The interactions between rutin or the inclusion complex of rutin-b-cyclodextrin and DNA were investigated by means of cyclic voltammetry, UV-vis absorption spectroscopy and fluorescence emission spectroscopy. The appa...The interactions between rutin or the inclusion complex of rutin-b-cyclodextrin and DNA were investigated by means of cyclic voltammetry, UV-vis absorption spectroscopy and fluorescence emission spectroscopy. The appar-ent binding constant of rutin with DNA is found to be 2.9×104 L/mol. The results showed that the ben-zopyranic-4-one plane of rutin mainly intercalated into DNA in the absence of b-cyclodextrin, while the catecholic portion of rutin was located in the double helix of DNA in the presence of b-cyclodextrin.展开更多
As the biggest inter-basin water transfer scheme in the world,the South-to-North Water Diversion Project(SNWD) was designed to alleviate the water crisis in North China.The main channel of the middle route of the SNWD...As the biggest inter-basin water transfer scheme in the world,the South-to-North Water Diversion Project(SNWD) was designed to alleviate the water crisis in North China.The main channel of the middle route of the SNWD is of great concern in terms of the drinking water quality.In this study,we tested the hypothesis that the dissolved organic matter(DOM) derived from the planktonic algae causes the rising levels of COD_(Mn) along the middle route by monitoring data on water quality(2015-2019,monthly resolution).The results showed that algal density in the main channel increased along the channel and was significantly correlated with COD_(Mn)(p <0.01).Five fluorescent components of DOM,including tyrosine-like(14.85%),tryptophan-like(22.48%),microbial byproduct-like(26.34%),fulvic acid-like(11.41%),and humic acid-like(24.92%) components,were detected.The level of tyrosine-like components increased along the channel and was significantly correlated with algal density(p<0.01),indicating that algae significantly changed the level of DOM in the channel.Algal decomposition and metabolism were found to be the main mechanisms that drive the changes in COD_(Mn).Therefore,controlling algal density would be an important measure to prevent further increase in CODMn and for the guarantee of excellent water quality.展开更多
基金Project supported by the National Natural Science Foundation of China (Nos. 90206037,20205007, 20075010).
文摘The interactions between rutin or the inclusion complex of rutin-b-cyclodextrin and DNA were investigated by means of cyclic voltammetry, UV-vis absorption spectroscopy and fluorescence emission spectroscopy. The appar-ent binding constant of rutin with DNA is found to be 2.9×104 L/mol. The results showed that the ben-zopyranic-4-one plane of rutin mainly intercalated into DNA in the absence of b-cyclodextrin, while the catecholic portion of rutin was located in the double helix of DNA in the presence of b-cyclodextrin.
基金This research was financially supported by the National Natural Science Foundation of China(No.U2040210)the National Key R&D Program(Nos.2019YFC0408904,2019YFC0408901).
文摘As the biggest inter-basin water transfer scheme in the world,the South-to-North Water Diversion Project(SNWD) was designed to alleviate the water crisis in North China.The main channel of the middle route of the SNWD is of great concern in terms of the drinking water quality.In this study,we tested the hypothesis that the dissolved organic matter(DOM) derived from the planktonic algae causes the rising levels of COD_(Mn) along the middle route by monitoring data on water quality(2015-2019,monthly resolution).The results showed that algal density in the main channel increased along the channel and was significantly correlated with COD_(Mn)(p <0.01).Five fluorescent components of DOM,including tyrosine-like(14.85%),tryptophan-like(22.48%),microbial byproduct-like(26.34%),fulvic acid-like(11.41%),and humic acid-like(24.92%) components,were detected.The level of tyrosine-like components increased along the channel and was significantly correlated with algal density(p<0.01),indicating that algae significantly changed the level of DOM in the channel.Algal decomposition and metabolism were found to be the main mechanisms that drive the changes in COD_(Mn).Therefore,controlling algal density would be an important measure to prevent further increase in CODMn and for the guarantee of excellent water quality.
