The mechanism of strengthening of cube texture ({001}<100>) by additional annealing of high purity aluminum foils was investigated by using orientation distribution functions (ODFs) and electron back scattered d...The mechanism of strengthening of cube texture ({001}<100>) by additional annealing of high purity aluminum foils was investigated by using orientation distribution functions (ODFs) and electron back scattered diffraction (EBSD). The results of ODFs and fiber show that the orientation densities of the S {123}<634> and Cu {112}<111> components increase in both the additional annealed samples and the 0.11 mm final cold rolled foils. And the EBSD results demonstrate that cube nuclei can be identified in the deformed matrix of those additional annealed samples. It is suggested that the strengthening of cube texture can be brought out by the increasing of components of S and Cu and the formation of cube nuclei caused by additional annealing. Moreover, it is found that the cube texture increases first and then decreases with increasing additional annealing temperature, and it is the strongest at 180 ℃.The strengthening of cube texture by additional annealing is proposed as the result of oriented growth of cube subgrains.展开更多
Slurry preparation is one of the most critical steps for semisolid casting, and its primary goal is to prepare slurry with uniformly distributed fine globules. In this work, electromagnetic stirring(EMS) and the addit...Slurry preparation is one of the most critical steps for semisolid casting, and its primary goal is to prepare slurry with uniformly distributed fine globules. In this work, electromagnetic stirring(EMS) and the addition of Sc and Zr elements were used to prepare semisolid slurry of 7A04 aluminum alloy in a large diameter slurry maker. The effects of different treatments on the microstructure, composition and their radial homogeneity were investigated. The results show that, compared to the slurry without any treatment, large volume slurry with finer and more uniform microstructure can be obtained when treated by EMS, Sc, or Zr additions individually. EMS is more competent in the microstructural and chemical homogenization of the slurry while Sc and Zr additions are more excellent in its microstructural refinement. The combined treatment of EMS, Sc and Zr produces premium 7A04 aluminum alloy slurry with uniformly distributed fine α-Al globules and composition. The interaction mechanism between EMS and Sc and Zr additions was also discussed.展开更多
Small amount of calcium addition to the Mg-9Al-0.8Zn-0.2Mn (AZ91) alloy resulted in obvious influence on mechanical properties. The yield strength of the alloys increased with the increase of Ca addition and the maxim...Small amount of calcium addition to the Mg-9Al-0.8Zn-0.2Mn (AZ91) alloy resulted in obvious influence on mechanical properties. The yield strength of the alloys increased with the increase of Ca addition and the maximum strength was obtained from the alloy containing 0.15% of Ca. The creep resistance at the temperatures between 150-220°C was also significantly increased with Ca addition. The creep rate (at 200°C, 50 MPa) of the alloy with 0.15% Ca addition was one order of magnitude lower than that of the base alloy (AZ91). Microstructural observations revealed that the addition of calcium refined the microstructure and enhanced the thermal stability of the β precipitates, which accounted for the improvement of creep resistance at high temperatures.展开更多
Porous ceramics were prepared from kaolinite gangue and Al(OH)3 with double addition of MgCO3 and CaCO3 by the pore-forming in-situ technique.The characterizations of porous ceramics were investigated by X-ray diffr...Porous ceramics were prepared from kaolinite gangue and Al(OH)3 with double addition of MgCO3 and CaCO3 by the pore-forming in-situ technique.The characterizations of porous ceramics were investigated by X-ray diffractometry,scanning electron microscopy,and mercury porosimetry measurements,etc.It is found that although the decomposition of MgCO3 and CaCO3 has little contribution to the porosity,the double addition of MgCO3 and CaCO3 strongly affects the formation of liquid phase,and then changes the phase compositions,pore characterization,and strength.The appropriate mode is the sample containing 1.17wt% MgCO3 and 1.17wt% CaCO3,which has high apparent porosity(41.0%),high crushing strength(53.5 MPa),high mullite content(76wt%),and small average pore size(3.24 μm).展开更多
The effects of La addition on the microstructure and tensile properties of B-refmed and Sr-modified A1-1 1Si-1.5Cu-0.3Mg cast- ing alloys were investigated. With a trace addition of La (0.05wt%-0. lwt%), the mutual ...The effects of La addition on the microstructure and tensile properties of B-refmed and Sr-modified A1-1 1Si-1.5Cu-0.3Mg cast- ing alloys were investigated. With a trace addition of La (0.05wt%-0. lwt%), the mutual poisoning effect between B and Sr can be neutral- ized by the formation of LaB6 rather than SrB6. By employing a La/B weight ratio of 2:1, uniform microstructures, which are characterized by well refined ct-A1 grains and adequately modified eutectic Si particles as well as the incorporation of precipitated strengthening intermetal- lics, are obtained and lead to appreciable tensile properties with an ultimate tensile strength of 270 MPa and elongation of 5.8%.展开更多
The mechanical properties of Al-Cu-Mn casting alloy mainly depend on the morphology, distribution, size, and number ofθ′(Al2Cu) precipitates. In this study, we have analyzed the effect of rare earth samarium (Sm...The mechanical properties of Al-Cu-Mn casting alloy mainly depend on the morphology, distribution, size, and number ofθ′(Al2Cu) precipitates. In this study, we have analyzed the effect of rare earth samarium (Sm) addition on the kinetics of precipitation in the Al-Cu-Mn casting alloy by using differential scanning calorimetry (DSC) and high-resolution transmission electron microscopy. Thermal ef-fect peaks that are attributed to the formation and the dissolution of Guinier-Preston (GP) zone andθ′phase were identified from the DSC curves. The activation energy ofθ′formation was calculated by using both the Kissinger method and the analytical model, and the corre-sponding results were compared. Results suggest that the activation energy ofθ′formation in Al-Cu-Mn alloy is dramatically higher than that in Al-Cu-Mn-Sm alloy. Accordingly, it is concluded that the addition of rare earth Sm decreases the activation energy ofθ′formation and promotes the formation ofθ′precipitates.展开更多
Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrost...Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrostructure of as-cast ingots. Although the addition of VC particles does not cause any significant change of the as-cast microstructure, the microstructure of the alloy after hot-working and recrystallization has been found to be refined. The formation of both VC and TiC particles results in the increase of yield strength, especially at the high temperature of 600°C.展开更多
Al-Cu-Mg-Ag alloys with different Yb contents were prepared by ingot metallurgy and thermomechanical treatment. The effect of Yb addition on the precipitation and microstructure of the alloys was investigated using me...Al-Cu-Mg-Ag alloys with different Yb contents were prepared by ingot metallurgy and thermomechanical treatment. The effect of Yb addition on the precipitation and microstructure of the alloys was investigated using mechanical properties testing, optical microscopy, differential scanning calorimetry(DSC), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The results show that adding 0.10%-0.35% Yb accelerates the aging hardening process, increases the maximum hardness and the tensile strength of the extruded alloys from room temperature to 300 ℃. Trace Yb element addition refines the grains of the casting alloys from 85 μm to 30 μm, decreases the precipitation temperature of Ω phase. Moreover, the addition of Yb into Al-Cu-Mg-Ag alloy decreases the precipitates size, and improves the density and the thermal stability of Ω phase between 200 ℃ and 300 ℃ .展开更多
Al-5.3Cu-0.8Mg-0.6Ag alloys containing 0, 0.1, 0.3 and 0.5 (mass. %) Sc were prepared by ingot metallurgy and thermomechanical treatment. The effect of Sc addition on the precipitation and microstructure of the alloys...Al-5.3Cu-0.8Mg-0.6Ag alloys containing 0, 0.1, 0.3 and 0.5 (mass. %) Sc were prepared by ingot metallurgy and thermomechanical treatment. The effect of Sc addition on the precipitation and microstructure of the alloys has been investigated using mechanical testing, optical microscope, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It has been shown that trace Sc element refines the grains of the casting alloys and the average grain size decreases from 85 μm to 30 μm. Increasing Sc content from 0.1 to 0.3% accelerates the aging hardening process, increases the maximum hardness and the tensile strength of the extruded alloys from room temperature to 300 ℃. The high strength of the alloys with Sc is attributed to the high density and high thermal stability of fine Ω precipitates, and nanosized Al3(Sc,Zr) and AlCu(Zr, Sc) particles.展开更多
Airburn reaction and carboxy reaction result in the excess consumption ofcarbon anode in aluminum electrolysis. To reduce the excess carbon consumption, carbon anode wasdoped with aluminum-containing additives, such a...Airburn reaction and carboxy reaction result in the excess consumption ofcarbon anode in aluminum electrolysis. To reduce the excess carbon consumption, carbon anode wasdoped with aluminum-containing additives, such as Al, Al_4C_3, AlF_3 and Al_2O_3. Their reactivityin air and CO_2 was determined with an isothermal-gravimetric method to study the effect ofaluminum-containing additives on the reactivity in air and CO_2 of carbon anode. Results shown thatthe airburn reactivity at 450℃ and carboxy reactivity at 970℃ of carbon anode both decreased withAl-containing additives adding, while shown a minimum with the amount of Al_4C_3, AlF_3 and Al_2O_3increasing. However, all Al-containing additives increase the airburn reactivity at 550℃ of carbonanodes. Coke yield measurement and XRD examination with aluminum containing additives doped pitchcokes revealed that the effect of Al-containing additives on the airburn reactivity and carboxyreactivity of carbon anode would result from chemical factors and structural factors.展开更多
10Cu/(10NiO-NiFe2O4)cermets doped with Yb2O3 were prepared by conventional powder metallurgy technique.The effects of Yb2O3 content and sintering temperature on the relative density,phase composition,microstructure of...10Cu/(10NiO-NiFe2O4)cermets doped with Yb2O3 were prepared by conventional powder metallurgy technique.The effects of Yb2O3 content and sintering temperature on the relative density,phase composition,microstructure of the sintered cermets and the corrosion resistance to Na3AlF6-Al2O3 melts were investigated by sintered density test,XRD analysis and SEM.YbFeO3 phase,which distributes in the ceramics grain boundary as particles or film,is produced by the reaction between Yb2O3 and ceramics. The addition of Yb2O3 accelerates the sintering process of ceramics matrix,eliminates pores in the boundary and results in coarsened crystalline grain.The relative density of the cermets with about 1%(mass fraction)Yb2O3 sintered at 1 275℃increases to above 95%.Addition of about 1.0%Yb2O3 can inhibit obviously the corrosion of NiFe2O4 grain boundary and Cu phase in Na3AlF6-Al2O3 melts.展开更多
Effects of Al- Si addition on hot modulus of rup- ture ~ HMOR) . thermal shock resistance ~ TSR~ . phase composition and mierostructure of low-carbon MgO - C materials were investigated. The results show that: Al an...Effects of Al- Si addition on hot modulus of rup- ture ~ HMOR) . thermal shock resistance ~ TSR~ . phase composition and mierostructure of low-carbon MgO - C materials were investigated. The results show that: Al and Si addition to low-carbon MgO - C materials leads to dramatic increase in MOR at elevated temperatures; it increases from 4 MPa to 11 -21 MPa at 1 200 ℃ and from 2 MPa to 21 -29 MPa at 1 400 ℃. Al and Si addition to low-carbon MgO - C materials also improves TSR: residual strength ratio after thermal shock when △T = 1 200 ℃ is increased,from 44% to 73% - 77%. Al reacts with C and N2 to form, Al4C3 and AlN, Si reacts with C to form SiC. Ultimately. in-situ formed non- oxides increase appreciably with temperature rising and are well interlaced in periclase skeleton structure at 1 300 -1 400 ℃. which is beneficial to thermomechanical properties.展开更多
文摘The mechanism of strengthening of cube texture ({001}<100>) by additional annealing of high purity aluminum foils was investigated by using orientation distribution functions (ODFs) and electron back scattered diffraction (EBSD). The results of ODFs and fiber show that the orientation densities of the S {123}<634> and Cu {112}<111> components increase in both the additional annealed samples and the 0.11 mm final cold rolled foils. And the EBSD results demonstrate that cube nuclei can be identified in the deformed matrix of those additional annealed samples. It is suggested that the strengthening of cube texture can be brought out by the increasing of components of S and Cu and the formation of cube nuclei caused by additional annealing. Moreover, it is found that the cube texture increases first and then decreases with increasing additional annealing temperature, and it is the strongest at 180 ℃.The strengthening of cube texture by additional annealing is proposed as the result of oriented growth of cube subgrains.
基金financially supported by the National Key Technology R&D Program(2015BAG12B01)the National Natural Science Foundation of China(11672251)the State Key Lab of Materials Processing and Die&Mould Technology,Huazhong University of Science and Technology(P2015-10)
文摘Slurry preparation is one of the most critical steps for semisolid casting, and its primary goal is to prepare slurry with uniformly distributed fine globules. In this work, electromagnetic stirring(EMS) and the addition of Sc and Zr elements were used to prepare semisolid slurry of 7A04 aluminum alloy in a large diameter slurry maker. The effects of different treatments on the microstructure, composition and their radial homogeneity were investigated. The results show that, compared to the slurry without any treatment, large volume slurry with finer and more uniform microstructure can be obtained when treated by EMS, Sc, or Zr additions individually. EMS is more competent in the microstructural and chemical homogenization of the slurry while Sc and Zr additions are more excellent in its microstructural refinement. The combined treatment of EMS, Sc and Zr produces premium 7A04 aluminum alloy slurry with uniformly distributed fine α-Al globules and composition. The interaction mechanism between EMS and Sc and Zr additions was also discussed.
文摘Small amount of calcium addition to the Mg-9Al-0.8Zn-0.2Mn (AZ91) alloy resulted in obvious influence on mechanical properties. The yield strength of the alloys increased with the increase of Ca addition and the maximum strength was obtained from the alloy containing 0.15% of Ca. The creep resistance at the temperatures between 150-220°C was also significantly increased with Ca addition. The creep rate (at 200°C, 50 MPa) of the alloy with 0.15% Ca addition was one order of magnitude lower than that of the base alloy (AZ91). Microstructural observations revealed that the addition of calcium refined the microstructure and enhanced the thermal stability of the β precipitates, which accounted for the improvement of creep resistance at high temperatures.
基金Puyang Re-fractories Co. Ltd. for financially supporting
文摘Porous ceramics were prepared from kaolinite gangue and Al(OH)3 with double addition of MgCO3 and CaCO3 by the pore-forming in-situ technique.The characterizations of porous ceramics were investigated by X-ray diffractometry,scanning electron microscopy,and mercury porosimetry measurements,etc.It is found that although the decomposition of MgCO3 and CaCO3 has little contribution to the porosity,the double addition of MgCO3 and CaCO3 strongly affects the formation of liquid phase,and then changes the phase compositions,pore characterization,and strength.The appropriate mode is the sample containing 1.17wt% MgCO3 and 1.17wt% CaCO3,which has high apparent porosity(41.0%),high crushing strength(53.5 MPa),high mullite content(76wt%),and small average pore size(3.24 μm).
基金supported by the Industry, Education, and Research Prospective Project of Jiangsu Province, China (No. BY2012191)the Open Research of Jiangsu Key Laboratory of Advanced Metallic Materials (No. AMM201202)
文摘The effects of La addition on the microstructure and tensile properties of B-refmed and Sr-modified A1-1 1Si-1.5Cu-0.3Mg cast- ing alloys were investigated. With a trace addition of La (0.05wt%-0. lwt%), the mutual poisoning effect between B and Sr can be neutral- ized by the formation of LaB6 rather than SrB6. By employing a La/B weight ratio of 2:1, uniform microstructures, which are characterized by well refined ct-A1 grains and adequately modified eutectic Si particles as well as the incorporation of precipitated strengthening intermetal- lics, are obtained and lead to appreciable tensile properties with an ultimate tensile strength of 270 MPa and elongation of 5.8%.
基金financially supported by the Aeronautical Science Foundation of China(No.2012ZF53080)the Shaanxi Province Science and Technology Research and Development Program of China(No.2013K08-11)+1 种基金the Fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University(No.SKLSP201009)the 111 Project of China(No.B08040)
文摘The mechanical properties of Al-Cu-Mn casting alloy mainly depend on the morphology, distribution, size, and number ofθ′(Al2Cu) precipitates. In this study, we have analyzed the effect of rare earth samarium (Sm) addition on the kinetics of precipitation in the Al-Cu-Mn casting alloy by using differential scanning calorimetry (DSC) and high-resolution transmission electron microscopy. Thermal ef-fect peaks that are attributed to the formation and the dissolution of Guinier-Preston (GP) zone andθ′phase were identified from the DSC curves. The activation energy ofθ′formation was calculated by using both the Kissinger method and the analytical model, and the corre-sponding results were compared. Results suggest that the activation energy ofθ′formation in Al-Cu-Mn alloy is dramatically higher than that in Al-Cu-Mn-Sm alloy. Accordingly, it is concluded that the addition of rare earth Sm decreases the activation energy ofθ′formation and promotes the formation ofθ′precipitates.
文摘Microstructure and tensile properties of Fe3 Al-based alloys with the additions of TiC and VC particles have been investigated. Results show that the formation of TiC particles results in the refinement of the macrostructure of as-cast ingots. Although the addition of VC particles does not cause any significant change of the as-cast microstructure, the microstructure of the alloy after hot-working and recrystallization has been found to be refined. The formation of both VC and TiC particles results in the increase of yield strength, especially at the high temperature of 600°C.
基金Project(20070410986) support by Postdoctoral Research Foundation of ChinaProject(ZMPL07SW0002) support by Laboratory of Material Physics of Zhengzhou University, China
文摘Al-Cu-Mg-Ag alloys with different Yb contents were prepared by ingot metallurgy and thermomechanical treatment. The effect of Yb addition on the precipitation and microstructure of the alloys was investigated using mechanical properties testing, optical microscopy, differential scanning calorimetry(DSC), scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The results show that adding 0.10%-0.35% Yb accelerates the aging hardening process, increases the maximum hardness and the tensile strength of the extruded alloys from room temperature to 300 ℃. Trace Yb element addition refines the grains of the casting alloys from 85 μm to 30 μm, decreases the precipitation temperature of Ω phase. Moreover, the addition of Yb into Al-Cu-Mg-Ag alloy decreases the precipitates size, and improves the density and the thermal stability of Ω phase between 200 ℃ and 300 ℃ .
基金Support by China Postdoctoral Research Function (20070410986)
文摘Al-5.3Cu-0.8Mg-0.6Ag alloys containing 0, 0.1, 0.3 and 0.5 (mass. %) Sc were prepared by ingot metallurgy and thermomechanical treatment. The effect of Sc addition on the precipitation and microstructure of the alloys has been investigated using mechanical testing, optical microscope, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It has been shown that trace Sc element refines the grains of the casting alloys and the average grain size decreases from 85 μm to 30 μm. Increasing Sc content from 0.1 to 0.3% accelerates the aging hardening process, increases the maximum hardness and the tensile strength of the extruded alloys from room temperature to 300 ℃. The high strength of the alloys with Sc is attributed to the high density and high thermal stability of fine Ω precipitates, and nanosized Al3(Sc,Zr) and AlCu(Zr, Sc) particles.
基金This work is supported by the National Basic Research Program of China (No. G1999064903).
文摘Airburn reaction and carboxy reaction result in the excess consumption ofcarbon anode in aluminum electrolysis. To reduce the excess carbon consumption, carbon anode wasdoped with aluminum-containing additives, such as Al, Al_4C_3, AlF_3 and Al_2O_3. Their reactivityin air and CO_2 was determined with an isothermal-gravimetric method to study the effect ofaluminum-containing additives on the reactivity in air and CO_2 of carbon anode. Results shown thatthe airburn reactivity at 450℃ and carboxy reactivity at 970℃ of carbon anode both decreased withAl-containing additives adding, while shown a minimum with the amount of Al_4C_3, AlF_3 and Al_2O_3increasing. However, all Al-containing additives increase the airburn reactivity at 550℃ of carbonanodes. Coke yield measurement and XRD examination with aluminum containing additives doped pitchcokes revealed that the effect of Al-containing additives on the airburn reactivity and carboxyreactivity of carbon anode would result from chemical factors and structural factors.
基金Project(2008AA030501)supported by the High-tech Research and Development Program of ChinaProject(200733)supported by the Postdoctoral Science Fund of Central South University,ChinaProject(50721003)supported by the National Natural Science Foundation for Innovation Group of China
文摘10Cu/(10NiO-NiFe2O4)cermets doped with Yb2O3 were prepared by conventional powder metallurgy technique.The effects of Yb2O3 content and sintering temperature on the relative density,phase composition,microstructure of the sintered cermets and the corrosion resistance to Na3AlF6-Al2O3 melts were investigated by sintered density test,XRD analysis and SEM.YbFeO3 phase,which distributes in the ceramics grain boundary as particles or film,is produced by the reaction between Yb2O3 and ceramics. The addition of Yb2O3 accelerates the sintering process of ceramics matrix,eliminates pores in the boundary and results in coarsened crystalline grain.The relative density of the cermets with about 1%(mass fraction)Yb2O3 sintered at 1 275℃increases to above 95%.Addition of about 1.0%Yb2O3 can inhibit obviously the corrosion of NiFe2O4 grain boundary and Cu phase in Na3AlF6-Al2O3 melts.
文摘Effects of Al- Si addition on hot modulus of rup- ture ~ HMOR) . thermal shock resistance ~ TSR~ . phase composition and mierostructure of low-carbon MgO - C materials were investigated. The results show that: Al and Si addition to low-carbon MgO - C materials leads to dramatic increase in MOR at elevated temperatures; it increases from 4 MPa to 11 -21 MPa at 1 200 ℃ and from 2 MPa to 21 -29 MPa at 1 400 ℃. Al and Si addition to low-carbon MgO - C materials also improves TSR: residual strength ratio after thermal shock when △T = 1 200 ℃ is increased,from 44% to 73% - 77%. Al reacts with C and N2 to form, Al4C3 and AlN, Si reacts with C to form SiC. Ultimately. in-situ formed non- oxides increase appreciably with temperature rising and are well interlaced in periclase skeleton structure at 1 300 -1 400 ℃. which is beneficial to thermomechanical properties.
基金supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(No.KYCX22_1311)the Natural Science Foundation of Jiangsu Province,China(No.BK20190684)the Natural Science Research of the Jiangsu Higher Education Institutions of China(No.18KJB460016)。