Aluminum silicon titanium master alloys were prepared in the laboratory by electrolysis of silica and titania dissolved in cryolite alumina melts. Alloys containing up to 12 mass% Si and 2.6 mass% Ti were formed af...Aluminum silicon titanium master alloys were prepared in the laboratory by electrolysis of silica and titania dissolved in cryolite alumina melts. Alloys containing up to 12 mass% Si and 2.6 mass% Ti were formed after about 90 min of electrolysis at 950℃. The current efficiency for the preparation of the Al Si Ti alloys varied with time, temperature and cathodic current density. It is concluded that this electrolytic method may be an interesting alternative to the direct metal mixing process for formation of Al Si Ti master alloys.展开更多
The effects of Na+ and Ca2+ in the purified water on the conductivity of zinc electrolyte and the current efficiency of zinc electrolysis were studied by the alternating current bridge method and the simulated electro...The effects of Na+ and Ca2+ in the purified water on the conductivity of zinc electrolyte and the current efficiency of zinc electrolysis were studied by the alternating current bridge method and the simulated electrolysis experiments,and the water quality index of reused water was established. The results show that the conductivity of the solution and the current efficiency decrease as these two kinds of positive ions are added in the electrolyte. The effect of Ca2+ is much more remarkable than that of Na+. ρ(Na+)≤ 8 g/L and ρ(Ca2+)≤20 mg/L are the quality indexes in the zinc electrolysis process and the concentrations of Na+ and Ca2+ in the purified water reused to the process should be less than the limited values,i.e. the water quality index of the purified water should be controlled by its reused amount.展开更多
文摘Aluminum silicon titanium master alloys were prepared in the laboratory by electrolysis of silica and titania dissolved in cryolite alumina melts. Alloys containing up to 12 mass% Si and 2.6 mass% Ti were formed after about 90 min of electrolysis at 950℃. The current efficiency for the preparation of the Al Si Ti alloys varied with time, temperature and cathodic current density. It is concluded that this electrolytic method may be an interesting alternative to the direct metal mixing process for formation of Al Si Ti master alloys.
基金Project(2007BAC25B01) supported by the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science and Technology of China during the 11th Five-Year PlanProject(308019) supported by the Key Scientific and Technical Project, Ministry of Education of China+1 种基金Project(08JJ3020) supported by Hunan Provincial Natural Science Foundation of ChinaProject (50830301) supported by the Key Project of the National Natural Science Foundation of China
文摘The effects of Na+ and Ca2+ in the purified water on the conductivity of zinc electrolyte and the current efficiency of zinc electrolysis were studied by the alternating current bridge method and the simulated electrolysis experiments,and the water quality index of reused water was established. The results show that the conductivity of the solution and the current efficiency decrease as these two kinds of positive ions are added in the electrolyte. The effect of Ca2+ is much more remarkable than that of Na+. ρ(Na+)≤ 8 g/L and ρ(Ca2+)≤20 mg/L are the quality indexes in the zinc electrolysis process and the concentrations of Na+ and Ca2+ in the purified water reused to the process should be less than the limited values,i.e. the water quality index of the purified water should be controlled by its reused amount.
