC in the sediments.展开更多
The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment sourc...The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.展开更多
Lacustrine sediments can provide potential information about environmental changes in the past. On the basis of high-resolution multi-proxy analysis including carbon and nitrogen contents of organic matter, C/N ratios...Lacustrine sediments can provide potential information about environmental changes in the past. On the basis of high-resolution multi-proxy analysis including carbon and nitrogen contents of organic matter, C/N ratios, inorganic carbon contents, and carbon and oxygen isotopic composition of carbonate, together with precise 137Cs dating, the environmental evolution of Lake Chenghai, Yunnan Province, during the past 100 years has been investigated. It is shown that the carbonate in Lake Chenghai is authigenic, and the organic matter is mainly derived from aquatic plants and algae, instead of terrestrial-source materials. The environmental evolution of Lake Chenghai can be diverged into three periods with the contrasting characteristics during the past 100 years. Before 1940, the stable carbon and oxygen isotope values, the poor correlation between them and the lower carbon and nitrogen contents of organic matter suggested that Lake Chenghai was open, and the lake water was oligotrophic during that period. During 1940-1993, the negative δ13C values and the gradual increase of carbon and nitrogen contents of organic matter and C/N ratios indicated that the eutrophication was aggravated. The closeness of Lake Chenghai and human activities may be responsible for this eutrophication. After 1993, notable increases in carbon and oxygen isotopic values of carbonate, carbon and nitrogen contents of organic matter, C/N ratios and inorganic carbon contents demonstrated that the increase of lacustrine productivity and the serious eutrophication were resulted from strong human activities. Therefore, the multi-proxy in Lake Chenghai sediments has reliably recorded the natural environmental evolution and the impacts from human activities.展开更多
Respect for human rights and protection of human rights are significant rules in the Constitution of the People’s Republic of China.In 2015,judicial administration departments at all levels legally exercised their du...Respect for human rights and protection of human rights are significant rules in the Constitution of the People’s Republic of China.In 2015,judicial administration departments at all levels legally exercised their duties,implemented the principles and rules in constitution,and kept strengthening propagation of human rights through creation of contents and methods which had acquired great effects.What they have done contributes significantly toward the development of human rights in China.展开更多
Understanding the temporal and spatial variation of hydrochemical components in large freshwater lakes is crucial for effective management and conversation.In this study,we identify the temporalspatial characteristics...Understanding the temporal and spatial variation of hydrochemical components in large freshwater lakes is crucial for effective management and conversation.In this study,we identify the temporalspatial characteristics and driving factors of the hydrochemical components in Baiyangdian Lake using geochemical methods(Gibbs diagram,Piper diagram and End-element diagram of ion ratio)and multivariate statistical techniques(Principal component analysis and Correlation analysis).16 sets of samples were collected from Baiyangdian Lake in May(normal season),July(flood season),and December(dry season)of 2022.Results indicate significant spatial variation in Nat,ci,SO and NO,,suggesting a strong influence of human activities.Cation concentrations exhibit greater seasonal variation in the dry season compared to the flood season,while the concentrations of the four anions show inconsistent seasonal changes due to the combined effects of river water chemical composition and human activities.The hydrochemical type of Baiyangdian Lake is primarily HCO,Cl-Na.Ca,Mg*and HCO,originate mainly from silicate and carbonate rock dissolution,while Kt,Nat and CI originate mainly from sewage and salt dissolution in sediments.SO42 may mainly stem from industrial wastewater,while NO,primarily originates from animal feces and domestic sewage.Through the use of Principal Component Analysis,it is identified that water-rock interaction(silicate and carbonate rocks dissolution,and dissolution of salt in sediments),carbonate sedimentation,sewage,agricultural fertilizer and manure,and nitrification are the main driving factors of the variation of hydrochemical components of Baiyangdian Lake across three hydrological seasons.These findings suggest the need for effective control of substandard domestic sewage discharge,optimization of agricultural fertilization strategies,and proper management of animal manure to comprehensively improve the water environment in Baiyangdian Lake.展开更多
基金financially supported by the Geological Survey Project of China Geological Survey(DD20230077,DD20230456,DD20230424)。
文摘The analysis of hydrochemical characteristics and influencing factors of surface river on plateau is helpful to study water hydrological cycle and environmental evolution,which can scientifically guide rational development and utilization of water resources and planning of ecological environment protection.With the expansion and diversification of human activities,the quality of surface rivers will be more directly affected.Therefore,it is of great significance to pay attention to the hydrochemical characteristics of plateau surface rivers and the influence of human activities on their circulation and evolution.In this study,surface water in the Duoqu basin of Jinsha River located in Hengduan mountain region of Eastern Tibet was selected as the representative case.Twenty-three groups of surface water samples were collected to analyze the hydrochemical characteristics and ion sources based on correlation analysis,piper trigram,gibbs model,hydrogen and oxygen isotopic techniques.The results suggest the following:(1)The pH showed slight alkalinity with the value ranged from 7.25 to 8.62.Ca^(2+),Mg^(2+)and HCO_(3)^(–)were the main cations and anions.HCO_(3)^(-)Ca and HCO_(3)^(-)Ca·Mg were the primary hydrochemical types for the surface water of Duoqu River.The correlation analysis showed that TDS had the most significant correlation with Ca^(2+),Mg^(2+)and HCO_(3)^(–).Analysis on hydrogen and oxygen isotopes indicated that the surface rivers were mainly recharged by atmospheric precipitation and glacial melt water in this study area.(2)The surface water had a certain reverse cation alternating adsorption,and surface water ions were mainly derived from rock weathering,mainly controlled by weathering and dissolution of carbonates,and secondly by silicates and sodium rocks.(3)The influence of human activities was weak,while the development of cinnabar minerals had a certain impact on the hydrochemistry characteristics,which was the main factor for causing the increase of SO_(4)^(2–).The densely populated county towns and temples with frequent incense burning activities may cause some anomalies of surface water quality.At present,the Duoqu River watershed had gone through a certain influence of mineral exploitation,so the hydrological cycle and river eco-environment at watershed scale will still bound to be change.The results could provide basic support for better understanding water balance evolution as well as the ecological protection of Duoqu River watershed.
基金supported by National Natural Science Foundation of China (NSFC) (No. 61804103)National Key R&D Program of China (No. 2017YFA0205002)+8 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Nos. 18KJA535001 and 14KJB 150020)Natural Science Foundation of Jiangsu Province of China (Nos. BK20170343 and BK20180242)China Postdoctoral Science Foundation (No. 2017M610346)State Key Laboratory of Silicon Materials, Zhejiang University (No. SKL2018-03)Nantong Municipal Science and Technology Program (No. GY12017001)Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University (KSL201803)supported by Collaborative Innovation Center of Suzhou Nano Science & Technology, the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the 111 ProjectJoint International Research Laboratory of Carbon-Based Functional Materials and Devices
文摘Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped stretchable and tailorable triboelectric nanogenerator(FST-TENG)based on the geometric construction of a steel wire as electrode and ingenious selection of silicone rubber as triboelectric layer.Owing to the great robustness and continuous conductivity,the FST-TENGs demonstrate high stability,stretchability,and even tailorability.For a single device with ~6 cm in length and ~3 mm in diameter,the open-circuit voltage of ~59.7 V,transferred charge of ~23.7 nC,short-circuit current of ~2.67 μA and average power of ~2.13 μW can be obtained at 2.5 Hz.By knitting several FST-TENGs to be a fabric or a bracelet,it enables to harvest human motion energy and then to drive a wearable electronic device.Finally,it can also be woven on dorsum of glove to monitor the movements of gesture,which can recognize every single finger,different bending angle,and numbers of bent finger by analyzing voltage signals.
基金The National Key Basic Research Program of China under contract No.2010CB428902the United Program of National Natural Science Foundation of China and Shandong Province under contract No.U1406403the Special Fund for Basic Scientific Research Business of Central Public Research Institutes under contrast No.20603022013003
文摘Long-term changes of composition, sources and burial fluxes of TOC (total organic carbon) in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, similarity analysis is employed to confirm that the carbon burial features resulted from two collected cores are typical in the central Yellow Sea mud area where YSWC (Yellow Sea Warm Current) is prevalent. On this basis, the burial flux of TOC here was considered to be 235.5-488.4 pmol/(cm^2.a) since the first industrial revolution, accounting for about 70%-90% among burial fluxes of TC (total carbon) in the sediments. Compared TOC/TC ratio in the two cores with that in other marine sediments worldwide, we suggest that the growth of calcareous/non-calcareous organisms and dissolution of IC (inorganic carbon) are important factors controlling the TOC/TC ratio in sediment. Results of two-end mixed model based on fi13C data indicate that marine-derived organic carbon (OCa) is the main part among total burial organic carbon which accounts for a ratio over 85%. Due to the high TOC/TC ratio in the two cores, TC in the sediments also mainly exists as OCa, and the proportion of OCa is about 60%-80%. Away from the shore and relatively high primary production in upper waters are the main reasons that OCa is predominant among all burial OC in sediments of the central Yellow Sea mud area. Burial of OC in this mud area is probably mainly influenced by the human activities. Although the economic development during the late 19th century caused by the first industrial revolution in China did not obviously increase the TOC burial fluxes in the sediments, the rise of industry and agriculture after the founding of new China has clearly increased the TOC burial flux since 1950s. Otherwise, we also realize that among TC burial fluxes, TIC account for about 10%-30% in sediments of the central Yellow Sea mud area, so its burial could not be simply ignored here. Distinct from TOC burial, long-term TIC burial fluxes variations relate with climate changes more closely: the East Asian summer monsoon may influence the strength of the Huanghe River (Yellow River) flood, which could further affect the transport of terrestrial IC from land to the central Yellow Sea as well as the burial of these IC in the sediments.
基金The National Natural Science Foundation of China under contract Nos 41930538,42076211 and 42076058the Scientific Research Foundation of the Third Institute of Oceanography,Ministry of Natural Resources under contract Nos 2022017 and 2019006the China Postdoctoral Science Foundation under contract No.2019M652248.
文摘The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.
基金financially supported jointly by the National Basic Research Program of China (Grant No. 2006CB403201)the National Natural Science Foundation of China (Grant No. 40673068)
文摘Lacustrine sediments can provide potential information about environmental changes in the past. On the basis of high-resolution multi-proxy analysis including carbon and nitrogen contents of organic matter, C/N ratios, inorganic carbon contents, and carbon and oxygen isotopic composition of carbonate, together with precise 137Cs dating, the environmental evolution of Lake Chenghai, Yunnan Province, during the past 100 years has been investigated. It is shown that the carbonate in Lake Chenghai is authigenic, and the organic matter is mainly derived from aquatic plants and algae, instead of terrestrial-source materials. The environmental evolution of Lake Chenghai can be diverged into three periods with the contrasting characteristics during the past 100 years. Before 1940, the stable carbon and oxygen isotope values, the poor correlation between them and the lower carbon and nitrogen contents of organic matter suggested that Lake Chenghai was open, and the lake water was oligotrophic during that period. During 1940-1993, the negative δ13C values and the gradual increase of carbon and nitrogen contents of organic matter and C/N ratios indicated that the eutrophication was aggravated. The closeness of Lake Chenghai and human activities may be responsible for this eutrophication. After 1993, notable increases in carbon and oxygen isotopic values of carbonate, carbon and nitrogen contents of organic matter, C/N ratios and inorganic carbon contents demonstrated that the increase of lacustrine productivity and the serious eutrophication were resulted from strong human activities. Therefore, the multi-proxy in Lake Chenghai sediments has reliably recorded the natural environmental evolution and the impacts from human activities.
文摘Respect for human rights and protection of human rights are significant rules in the Constitution of the People’s Republic of China.In 2015,judicial administration departments at all levels legally exercised their duties,implemented the principles and rules in constitution,and kept strengthening propagation of human rights through creation of contents and methods which had acquired great effects.What they have done contributes significantly toward the development of human rights in China.
基金supported by the Natural Science Foundation of China(Grant No.42377232)Natural Science Foundation of Hebei Province of China(Grant No.D2022504015)+1 种基金the Fundamental Research Funds for the Chinese Academy of Geological Sciences(No.YK202310)the open funds of laboratory of water environmental science of Hebei Province,China(Grant No.HBSHJ 202103).
文摘Understanding the temporal and spatial variation of hydrochemical components in large freshwater lakes is crucial for effective management and conversation.In this study,we identify the temporalspatial characteristics and driving factors of the hydrochemical components in Baiyangdian Lake using geochemical methods(Gibbs diagram,Piper diagram and End-element diagram of ion ratio)and multivariate statistical techniques(Principal component analysis and Correlation analysis).16 sets of samples were collected from Baiyangdian Lake in May(normal season),July(flood season),and December(dry season)of 2022.Results indicate significant spatial variation in Nat,ci,SO and NO,,suggesting a strong influence of human activities.Cation concentrations exhibit greater seasonal variation in the dry season compared to the flood season,while the concentrations of the four anions show inconsistent seasonal changes due to the combined effects of river water chemical composition and human activities.The hydrochemical type of Baiyangdian Lake is primarily HCO,Cl-Na.Ca,Mg*and HCO,originate mainly from silicate and carbonate rock dissolution,while Kt,Nat and CI originate mainly from sewage and salt dissolution in sediments.SO42 may mainly stem from industrial wastewater,while NO,primarily originates from animal feces and domestic sewage.Through the use of Principal Component Analysis,it is identified that water-rock interaction(silicate and carbonate rocks dissolution,and dissolution of salt in sediments),carbonate sedimentation,sewage,agricultural fertilizer and manure,and nitrification are the main driving factors of the variation of hydrochemical components of Baiyangdian Lake across three hydrological seasons.These findings suggest the need for effective control of substandard domestic sewage discharge,optimization of agricultural fertilization strategies,and proper management of animal manure to comprehensively improve the water environment in Baiyangdian Lake.