Triboelectric‘electrostatic tweezers'for manipulating droplets on lubricated slippery surfaces prepared by femtosecond laser processing

The use of‘Electrostatic tweezers'is a promising tool for droplet manipulation,but it faces many limitations in manipulating droplets on superhydrophobic surfaces.Here,we achieve noncontact and multifunctional droplet manipulation on Nepenthes-inspired lubricated slippery surfaces via triboelectric electrostatic tweezers(TETs).The TET manipulation of droplets on a slippery surface has many advantages over electrostatic droplet manipulation on a superhydrophobic surface.The electrostatic field induces the redistribution of the charges inside the neutral droplet,which causes the triboelectric charged rod to drive the droplet to move forward under the electrostatic force.Positively or negatively charged droplets can also be driven by TET based on electrostatic attraction and repulsion.TET enables us to manipulate droplets under diverse conditions,including anti-gravity climb,suspended droplets,corrosive liquids,low-surface-tension liquids(e.g.ethanol with a surface tension of 22.3 mN·m^(-1)),different droplet volumes(from 100 nl to 0.5 ml),passing through narrow slits,sliding over damaged areas,on various solid substrates,and even droplets in an enclosed system.Various droplet-related applications,such as motion guidance,motion switching,droplet-based microreactions,surface cleaning,surface defogging,liquid sorting,and cell labeling,can be easily achieved with TETs.

Automatic Extraction Method of 3D Feature Guidelines for Complex Cultural Relic Surfaces Based on Point Cloud

Cultural relics line graphic serves as a crucial form of traditional artifact information documentation,which is a simple and intuitive product with low cost of displaying compared with 3D models.Dimensionality reduction is undoubtedly necessary for line drawings.However,most existing methods for artifact drawing rely on the principles of orthographic projection that always cannot avoid angle occlusion and data overlapping while the surface of cultural relics is complex.Therefore,conformal mapping was introduced as a dimensionality reduction way to compensate for the limitation of orthographic projection.Based on the given criteria for assessing surface complexity,this paper proposed a three-dimensional feature guideline extraction method for complex cultural relic surfaces.A 2D and 3D combined factor that measured the importance of points on describing surface features,vertex weight,was designed.Then the selection threshold for feature guideline extraction was determined based on the differences between vertex weight and shape index distributions.The feasibility and stability were verified through experiments conducted on real cultural relic surface data.Results demonstrated the ability of the method to address the challenges associated with the automatic generation of line drawings for complex surfaces.The extraction method and the obtained results will be useful for line graphic drawing,displaying and propaganda of cultural relics.

Discontinuity development patterns and the challenges for 3D discrete fracture network modeling on complicated exposed rock surfaces

Natural slopes usually display complicated exposed rock surfaces that are characterized by complex and substantial terrain undulation and ubiquitous undesirable phenomena such as vegetation cover and rockfalls.This study presents a systematic outcrop research of fracture pattern variations in a complicated rock slope,and the qualitative and quantitative study of the complex phenomena impact on threedimensional(3D)discrete fracture network(DFN)modeling.As the studies of the outcrop fracture pattern have been so far focused on local variations,thus,we put forward a statistical analysis of global variations.The entire outcrop is partitioned into several subzones,and the subzone-scale variability of fracture geometric properties is analyzed(including the orientation,the density,and the trace length).The results reveal significant variations in fracture characteristics(such as the concentrative degree,the average orientation,the density,and the trace length)among different subzones.Moreover,the density of fracture sets,which is approximately parallel to the slope surface,exhibits a notably higher value compared to other fracture sets across all subzones.To improve the accuracy of the DFN modeling,the effects of three common phenomena resulting from vegetation and rockfalls are qualitatively analyzed and the corresponding quantitative data processing solutions are proposed.Subsequently,the 3D fracture geometric parameters are determined for different areas of the high-steep rock slope in terms of the subzone dimensions.The results show significant variations in the same set of 3D fracture parameters across different regions with density differing by up to tenfold and mean trace length exhibiting differences of 3e4 times.The study results present precise geological structural information,improve modeling accuracy,and provide practical solutions for addressing complex outcrop issues.

Theoretical Modeling and Surface Roughness Prediction of Microtextured Surfaces in Ultrasonic Vibration-Assisted Milling

Textured surfaces with certain micro/nano structures have been proven to possess some advanced functions,such as reducing friction,improving wear and increasing wettability.Accurate prediction of micro/nano surface textures is of great significance for the design,fabrication and application of functional textured surfaces.In this paper,based on the kinematic analysis of cutter teeth,the discretization of ultrasonic machining process,transformation method of coordinate systems and the cubic spline data interpolation,an integrated theoretical model was established to characterize the distribution and geometric features of micro textures on the surfaces machined by different types of ultrasonic vibration-assisted milling(UVAM).Based on the theoretical model,the effect of key process parameters(vibration directions,vibration dimensions,cutting parameters and vibration parameters)on tool trajectories and microtextured surface morphology in UVAM is investigated.Besides,the effect of phase difference on the elliptical shape in 2D/3D ultrasonic elliptical vibration-assisted milling(UEVAM)was analyzed.Compared to conventional numerical models,the method of the cubic spline data interpolation is applied to the simulation of microtextured surface morphology in UVAM,which is more suitable for characterizing the morphological features of microtextured surfaces than traditional methods due to the presence of numerous micro textures.The prediction of surface roughness indicates that the magnitude of ultrasonic amplitude in z-direction should be strictly limited in 1D rotary UVAM,2D and 3D UEVAM due to the unfavorable effect of axial ultrasonic vibration on the surface quality.This study can provide theoretical guidance for the design and fabrication of microtextured surfaces in UVAM.

Acoustic Bilayer Gradient Metasurfaces for Perfect and Asymmetric Beam Splitting

We experimentally and theoretically present a paradigm for the accurate bilayer design of gradient metasurfaces for wave beam manipulation,producing an extremely asymmetric splitting effect by simply tailoring the interlayer size.This concept arises from anomalous diffraction in phase gradient metasurfaces and the precise combination of the phase gradient in bilayer metasurfaces.Ensured by different diffraction routes in momentum space for incident beams from opposite directions,extremely asymmetric acoustic beam splitting can be generated in a robust way,as demonstrated in experiments through a designed bilayer system.Our work provides a novel approach and feasible platform for designing tunable devices to control wave propagation.

Reconfigurable optical neural networks with Plug-and-Play metasurfaces

In a very recent study,Prof.Lingling Huang and co-workers proposed and demonstrated reconfigurable optical neural networks based on cascaded metasurfaces.By fixing one metasurface and switching the other pluggable metasurfaces,the neural networks,which operate at near-infrared wavelengths,can perform distinct recognition tasks for handwritten digits and fashion products.This innovative device opens up an avenue for all-optical,high-speed,low-power,and multifunctional artificial intelligence systems.

Ultrafast dynamics of femtosecond laser-induced high spatial frequency periodic structures on silicon surfaces

Femtosecond laser-induced periodic surface structures(LIPSS)have been extensively studied over the past few decades.In particular,the period and groove width of high-spatial-frequency LIPSS(HSFL)is much smaller than the diffraction limit,making it a useful method for efficient nanomanufacturing.However,compared with the low-spatial-frequency LIPSS(LSFL),the structure size of the HSFL is smaller,and it is more easily submerged.Therefore,the formation mechanism of HSFL is complex and has always been a research hotspot in this field.In this study,regular LSFL with a period of 760 nm was fabricated in advance on a silicon surface with two-beam interference using an 800 nm,50 fs femtosecond laser.The ultrafast dynamics of HSFL formation on the silicon surface of prefabricated LSFL under single femtosecond laser pulse irradiation were observed and analyzed for the first time using collinear pump-probe imaging method.In general,the evolution of the surface structure undergoes five sequential stages:the LSFL begins to split,becomes uniform HSFL,degenerates into an irregular LSFL,undergoes secondary splitting into a weakly uniform HSFL,and evolves into an irregular LSFL or is submerged.The results indicate that the local enhancement of the submerged nanocavity,or the nanoplasma,in the prefabricated LSFL ridge led to the splitting of the LSFL,and the thermodynamic effect drove the homogenization of the splitting LSFL,which evolved into HSFL.

A Fast and Memory-Efficient Direct Rendering Method for Polynomial-Based Implicit Surfaces

Three-dimensional surfaces are typically modeled as implicit surfaces.However,direct rendering of implicit surfaces is not simple,especially when such surfaces contain finely detailed shapes.One approach is ray-casting,where the field of the implicit surface is assumed to be piecewise polynomials defined on the grid of a rectangular domain.A critical issue for direct rendering based on ray-casting is the computational cost of finding intersections between surfaces and rays.In particular,ray-casting requires many function evaluations along each ray,severely slowing the rendering speed.In this paper,a method is proposed to achieve direct rendering of polynomial-based implicit surfaces in real-time by strategically narrowing the search range and designing the shader to exploit the structure of piecewise polynomials.In experiments,the proposed method achieved a high framerate performance for different test cases,with a speed-up factor ranging from 1.1 to 218.2.In addition,the proposed method demonstrated better efficiency with high cell resolution.In terms of memory consumption,the proposed method saved between 90.94%and 99.64%in different test cases.Generally,the proposed method became more memoryefficient as the cell resolution increased.

Additive manufacturing of micropatterned functional surfaces:a review

Over the course of millions of years,nature has evolved to ensure survival and presents us with a myriad of functional surfaces and structures that can boast high efficiency,multifunctionality,and sustainability.What makes these surfaces particularly practical and effective is the intricate micropatterning that enables selective interactions with microstructures.Most of these structures have been realized in the laboratory environment using numerous fabrication techniques by tailoring specific surface properties.Of the available manufacturing methods,additive manufacturing(AM)has created opportunities for fabricating these structures as the complex architectures of the naturally occurring microstructures far exceed the traditional ways.This paper presents a concise overview of the fundamentals of such patterned microstructured surfaces,their fabrication techniques,and diverse applications.A comprehensive evaluation of micro fabrication methods is conducted,delving into their respective strengths and limitations.Greater emphasis is placed on AM processes like inkjet printing and micro digital light projection printing due to the intrinsic advantages of these processes to additively fabricate high resolution structures with high fidelity and precision.The paper explores the various advancements in these processes in relation to their use in microfabrication and also presents the recent trends in applications like the fabrication of microlens arrays,microneedles,and tissue scaffolds.

Target Detection on Water Surfaces Using Fusion of Camera and LiDAR Based Information

To address the challenges of missed detections in water surface target detection using solely visual algorithms in unmanned surface vehicle(USV)perception,this paper proposes a method based on the fusion of visual and LiDAR point-cloud projection for water surface target detection.Firstly,the visual recognition component employs an improved YOLOv7 algorithmbased on a self-built dataset for the detection of water surface targets.This algorithm modifies the original YOLOv7 architecture to a Slim-Neck structure,addressing the problemof excessive redundant information during feature extraction in the original YOLOv7 network model.Simultaneously,this modification simplifies the computational burden of the detector,reduces inference time,and maintains accuracy.Secondly,to tackle the issue of sample imbalance in the self-built dataset,slide loss function is introduced.Finally,this paper replaces the original Complete Intersection over Union(CIoU)loss function with the Minimum Point Distance Intersection over Union(MPDIoU)loss function in the YOLOv7 algorithm,which accelerates model learning and enhances robustness.To mitigate the problem of missed recognitions caused by complex water surface conditions in purely visual algorithms,this paper further adopts the fusion of LiDAR and camera data,projecting the threedimensional point-cloud data from LiDAR onto a two-dimensional pixel plane.This significantly reduces the rate of missed detections for water surface targets.

Development of vehicle-recognition method on water surfaces using LiDAR data:SPD^(2)(spherically stratified point projection with diameter and distance)

Swarm robot systems are an important application of autonomous unmanned surface vehicles on water surfaces.For monitoring natural environments and conducting security activities within a certain range using a surface vehicle,the swarm robot system is more efficient than the operation of a single object as the former can reduce cost and save time.It is necessary to detect adjacent surface obstacles robustly to operate a cluster of unmanned surface vehicles.For this purpose,a LiDAR(light detection and ranging)sensor is used as it can simultaneously obtain 3D information for all directions,relatively robustly and accurately,irrespective of the surrounding environmental conditions.Although the GPS(global-positioning-system)error range exists,obtaining measurements of the surface-vessel position can still ensure stability during platoon maneuvering.In this study,a three-layer convolutional neural network is applied to classify types of surface vehicles.The aim of this approach is to redefine the sparse 3D point cloud data as 2D image data with a connotative meaning and subsequently utilize this transformed data for object classification purposes.Hence,we have proposed a descriptor that converts the 3D point cloud data into 2D image data.To use this descriptor effectively,it is necessary to perform a clustering operation that separates the point clouds for each object.We developed voxel-based clustering for the point cloud clustering.Furthermore,using the descriptor,3D point cloud data can be converted into a 2D feature image,and the converted 2D image is provided as an input value to the network.We intend to verify the validity of the proposed 3D point cloud feature descriptor by using experimental data in the simulator.Furthermore,we explore the feasibility of real-time object classification within this framework.

Variations in evaporation from water surfaces along the margins of the Badain Jaran Desert over nearly 60 years and influencing factors

Based on meteorological data collected over nearly 60 years(1960-2017)from four national meteorological stations along the margins of the Badain Jaran Desert,this study analyzed the spatiotemporal variations in evaporation from water surfaces and identified the dominant controlling factors.Methods used included linear trend analysis,linear tendency estimation,the departure method,the rank correlation coefficient-based method,and Multiple Linear Regression(MLR).Results indicate notable spatiotemporal differences in evaporation distribution and evolution.Spatially,average annual evaporation exhibited a pronounced altitude effect,decreasing at a rate of about 8.23 mm/m from east to west with increasing altitude.Temporally,annual evaporation showed significant upward trends after 1996 at the northeastern(Guaizi Lake)and western(Dingxin)margins,with rates of 132 mm/10a and 105 mm/10a,respectively.Conversely,along the northwestern(Ejina Banner)and southern(Alxa Right Banner)margins of the desert,an evaporation paradox was observed,with annual evaporation trending downward at rates of 162 mm/10a and 187 mm/10a,respectively,especially after 1987.The dominant factors controlling evaporation varied spatially:Average annual temperature and relative humidity influended the western margin(Dingxin),average annual temperature was the key factor for the northeastern margin(Guaizi Lake),and average wind speed was crucial for the northern(Ejina Banner)and southern(Alxa Right Banner)margins.

Magnetic Field Curves and Magnetic Equipotential Surfaces around Crossing Electrical Wires Replacing Classical Magnetic Field Lines

This article is based on a recent model specifically defining magnetic field values around electrical wires. With this model, calculations of field around parallel wires were obtained. Now, this model is extended with the new concept of magnetic equipotential surface to magnetic field curves around crossing wires. Cases of single, double, and triple wires are described. Subsequent article will be conducted for more general scenarios where wires are neither infinite nor parallel.

Energy-efficient joint UAV secure communication and 3D trajectory optimization assisted by reconfigurable intelligent surfaces in the presence of eavesdroppers

We consider a scenario where an unmanned aerial vehicle(UAV),a typical unmanned aerial system(UAS),transmits confidential data to a moving ground target in the presence of multiple eavesdroppers.Multiple friendly reconfigurable intelligent surfaces(RISs) help to secure the UAV-target communication and improve the energy efficiency of the UAV.We formulate an optimization problem to minimize the energy consumption of the UAV,subject to the mobility constraint of the UAV and that the achievable secrecy rate at the target is over a given threshold.We present an online planning method following the framework of model predictive control(MPC) to jointly optimize the motion of the UAV and the configurations of the RISs.The effectiveness of the proposed method is validated via computer simulations.

Shear sliding of rough-walled fracture surfaces under unloading normal stress

Through high-precision engraving,self-affine sandstone joint surfaces with various joint roughness coefficients(JRC=3.21e12.16)were replicated and the shear sliding tests under unloading normal stress were conducted regarding various initial normal stresses(1e7 MPa)and numbers of shearing cycles(1 e5).The peak shear stress of fractures decreased with shear cycles due to progressively smooth surface morphologies,while increased with both JRC and initial normal stress and could be verified using the nonlinear Barton-Bandis failure criterion.The joint friction angle of fractures exponentially increased by 62.22%e64.87%with JRC while decreased by 22.1%e24.85%with shearing cycles.After unloading normal stress,the sliding initiation time of fractures increased with both JRC and initial normal stress due to more tortuous fracture morphologies and enhanced shearing resistance capacity.The surface resistance index(SRI)of fractures decreased by 4.35%e32.02%with increasing shearing cycles due to a more significant reduction of sliding initiation shear stress than that for sliding initiation normal stress,but increased by a factor of 0.41e1.64 with JRC.After sliding initiation,the shear displacement of fractures showed an increase in power function.By defining a sliding rate threshold of 5105 m/s,transition from“quasi-static”to“dynamic”sliding of fractures was identified,and the increase of sliding acceleration steepened with JRC while slowed down with shearing cycles.The normal displacement experienced a slight increase before shear sliding due to deformation recovery as the unloading stress was unloaded,and then enhanced shear dilation after sliding initiation due to climbing effects of surface asperities.Dilation was positively related to the shear sliding velocity of fractures.Wear characteristics of the fracture surfaces after shearing failure were evaluated using binary calculation,indicating an increasing shear area ratio by 45.24%e91.02%with normal stress.

Carnivorous plants inspired shape-morphing slippery surfaces

Carnivorous plants,for instance,Dionaea muscipula and Nepenthes pitcher plant,inspired the innovation of advanced stimuli-responsive actuators and lubricant-infused slippery surfaces,respectively.However,hybrid bionic devices that combine the active and passive prey trapping capabilities of the two kinds of carnivorous plants remain a challenge.Herein,we report a moisture responsive shape-morphing slippery surface that enables both moisture responsive shapemorphing and oil-lubricated water repellency for simultaneous active-and passive-droplet manipulation.The moisture deformable slippery surface is prepared by creating biomimetic microstructures on graphene oxide(GO)membrane via femtosecond laser direct writing and subsequent lubricating with a thin layer of oil on the laser structured reduced GO(LRGO)surface.The integration of a lubricant-infused slippery surface with an LRGO/GO bilayer actuator endows the actuator with droplet sliding ability and promotes the moisture deformation performance due to oil-enhanced water repellency of the inert layer(LRGO).Based on the shape-morphing slippery surface,we prepared a series of proof-of-concept actuators,including a moisture-response Dionaea muscipula actuator,a smart frog tongue,and a smart flower,demonstrating their versatility for active/passive trapping,droplet manipulation,and sensing.

Marine antifouling behavior of the surfaces modified by dopamine and antibacterial peptide

Marine biofouling causes serious harms to surfaces of marine devices in transportation,aquaculture,and offshore construction.Traditional antifouling methods pollute the environment.A novel and green antifouling strategy was developed to prevent effectively the adhe sion of bacteria and microalgae.An antifouling surface was fabricated via coating Turgencin BMox2(TB)onto dopamine-modified 304stainless steel(304 SS).The surface physical and chemical properties before and after modification were characterized by Fourier transform infrared spectrometer(FTIR),X-ray photoelectron spectrometer(XPS),contact angle measurement(CA),3D optical profilometer,ellipsometer,and atomic force microscope(AFM).Antimicrobial peptide was coated onto the surface of 304 SS successfully,and the surface morphology and wettability of the modified sample were modified.Moreover,cytocompatibility of the peptide was evaluated by co-culture of peptide and cells,indicating promising cell biocompatibility at the modified sample surface.At last,antifouling performance and electrochemical corrosion were tested.Results show that the adhesion rates of Vibrio natriegens and Phaeodactylum tricornutum on the antifouling surface were reduced by 99.85% and 67.93%,respectively from those of untreated samples.Therefore,the modified samples retained superior corrosion resistance.The study provide a simply and green way against biofouling on ship hulls and marine equipment.

Enhanced energy-absorbing and sound-absorbing capability of functionally graded and helicoidal lattice structures with triply periodic minimal surfaces

Lattice structures have drawn much attention in engineering applications due to their lightweight and multi-functional properties.In this work,a mathematical design approach for functionally graded(FG)and helicoidal lattice structures with triply periodic minimal surfaces is proposed.Four types of lattice structures including uniform,helicoidal,FG,and combined FG and helicoidal are fabricated by the additive manufacturing technology.The deformation behaviors,mechanical properties,energy absorption,and acoustic properties of lattice samples are thoroughly investigated.The load-bearing capability of helicoidal lattice samples is gradually improved in the plateau stage,leading to the plateau stress and total energy absorption improved by over 26.9%and 21.2%compared to the uniform sample,respectively.This phenomenon was attributed to the helicoidal design reduces the gap in unit cells and enhances fracture resistance.For acoustic properties,the design of helicoidal reduces the resonance frequency and improves the peak of absorption coefficient,while the FG design mainly influences the peak of absorption coefficient.Across broad range of frequency from 1000 to 6300 Hz,the maximum value of absorption coefficient is improved by18.6%-30%,and the number of points higher than 0.6 increased by 55.2%-61.7%by combining the FG and helicoidal designs.This study provides a novel strategy to simultaneously improve energy absorption and sound absorption properties by controlling the internal architecture of lattice structures.

Wind dynamic environment and wind-sand erosion and deposition processes on different surfaces along the Dunhuang–Golmud railway,China

The Dunhuang–Golmud railway passes through different deserts in arid areas,especially drifting-sand desert and sandy-gravel Gobi.The near-surface wind environment and wind-sand transport process vary due to different external factors,such as topography,vegetation,and regional climate,resulting in evident spatial differences in surface erosion and deposition.Consequently,the measures for preventing wind-sand hazards will differ.However,the mechanism and control theory of sand damage remain poorly understood.In this study,we used meteorological observation,three-dimensional(3D)laser scanning,and grain-size analysis to compare and evaluate the spatial distribution of wind conditions,sand erosion and deposition patterns,and grain composition in the drifting-sand desert and sandy-gravel Gobi along the Dunhuang–Golmud railway in China.Results show that the annual mean wind speed,the frequency of sand-driving wind,and the drift potential of sandy-gravel Gobi are higher than those of drifting-sand desert,indicating a greater wind strength in the sandy-gravel Gobi,which exhibits spatial heterogeneity in wind conditions.The major sediment components in sandy-gravel Gobi are very fine sand,fine sand,and medium sand,and that in drifting-sand desert are very fine sand and fine sand.We found that the sediment in the sandy-gravel Gobi is coarser than that in the drifting-sand desert based on mean grain size and sediment component.The spatial distributions of sand erosion and deposition in the sandy-gravel Gobi and drifting-sand desert are consistent,with sand deposition mainly on the west side of the railway and sand erosion on the east side of the railway.The area of sand deposition in the drifting-sand desert accounts for 75.83%of the total area,with a mean deposition thickness of 0.032 m;while the area of sand deposition in the sandy-gravel Gobi accounts for 65.31%of the total area,with a mean deposition thickness of 0.028 m,indicating greater deposition amounts in the drifting-sand desert due to the presence of more fine sediment components.However,the sand deposition is more concentrated with a greater thickness on the embankment and track in the sandy-gravel Gobi and is dispersed with a uniform thickness in the drifting-sand desert.The sand deposition on the track of the sandy-gravel Gobi mainly comes from the east side of the railway.The results of this study are helpful in developing the preventive measures and determining appropriate selection and layout measures for sand control.

A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

Melt extrusion-based additive manufacturing(ME-AM)is a promising technique to fabricate porous scaffolds for tissue engi-neering applications.However,most synthetic semicrystalline polymers do not possess the intrinsic biological activity required to control cell fate.Grafting of biomolecules on polymeric surfaces of AM scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface density.Here,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(PCL5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight PCL75k at different ratios.Stable porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight PCL 5k.As a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).Subsequently,a bone morphogenetic protein 2(BMP-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hMSCs)was assessed.After two weeks of culturing in a basic medium,cells expressed higher levels of BMP receptor II(BMPRII)on films with the conjugated peptide.In addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface density.Taken together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material interface.Moreover,we have presented a viable strategy for ME-AM community that desires to tune the bulk and surface functionality via blending of(modified)polymers.Furthermore,the use of alkyne-azide“click”chemistry enables spatial control over bioconjugation of many tissue-specific moieties,making this approach a versatile strategy for tissue engineering applications.