Utilizing ANSYS CFX commercial software and volume fraction of fluid （VOF） model, fluctuation behav- ior of steel/slag interface was numerically simulated in continuous casting mold with static magnetic field, and t...Utilizing ANSYS CFX commercial software and volume fraction of fluid （VOF） model, fluctuation behav- ior of steel/slag interface was numerically simulated in continuous casting mold with static magnetic field, and the influence of metal jet characteristics on the behavior of steel/slag interface was investigated. The results indicated that the behavior of steel/slag interface is similar at different process parameters, which is closely related to the characteristic of the flow field. The steel/slag interface has an obvious trough characteristic, which can be divided in- to three zones： frontal valley zone, back valley zone and horizontal zone~ as the magnetic flux density increases, the fluctuation of liquid level increases firstly and then decreases, and a reasonable magnetic flux density can make steel/ slag interface obtain a relatively flat interface, which can prevent slag from being entrapped into liquid steel. For a thin slab continuous casting process, when the casting speed is 4 m/min, a reasonable magnetic flux density is about 0.5 T, and the interfacial fluctuation is weaker. No matter the position of magnetic field is horizontal or vertical, for different operating parameters, there is a corresponding reasonable magnetic field position where the steel/slag inter- face fluctuation can be properly controlled and slag entrapment can be prevented.展开更多
The curve of % S vs reaction time is described quantitatively based on the electrochemical model directly deduced from the principle of electrochemistry as well as the given method for calculating the initial oxygen p...The curve of % S vs reaction time is described quantitatively based on the electrochemical model directly deduced from the principle of electrochemistry as well as the given method for calculating the initial oxygen potential along slag/steel interface.The calculated data is in good agreement with the experimental results. During desulphurization,both L_s~* and L_s,the sulphur partition along the interface and that in the bulk,go up in association with the descending of oxygen potential along interface. The plot of L_s~* against reaction time follows a parabolic curve,while that of L_s is of hyperbola type.Correspondingly,on curves of driving force parameter vs reaction tone,either calculated or experimental,a hump occurs.展开更多
Laboratory-scale experiments were performed to investigate the deoxidation of H13 tool steel with CaF_(2)-MgO-Al_(2)O_(3)-CaO-SiO_(2) slags at 1873 K.The calculation of thermodynamics and kinetics was also verified th...Laboratory-scale experiments were performed to investigate the deoxidation of H13 tool steel with CaF_(2)-MgO-Al_(2)O_(3)-CaO-SiO_(2) slags at 1873 K.The calculation of thermodynamics and kinetics was also verified through the experimental results.The results show that[Si]-[O]reaction is the control reaction,and with the increase of basicity of slag,the limitation of deoxidation was decreased.The limitation of deoxidation is the lowest for the slag with basicity of 2.0.Under the conditions of the basicity of 2.0 and the content of CaF_(2) more than 50%,the limitation of deoxidation is less than 10×10^(−6),and it does not depend on the contents of Al_(2)O_(3) and CaF_(2) in slags.The mass transport of oxygen in the metal phase is the rate-controlling step,and the slag composition has no effect on the equilibrium time of deoxidation.Based on this finding,the optimized slag composition is designed and it contains the following components:51.5%CaF_(2),20.3%MgO,16.2%Al_(2)O_(3),8.2%CaO and 3.8%SiO_(2).In the case of the optimized deoxidizing slag,the total oxygen content in H13 steel can be reduced from 25×10^(−6) to 6×10^(−6).展开更多
A boundary layer model was developed to predict the capture of inclusions by steel-slag interface in a turbulent fluid flow,which is based on the detailed analysis of inclusion trajectories.The effective boundary laye...A boundary layer model was developed to predict the capture of inclusions by steel-slag interface in a turbulent fluid flow,which is based on the detailed analysis of inclusion trajectories.The effective boundary layer for inclusion removal was proposed by a statistical method.It is noticed that the capture of inclusions by steel-slag interface is not only dependent on the diameter of inclusions but also related to the local turbulent conditions.In high turbulent flow fields,the transport of inclusions is mainly dominated by the turbulent flow,and thus,the effective boundary layer thickness is mainly affected by the level of turbulent kinetic energy and is almost independent of the inclusion diameter.The inertia of inclusions gradually takes over the stochastic effect of turbulent flow,and the effect of inclusion diameter on effective boundary layer thickness becomes more noticeable with the decrease in the level of turbulent kinetic energy.Besides,the effective boundary layer thickness is more susceptible to the inclusion diameter for larger inclusions due to its greater inertia under the same turbulent condition while it principally depends on the level of turbulent kinetic energy for smaller inclusions.As the characteristic velocity increases,the time for inclusions transport and interaction with steel-slag interface decreases,and thus,the effective boundary layer thickness decreases.Moreover,the graphical user interface was developed by using the cubic spline interpolation for ease of coupling the current boundary layer model with the macro-scale model of a turbulent fluid flow in the metallurgical vessel.展开更多
The flow field of molten steel and the interfacial behaviour between molten steel and liquid slag layer in medium-thin slab continuous casting mold with argon gas injection were studied by numerical simulation, in whi...The flow field of molten steel and the interfacial behaviour between molten steel and liquid slag layer in medium-thin slab continuous casting mold with argon gas injection were studied by numerical simulation, in which the effects of nozzle submergence depth and port angle, casting speed, and argon gas flow rate on the flow and the level fluctuation of molten steel were considered. The results show that the molten steel is jetted from the submerged en- try nozzle （SEN） with three ports into the mold and forms three recirculation zones including one upper recireulation zone and two lower recirculation zones. Argon gas injection results in a secondary vortex flow in the upper zone near the nozzle. For a given casting speed and argon gas flow rate, increasing the side port angle and submergence depth of nozzle can effectively restrain the steel/slag interracial fluctuation. Increasing the casting speed would prick up the level fluctuation. For a fixed casting speed, argon gas flow rate has a critical value, the interracial fluctuation with argon gas injection are stronger than the case without argon gas injection when the argon gas flow rate is less than the critical value, but when the argon gas flow rate exceeds the critical value, the level fluctuation is calmer than that without argon gas injection.展开更多
基金Item Sponsored by National Natural Science Foundation of China(50604005,50834009)Natural Science Foundation of Liaoning Province of China(20102074)+2 种基金Fundamental Research Funds for the Central Universities of China(N100409005)Key Grant Project of Chinese Ministry of Education(311014)"111" Project of China(B07015)
文摘Utilizing ANSYS CFX commercial software and volume fraction of fluid （VOF） model, fluctuation behav- ior of steel/slag interface was numerically simulated in continuous casting mold with static magnetic field, and the influence of metal jet characteristics on the behavior of steel/slag interface was investigated. The results indicated that the behavior of steel/slag interface is similar at different process parameters, which is closely related to the characteristic of the flow field. The steel/slag interface has an obvious trough characteristic, which can be divided in- to three zones： frontal valley zone, back valley zone and horizontal zone~ as the magnetic flux density increases, the fluctuation of liquid level increases firstly and then decreases, and a reasonable magnetic flux density can make steel/ slag interface obtain a relatively flat interface, which can prevent slag from being entrapped into liquid steel. For a thin slab continuous casting process, when the casting speed is 4 m/min, a reasonable magnetic flux density is about 0.5 T, and the interfacial fluctuation is weaker. No matter the position of magnetic field is horizontal or vertical, for different operating parameters, there is a corresponding reasonable magnetic field position where the steel/slag inter- face fluctuation can be properly controlled and slag entrapment can be prevented.
文摘The curve of % S vs reaction time is described quantitatively based on the electrochemical model directly deduced from the principle of electrochemistry as well as the given method for calculating the initial oxygen potential along slag/steel interface.The calculated data is in good agreement with the experimental results. During desulphurization,both L_s~* and L_s,the sulphur partition along the interface and that in the bulk,go up in association with the descending of oxygen potential along interface. The plot of L_s~* against reaction time follows a parabolic curve,while that of L_s is of hyperbola type.Correspondingly,on curves of driving force parameter vs reaction tone,either calculated or experimental,a hump occurs.
基金Project(18SYXHZ0069)supported by the Science and Technology Program of Sichuan Province,ChinaProjects(51974139,51664021)supported by the National Natural Science Foundation of China。
文摘Laboratory-scale experiments were performed to investigate the deoxidation of H13 tool steel with CaF_(2)-MgO-Al_(2)O_(3)-CaO-SiO_(2) slags at 1873 K.The calculation of thermodynamics and kinetics was also verified through the experimental results.The results show that[Si]-[O]reaction is the control reaction,and with the increase of basicity of slag,the limitation of deoxidation was decreased.The limitation of deoxidation is the lowest for the slag with basicity of 2.0.Under the conditions of the basicity of 2.0 and the content of CaF_(2) more than 50%,the limitation of deoxidation is less than 10×10^(−6),and it does not depend on the contents of Al_(2)O_(3) and CaF_(2) in slags.The mass transport of oxygen in the metal phase is the rate-controlling step,and the slag composition has no effect on the equilibrium time of deoxidation.Based on this finding,the optimized slag composition is designed and it contains the following components:51.5%CaF_(2),20.3%MgO,16.2%Al_(2)O_(3),8.2%CaO and 3.8%SiO_(2).In the case of the optimized deoxidizing slag,the total oxygen content in H13 steel can be reduced from 25×10^(−6) to 6×10^(−6).
基金the National Natural Science Foundation of China(Grant Nos.51904025 and U22A20171)the Fundamental Research Funds for the Central Universities(Grant No.FRF-IDRY-20-011)+1 种基金National Postdoctoral Program for Innovative Talents(Grant No.BX20190030)the High Steel Center(HSC)at North China University of Technology and University of Science and Technology Beijing,China.
文摘A boundary layer model was developed to predict the capture of inclusions by steel-slag interface in a turbulent fluid flow,which is based on the detailed analysis of inclusion trajectories.The effective boundary layer for inclusion removal was proposed by a statistical method.It is noticed that the capture of inclusions by steel-slag interface is not only dependent on the diameter of inclusions but also related to the local turbulent conditions.In high turbulent flow fields,the transport of inclusions is mainly dominated by the turbulent flow,and thus,the effective boundary layer thickness is mainly affected by the level of turbulent kinetic energy and is almost independent of the inclusion diameter.The inertia of inclusions gradually takes over the stochastic effect of turbulent flow,and the effect of inclusion diameter on effective boundary layer thickness becomes more noticeable with the decrease in the level of turbulent kinetic energy.Besides,the effective boundary layer thickness is more susceptible to the inclusion diameter for larger inclusions due to its greater inertia under the same turbulent condition while it principally depends on the level of turbulent kinetic energy for smaller inclusions.As the characteristic velocity increases,the time for inclusions transport and interaction with steel-slag interface decreases,and thus,the effective boundary layer thickness decreases.Moreover,the graphical user interface was developed by using the cubic spline interpolation for ease of coupling the current boundary layer model with the macro-scale model of a turbulent fluid flow in the metallurgical vessel.
基金Item Sponsored by National Natural Science Foundation of China and Baosteel Co(50674020)
文摘The flow field of molten steel and the interfacial behaviour between molten steel and liquid slag layer in medium-thin slab continuous casting mold with argon gas injection were studied by numerical simulation, in which the effects of nozzle submergence depth and port angle, casting speed, and argon gas flow rate on the flow and the level fluctuation of molten steel were considered. The results show that the molten steel is jetted from the submerged en- try nozzle （SEN） with three ports into the mold and forms three recirculation zones including one upper recireulation zone and two lower recirculation zones. Argon gas injection results in a secondary vortex flow in the upper zone near the nozzle. For a given casting speed and argon gas flow rate, increasing the side port angle and submergence depth of nozzle can effectively restrain the steel/slag interracial fluctuation. Increasing the casting speed would prick up the level fluctuation. For a fixed casting speed, argon gas flow rate has a critical value, the interracial fluctuation with argon gas injection are stronger than the case without argon gas injection when the argon gas flow rate is less than the critical value, but when the argon gas flow rate exceeds the critical value, the level fluctuation is calmer than that without argon gas injection.
