This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the...This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the proposed decoupling control scheme. Through simulation study shown that the decoupling is effective, stable and it presents advantage over controller without decoupler. Also, this scheme is able to offer good dynamic performance for most disturbances.展开更多
The failure of a fluid catalysis and cracking unit (FCCU) in a Chinese refinery was investigated by using nondestructive detection methods, fracture surface examination, hardness measurement, chemical composition and...The failure of a fluid catalysis and cracking unit (FCCU) in a Chinese refinery was investigated by using nondestructive detection methods, fracture surface examination, hardness measurement, chemical composition and corrosion products analysis. The results showed that the failure was caused by the dew point nitrate stress corrosion cracking. For a long operation period, the wall temperature of the regenerator in the FCCU was below the fume dew point. As a result, an acid fume NOx-SOx-H2O medium present- ed on the surface, resulting in stress corrosion cracking of the component with high residual stress. In order to confirm the relative conclusion, simulated testing was conducted in laboratory, and the results showed similar cracking characteristics. Finally, some sug- gestions have been made to prevent the stress corrosion cracking of an FCCU from re-occurring in the future.展开更多
In our present work, a post-riser regeneration technology （PRRT） for fluid catalytic cracking （FCC） units was developed to deal with increasingly heavier feedstock and hereby the larger amount of coke deposited on...In our present work, a post-riser regeneration technology （PRRT） for fluid catalytic cracking （FCC） units was developed to deal with increasingly heavier feedstock and hereby the larger amount of coke deposited on the catalyst particles during reaction. This technology can make full use of the advantages of riser regenerator, such as high cokeburning efficiency and low residual carbon, and at the same time overcome its disadvantages, such as difficulty in starting combustion. The average particles concentration on the cross section of the system was studied on a large scale cold model experimental set-up. Also a necessary software was developed by combining the hydrodynamics research results in our work with the coke-burning kinetics model and the heat and mass transfer model developed by previous researchers. The simulation results showed that the PRRT could increase regeneration capability by 16.28%-26.24% over the conventional turbulent fluidized bed regenerator under the similar operation conditions, and that the residual carbon could be kept below 0.1 wt %.展开更多
Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS)...Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.展开更多
The cracking of polyolefins, especially polyethylene in the molten state was effectively catalyzed by the powdery spent FCC （Fluid Catalytic Cracking） catalyst which was dispersed in it. The activation energy of the...The cracking of polyolefins, especially polyethylene in the molten state was effectively catalyzed by the powdery spent FCC （Fluid Catalytic Cracking） catalyst which was dispersed in it. The activation energy of the catalytic cracking of polyethylene was about 74 kJ/mol. The cracked product was naphtha and middle distillate as the major product and gaseous hydrocarbon （C1-C4） as the minor product while little heavy oil was produced. The chemical compositions of the product were： aromatic hydrocarbons, isoparaffins and branched olefins, whereas that of the non-catalyzed products were： n-olefins and n-paraffins with minor amount of dienes with increasing the process time. Additionally, the product pattern shifted from naphtha rich product to kerosene and gas-oil rich product. However, any catalytic product showed low fluid point （〈 -10 ℃）, while that of the non-catalyzed product was as high as 40 ℃. Catalyst could process, more than 100 times by weight of polyethylene with fairly small amount （- 30 wt%） of coke deposition. Spent catalyst gave higher hydrocarbons while fresh catalyst gave gaseous product as the major product. Other polyolefins such as polypropylene and polystyrene were tested on same catalyst to show that their reactivity is higher than that of polyethylene and gave the aliphatic products, alkyl benzenes and C6-C9 iso-paraffins as the major product. Product pattern of the cracked product suggested that the reaction proceeded via the primary reactions making paraffins and olefins which were followed by the isomerization, secondary cracking, aromatization and hydrogen transfer which based on the carbenium ion mechanism.展开更多
A steady state model was developed for simulating the performance of an industrial fluid catalytic cracking (FCC) unit which was subsequently used in parametric sensitivity studies. The simulator includes kinetic mode...A steady state model was developed for simulating the performance of an industrial fluid catalytic cracking (FCC) unit which was subsequently used in parametric sensitivity studies. The simulator includes kinetic models for the riser reactor and the regeneration systems. Mass and energy balances were performed for each of these sections and simulation results were compared with the plant data available in the literature. Model predictions were found to be in close agreement with the reported data. Finally this validated model was used for studying the effects of independent variables such as feed preheat temperature (Tfeed) and feed flow rate (Ffeed) on the unit performance at either fixed regenerated catalyst temp/regenerator temp (Trgn) or constant reactor outlet temperature (ROT). The catalyst circulation rate (CCR) was automatically adjusted to keep the ROT constant with varying the independent variables feed preheat temperature while the air rate adjusted for keeping the regenerator temperature constant which consequences the dependency of both dependent and independent variables on the unit performance. The air flow rate to the regenerator was also an independent variable during the parametric sensitivity analysis and its effect on FCC performance was investigated at constant Tfeed, Ffeed and CCR. Combining all the sensitivity analysis, it has been found to increase gas oil conversion and product yields by 5 to 6 percent with decrease of say, 10 K, in the feed preheat temperature (Tfeed) and corresponding increase in air rate (Fair) and catalyst circulation rate (Frgc) at constant reactor outlet temperature (ROT) and regenerated catalyst temperature (Trgc).展开更多
文摘This study presents a decoupling control scheme of fluid catalytic cracking unit to account for the high interaction between two temperature control loops. The feed flow rate load disturbance is introduced to test the proposed decoupling control scheme. Through simulation study shown that the decoupling is effective, stable and it presents advantage over controller without decoupler. Also, this scheme is able to offer good dynamic performance for most disturbances.
基金This work was financially supported by the Major State Basic Research Development Program of China (973 ProgramNo.19990970) and Petrochemical Company of China.
文摘The failure of a fluid catalysis and cracking unit (FCCU) in a Chinese refinery was investigated by using nondestructive detection methods, fracture surface examination, hardness measurement, chemical composition and corrosion products analysis. The results showed that the failure was caused by the dew point nitrate stress corrosion cracking. For a long operation period, the wall temperature of the regenerator in the FCCU was below the fume dew point. As a result, an acid fume NOx-SOx-H2O medium present- ed on the surface, resulting in stress corrosion cracking of the component with high residual stress. In order to confirm the relative conclusion, simulated testing was conducted in laboratory, and the results showed similar cracking characteristics. Finally, some sug- gestions have been made to prevent the stress corrosion cracking of an FCCU from re-occurring in the future.
文摘In our present work, a post-riser regeneration technology （PRRT） for fluid catalytic cracking （FCC） units was developed to deal with increasingly heavier feedstock and hereby the larger amount of coke deposited on the catalyst particles during reaction. This technology can make full use of the advantages of riser regenerator, such as high cokeburning efficiency and low residual carbon, and at the same time overcome its disadvantages, such as difficulty in starting combustion. The average particles concentration on the cross section of the system was studied on a large scale cold model experimental set-up. Also a necessary software was developed by combining the hydrodynamics research results in our work with the coke-burning kinetics model and the heat and mass transfer model developed by previous researchers. The simulation results showed that the PRRT could increase regeneration capability by 16.28%-26.24% over the conventional turbulent fluidized bed regenerator under the similar operation conditions, and that the residual carbon could be kept below 0.1 wt %.
基金supported by the[Natural Science Foundation Project of Shandong Province#1]under Grant[ZR2019MEE033][Fundamental Research Funds for the central Universities#2]under Grant[19CX02035A].
文摘Catalytic cracking is the main method to lighten heavy crude oil,this process can produce high quality oil products such as gasoline and diesel,but also produces a large amount of fluid catalytic cracking slurry(FCCS).The catalyst particles in FCCS seriously restrict the secondary processing of FCCS and need to be removed,and the properties of Fccs is an important factor that affects the removal efficiency of the catalyst particles.Based on the"effective contact point"model proposed by the research group,this study further proposed the"electrostatic separation efficiency calculation"model.In this model,since Fccs has a uniform distribution of catalyst particles,the ratio of the number of catalyst particles can be expressed as the ratio of area to achieve the calculation of separation efficiency.Then the catalyst removal efficiency under different viscosity was analyzed,thus verifying the feasibility of this model.The effects of temperature and mass ratio of four components on the viscosity of FccS were investigated respectively,then the effects of temperature and four components'mass ratio on the electrostatic sep-aration can be directly converted into the effect of viscosity on the electrostatic separation efficiency.All the results show the electrostatic separation efficiency decreases with increasing viscosity,and the best separationtemperatureis120℃.
文摘The cracking of polyolefins, especially polyethylene in the molten state was effectively catalyzed by the powdery spent FCC （Fluid Catalytic Cracking） catalyst which was dispersed in it. The activation energy of the catalytic cracking of polyethylene was about 74 kJ/mol. The cracked product was naphtha and middle distillate as the major product and gaseous hydrocarbon （C1-C4） as the minor product while little heavy oil was produced. The chemical compositions of the product were： aromatic hydrocarbons, isoparaffins and branched olefins, whereas that of the non-catalyzed products were： n-olefins and n-paraffins with minor amount of dienes with increasing the process time. Additionally, the product pattern shifted from naphtha rich product to kerosene and gas-oil rich product. However, any catalytic product showed low fluid point （〈 -10 ℃）, while that of the non-catalyzed product was as high as 40 ℃. Catalyst could process, more than 100 times by weight of polyethylene with fairly small amount （- 30 wt%） of coke deposition. Spent catalyst gave higher hydrocarbons while fresh catalyst gave gaseous product as the major product. Other polyolefins such as polypropylene and polystyrene were tested on same catalyst to show that their reactivity is higher than that of polyethylene and gave the aliphatic products, alkyl benzenes and C6-C9 iso-paraffins as the major product. Product pattern of the cracked product suggested that the reaction proceeded via the primary reactions making paraffins and olefins which were followed by the isomerization, secondary cracking, aromatization and hydrogen transfer which based on the carbenium ion mechanism.
文摘A steady state model was developed for simulating the performance of an industrial fluid catalytic cracking (FCC) unit which was subsequently used in parametric sensitivity studies. The simulator includes kinetic models for the riser reactor and the regeneration systems. Mass and energy balances were performed for each of these sections and simulation results were compared with the plant data available in the literature. Model predictions were found to be in close agreement with the reported data. Finally this validated model was used for studying the effects of independent variables such as feed preheat temperature (Tfeed) and feed flow rate (Ffeed) on the unit performance at either fixed regenerated catalyst temp/regenerator temp (Trgn) or constant reactor outlet temperature (ROT). The catalyst circulation rate (CCR) was automatically adjusted to keep the ROT constant with varying the independent variables feed preheat temperature while the air rate adjusted for keeping the regenerator temperature constant which consequences the dependency of both dependent and independent variables on the unit performance. The air flow rate to the regenerator was also an independent variable during the parametric sensitivity analysis and its effect on FCC performance was investigated at constant Tfeed, Ffeed and CCR. Combining all the sensitivity analysis, it has been found to increase gas oil conversion and product yields by 5 to 6 percent with decrease of say, 10 K, in the feed preheat temperature (Tfeed) and corresponding increase in air rate (Fair) and catalyst circulation rate (Frgc) at constant reactor outlet temperature (ROT) and regenerated catalyst temperature (Trgc).
