Types, Evolution and Pool-Controlling Significance of Pool Fluid Sources in Superimposed Basins:A Case Study from Paleozoic and Mesozoic in South China

Having multiple tectonic evolution stages, South China belongs to a superimposed basin in nature. Most marine gas pools became secondary pools. The pool fluid sources serve as the principal pool-controlling factors. On the basis of eight typical petroleum pools, the type, evolution in time-space, and the controlling of petroleum distribution of pool fluid sources are comprehensively analyzed. The main types of pool fluid sources include hydrocarbon, generated primarily and secondly from source rocks, gas cracked from crude oil, gas dissolved in water, inorganic gas, and mixed gases. In terms of evolution, the primary hydrocarbon was predominant prior to Indosinian; during Indosinian to Yenshanian the secondary gas includes gas cracked from crude oil, gas generated secondarily, gas dissolved in water, and inorganic gas dominated; during Yenshanian to Himalayan the most fluid sources were mixed gases. Controlled by pool fluid sources, the pools with mixed gas sources distributed mainly in Upper Yangtze block, especially Sichuan （四川） basin; the pools with primary hydrocarbon sources distributed in paleo-uplifts such as Jiangnan （江南）, but most of these pools became fossil pools; the pools with secondary hydrocarbon source distributed in the areas covered by Cretaceous and Eogene in Middle-Lower Yangtze blocks, and Chuxiong （楚雄）, Shiwandashan （十万大山）, and Nanpanjiang （南盘江） basins; the pools with inorganic gas source mainly formed and distributed in tensional structure areas.

Three-dimensional steady-state closed form solution for multilayered fluid-saturated anisotropic finite media due to surface/internal point source

A three-dimensional(3 D)steady-state solution of fluid saturated anisotropic finite media is presented.The eigenequation method and the pseudo-Stroh formalism are used to obtain the exact solution for homogeneous saturated finite media.The propagator matrix method is introduced to deal with the corresponding multilayered poroelastic media.The poroelastic solutions due to surface or internal point fluid source are obtained.The comparison of the results of the saturated isotropic media in a half space and those obtained by the finite element method is given to illustrate the accuracy of the solution in a finite domain.Numerical solutions of a sandwich poroelastic medium are presented to analyze its hydromechanical behaviors.Two ratios of the horizontal permeability to vertical permeability and different source positions are investigated.The results show that the fluid parameters and source positions have great influence on the hydromechanical behaviors of the layered media.

Ore-forming fluid characteristics and ore-forming materials source of the Tudimiaogou – Yindongshan lead-zinc polymetallic orefield, west Henan

1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc

Fluid evolution and hydrocarbon accumulation model of ultra-deep gas reservoirs in Permian Qixia Formation of northwest Sichuan Basin,SW China

The fluid evolution and reservoir formation model of the ultra-deep gas reservoirs in the Permian Qixia Formation of the northwestern Sichuan Basin are investigated by using thin section,cathodoluminescence,inclusion temperature and U-Pb isotopic dating,combined with gas source identification plates and reservoir formation evolution profiles established based on burial history,thermal history,reservoir formation history and diagenetic evolution sequence.The fluid evolution of the marine ultra-deep gas reservoirs in the Qixia Formation has undergone two stages of dolomitization and one phase of hydrothermal action,two stages of oil and gas charging and two stages of associated burial dissolution.The diagenetic fluids include ancient seawater,atmospheric freshwater,deep hydrothermal fluid and hydrocarbon fluids.The two stages of hydrocarbon charging happened in the Late Triassic and Late Jurassic–Early Cretaceous respectively,and the Middle to Late Cretaceous is the period when the crude oil cracked massively into gas.The gas reservoirs in deep marine Permian strata of northwest Sichuan feature multiple source rocks,composite transportation,differential accumulation and late finalization.The natural gas in the Permian is mainly cracked gas from Permian marine mixed hydrocarbon source rocks,with cracked gas from crude oil in the deeper Sinian strata in local parts.The scale development of paleo-hydrocarbon reservoirs and the stable and good preservation conditions are the keys to the forming large-scale gas reservoirs.

Numerical simulation of spatial-temporal evolution characteristics of subsurface fluid based on strong body seismogenic model$$$$

Using finite element technique of the plane-strain problem in solid-liquid two-phase medium, we Studied the char acteristics of 'field precursors' and 'focus precursors' of subsurface fluid and their spatial-temporal evolution in case of dip-slip earthquake. The results show that: ① the change of ground fluid is slow and the anomaly is not prominent in the early period which is of elastic accumulation and non-linear; ② dilatancy emerges and anomalyfocus mainly in the source region in the moderate period which is hardening and of local dilatancy. In the period the focus precursors emerge earlier than the field precursors; ③ anomalies spreed continuously in the source area and new regions with big anomaly emerge out of the source region in the middle-short period which is of large scale dilatancy.

Origin of dolomites in the Permian dolomitic reservoirs of Fengcheng Formation in Mahu Sag,Junggar Basin, NW China

Origin of authigenic dolomites in the dolomitic reservoir of the Permian Fengcheng Formation in the Mahu Sag of Junggar Basin is unclear.Occurrence and genetic evolution of the authigenic dolomites in dolomitic rock reservoir of the Fengcheng Formation in the Mahu Sag were analyzed by polarized and fluorescence thin sections,scanning electron microscope(SEM),electron microprobe(EMP),C,O and Sr isotopes analysis,and other techniques.(1)Dolomites were mainly precipitated in three stages:penecontemporaneous-shallow burial stage(early stage of the Middle Permian),middle burial stage(middle stage of the Middle Permian),and middle-deep burial stage,with the former two stages in dominance.(2)Dolomitization fluid was high-salinity brine originating from alkaline lake.In the penecontemporaneous-shallow burial stage,Mg^(2+)was mainly supplied by alkaline-lake fluid and devitrification of volcanic glass.In the middle burial stage,Mg^(2+)mainly came from the transformation of clay minerals,devitrification of volcanic glass and dissolution of aluminosilicates such as feldspar.(3)Regular changes of Mg,Mn,Fe,Sr,Si and other elements during the growth of dolomite were mainly related to the alkaline-lake fluid,and to different influences of devitrification and diagenetic alteration of volcanic materials during the burial.(4)In the penecontemporaneous stage,induced by alkaline-lake microorganisms,the micritic-microcrystalline dolomites were formed by primary precipitation,replacement of aragonite and high-Mg calcite,and other processes;in the shallow burial stage,the silt-sized dolomites were formed by continuous growth of micritic-microcrystalline dolomite and replacement of calcites,tuffs and other substances;in the middle burial stage,the dolomites,mainly silt-and fine-sized,were formed by replacement of volcanic materials.The research results are referential for investigating the formation mechanism and distribution patterns of tight dolomitic reservoirs in the Mahu Sag and other similar oil and gas bearing areas.

Genesis, metallogenic model, and prospecting prediction of the Nibao gold deposit in the Guizhou Province, China

Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.

Geochemical characteristics of cold-seep carbonates in Shenhu area,South China Sea

Cold seeps spread worldwide along the continental margins,which are closely related to the exploration of gas hydrates.Cold-seep carbonates have been reported to record the nature of seepage,including fluid source,sedimentary environment,and variation of seepage activity.We investigated the morphology,mineralogy,element compositions,and carbon and oxygen isotopes of 15 cold-seep carbonates collected from the Shenhu area,and compared them with 2 carbonates from the Haima cold seep,the South China Sea(SCS),to promote our knowledge of cold-seep system in SCS.Most of the Shenhu carbonates exhibit crust morphology,and some are in the form of chimneys and blocks.Their absolute(20%–65%)and relative carbonate mineral contents(mainly aragonite and calcite,with minor samples containing dolomite)vary significantly,indicating the multi-stage methane leakage in our study area.Some samples show a slight negative Ce anomaly,suggesting either the mixing of seawater or variation of the redox condition during the precipitation;the cooccurrence of strongly enriched U and Mo demonstrates anoxic condition during precipitation.The mixed genetic methane source was interpreted by δ^(13)C of the Shenhu carbonates to range from-22.34‰to-59.30‰Vienna PeeDee Belemnite(VPDB),and the slight ^(18)O-enrichment imprinted on the carbonates suggests the possible influence from hydrate dissociation.The Haima carbonates,with biogenic methane as the main gas source,were presumably formed in a stronger fluid flux by compared with our Shenhu samples.

Genesis of calcite vein in basalt and its effect on reservoir quality: A case study of the Carboniferous in the east slope of Mahu sag, Junggar Basin, NW China

The characteristics and genesis of the calcite veins in Carboniferous basalt in the east slope of Mahu Sag,Junggar Basin are investigated based on observation of cores and thin sections;analyses of X-ray fluorescence,in situ major,trace and rare earth elements(REE),carbon,oxygen and strontium isotopes,fluid inclusions,as well as basin modeling.There are three periods of calcite fillings.The Period I calcite is characterized by low Mn content,flat REE pattern,strong negative cerium(Ce)anomaly,weak to moderate negative Eu anomaly,and light carbon isotopic composition,indicating the formation of the calcite was affected by meteoric water.The Period II calcite shows higher Mn and light REE contents,weak positive Ce anomaly and slight positive europium(Eu)anomaly,and a little heavier carbon isotopic composition and slightly lower strontium isotope ratio than the Period I calcite,suggesting that deep diagenetic fluids affected the formation of the Period II calcite to some extent.The Period III calcite is rich in iron and manganese and has REE pattern similar to that of the Period II calcite,but the cerium and europium enomalies vary significantly.The Period I and II calcites were formed in shallow diagenetic environment at approximately 250–260 Ma,corresponding to Late Hercynian orogeny at Late Permian.The PeriodⅢcalcite was probably formed in the Indo-China movement during Late Triassic.It is believed that the precipitation of calcite in basalt fractures near unconformity was related to leaching and dissolution of carbonates in the overlying Lower Permian Fengcheng Formation by meteoric water,which destructed the Carboniferous weathering crust reservoirs in early stage.Relatively high quality reservoirs could be developed in positions with weak filling and strong late dissolution,such as structural high parts with Fengcheng Formation missing,distant strata from Fengcheng Formation vertically,buried hills inside lake basin,etc.

H-O-S-Cu-Pb Isotopic Constraints on the Origin of the Nage Cu-Pb Deposit, Southeast Guizhou Province, SW China

The Nage Cu-Pb deposit, a new found ore deposit in the southeast Guizhou province, southwest China, is located on the southwestern margin of the Jiangnan Orogenic Belt. Ore bodies are hosted in slate and phyllite of Neoproterozoic Jialu and Wuye Formations, and are structurally controlled by EW-trending fault. It contains Cu and Pb metals about 0.12 million tonnes with grades of 0.2 wt% to 3.4 wt% Cu and 1.1 wt% to 9.27 wt% Pb. Massive and disseminated Cu-Pb ores from the Nage deposit occur as either veinlets or disseminations in silicified rocks. The ore minerals include chalcopyrite, galena and pyrite, and gangue minerals are quartz, sericite and chlorite. The H-O isotopic compositions of quartz, S-Cu-Pb isotopic compositions of sulfide minerals, Pb isotopic compositions of whole rocks and ores have been analyzed to trace the sources of ore-forming fluids and metals for the Nage Cu-Pb deposit. The oSCUNBs values of chalcopyrite range from -0.09% to ＋0.33%0, similar to basic igneous rocks and chalcopyrite from magmatic deposits. J6SCUNBS values of chalcopyrite from the early, middle and final mineralization stages show an increasing trend due to 63Cu prior migrated in gas phase when fluids exsolution from magma, ja4ScDT values of sulfide minerals range from -2.7‰ to ＋2.8‰, similar to mantle-derived sulfur （0±3‰）. The positive correlation between J65CUNBs and ja4SCDT values of chalcopyrite indicates that a common source of copper metal and sulfur from magma. JDu2o- SMOW and JlSOH2O-SMOW values of water in fluid inclusions of quartz range from -60.7‰ to -44.4‰ and ＋7.9‰ to ＋9.0%0 （T=260℃）, respectively and fall in the field for magmatic and metamorphic waters, implicating that mixed sources for H20 in hydrothermal fluids. Ores and sulfide minerals have a small range of Pb isotopic compositions （208Pb/204pb=38.152 to 38.384, 207Pb/204Pb=15.656 to 17.708 and 206Pb/204Pb=17.991 to 18.049） that are close to orogenic belt and upper crust Pb evolution curve, and similar to Neoproterozoic host rocks （208Pb/204Pb=38.201 to 38.6373, 207pb/204pb=15.648 to 15.673 and 206pb/204pb=17.820 to 18.258）, but higher than diabase （208Pb/204pb=37.830 to 38.012, 207pb/204pb=15.620 to 15.635 and 206pb/204pb=17.808 to 17.902）. These results imply that the Pb metal originated mainly from host rocks. The H-O-S-Cu-Pb isotopes tegather with geology, indicating that the ore genesis of the Nage Cu-Pb deposit is post-magmatic hydrothermal type.

Geology and Isotope Geochemistry of the Yinchanggou-Qiluogou Pb-Zn Deposit,Sichuan Province,Southwest China

The Yinchanggou-Qiluogou Pb-Zn deposit,located in the western Yangtze Block,southwest China,is hosted by the Upper Sinian Dengying Formation dolostone.Ore bodies occur in the Qiluogou anticline and the NS-and NNW-trending faults.Sulfide ores mainly consist of sphalerite,pyrite,galena and calcite,with subordinate dolomite and quartz.Seventeen ore bodies have been discovered to date and they have a combined 1.0 million tons of sulfide ores with average grades of 2.27wt%Zn and 6.89wt%Pb.The δD（H2O-SMOW） and δ18O（H2O-SMOW） values of fluid inclusions in quartz and calcite samples range from-68.9‰ to-48.7‰ and 7.3‰ to 15.9‰,respectively,suggesting that H2O in the hydrothermal fluids sourced from metamorphic water.Calcite samples have δ13C（PDB） values ranging from-6.2‰ to-4.1‰ and δ18O（SMOW） values ranging from 15.1‰ to 17.4‰,indicating C and O in the hydrothermal fluids likely derived from a mixed source of metamorphic fluids and the host carbonates.The δ34S（CDT） values of sulfide minerals range from 5.5‰ to 20.3‰,suggesting that thermal chemical reduction of sulfate minerals in evaporates were the most probable source of S in the hydrothermal fluids.The 206Pb/204Pb,207Pb/204Pb and 208Pb/204Pb ratios of sulfide minerals fall in the range of 18.11 to 18.40,15.66 to 15.76 and 38.25 to 38.88,respectively.The Pb isotopic data of the studied deposit plot near the upper crust Pb evolution curve and overlap with the age-corrected Proterozoic basement rocks and the Upper Sinian Dengying Formation hosting dolostone.This indicates that the Pb originated from a mixed source of the basement metamorphic rocks and the ore-hosting carbonate rocks.The ore geology and C-H-O-S-Pb isotopic data suggest that the YinchanggouQiluogou deposit is an unusual carbonate-hosted,strata-bound and epigenetic deposit that derived ore-forming materials from a mixed source of the underlying Porterozoic basements and the Sinian hosting carbonates.

Source and Evolution of the Ore-Forming Fluids of Carlin-Type Gold Deposit in the Youjiang Basin,South China:Evidences from Solute Data of Fluid Inclusion Extracts

The source and evolution of ore-forming fluids is important to understand the genesis of Carlin-type gold deposit.Constraints on the source and evolution of ore fluid components by the con-ventional geochemical methods have long been a challenge due to the very fine-grained nature and complex textures of hydrothermal minerals in these deposits.In this study,we present the crush-leach analyzed solute data of fluid inclusion extracts within quartz,calcite,realgar,and fluorite from the Shuiyindong,Nibao,and Yata gold deposits in the Youjiang Basin,providing new insights into the source and evolution of ore-forming fluids.The results show that the high molar Cl/Br ratios up to 2508 in fluid inclusion extracts are indicative of a contribution of magmatic hydrothermal fluids.Flu-ids mixing between basinal and magmatic-hydrothermal fluids are evident on the plots of Cl/Br versus Na/K ratios,showing that ore-stage milky quartz near the magmatic-hydrothermal fluids reflects magma origin of the ore-forming fluids,whereas late ore-stage drusy quartz and realgar near the de-fined basinal fluids suggest the later input of basinal fluids in late-ore stage.Although the predominate-ly host rocks in Shuiyindong,Nibao and Yata gold deposit are bioclastic limestone,sedimentary tuff,and calcareous siltstone,respectively,the solute data of fluid inclusion extracts records they underwent the similar fluid-rocks reactions between the Na-rich magmatic hydrothermal fluids and the Ca-and Mg-rich host rocks.This study highlights the solute data of fluid inclusion extracts obtained by crush-leach analyses have the potential to fingerprint the source and evolution of ore-forming fluids of the Carlin-type gold deposit.

Analysis on capabilities of density-based solvers within OpenFOAM to distinguish aerothermal variables in difusion boundary layer

Open source feld operation and manipulation（OpenFOAM）is one of the most prevalent open source computational fluid dynamics（CFD）software.It is very convenient for researchers to develop their own codes based on the class library toolbox within OpenFOAM.In recent years,several density-based solvers within OpenFOAM for supersonic/hypersonic compressible flow are coming up.Although the capabilities of these solvers to capture shock wave have already been verifed by some researchers,these solvers still need to be validated comprehensively as commercial CFD software.In boundary layer where diffusion is the dominant transportation manner,the convective discrete schemes＇capability to capture aerothermal variables,such as temperature and heat flux,is different from each other due to their own numerical dissipative characteristics and from viewpoint of this capability,these compressible solvers within OpenFOAM can be validated further.In this paper,frstly,the organizational architecture of density-based solvers within OpenFOAM is analyzed.Then,from the viewpoint of the capability to capture aerothermal variables,the numerical results of several typical geometrical felds predicted by these solvers are compared with both the outcome obtained from the commercial software Fastran and the experimental data.During the computing process,the Roe,AUSM＋（Advection Upstream Splitting Method）,and HLLC（Harten-Lax-van Leer-Contact）convective discrete schemes of which the spatial accuracy is 1st and 2nd order are utilized,respectively.The compared results show that the aerothermal variables are in agreement with results generated by Fastran and the experimental data even if the1st order spatial precision is implemented.Overall,the accuracy of these density-based solvers can meet the requirement of engineering and scientifc problems to capture aerothermal variables in diffusion boundary layer.