Bio-based polyurethane foam has attracted increasing attentions due to eco-friendliness and fossil feedstock issues.However,the inherent flammability limits its application in different fields.Herein,we demonstrate a ...Bio-based polyurethane foam has attracted increasing attentions due to eco-friendliness and fossil feedstock issues.However,the inherent flammability limits its application in different fields.Herein,we demonstrate a green bio-based flame-retardant system to fabricate polyurethane foam composite with durable flame retardancy,smoke suppression,and thermal insulation property.In this system,the green bio-based polyol(VED)with good reactivity and compatibility plays a role of flame retardant and EG acts as a synergistic filler.As a result,the LOI value of foam composite increased to 30.5 vol.%and it achieved a V-0 rating in the UL-94 vertical burning test.Additionally,the peak heat release rate(pHRR)and the total smoke production(TSP)decreased by 66.1%and 63.4%,respectively.Furthermore,the foam composite maintained durable flame retardancy after accelerated thermal aging test,whose thermal-insulating property was maintained even after being treated in high-humidity environment with 85%R.H.for a week.This work provides a facile strategy for durable flame retardancy and long-term thermal insulation performance,and creates opportunities for the practical applications of bio-based foam composites.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22175123,52122302,and 51991351)the 111 Project(No.B20001)Fundamental Research Funds for the Central Universities,and Open and Innovative Fund of Hubei Three Gorges Laboratory(Nos.2022LF2021 and SC213011).
文摘Bio-based polyurethane foam has attracted increasing attentions due to eco-friendliness and fossil feedstock issues.However,the inherent flammability limits its application in different fields.Herein,we demonstrate a green bio-based flame-retardant system to fabricate polyurethane foam composite with durable flame retardancy,smoke suppression,and thermal insulation property.In this system,the green bio-based polyol(VED)with good reactivity and compatibility plays a role of flame retardant and EG acts as a synergistic filler.As a result,the LOI value of foam composite increased to 30.5 vol.%and it achieved a V-0 rating in the UL-94 vertical burning test.Additionally,the peak heat release rate(pHRR)and the total smoke production(TSP)decreased by 66.1%and 63.4%,respectively.Furthermore,the foam composite maintained durable flame retardancy after accelerated thermal aging test,whose thermal-insulating property was maintained even after being treated in high-humidity environment with 85%R.H.for a week.This work provides a facile strategy for durable flame retardancy and long-term thermal insulation performance,and creates opportunities for the practical applications of bio-based foam composites.
