Poly(triphenylamine-p-phenylenevinylene)s with two different end-groups were obtained through a Wittig polycondensation.The structures of two copoly-mers were characterized.Ultraviolet and visible spectro-scopy(UV-Vis...Poly(triphenylamine-p-phenylenevinylene)s with two different end-groups were obtained through a Wittig polycondensation.The structures of two copoly-mers were characterized.Ultraviolet and visible spectro-scopy(UV-Vis)and photoluminescence(PL)spectra show the end-capped polymer emits intensive green light in both solution and film state.Their applications in the detection of nitro compounds were investigated,and the results show high fluorescence quenching sensitivity of the end-capped polymer towards o-nitrotoluene(o-NT).When the concentration of o-NT was 21.5×10^(-3) mol/L,the fluorescence quenching reached 96%.Additionally,after the exposure of polymer film in three different quenchers such as dinitrotoluene(DNT),p-nitrobenzo-quinone(p-BQ)and p-nitrotoluene(p-NT)for 600 s,its fluorescence quenching reached 93.6%,11.5%and 77.9%,respectively.This kind of polymer has great advantages in preparation and may find applications in the detection of nitro explosives.展开更多
High efficient yellow organic light emitting diodes （OLEDs） based on exciplex were reported. The exciplex was formed by 4, 4＇, 4″-tris β-methylphenyl （phenyi） amino]-triphenylamine （m-MTDATA） and 4, 7- diphen...High efficient yellow organic light emitting diodes （OLEDs） based on exciplex were reported. The exciplex was formed by 4, 4＇, 4″-tris β-methylphenyl （phenyi） amino]-triphenylamine （m-MTDATA） and 4, 7- diphenyl-1, 10-phenanthroline （BPhen）. The resulting yellow OLEDs exhibited an external quantum efficiency of over 7%, which is attributed to the effective energy back transfer from exciplex triplet state to exciplex singlet state. The maximum power efficiency of 25 lm/W was achieved. Doping a yellow phosphor Ir（bt）2（acac） into m-MTDATA： BPhen blend, a high efficiency device was achieved with a turn-on voltage of 2.1 V, maximum power efficiency and external quantum efficiency of 86.1 lm/W and 20.7%, respectively.展开更多
基金supported by the Key National Science Foundation of China(No.20736002)the National Natural Science Foundation of China(Grant No.20776045)the Science Foundation of Shanghai Government(07ZR14029).
文摘Poly(triphenylamine-p-phenylenevinylene)s with two different end-groups were obtained through a Wittig polycondensation.The structures of two copoly-mers were characterized.Ultraviolet and visible spectro-scopy(UV-Vis)and photoluminescence(PL)spectra show the end-capped polymer emits intensive green light in both solution and film state.Their applications in the detection of nitro compounds were investigated,and the results show high fluorescence quenching sensitivity of the end-capped polymer towards o-nitrotoluene(o-NT).When the concentration of o-NT was 21.5×10^(-3) mol/L,the fluorescence quenching reached 96%.Additionally,after the exposure of polymer film in three different quenchers such as dinitrotoluene(DNT),p-nitrobenzo-quinone(p-BQ)and p-nitrotoluene(p-NT)for 600 s,its fluorescence quenching reached 93.6%,11.5%and 77.9%,respectively.This kind of polymer has great advantages in preparation and may find applications in the detection of nitro explosives.
基金Acknowledgements We sincerely thank Y. Gu, C. L. Yang and H. Xu for their careful testing of the samples. The authors gratefully acknowledge the National Natural Science Foundation of China （Grant Nos. 51333007 and 50973104）, the National Basic Research Program of China （No. 2013CB834805）, the Foundation of Jilin Research Council （Nos.2012ZDGG001, 20130206003GX and 201105028）, and Chinese Academy of Sciences Instrument Project （No. YZ201103） for the support of this research.
文摘High efficient yellow organic light emitting diodes （OLEDs） based on exciplex were reported. The exciplex was formed by 4, 4＇, 4″-tris β-methylphenyl （phenyi） amino]-triphenylamine （m-MTDATA） and 4, 7- diphenyl-1, 10-phenanthroline （BPhen）. The resulting yellow OLEDs exhibited an external quantum efficiency of over 7%, which is attributed to the effective energy back transfer from exciplex triplet state to exciplex singlet state. The maximum power efficiency of 25 lm/W was achieved. Doping a yellow phosphor Ir（bt）2（acac） into m-MTDATA： BPhen blend, a high efficiency device was achieved with a turn-on voltage of 2.1 V, maximum power efficiency and external quantum efficiency of 86.1 lm/W and 20.7%, respectively.
