This work investigates a multi-product parallel disassembly line balancing problem considering multi-skilled workers.A mathematical model for the parallel disassembly line is established to achieve maximized disassemb...This work investigates a multi-product parallel disassembly line balancing problem considering multi-skilled workers.A mathematical model for the parallel disassembly line is established to achieve maximized disassembly profit and minimized workstation cycle time.Based on a product’s AND/OR graph,matrices for task-skill,worker-skill,precedence relationships,and disassembly correlations are developed.A multi-objective discrete chemical reaction optimization algorithm is designed.To enhance solution diversity,improvements are made to four reactions:decomposition,synthesis,intermolecular ineffective collision,and wall invalid collision reaction,completing the evolution of molecular individuals.The established model and improved algorithm are applied to ball pen,flashlight,washing machine,and radio combinations,respectively.Introducing a Collaborative Resource Allocation(CRA)strategy based on a Decomposition-Based Multi-Objective Evolutionary Algorithm,the experimental results are compared with four classical algorithms:MOEA/D,MOEAD-CRA,Non-dominated Sorting Genetic Algorithm Ⅱ(NSGA-Ⅱ),and Non-dominated Sorting Genetic Algorithm Ⅲ(NSGA-Ⅲ).This validates the feasibility and superiority of the proposed algorithm in parallel disassembly production lines.展开更多
A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PT...A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PTFE/Al/Bi_(2)O_(3)on both mechanical properties and the energy release were investigated through various tests such as thermogravimetry-differential scanning calorimetry,adiabatic oxygen bomb test and split Hopkinson pressure bar test.The microstructure observed through scanning electron microscope and Xray diffraction results are used to analyze the ignition and reaction mechanism of PTFE/Al/Bi_(2)O_(3).The results indicate that the PTFE/Al/Bi_(2)O_(3)are capable of triggering the exothermic reaction of molten PTFE/Bi_(2)O_(3)and Al/Bi_(2)O_(3)over the PTFE/Al reactive materials,thereby promoting reactions.The excessive aluminum in the ternary system is beneficial for increasing energy release.The ignition of shock-induced chemical reactions in PTFE/Al/Bi_(2)O_(3)is closely related to the material fracture.The dominant mechanism for hot-spot generation under Split Hopkinson Pressure Bar test is the frictional temperature rise at the microcrack after failure.展开更多
There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of...There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions.展开更多
In the current work,inclined magnetic field,thermal radiation,and the Cattaneo-Christov heat flux are taken into account as we analyze the impact of chemical reaction on magneto-hydrodynamic Casson nanofluid flow on a...In the current work,inclined magnetic field,thermal radiation,and the Cattaneo-Christov heat flux are taken into account as we analyze the impact of chemical reaction on magneto-hydrodynamic Casson nanofluid flow on a stretching sheet.Modified Buongiorno’s nanofluid model has been used to model the flow governing equations.The stretching surface is embedded in a porousmedium.By using similarity transformations,the nonlinear partial differential equations are transformed into a set of dimensionless ordinary differential equations.The numerical solution of transformed dimensionless equations is achieved by applying the shooting procedure together with Rung-Kutta 4th-order method employing MATLAB.The impact of significant parameters on the velocity profile f(ζ),temperature distributionθ(ζ),concentration profileϕ(ζ),skin friction coefficient(Cf),Nusselt number(Nux)and Sherwood number(Shx)are analyzed and displayed in graphical and tabular formats.With an increase in Casson fluid 0.5<β<2,the motion of the Casson fluid decelerates whereas the temperature profile increases.As the thermal relation factor expands 0.1<γ1<0.4,the temperature reduces,and consequently thermal boundary layer shrinks.Additionally,by raising the level of thermal radiation 1<Rd<7,the temperature profile significantly improves,and an abrupt expansion has also been observed in the associated thermal boundary with raise thermal radiation strength.It was observed that higher permeability 0<K<4 hinders the acceleration of Casson fluid.Higher Brownian motion levels 0.2<Nb<0.6 correspond to lower levels of the Casson fluid concentration profile.Moreover,it is observed that chemical reaction 0.2<γ2<0.5 has an inverse relation with the concentration level of Casson fluid.The current model’s significant uses include heat energy enhancement,petroleum recovery,energy devices,food manufacturing processes,and cooling device adjustment,among others.Furthermore,present outcomes have been found in great agreementwith already publishedwork.展开更多
In this study, Hydromagnetic Squeezing Nanofluid flow between two vertical plates in presence of a chemical reaction has been investigated. The governing equations were transformed by similarity transformation and the...In this study, Hydromagnetic Squeezing Nanofluid flow between two vertical plates in presence of a chemical reaction has been investigated. The governing equations were transformed by similarity transformation and the resulting ordinary differential equations were solved by collocation method. The velocity, temperature, concentration and magnetic induction profiles were determined with help of various flow parameters. The numerical scheme was simulated with aid of MATLAB. The results showed that increasing the squeeze number only boosts velocity and concentration while lowering temperature. Conversely, increasing the Hartmann number, Reynold’s magnetic number, Eckert number and Thermal Grashof number generally increases temperature but decreases both velocity and concentration. Chemical reaction rate and Soret number solely elevate concentration while Schmidt number only reduces it. The results of this study will be useful in the fields of oil and gas industry, plastic processing industries, filtration, food processing, lubrication system in machinery, Microfluidics devices for drug delivery and other related fields of nanotechnology.展开更多
Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and pro...Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and propagation.Fire propagation develops in coal seams because of a set of factors such as direction and wind speed,fracturing and temperature.In this work,heat transfer and chemical kinetics are studied from conservation equations of energy and species,respectively,using the software COMSOL Multiphysics to simulate the propagation of fires in coal seams.Two possible scenarios were analyzed that usually occur in the walls of the coal seams,such as fire focus and fire complete screens.It was found that the propagation kinetics of the fire changes depending on the temperature,the fractur-ing of rock mass and the area of fire influence.For temperature values lower than 300℃,there is con-sumption around 250 cm^3/h,values around 700℃,the consumption is 1500 cm^3/h,and for fires of 1200℃ have values of 3000 cm^3/h.Depending on the speed of propagation can vary from 4 to 17cm/day,considering on the level and fracturing of the final wall of the open pit.展开更多
There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. Fo...There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. For the first time, the solidification course of a modified two-component acrylic structural adhesive is measured by using reed-vibration mechanical spectroscopy for liquids (RMS-L) in this work, and results show that there are four sequential processes of mechanical spectra with time. The in-depth analyses indicate that RMS-L can detect in real-time the generation and disappearance of active free radicals, as well as the chemical cross-link processes in the adhesive. This kind of real-time detection will undoubtedly facilitate the study of the chemical reaction dynamics controlled by free radicals.展开更多
The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic d...The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic deposit is always an interesting topic of research. We used the finite difference method to model the mineralizing process of the chalcopyrite in this region with considering the field geological features, mineralogy and geochemistry. In particular, the modern mineralization theory was used to quantitatively estimate the related chemical reactions associated with the chalcopyrite formation in the Kaerqueka polymetallic deposit. The numerical results indicate that the hydrothermal fluid flow is a key controlling factor of mineralization in this area and the temperature gradient is the driving force of pore-fluid flow. The metallogenic temperature of chalcopyrite in the Kaerqueka polymetallic deposit is between 250 and 350 ℃. The corresponding computational results have been verified by the field observations. It has been further demonstrated that the simulation results of coupled models in the field of emerging computational geosciences can enhance our understanding of the ore-forming processes in this area.展开更多
This paper presents the study of convective heat and mass transfer characteristics of an incompressible MHD visco-elastic fluid flow immersed in a porous medium over a stretching sheet with chemical reaction and therm...This paper presents the study of convective heat and mass transfer characteristics of an incompressible MHD visco-elastic fluid flow immersed in a porous medium over a stretching sheet with chemical reaction and thermal stratification effects. The resultant governing boundary layer equations are highly non-linear and coupled form of partial differential equations, and they have been solved by using fourth order Runge-Kutta integration scheme with Newton Raphson shooting method. Numerical computations are carried out for the non-dimensional physical parameters. Here a numerical has been carried out to study the effect of different physical parameters such as visco-elasticity, permeability of the porous medium, magnetic field, Grashof number, Schmidt number, heat source parameter and chemical reaction parameter on the flow, heat and mass transfer characteristics.展开更多
A new reaction system to determine nonlinear chemical fingerprint(NCF)and its use in identification method based on double reaction system was researched.Panax ginsengs,such as ginseng,American ginseng and notoginseng...A new reaction system to determine nonlinear chemical fingerprint(NCF)and its use in identification method based on double reaction system was researched.Panax ginsengs,such as ginseng,American ginseng and notoginseng were identified by the method.The NCFs of the three samples of Panax ginsengs were determined through two nonlinear chemical systems,namely system 1 consisting of sample components,H2SO4,MnSO4,NaBrO3,acetone and the new system,system 2 consisting of sample components,H2SO4,(NH4)4Ce(SO4)2,NaBrO3 and citric acid.The comparison between the results determined through systems 1 and 2 shows that the speed to determine NCF through system 2 is much faster than that through system 1;for systems 1 and 2,the system similarities of the same kind of samples are≥98.09%and 99.78%,respectively,while those of different kinds of samples are≤63.04%and 86.34%,respectively.The results to identify the kinds of some samples by system similarity pattern show that both the accuracies of identification methods based on single system 1 and 2 are≥95.6%,and the average values are 97.1%and 96.3%,respectively;the accuracy of the method based on double system is≥97.8%,and the average accuracy is 99.3%.The accuracy of the method based on double system is higher than that based on any single system.展开更多
Heat and mass transfer effects on the unsteady flow of a micropolar fluid through a porous medium bounded by a semi-infinite vertical plate in a slip-flow regime are studied taking into account a homogeneous chemical ...Heat and mass transfer effects on the unsteady flow of a micropolar fluid through a porous medium bounded by a semi-infinite vertical plate in a slip-flow regime are studied taking into account a homogeneous chemical reaction of the first order. A uniform magnetic field acts perpendicular to the porous surface absorb micropolar fluid with a suction velocity varying with time. The free stream velocity follows an exponentially increasing or decreasing small perturbation law. Using the approximate method, the expressions for the velocity microrotation, temperature, and concentration are obtained. Futher, the results of the skin friction coefficient, the couple stress coefficient, and the rate of heat and mass transfer at the wall are presented with various values of fluid properties and flow conditions.展开更多
The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of ...The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of the yield stress and the Soret effect. The governing boundary layer equations and boundary conditions are cast into a dimen- sionless form by similarity transformations, and the resulting system of equations is solved by a finite difference method. The results are preSented and discussed for concentration profiles, as well as the Nusselt number and the Sherwood number for various values of the parameters, which govern the problem. The results obtained show that the flow field is influenced appreciably by the presence of the chemical reaction parameter γ the order of.the chemical reaction parameter m, the Soret number St, the buoyancy ratio N, the Lewis number Le, and the dimensionless rheological parameter Ω.展开更多
The high temperature chemical reaction process of La2O3 in H3BO3-C system was studied by means of XRD and TG-DTA.The results showed that dehydration reaction of H3BO3 occurred in the temperature range of 82~390 ℃;La...The high temperature chemical reaction process of La2O3 in H3BO3-C system was studied by means of XRD and TG-DTA.The results showed that dehydration reaction of H3BO3 occurred in the temperature range of 82~390 ℃;La2O3 and B2O3 reacted to form LaB3O6,LaBO3,and B4C in the temperature range of 836~1400℃;at 1450 ℃,B4C and LaBO3 further reacted to form LaB4,and partial LaB4 and B reacted to form LaB6;at 1500 ℃,LaB4 and B reacting into LaB6 was the main reaction,and the content of LaB6 increased with prolonging time.展开更多
In this article, we have considered the simultaneous influence of ohmic heating and chemical reaction on heat and mass transfer over a stretching sheet. The effects of applied magnetic field are also taken into consid...In this article, we have considered the simultaneous influence of ohmic heating and chemical reaction on heat and mass transfer over a stretching sheet. The effects of applied magnetic field are also taken into consideration while the induced magnetic field is not considered due to very small magnetics Reynolds number. The governing flow problem comprises of momentum, continuity, thermal energy and concentration equation which are transformed into highly nonlinear coupled ordinary differential equations by means of similarity transforms, which are then, solved numerically with the help of Successive Linearization method(SLM) and Chebyshev Spectral collocation method. Numerical values of skin friction coefficient, local Nusselt number, and Sherwood number are also taken into account with the help of tables. The physical influence of the involved parameters of flow velocity, temperature and concentration distribution is discussed and demonstrated graphically. The numerical comparison is also presented with the existing published results and found that the present results are in excellent agreement which also confirms the validity of the present methodology.展开更多
An analysis is presented to investigate the effects of variable viscosities and thermal stratification on the MHD mixed convective heat and mass transfer of a viscous, incompressible, and electrically conducting fluid...An analysis is presented to investigate the effects of variable viscosities and thermal stratification on the MHD mixed convective heat and mass transfer of a viscous, incompressible, and electrically conducting fluid past a porous wedge in the presence of a chemical reaction. The wall of the wedge is embedded in a uniform nonDarcian porous medium in order to allow for possible fluid wall suction or injection. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically with finite difference methods. Numerical calculations up to the thirdorder level of truncation are carried out for different values of dimensionless parameters. The results are presented graphically, and show that the flow field and other quantities of physical interest are significantly influenced by these parameters. The results are compared with those available in literature, and show excellent agreement.展开更多
Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite ...Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.展开更多
An integral description of chemical reactions taken place under mixing was formulated on the basis of the three-region model pictured in Part Ⅰ of this study. A mathematically simplified version of the model was deve...An integral description of chemical reactions taken place under mixing was formulated on the basis of the three-region model pictured in Part Ⅰ of this study. A mathematically simplified version of the model was developed. It was shown that the converted portion of the material in the dispersion region can be neglected provided that the initial concentration ratio of A and B was less than 0.1, and the effects of micro - and macromixing on the chemical reactions could be represented by two dimensionless numbers: Dα and Π. The model was applied to two reacting systems: competitive-consecutive reactions and parallel reactions. Agreement between model prediction and experimental results demonstrated that the present framework, though in simplified form, is capable of describing reactive mixing without loss of any significant features of the process.展开更多
The Soret and Dufour effects on unsteady MHD mixed convection flow past an infinite radiative vertical porous plate embedded in a porous medium in the presence of chemical reaction have been studied. A uniform magneti...The Soret and Dufour effects on unsteady MHD mixed convection flow past an infinite radiative vertical porous plate embedded in a porous medium in the presence of chemical reaction have been studied. A uniform magnetic field acts perpendicular to the porous surface. The Rosseland approximation has been used to describe the radiative heat flux in energy equation. The governing equations are solved numerically by applying explicit finite difference Method. The effects of various parameters on the velocity, temperature and concentration fields have been examined with the help of graphs.展开更多
This communiquéis opted to study the flow of nanofluid because of heated disk rotation subjected to the convective boundaries with chemical reaction of first order.Wherein Buongiorno’s model for nanofluids is us...This communiquéis opted to study the flow of nanofluid because of heated disk rotation subjected to the convective boundaries with chemical reaction of first order.Wherein Buongiorno’s model for nanofluids is used due to its wide range of applications and the rotating disk under investigation is permeable.Small magneto Reynolds parameter and boundary layer assumptions are carried out to formulate the problem.The system of nonlinear partial differential equations governing the flow problem is converted into the set of ordinary differential equations by using particular relations known as Von Karman transformations.The complicated set of coupled ordinary differential equations with complicated boundary conditions is set to solve by an analytical technique Homotopy Analysis Method(HAM).Whereby the results obtained by the aforementioned method are provided analytically and analyzed graphically.Also validation of the work is confirmed by providing comparison of previous works in tabular form.Effect of chemical reaction parameter on mass transfer rate is also highlighted tabularly for its increament.Nusselt and Sherwood numbers calculated and compared to the like literature and found in good agreement.展开更多
The chemical reaction effect on an unsteady magnetohydrodynamic (MHD) flow past a semi-infinite vertical porous plate with viscous dissipation is analyzed. The governing equations of motion, energy, and species are ...The chemical reaction effect on an unsteady magnetohydrodynamic (MHD) flow past a semi-infinite vertical porous plate with viscous dissipation is analyzed. The governing equations of motion, energy, and species are transformed into ordinary differential equations (ODEs) using the time dependent similarity parameter. The resultant ODEs are then solved numerically by a finite element method. The effects of various parameters on the velocity, temperature, and concentration profiles are presented graphically, and the values of the skin-friction, Nusselt number, and Sherwood number for various values of physical parameters are presented through tables.展开更多
文摘This work investigates a multi-product parallel disassembly line balancing problem considering multi-skilled workers.A mathematical model for the parallel disassembly line is established to achieve maximized disassembly profit and minimized workstation cycle time.Based on a product’s AND/OR graph,matrices for task-skill,worker-skill,precedence relationships,and disassembly correlations are developed.A multi-objective discrete chemical reaction optimization algorithm is designed.To enhance solution diversity,improvements are made to four reactions:decomposition,synthesis,intermolecular ineffective collision,and wall invalid collision reaction,completing the evolution of molecular individuals.The established model and improved algorithm are applied to ball pen,flashlight,washing machine,and radio combinations,respectively.Introducing a Collaborative Resource Allocation(CRA)strategy based on a Decomposition-Based Multi-Objective Evolutionary Algorithm,the experimental results are compared with four classical algorithms:MOEA/D,MOEAD-CRA,Non-dominated Sorting Genetic Algorithm Ⅱ(NSGA-Ⅱ),and Non-dominated Sorting Genetic Algorithm Ⅲ(NSGA-Ⅲ).This validates the feasibility and superiority of the proposed algorithm in parallel disassembly production lines.
基金the National Natural Science Foundation of China (Grant No.12002045)State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology (Grant No.QNKT22-09)。
文摘A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PTFE/Al/Bi_(2)O_(3)on both mechanical properties and the energy release were investigated through various tests such as thermogravimetry-differential scanning calorimetry,adiabatic oxygen bomb test and split Hopkinson pressure bar test.The microstructure observed through scanning electron microscope and Xray diffraction results are used to analyze the ignition and reaction mechanism of PTFE/Al/Bi_(2)O_(3).The results indicate that the PTFE/Al/Bi_(2)O_(3)are capable of triggering the exothermic reaction of molten PTFE/Bi_(2)O_(3)and Al/Bi_(2)O_(3)over the PTFE/Al reactive materials,thereby promoting reactions.The excessive aluminum in the ternary system is beneficial for increasing energy release.The ignition of shock-induced chemical reactions in PTFE/Al/Bi_(2)O_(3)is closely related to the material fracture.The dominant mechanism for hot-spot generation under Split Hopkinson Pressure Bar test is the frictional temperature rise at the microcrack after failure.
文摘There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions.
文摘In the current work,inclined magnetic field,thermal radiation,and the Cattaneo-Christov heat flux are taken into account as we analyze the impact of chemical reaction on magneto-hydrodynamic Casson nanofluid flow on a stretching sheet.Modified Buongiorno’s nanofluid model has been used to model the flow governing equations.The stretching surface is embedded in a porousmedium.By using similarity transformations,the nonlinear partial differential equations are transformed into a set of dimensionless ordinary differential equations.The numerical solution of transformed dimensionless equations is achieved by applying the shooting procedure together with Rung-Kutta 4th-order method employing MATLAB.The impact of significant parameters on the velocity profile f(ζ),temperature distributionθ(ζ),concentration profileϕ(ζ),skin friction coefficient(Cf),Nusselt number(Nux)and Sherwood number(Shx)are analyzed and displayed in graphical and tabular formats.With an increase in Casson fluid 0.5<β<2,the motion of the Casson fluid decelerates whereas the temperature profile increases.As the thermal relation factor expands 0.1<γ1<0.4,the temperature reduces,and consequently thermal boundary layer shrinks.Additionally,by raising the level of thermal radiation 1<Rd<7,the temperature profile significantly improves,and an abrupt expansion has also been observed in the associated thermal boundary with raise thermal radiation strength.It was observed that higher permeability 0<K<4 hinders the acceleration of Casson fluid.Higher Brownian motion levels 0.2<Nb<0.6 correspond to lower levels of the Casson fluid concentration profile.Moreover,it is observed that chemical reaction 0.2<γ2<0.5 has an inverse relation with the concentration level of Casson fluid.The current model’s significant uses include heat energy enhancement,petroleum recovery,energy devices,food manufacturing processes,and cooling device adjustment,among others.Furthermore,present outcomes have been found in great agreementwith already publishedwork.
文摘In this study, Hydromagnetic Squeezing Nanofluid flow between two vertical plates in presence of a chemical reaction has been investigated. The governing equations were transformed by similarity transformation and the resulting ordinary differential equations were solved by collocation method. The velocity, temperature, concentration and magnetic induction profiles were determined with help of various flow parameters. The numerical scheme was simulated with aid of MATLAB. The results showed that increasing the squeeze number only boosts velocity and concentration while lowering temperature. Conversely, increasing the Hartmann number, Reynold’s magnetic number, Eckert number and Thermal Grashof number generally increases temperature but decreases both velocity and concentration. Chemical reaction rate and Soret number solely elevate concentration while Schmidt number only reduces it. The results of this study will be useful in the fields of oil and gas industry, plastic processing industries, filtration, food processing, lubrication system in machinery, Microfluidics devices for drug delivery and other related fields of nanotechnology.
基金CIMEX Mineral Institute of the National University of Colombia for the trust and support provided for the development of this researchthe Cerrejón company for financing this project
文摘Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and propagation.Fire propagation develops in coal seams because of a set of factors such as direction and wind speed,fracturing and temperature.In this work,heat transfer and chemical kinetics are studied from conservation equations of energy and species,respectively,using the software COMSOL Multiphysics to simulate the propagation of fires in coal seams.Two possible scenarios were analyzed that usually occur in the walls of the coal seams,such as fire focus and fire complete screens.It was found that the propagation kinetics of the fire changes depending on the temperature,the fractur-ing of rock mass and the area of fire influence.For temperature values lower than 300℃,there is con-sumption around 250 cm^3/h,values around 700℃,the consumption is 1500 cm^3/h,and for fires of 1200℃ have values of 3000 cm^3/h.Depending on the speed of propagation can vary from 4 to 17cm/day,considering on the level and fracturing of the final wall of the open pit.
基金supported by the Natural Science Foundations of Xinjiang Automatic Region, China (Grant Nos. 200821104, 2009211B16, and 2010211B16)the Support Program of Science and Technology of Xinjiang Automatic Region, China (Grant No. 201091112)the West-Light Foundation of the Chinese Academy of Sciences (Grant No. RCPY200906)
文摘There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. For the first time, the solidification course of a modified two-component acrylic structural adhesive is measured by using reed-vibration mechanical spectroscopy for liquids (RMS-L) in this work, and results show that there are four sequential processes of mechanical spectra with time. The in-depth analyses indicate that RMS-L can detect in real-time the generation and disappearance of active free radicals, as well as the chemical cross-link processes in the adhesive. This kind of real-time detection will undoubtedly facilitate the study of the chemical reaction dynamics controlled by free radicals.
基金Project(2017YFC0601503)supported by the National Key R&D Program of ChinaProjects(41872249,41472302,41772348)supported by the National Natural Science Foundation of China
文摘The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic deposit is always an interesting topic of research. We used the finite difference method to model the mineralizing process of the chalcopyrite in this region with considering the field geological features, mineralogy and geochemistry. In particular, the modern mineralization theory was used to quantitatively estimate the related chemical reactions associated with the chalcopyrite formation in the Kaerqueka polymetallic deposit. The numerical results indicate that the hydrothermal fluid flow is a key controlling factor of mineralization in this area and the temperature gradient is the driving force of pore-fluid flow. The metallogenic temperature of chalcopyrite in the Kaerqueka polymetallic deposit is between 250 and 350 ℃. The corresponding computational results have been verified by the field observations. It has been further demonstrated that the simulation results of coupled models in the field of emerging computational geosciences can enhance our understanding of the ore-forming processes in this area.
文摘This paper presents the study of convective heat and mass transfer characteristics of an incompressible MHD visco-elastic fluid flow immersed in a porous medium over a stretching sheet with chemical reaction and thermal stratification effects. The resultant governing boundary layer equations are highly non-linear and coupled form of partial differential equations, and they have been solved by using fourth order Runge-Kutta integration scheme with Newton Raphson shooting method. Numerical computations are carried out for the non-dimensional physical parameters. Here a numerical has been carried out to study the effect of different physical parameters such as visco-elasticity, permeability of the porous medium, magnetic field, Grashof number, Schmidt number, heat source parameter and chemical reaction parameter on the flow, heat and mass transfer characteristics.
基金Project(61533021)supported by the National Natural Science Foundation of ChinaProject(R201706)supported by Hunan Food Pharmaceutical,China
文摘A new reaction system to determine nonlinear chemical fingerprint(NCF)and its use in identification method based on double reaction system was researched.Panax ginsengs,such as ginseng,American ginseng and notoginseng were identified by the method.The NCFs of the three samples of Panax ginsengs were determined through two nonlinear chemical systems,namely system 1 consisting of sample components,H2SO4,MnSO4,NaBrO3,acetone and the new system,system 2 consisting of sample components,H2SO4,(NH4)4Ce(SO4)2,NaBrO3 and citric acid.The comparison between the results determined through systems 1 and 2 shows that the speed to determine NCF through system 2 is much faster than that through system 1;for systems 1 and 2,the system similarities of the same kind of samples are≥98.09%and 99.78%,respectively,while those of different kinds of samples are≤63.04%and 86.34%,respectively.The results to identify the kinds of some samples by system similarity pattern show that both the accuracies of identification methods based on single system 1 and 2 are≥95.6%,and the average values are 97.1%and 96.3%,respectively;the accuracy of the method based on double system is≥97.8%,and the average accuracy is 99.3%.The accuracy of the method based on double system is higher than that based on any single system.
文摘Heat and mass transfer effects on the unsteady flow of a micropolar fluid through a porous medium bounded by a semi-infinite vertical plate in a slip-flow regime are studied taking into account a homogeneous chemical reaction of the first order. A uniform magnetic field acts perpendicular to the porous surface absorb micropolar fluid with a suction velocity varying with time. The free stream velocity follows an exponentially increasing or decreasing small perturbation law. Using the approximate method, the expressions for the velocity microrotation, temperature, and concentration are obtained. Futher, the results of the skin friction coefficient, the couple stress coefficient, and the rate of heat and mass transfer at the wall are presented with various values of fluid properties and flow conditions.
文摘The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of the yield stress and the Soret effect. The governing boundary layer equations and boundary conditions are cast into a dimen- sionless form by similarity transformations, and the resulting system of equations is solved by a finite difference method. The results are preSented and discussed for concentration profiles, as well as the Nusselt number and the Sherwood number for various values of the parameters, which govern the problem. The results obtained show that the flow field is influenced appreciably by the presence of the chemical reaction parameter γ the order of.the chemical reaction parameter m, the Soret number St, the buoyancy ratio N, the Lewis number Le, and the dimensionless rheological parameter Ω.
基金Project supported by the National Natural Science Foundation of China(5057403)Scientific Research Special Foundation of Doctor Subject of Chinese University(20030145015)
文摘The high temperature chemical reaction process of La2O3 in H3BO3-C system was studied by means of XRD and TG-DTA.The results showed that dehydration reaction of H3BO3 occurred in the temperature range of 82~390 ℃;La2O3 and B2O3 reacted to form LaB3O6,LaBO3,and B4C in the temperature range of 836~1400℃;at 1450 ℃,B4C and LaBO3 further reacted to form LaB4,and partial LaB4 and B reacted to form LaB6;at 1500 ℃,LaB4 and B reacting into LaB6 was the main reaction,and the content of LaB6 increased with prolonging time.
文摘In this article, we have considered the simultaneous influence of ohmic heating and chemical reaction on heat and mass transfer over a stretching sheet. The effects of applied magnetic field are also taken into consideration while the induced magnetic field is not considered due to very small magnetics Reynolds number. The governing flow problem comprises of momentum, continuity, thermal energy and concentration equation which are transformed into highly nonlinear coupled ordinary differential equations by means of similarity transforms, which are then, solved numerically with the help of Successive Linearization method(SLM) and Chebyshev Spectral collocation method. Numerical values of skin friction coefficient, local Nusselt number, and Sherwood number are also taken into account with the help of tables. The physical influence of the involved parameters of flow velocity, temperature and concentration distribution is discussed and demonstrated graphically. The numerical comparison is also presented with the existing published results and found that the present results are in excellent agreement which also confirms the validity of the present methodology.
文摘An analysis is presented to investigate the effects of variable viscosities and thermal stratification on the MHD mixed convective heat and mass transfer of a viscous, incompressible, and electrically conducting fluid past a porous wedge in the presence of a chemical reaction. The wall of the wedge is embedded in a uniform nonDarcian porous medium in order to allow for possible fluid wall suction or injection. The governing boundary layer equations are written into a dimensionless form by similarity transformations. The transformed coupled nonlinear ordinary differential equations are solved numerically with finite difference methods. Numerical calculations up to the thirdorder level of truncation are carried out for different values of dimensionless parameters. The results are presented graphically, and show that the flow field and other quantities of physical interest are significantly influenced by these parameters. The results are compared with those available in literature, and show excellent agreement.
基金Projects(51304035,50974030)supported by the National Natural Science Foundation of ChinaProject(20110491512)supported by the Postdoctoral Science Foundation of China+2 种基金Project(20130042120034)supported by the Specialized Research Fund for the Doctoral Program of Higher Education(New Teachers),ChinaProject(120401008)supported by the Fundamental Research Funds for Central Universities,ChinaProject(L20150173)supported by the Scientific Research Fund of Liaoning Provincial Education Department,China
文摘Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.
基金Supported by the National Natural Science Foundation of China and China Petrochemical Corporation.
文摘An integral description of chemical reactions taken place under mixing was formulated on the basis of the three-region model pictured in Part Ⅰ of this study. A mathematically simplified version of the model was developed. It was shown that the converted portion of the material in the dispersion region can be neglected provided that the initial concentration ratio of A and B was less than 0.1, and the effects of micro - and macromixing on the chemical reactions could be represented by two dimensionless numbers: Dα and Π. The model was applied to two reacting systems: competitive-consecutive reactions and parallel reactions. Agreement between model prediction and experimental results demonstrated that the present framework, though in simplified form, is capable of describing reactive mixing without loss of any significant features of the process.
文摘The Soret and Dufour effects on unsteady MHD mixed convection flow past an infinite radiative vertical porous plate embedded in a porous medium in the presence of chemical reaction have been studied. A uniform magnetic field acts perpendicular to the porous surface. The Rosseland approximation has been used to describe the radiative heat flux in energy equation. The governing equations are solved numerically by applying explicit finite difference Method. The effects of various parameters on the velocity, temperature and concentration fields have been examined with the help of graphs.
文摘This communiquéis opted to study the flow of nanofluid because of heated disk rotation subjected to the convective boundaries with chemical reaction of first order.Wherein Buongiorno’s model for nanofluids is used due to its wide range of applications and the rotating disk under investigation is permeable.Small magneto Reynolds parameter and boundary layer assumptions are carried out to formulate the problem.The system of nonlinear partial differential equations governing the flow problem is converted into the set of ordinary differential equations by using particular relations known as Von Karman transformations.The complicated set of coupled ordinary differential equations with complicated boundary conditions is set to solve by an analytical technique Homotopy Analysis Method(HAM).Whereby the results obtained by the aforementioned method are provided analytically and analyzed graphically.Also validation of the work is confirmed by providing comparison of previous works in tabular form.Effect of chemical reaction parameter on mass transfer rate is also highlighted tabularly for its increament.Nusselt and Sherwood numbers calculated and compared to the like literature and found in good agreement.
文摘The chemical reaction effect on an unsteady magnetohydrodynamic (MHD) flow past a semi-infinite vertical porous plate with viscous dissipation is analyzed. The governing equations of motion, energy, and species are transformed into ordinary differential equations (ODEs) using the time dependent similarity parameter. The resultant ODEs are then solved numerically by a finite element method. The effects of various parameters on the velocity, temperature, and concentration profiles are presented graphically, and the values of the skin-friction, Nusselt number, and Sherwood number for various values of physical parameters are presented through tables.