Direct growth of graphene films without catalyst on flexible glass substrates by PECVD

A hydrogen-plasma-etching-based plasma-enhanced chemical vapor deposition(PECVD)synthesis route without metal catalyst for preparing the graphene films on flexible glass is developed.The quality of the prepared graphene films is evaluated by scanning electron microscopy,x-ray photoelectron spectroscopy,high-resolution transmission electron microscopy,ultraviolet-visible spectroscopy,and electrochemical measurements.In a radio frequency(RF)power range of 50 W-300 W,the graphene growth rate increases with RF power increasing,while the intensity ratio of D-to G-Raman peak(I_(D)/I_(G))decreases.When the RF power is higher than 300 W,the I_(D)/I_(G)rises again.By optimizing experimental parameters of hydrogen plasma etching and RF power,the properties of as-prepared flexible graphene on glass are modulated to be able to achieve the graphene's transparency,good electrical conductivity,and better macroscopic uniformity.Direct growth of graphene film without any metal catalyst on flexible glass can be a promising candidate for applications in flexible transparent optoelectronics.

Study on Heating Uniformity of Pt-Rh Alloy Bushing for Producing Flexible Glass

The numerical simulation for temperature distribution of Pt-Rh alloy bushing was carried out using a thermal-electric module in ANSYS Workbench finite element analysis software.The effects of side wall thickness,plug thickness,the angle of two side walls and electrode structure on the uniformity of temperature distribution were investigated.Meanwhile,the contrastive analysis results of bushing with and without glass melt were discussed.The simulation results show that,when the homogeneous glass melt flows through bushing,the temperature difference between the center and both ends of bushing is decreased significantly,but the temperature distribution at both ends of bushing is still affected by heating non-uniformity of bushing.Compared with side wall thickness,plug thickness and the angle of two side walls,electrode structure plays a greater role in adjusting heating uniformity of bushing.

Numerical Simulation of a Viscoelastic Thinning Process for Preparing Flexible Glasses by Redrawing Method

The forming process of the flexible ultrathin glasses(UTG)prepared by the redrawing method was numerically simulated using ANSYS Polyflow software.In the forming process by the redrawing method,temperature,viscosity,transverse and longitudinal velocity distribution of the glasses with different compositions were studied.Furthermore,the influence of these factors on the width and thickness of the flexible glass plate was investigated.It is found that the internal and external heat exchange of glass has a dominant influence on the viscosity variation during the UTG forming process,which is inconsistent with the general viscosity-temperature dependence.The glass that first reaches the lower limit of forming viscosity can significantly resist the shrinking effect caused by surface tension,making the glass wider during the forming.If the original glass width remains unchanged,the glass thickness or feeding speed is reduced,wider and thinner flexible glasses can be produced.