Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low th...Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low thermal conductivity,lack of efficient solar-thermal media,and flamma-bility have constrained their broad applications.Herein,we present an innova-tive class of versatile composite phase change materials(CPCMs)developed through a facile and environmentally friendly synthesis approach,leveraging the inherent anisotropy and unidirectional porosity of wood aerogel(nanowood)to support polyethylene glycol(PEG).The wood modification process involves the incorporation of phytic acid(PA)and MXene hybrid structure through an evaporation-induced assembly method,which could impart non-leaking PEG filling while concurrently facilitating thermal conduction,light absorption,and flame-retardant.Consequently,the as-prepared wood-based CPCMs showcase enhanced thermal conductivity(0.82 W m^(-1)K^(-1),about 4.6 times than PEG)as well as high latent heat of 135.5 kJ kg^(-1)(91.5%encapsula-tion)with thermal durability and stability throughout at least 200 heating and cooling cycles,featuring dramatic solar-thermal conversion efficiency up to 98.58%.In addition,with the synergistic effect of phytic acid and MXene,the flame-retardant performance of the CPCMs has been significantly enhanced,showing a self-extinguishing behavior.Moreover,the excellent electromagnetic shielding of 44.45 dB was endowed to the CPCMs,relieving contemporary health hazards associated with electromagnetic waves.Overall,we capitalize on the exquisite wood cell structure with unidirectional transport inherent in the development of multifunctional CPCMs,showcasing the operational principle through a proof-of-concept prototype system.展开更多
Three-dimensional（3D） crossbar array architecture is one of the leading candidates for future ultra-high density nonvolatile memory applications. To realize the technological potential, understanding the reliability...Three-dimensional（3D） crossbar array architecture is one of the leading candidates for future ultra-high density nonvolatile memory applications. To realize the technological potential, understanding the reliability mechanisms of the3 D RRAM array has become a field of intense research. In this work, the endurance performance of the 3D 1D1 R crossbar array under the thermal effect is investigated in terms of numerical simulation. It is revealed that the endurance performance of the 3D 1D1 R array would be seriously deteriorated under thermal effects as the feature size scales down to a relatively small value. A possible method to alleviate the thermal effects is provided and verified by numerical simulation.展开更多
Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and The...Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and Thermal Gravity(TG)analysis that the blended material was superior in thermal behaviors to the material made from either Nomex or Viscose FR filament,when the ratio of Nomex and Lenzing Viscose FR reached 80∶20,and excellent thermal properties were achieved with the value of Limiting Oxygen Index(LOI)up to 36.1%.Blending Nomex and Viscose FR filaments may be recommended for better fire retardant property of related fabric.展开更多
The advancement of lithium-based batteries has spurred anticipation for enhanced energy density,extended cycle life and reduced capacity degradation.However,these benefits are accompanied by potential risks,such as th...The advancement of lithium-based batteries has spurred anticipation for enhanced energy density,extended cycle life and reduced capacity degradation.However,these benefits are accompanied by potential risks,such as thermal runaway and explosions due to higher energy density.Currently,liquid organic electrolytes are the predominant choice for lithium batteries,despite their limitations in terms of mechanical strength and vulnerability to leakage.The development of polymer electrolytes,with their high Young’s modulus and enhanced safety features,offers a potential solution to the drawbacks of traditional liquid electrolytes.Despite these advantages,polymer electrolytes are still susceptible to burning and decomposition.To address this issue,researchers have conducted extensive studies to improve their flame-retardant properties from various perspectives.This review provides a concise overview of the thermal runaway mechanisms,flame-retardant mechanisms and electrochemical performance of polymer electrolytes.It also outlines the advancements in flame-retardant polymer electrolytes through the incorporation of various additives and the selection of inherently flame-retardant matrix.This review aims to offer a comprehensive understanding of flame-retardant polymer electrolytes and serve as a guide for future research in this field.展开更多
基金funding from the National Natural Science Foundation of China(No.22268025)China Postdoctoral Science Foundation(NO.2022MD713757)+2 种基金Yunnan Provincial Postdoctoral Science Foundation(NO.34Y2022)Yunnan Province Joint Special Project for Enterprise Fundamental Research and Applied Basic Research(No.202101BC070001-016)Guangdong Basic and Applied Basic Research Foundation(No.2023A1515011985).
文摘Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low thermal conductivity,lack of efficient solar-thermal media,and flamma-bility have constrained their broad applications.Herein,we present an innova-tive class of versatile composite phase change materials(CPCMs)developed through a facile and environmentally friendly synthesis approach,leveraging the inherent anisotropy and unidirectional porosity of wood aerogel(nanowood)to support polyethylene glycol(PEG).The wood modification process involves the incorporation of phytic acid(PA)and MXene hybrid structure through an evaporation-induced assembly method,which could impart non-leaking PEG filling while concurrently facilitating thermal conduction,light absorption,and flame-retardant.Consequently,the as-prepared wood-based CPCMs showcase enhanced thermal conductivity(0.82 W m^(-1)K^(-1),about 4.6 times than PEG)as well as high latent heat of 135.5 kJ kg^(-1)(91.5%encapsula-tion)with thermal durability and stability throughout at least 200 heating and cooling cycles,featuring dramatic solar-thermal conversion efficiency up to 98.58%.In addition,with the synergistic effect of phytic acid and MXene,the flame-retardant performance of the CPCMs has been significantly enhanced,showing a self-extinguishing behavior.Moreover,the excellent electromagnetic shielding of 44.45 dB was endowed to the CPCMs,relieving contemporary health hazards associated with electromagnetic waves.Overall,we capitalize on the exquisite wood cell structure with unidirectional transport inherent in the development of multifunctional CPCMs,showcasing the operational principle through a proof-of-concept prototype system.
基金Project supported by the Opening Project of Key Laboratory of Microelectronics Devices&Integrated Technology,Institute of Microelectronics of Chinese Academy of Sciences,the National High Technology Research and Development Program of China(Grant No.2014AA032901)the National Natural Science Foundation of China(Grant Nos.61574166,61334007,61306117,61322408,61221004,and 61274091)+1 种基金Beijing Training Project for the Leading Talents in S&T,China(Grant No.Z151100000315008)the CAEP Microsystem and THz Science and Technology Foundation,China(Grant No.CAEPMT201504)
文摘Three-dimensional（3D） crossbar array architecture is one of the leading candidates for future ultra-high density nonvolatile memory applications. To realize the technological potential, understanding the reliability mechanisms of the3 D RRAM array has become a field of intense research. In this work, the endurance performance of the 3D 1D1 R crossbar array under the thermal effect is investigated in terms of numerical simulation. It is revealed that the endurance performance of the 3D 1D1 R array would be seriously deteriorated under thermal effects as the feature size scales down to a relatively small value. A possible method to alleviate the thermal effects is provided and verified by numerical simulation.
文摘Based on the analysis of the properties of Nomex 450 and Nomex 462,the thermal properties of Nomex 462/Lenzing Viscose Flame retardent(FR)blending materials were analyzed.It was discovered through burning test and Thermal Gravity(TG)analysis that the blended material was superior in thermal behaviors to the material made from either Nomex or Viscose FR filament,when the ratio of Nomex and Lenzing Viscose FR reached 80∶20,and excellent thermal properties were achieved with the value of Limiting Oxygen Index(LOI)up to 36.1%.Blending Nomex and Viscose FR filaments may be recommended for better fire retardant property of related fabric.
基金support by the National Key Research and Development Program(No.2023YFC3008804)the Tsinghua University-China Petrochemical Corporation Joint Institute for Green Chemical Engineering(No.224247)Beijing Municipal Science and Technology Commission(No.Z231100006123003).
文摘The advancement of lithium-based batteries has spurred anticipation for enhanced energy density,extended cycle life and reduced capacity degradation.However,these benefits are accompanied by potential risks,such as thermal runaway and explosions due to higher energy density.Currently,liquid organic electrolytes are the predominant choice for lithium batteries,despite their limitations in terms of mechanical strength and vulnerability to leakage.The development of polymer electrolytes,with their high Young’s modulus and enhanced safety features,offers a potential solution to the drawbacks of traditional liquid electrolytes.Despite these advantages,polymer electrolytes are still susceptible to burning and decomposition.To address this issue,researchers have conducted extensive studies to improve their flame-retardant properties from various perspectives.This review provides a concise overview of the thermal runaway mechanisms,flame-retardant mechanisms and electrochemical performance of polymer electrolytes.It also outlines the advancements in flame-retardant polymer electrolytes through the incorporation of various additives and the selection of inherently flame-retardant matrix.This review aims to offer a comprehensive understanding of flame-retardant polymer electrolytes and serve as a guide for future research in this field.
