Preparation of α-High Strength Gypsum from Flue Gas Desulfurization Gypsum Pretreated by Hydrothermal-aging Method

The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD)gypsum is a good way to realize the comprehensive utilization of FGD gypsum. To obtainα-CSH with the satisfactory performances, a facile hydrothermal-aging pretreatment process for FGD gypsum raw materials was proposed, where FGD gypsum was firstly hydrothermally converted to α-CSH whiskers, and α-CSH whiskers were further hydrated to synthesize CaSO4·2H2O (CSD) by aging under the regulation of N,N'-methylenebisacrylamide (MBA). The effects of aging time, MBA addition, aging temperature, and pH on the morphology of the synthesized CSD were investigated. The synthesized CSD crystals exhibit highly uniform prismatic morphology with the length of ca 100μm and the whiteness of 91.56%. The regulation mechanism of MBA was also illustrated. The synthesized CSD crystals with prismatic morphology were further used as raw materials to synthesize the short columnar α-CSH. The absolute dry compressive strength of paste prepared from the short columnar α-CSH is 40.85 MPa, which reaches α40 strength grade.

Multiobjective economic model predictive control using utopia-tracking for the wet flue gas desulphurization system

Efficient control of the desulphurization system is challenging in maximizing the economic objective while reducing the SO_(2) emission concentration. The conventional optimization method is generally based on a hierarchical structure in which the upper optimization layer calculates the steady-state results and the lower control layer is responsible to drive the process to the target point. However, the conventional hierarchical structure does not take the economic performance of the dynamic tracking process into account. To this end, multi-objective economic model predictive control(MOEMPC) is introduced in this paper, which unifies the optimization and control layers in a single stage. The objective functions are formulated in terms of a dynamic horizon and to balance the stability and economic performance. In the MOEMPC scheme, economic performance and SO_(2) emission performance are guaranteed by tracking a set of utopia points during dynamic transitions. The terminal penalty function and stabilizing constraint conditions are designed to ensure the stability of the system. Finally, an optimized control method for the stable operation of the complex desulfurization system has been established. Simulation results demonstrate that MOEMPC is superior over another control strategy in terms of economic performance and emission reduction, especially when the desulphurization system suffers from frequent flue gas disturbances.

Activation of Rejected Fly Ash Using Flue Gas Desulphurization (FGD) Sludge

Low-grade fly ash (rejected fly ash,rFA),a significant portion of the pulverized fuel ash (PFA) produced from coal-fired power plants and rejected from the ash classifying process,remains unused due to its high carbon content and large particle size (>45μm).But it is thought that the rejected ash may have potential uses in chemical stabilization/solidification (S/S) processes which need relatively lower strengths and a lower chemical reactivity.Flue Gas Desulphurisation (FGD) sludge is a by-product of air pollution control equipment in coal fired power plants whose chemical composition is mainly gypsum.As there is no effective usage of both of these two materials,it is of interest to research on the possible activation of rFA using FGD.This paper presents experimental results of a study on the properties of rFA activated by the FGD in rFA-cement pastes.Different percentages of FGD were added into the mix to study the effects of the FGD on the reaction of the rFA blended cement pastes.The results show that FGD takes effect as an activator only at late curing ages.Adding Ca(OH) 2 enhances the effect of FGD on activating the hydration of rFA.Also,10% FGD by weight of rFA is the optimal addition in the rFA-cement pastes.The results of the compressive strength measurements correlate well with the porosity results.

The Analysis of Using MGGH in Flue Gas Desulphurization (FGD) System in Cement Plant

The paper first introduces the background and the mechanism of secondary pollution from desulfurization in cement plant. Then, take plant A as an example, using MGGH (media gas-gas heater) to control “white smoke”. MGGH uses heat medium water to heat transfer between the original flue gas and the clean flue gas, without additional heat source, and has obvious economic benefits, which is the inevitable development direction of desulfurization reform of cement kiln system in the future.

Utilization of Thermally Treated Flue Gas Desulfurization (FGD) Gypsum and Class-C Fly Ash (CFA) to Prepare CFA-Based Geopolymer

The feasibility of utilization of flue gas desulfurization （FGD） gypsum and Class-C fly ash （CFA） to prepare CFA-based geopolymer were studied. The results showed that geopolymer made from 90% CFA and 10% FGD gypsum （FGDG） which was thermally treated at 800 ℃ for 1 h obtained the better compressive strength of 37.0 MPa. The micro characteristics and structures of the geopolymer samples of CFA and CFA-FGDG were tested by XRD, FT-IR, and SEM-EDXA after these samples cured at 75 ℃ for 8 h followed by 23 ℃ for 28 d. Both the geopolymer samples of CFA and CFA-FGDG have significant asymmetric stretching of A1-O/Si-O bonds and Si-O-Si / Si-O-A1 bending band. In geopolymer sample of CFA-FGDG, a small quantity of lathy products probably being the ettringite wrapped over the spherical fly ash particle, and the concentration of sulfur is much more than that in geopolymer sample of CFA. It is indicated that FGD gypsum may react during alkali-activated and geopolymeric process.

Influence of Thermally Treated Flue Gas Desulfurization(FGD) Gypsum on Performance of the Slag Powder Concrete

The feasibility of flue gas desulphurization （FGD） as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200℃ for 60 min and then mixed with the slag powder to form FGD gypsum-slag powder combined admixture in which the SO3 content was 3.5wt%. Cement was partially and equivalently replaced by slag powder alone or FGD gypsum-slag powder, at concentration of 25wt%, 40wt%, and 50wt%, respectively. The setting times, hydration products, total porosity and pore size distributions of the paste were determined. The compressive strength and drying shrinkage of cement mortar and concrete were also tested. The experimental results show that, in the presence of FGD gypsum, the setting times are much slower than those of pastes in the absence of FGD gypsum. The combination of FGD gypsum and slag powder provides synergistic benefits above that of slag powder alone. The addition of FGD gypsum provides benefit by promoting ettringite formation and forms a compact microstructure, increasing the compressive strength and reduces the drying shrinkage of cement mortar and concrete.

Development and applications of Baosteel sintering flue gas desulphurization technology

The research background and technical features of Baosteel sintering flue gas desulphurization （ FGD）--swirl- jet-absorbing wet limestone-gypsum sintering FGD technology, process and equipment are introduced in this paper. Main contents and achievements of the pilot experiment and the engineering practice of Baosteel FGD are analyzed and discussed systematically. Past engineering practice experiences indicate that Baosteel FGD has the following merits： wide applicability to sintering flue gas features, such as frequently changing temperatures, unstable SO2 concentration, intensively fluctuating flow rates ,etc. ,high pollutants removal efficiency ,low investment and energy consumption; stable and reliable operation ,utilizable byproduct （gypsum）, etc. It indicates that Baosteel sintering FGD is of extensive application value for the FGD of large and medium-scaled sintering machines.

Mercury Speciation of Flue Gas Desulphurization By-Products in Coal-Fired Power Plants in China

The aim of this study was to develop and examine the morphology and distribution of mercury (Hg) in flue gas desulfurization (FGD) by-product. Mercury in the coal of coal-fired power plants is concentrated in the by-products of desulfurization process, and it is widely used as an additive in cement, building materials and other industries. Due to the different stability of various forms of mercury in the environment, subsequent use of products containing desulfurization by-product additives will continue to be released into the environment, endangering human health. Therefore, it is very necessary to study the form and distribution of mercury in the by-products of desulfurization in coal-fired power plants to provide a theoretical basis for subsequent harmless treatment. For content and morphology of mercury analysis, 1 sample of dry FGD ash and 6 samples of wet FGD gypsum were analyzed. The total 7 samples were extracted using a modification of sequential chemical extractions (SCE) method, which was employed for the partitioning Hg into four fractions: water soluble, acid soluble, H2O2 soluble, and residual. The Hg analysis was done with United States Environmental Protection Agency (USEPA) method 7471B. Comparing with the wet FGD gypsums of coal-fired boilers, the total Hg content in the dry FGD by-product was as high as 1.22 mg/kg, while the total Hg content in the FGD gypsum is 0.23 - 0.74 mg/kg, which was 2 times over the wet FGD gypsum. The concentration of water soluble Hg in the dry FGD by-product was the highest amount (0.72 mg/kg), accounting for 59.02% of the total mercury. While residual Hg content was 0.16 mg/kg, only about 13.11% of the total mercury. Mercury content in FGD gypsum was expressed in the form of ρ (residual Hg) > ρ (H2O2 soluble Hg) > ρ (water soluble Hg) > ρ (acid soluble Hg). The morphology and distribution of mercury in FGD by-products is supposed to be analyzed before utilization, and the impact of mercury on the environment should be considered.

Investigations on removal of SO_2 from flue gas by aerosol formation in pulsed corona discharge process

The removal of SO 2 from flue gas by pulsed corona discharge in presence of ammonia was experimentally investigated. The results showed that the SO 2 removal mainly depends on thermal reaction of SO 2 with NH 3 and enhancements of 0%—25% by pulsed corona discharge in the range of the specific energy 0—5 Wh/Nm 3. The aerosol mass concentration, mainly composed of ammonium sulfate, increased with specific energy dissipated into the reactor. With an initial concentration of 2000—2100 ppmv SO 2 and energy consumption of 3 Wh/Nm 3, when a stoichiometric amount of ammonia is injected, the removal efficiency of SO 2 and percentage of ammonium sulfates in reaction products are all ≥80%. The collection efficiency of the reactor for aerosol is about 74% at a flue gas temperature of 60 to 65℃ and a water vapor content of 9% to 11% volume.

Dynamic optimization oriented modeling and nonlinear model predictive control of the wet limestone FGD system

Nonlinear model predictive control(NMPC)scheme is an effective method of multi-objective optimization control in complex industrial systems.In this paper,a NMPC scheme for the wet limestone flue gas desulphurization(WFGD)system is proposed which provides a more flexible framework of optimal control and decision-making compared with PID scheme.At first,a mathematical model of the FGD process is deduced which is suitable for NMPC structure.To equipoise the model’s accuracy and conciseness,the wet limestone FGD system is separated into several modules.Based on the conservation laws,a model with reasonable simplification is developed to describe dynamics of different modules for the purpose of controller design.Then,by addressing economic objectives directly into the NMPC scheme,the NMPC controller can minimize economic cost and track the set-point simultaneously.The accuracy of model is validated by the field data of a 1000 MW thermal power plant in Henan Province,China.The simulation results show that the NMPC strategy improves the economic performance and ensures the emission requirement at the same time.In the meantime,the control scheme satisfies the multiobjective control requirements under complex operation conditions(e.g.,boiler load fluctuation and set point variation).The mathematical model and NMPC structure provides the basic work for the future development of advanced optimized control algorithms in the wet limestone FGD systems.

Deep Desulphurization and DeNO_X in Circulating Fluidized Bed Boiler

With the revision of emission standards, deep desulphurization and DeNO X is needed in circulating fluidized bed (CFB) boilers. The operation of the first set of 300-MW CFB boiler plus limestone/gypsum wet flue gas desulphurization (FGD) system in the world shows that deep desulphurization and DeNO X of CFB boilers has higher SO2 removal efficiency at a lower Ca/S ratio compared with traditional inner desulphurization mode. It can meet the increasingly rigid emission standards, and is suitable for more fuels. Deep desulphurization and DeNO X can also achieve a highly-efficient high-temperature CFB boiler that can not only achieve inner desulphurization and low NO X emission, but benefits low-grade, high sulfur content fuels as well. Research of deep desulphurization and DeNO X will be a developing direction for CFB boilers.

INTERACTION BETWEEN SO_2 FROM FLUE GAS AND SORBENT PARTICLES IN DRY FGD PROCESSES

Among the technologies to control SO2 emission from coal-fired boilers, the dry flue gas desulphurization (FGD) method, with appropriate modifications, has been identified as a candidate for realizing high SO2 removal efficiency to meet both technical and economic requirements, and for making the best quality byproduct gypsum as a useful additive for improving alkali soil. Among the possible modifications two major factors have been selected for study: (1) favorable chemical reaction kinetics at elevated temperatures and the sorbent characteristics; (2) enhanced diffusion of SO2 to the surface and within the pores of sorbent particles that are closely related to gas-solid two-phase flow patterns caused by flue gas and sorbent particles in the reactor. To achieve an ideal pore structure, a sorbent was prepared through hydration reaction by mixing lime and fly ash collected from bag house of power plants to form a slurry, which was first dewatered and then dried. The dry sorbent was found capable of rapid conversion of 70% of its calcium content at 700℃, reaching a desulphurization efficiency of over 90% at a Ca/S ratio of 1.3. Experiments confirmed that the diffusion effect of SO2 is an important factor and that gas-solid two-phase flow plays a key role to mixing and contact between SO2 and sorbent particles. For designing the FDG reactor, a new theoretical drag model was developed by combination of CFD with the Energy Minimization Multi-Scale (EMMS) theory for dense fluidi-zation systems. This new drag model was first verified by comparing calculated and measured drag values, and was then implemented in simulation of gas-solid two-phase flow in two circulating fluidized beds with different sizes and flow parameters. One riser has diameter and height of 0.15 m×3m and another one 0.2m×14.2m. Their superficial gas velocities are 4 and 5.2 m·s-1, respectively, and the circulating rate 53 and 489 kg·(m-2·s-1). FCC particles were used in both cases. The results show that not only the static pressure drop along the riser height, but also radial distributions of particle volume fraction have been very well predicted in comparison with experiments. The new drag model is expected to shed more light on the further improvement of SO2 diffusion to solid sorbent and optimization of reactor structure.

氨法烟气脱硫工艺实验研究

利用亚硫酸铵作为吸收剂进行氨法烟气脱硫模拟实验,主要考察了吸收液进塔pH值、液气比、吸收液浓度、进口SO2浓度、进口烟气温度等主要影响因素对脱硫效率的影响,并从理论上分析了它们之间的内在关系,得出了适宜的操作条件范围。

氨法烟气脱硫中的氨逃逸

以脱硫喷淋塔出口的游离氨气为监测对象,通过模拟烟气实验,研究了吸收液的pH值、浓度、液气比(liquid to gas,L/G)和进口烟气温度等对氨逃逸量的影响.实验结果显示,随着吸收液pH值、浓度和液气比的增加,氨逃逸量逐渐增多.为减少氨逃逸,保证高脱硫率,得到较为合适的工艺参数如下:pH=6.0,吸收液浓度为1%,液气比为4 L/m^3.从氨逃逸和硫酸铵结晶两方面综合考虑,进口烟气温度控制在90~110℃较为合适.

石膏浆液旋流器的分离性能实验研究

通过理论分析及工程经验对石灰石/石膏法烟气脱硫工艺中石膏浆液脱水系统的旋流器进行优化设计,在与工业实际相近的操作条件下,优选出了一根综合性能较好的旋流器。考察了该旋流器的压力、流量与分离效率之间相互关系,与常规石膏浆液旋流器的分级效率进行了比较,确定了最佳操作条件。结果表明,旋流器的进口流量随着进出口压力差的增大而增大,分离效率随着流量增加先上升后下降。在进口硫石膏颗粒平均粒径为24μm,流量为11.814.8 m^3/h时,分离效率在85%以上,底流出口10μm、15μm以下的颗粒分别占底流出口颗粒总体积的1%、10%左右,起到了很明显的分级浓缩作用,分离性能也优于常规使用的石膏浆液旋流器。

钢铁厂烧结烟气脱硫技术的探讨

概述了钢铁企业二氧化硫污染的现状和主要控制技术,指出烧结烟气脱硫是有效的控制措施。分析了烧结烟气的特点,主要介绍了密相干塔烟气脱硫工艺,并对烧结烟气脱硫技术的选择提出了建议。

脱硫石膏改良宁夏典型龟裂碱土效果及其安全性评价

脱硫石膏是燃煤烟气湿法脱硫的副产物,已广泛应用于盐碱地改良。宁夏地区龟裂碱土质地坚硬、渗透性差,不易改良利用。为了评价脱硫石膏改良宁夏地区典型龟裂碱土的有效性和可行性,以早熟粳稻"吉特605"为试验材料,在大田试验条件下,研究了脱硫石膏对土壤特性、水稻产量和品质的影响,以及脱硫石膏作为盐碱地改良剂的安全性。结果表明:施用脱硫石膏降低了土壤的pH值和碱化度;显著提高水稻产量(P<0.05),2013年水稻产量由2 333.3提高到3 317.4 kg/hm^2;脱硫石膏对稻米品质的影响主要体现在整精米率、垩白度、垩白粒率、胶稠度和直链淀粉上,2013年加工品质中的整精米率由52.6%提高到59.7%;比较施用脱硫石膏和未施用脱硫石膏的籽粒中的重金属含量的变化,施用脱硫石膏的籽粒中重金属除Cr含量较高外,Cd、As、Hg、Pb含量均比对照低,且都符合联合国粮农组织和国家食品标准规定的人类摄入标准。综合评价脱硫石膏施用效果,以施用量3.15×104 kg/hm^2作用效果显著。该研究为脱硫石膏改良龟裂碱土,提高资源利用率提供参考。

火电厂烟气脱硫石膏重金属含量监测与分析

为有效利用脱硫石膏改良盐碱地,避免改良过程中带来土壤重金属污染风险,在山西省境内不同地区选择有代表性的8个火电厂烟气脱硫废弃物-脱硫石膏采样点,在1a内每月定期进行脱硫石膏的采集及重金属（Cd、Ni、Pb、Cu、Zn、Cr、Hg、As）浓度的分析。结果表明,8个采样点脱硫石膏中重金属Cd、Ni、Pb、Cu、Zn、Cr、As含量基本低于适用于耕地的国家土壤环境质量二级标准（GB 15618-1995）,而1~8号采样点只有一小部分脱硫石膏中Hg含量低于适用于耕地的国家土壤环境质量二级标准（GB 15618-1995）。8号采样点除极个别批次重金属含量较1~7号采样点低之外,其余均高于1~7号采样点脱硫石膏中重金属浓度。因此,在利用脱硫石膏改良盐碱地之前,要明确脱硫石膏中不同重金属元素浓度,适量施用脱硫石膏,达到改良盐碱地,保证农产品安全,提高作物产量的目的。

燃煤电厂锅炉中颗粒物在选择性催化还原、静电除尘器和烟气脱硫入口处的分布特性

采用承重撞击器颗粒物采样系统在国内某燃煤电厂4#锅炉进行颗粒物采集,采样点包括选择性催化还原（SCR）入口、静电除尘器（ESP）入口和烟气脱硫（FGD）入口。对采集的颗粒物的质量粒径分布特性和无机成分分布特性进行研究,结果表明相较于SCR入口,ESP入口处PM0.2～10的量减少24.45%,但主要减少超微米颗粒物;该锅炉ESP的效率很高,对PM0.2～1.0、PM0.2～2.5和PM0.2～10的脱除率分别达到99.52%、99.64%和99.79%;S在各采样点浓度差异明显,Al、Si的差异主要体现在亚微米颗粒物,Na、Ca浓度几乎不变;FGD入口,PM0.2～1.0中各无机元素的排放总量分别为：Na 0.03mg/m^3、Ca 0.19mg/m^3、Al 0.11mg/m^3、Si 0.26 mg/m^3和S 0.08mg/m^3。

柠檬酸添加方式对脱硫石膏性能影响

系统研究了柠檬酸的两种添加方式对脱硫石膏凝结时间、强度、晶体生长发育等的影响。结果表明:相对于先掺法而言,同掺法的凝结时间较长,强度降低,在掺量为0.07%时,强度达到一致;随掺量的增加,晶体粗化,晶粒由针状生长成为短柱状结构。