在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组...在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组再有一个副本所在的硬盘发生故障,将导致系统无法继续提供服务,且不能自动恢复.本文提出一种基于日志副本的改进的Raft共识算法,即LR-Raft (log replica based Raft),日志副本没有完整状态机,可以快速加入集群,并参与投票与共识,提升了存在故障硬盘时系统的可用性;可以解决短时间内三副本中两个副本故障导致集群不可用和丢失数据的问题.实验结果表明,在副本组中引入日志副本后,与原Raft相比,LR-Raft在不同的工作负载下读写时延均明显降低,吞吐量显著提升.展开更多
It was demonstrated that the fast RAFT polymerization of styrene with almost perfect polymerization performance could be achieved by using a carefully designed miniemulsion polymerization system.With much higher level...It was demonstrated that the fast RAFT polymerization of styrene with almost perfect polymerization performance could be achieved by using a carefully designed miniemulsion polymerization system.With much higher levels of surfactant (9 wt% based on monomer) and co-stabilizer (5 wt% based on monomer) than those in typical miniemulsion polymerization,the miniemulsion polymerization using 1-phenylethyl phenyl-dithioacetate as a RAFT agent showed a very fast polymerization rate,excellent performance of living radical polymerization during the entire polymerization process,and narrow particle size distributions.It was concluded that RAFT miniemulsion polymerization presented an excellent commercial process for a living radical polymerization system.展开更多
Two opposing explanations to significant rate retardation in dithioester-mediated polymerization with reversible addition fragmentation chain transfer process(RAFT),e.g: slow fragmentation of intermediate radicals (Mo...Two opposing explanations to significant rate retardation in dithioester-mediated polymerization with reversible addition fragmentation chain transfer process(RAFT),e.g: slow fragmentation of intermediate radicals (Model A),and cross termination between intermediates and growing radicals (Model B),had been proposed by Davis and Monteiro independently. In this paper,a comparison of simulation results of Model A and Model B with experiment results was presented. The simulated results show that the intermediate concentration of Model A is much higher than that of experiments,while Model B gives a rather high polymerization rate than experiments with large concentration of dithioesters. The reaction model was better fitted,in light of kinetics,intermediate concentration and distribution of molecular weight,to experimental data when both cross termination and slow fragmentation were taken into account. [WT5HZ]展开更多
文摘在基于三副本策略的分布式存储系统中,当存储节点上的硬盘出现故障时,常见的处理方式是等待系统预设的时间.如果该故障硬盘超时未恢复,才开始恢复故障硬盘上的副本.这种处理方式存在的问题是,当三副本组中存在故障副本时,如果该副本组再有一个副本所在的硬盘发生故障,将导致系统无法继续提供服务,且不能自动恢复.本文提出一种基于日志副本的改进的Raft共识算法,即LR-Raft (log replica based Raft),日志副本没有完整状态机,可以快速加入集群,并参与投票与共识,提升了存在故障硬盘时系统的可用性;可以解决短时间内三副本中两个副本故障导致集群不可用和丢失数据的问题.实验结果表明,在副本组中引入日志副本后,与原Raft相比,LR-Raft在不同的工作负载下读写时延均明显降低,吞吐量显著提升.
文摘It was demonstrated that the fast RAFT polymerization of styrene with almost perfect polymerization performance could be achieved by using a carefully designed miniemulsion polymerization system.With much higher levels of surfactant (9 wt% based on monomer) and co-stabilizer (5 wt% based on monomer) than those in typical miniemulsion polymerization,the miniemulsion polymerization using 1-phenylethyl phenyl-dithioacetate as a RAFT agent showed a very fast polymerization rate,excellent performance of living radical polymerization during the entire polymerization process,and narrow particle size distributions.It was concluded that RAFT miniemulsion polymerization presented an excellent commercial process for a living radical polymerization system.
文摘Two opposing explanations to significant rate retardation in dithioester-mediated polymerization with reversible addition fragmentation chain transfer process(RAFT),e.g: slow fragmentation of intermediate radicals (Model A),and cross termination between intermediates and growing radicals (Model B),had been proposed by Davis and Monteiro independently. In this paper,a comparison of simulation results of Model A and Model B with experiment results was presented. The simulated results show that the intermediate concentration of Model A is much higher than that of experiments,while Model B gives a rather high polymerization rate than experiments with large concentration of dithioesters. The reaction model was better fitted,in light of kinetics,intermediate concentration and distribution of molecular weight,to experimental data when both cross termination and slow fragmentation were taken into account. [WT5HZ]
