One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis

One new polymer [Co（L）（H2O）2]n（1） was synthesized by 4-（ethoxycarbonyl）-5-methyl-1H-1,2,3-triazole-1-carboxylic acid（Emtc） under the in situ solvent thermal reaction（H2L = 1-（carboxymethyl）-5-methyl-1H-1,2,3-triazole-4-carboxylic acid）. The title complex performs a wave-like 2D framework and the ligand H2L demonstrates the coordination mode as μ4-η-2：η-1η-1：η-1. The crystal structure has been established by single-crystal X-ray diffraction, and characterized by FT-IR. Fluorescent property was investigated in this work. Hirshfeld surface analysis has also been carried out on 1, and obvious main intermolecular interactions are observed.

Syntheses,Crystal Structures and Fluorescence Properties of Two Mononuclear Copper(Ⅱ) Compounds

Two new compounds,1（[Cu（IDB_）2]Cl_2·2CH_3CH_2OH·2H_2O（IDB = N,N-di（2-benzimidazolylmethyl）imine]） and 2（[Cu（EDTB）]·2[C_6H_4（OH）COO]·6H_2O（EDTB = N,N,N＇,N＇-tetrakis-[（2-benzimidazolyl）methyl]-1,2-ethanediamine]）,have been synthesized and their crystal structures were determined by single-crystal X-ray diffraction. Crystal 1 belongs to the triclinic system,space group P1 with a = 9.565（2）,b = 9.863（2）,c = 10.252（3） ？,α = 81.915,β = 88.330,γ = 87.347°,V = 956.28（40） ？3,Z = 1,F（000） = 427,D_c = 1.419 g/cm3,Mr = 817.27 and μ（MoKα） = 0.764 mm^（-1）. The final R indices（I 〉 2σ（I））： R = 0.0505,wR = 0.1417; R indices（all data）： R = 0.0591,wR = 0.1525. Crystal 2 is of triclinic system,space group P1 with a = 11.487（3）,b = 13.396（4）,c = 17.977（5） ？,α = 73.899（5）,β = 86.629（5）,γ = 65.018（4）°,V = 2403.8（12） ？3,Z = 2,F（000） = 1072,D3c = 1.417 g/cm,Mr = 1025.54,μ（MoKα） = 0.528 mm^（-1）. The final R indices（I 〉 2σ（I））： R = 0.0769,w R = 0.163 2; R indices（all data）： R = 0.0769,wR = 0.1632. The two compounds exhibit mononuclear structures. The copper（Ⅱ） atom of crystal 1 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand IDB to adopt a distorted octahedral coordination geometry. The copper（Ⅱ） atom of crystal 2 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand EDTB to show a distorted octahedral coordination geometry. Particularly,the two compounds exhibit fluorescent properties at room temperature in ethanol.

Fluorescence Properties and Crystal Structures of Metal-organic Coordination Complexes Based on the 2,6-Naphthalenedicarboxylic Acid

Two metal-organic coordination complexes, [Zn（2,6-ndc）（1,2-bix）]n（1） and [Zn（2,6-ndc）（1,3-bix）]n（2）（2,6-H2ndc = 2,6-naphthalenedicarboxylic acid, 1,2-bix = 1,2-bis（imidazole-1-ylmethyl）-benzene and 1,3-bix = 1,3-bis（imidazole-1-ylmethyl）-benzene） have been synthesized by the hydrothermal method. Though the two complexes both crystallize in a triclinic system, space group P1 and show similar two-dimensional structures, weak intermolecular interactions（π-π packing interactions） only exist in complex 2. They are characterized by single-crystal X-ray diffraction analysis, fluorescence measurement, IR spectroscopy and TGA. Moreover, the solid-state fluorescence spectra of two complexes show maximal emission peaks at 365（λ（ex） = 329 nm） and 367 nm（λex = 344 nm）, respectively.

Effect of Anionic Ancillary Ligands on Terpyridine Based Coordination Polymers:Synthesis,Crystal Structure and Fluorescence Property

By using different anionic ancillary ligands, two new coordination polymers, [Cd（L）I_2]_n（1） and {[Cd（L）_2（1,4-bdc）]·H_2O}_n（2）（L = 2,4,6-tris（4-pyridyl）pyridine, 1,4-H_2bdc = benzene-1,4-dicarboxylic acid）, have been synthesized under hydrothermal conditions. Compound 1 crystallizes in monoclinic, space group C2/c with a = 11.625（2）, b = 13.871（3）, c = 13.676（3） A, β = 108.11（3）°, V = 2096.0（7）A3, D_c = 2.144 g/cm^3, C_（20）H_（14）I_2N_4Cd, M_r = 676.55, F（000） = 1264, μ（MoKα） = 3.999 mm^（-1）, Z = 4, Rint = 0.0308,（Δρ）_（max） = 0.354,（Δρ）_（min） = 0.289, R = 0.0332 and wR = 0.0721 for 2401 observed reflections（I 〉 2σ（I））. However, compound 2 crystallizes in triclinic, space group P1 with a = 10.315（2）, b = 14.060（3）, c = 15.090（3） A, β = 98.40（3）o, V = 1990.0（9） ？~3, D_c = 1.527 g/cm^3, C_（48）H_（34）N_8O_5Cd, M_r = 915.23, F（000） = 932, μ（MoKα）= 0.610 mm^（-1）, Z = 2, Rint = 0.0776,（Δρ）_（max） = 0.869,（Δρ）_（min） = 0.843, R = 0.0815 and wR = 0.1930 for 6999 observed reflections（I 〉 2σ（I））. Compound 1 is a 1D chain structure, which adopts inorganic anion I- as the counterion, and 2 exists a 2D（4,4） network constructed by benzene-1,4-dicarboxylic acid.

Two Metal-organic Coordination Polymers with Rigid Bis(triazole) Ligand： Assembly, Structures, and Fluorescence Properties

Two new coordination polymers containing rigid bis（triazole）, namely, [Ni（btb）_（0.5）（nph）（H_2O）]_n（1） and [Zn（btb）（SO_4）]_n（2）（btb = 4,4a-bis（1,2,4-triazolyl-1-yl）-biphenyl, H_2nph = 3-nitrophthalic acid） have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a 3D trinodal（3,4,4）-connected sqc69 topology. Complex 2 presents a 2D uninodal 4-connected sql network, which is further packed into a 3D supramolecular framework by C-H···O hydrogen bonds. Thermal stabilities and fluorescence properties of two complexes have been discussed in detail.

Synthesis, Crystal Structure, Fluorescent Property and DFT Calculations of a New Zn(Ⅱ) Complex Based on 3-(2-Pyridyl)-5-(4-pyridyl)-1H-1,2,4-triazole

A new coordination compound Zn（2,4＇-bpt）2（H2O）（1） based on the versatile ligand 2,4＇-Hbpt（2,4？-Hbpt = 3-（2-pyridyl）-5-（4-pyridyl）-1H-1,2,4-triazole） was prepared by hydrothermal reactions. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, X-ray powder diffraction, IR spectrum analysis and thermogravimetric analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to monoclinic system, space group C2/c with a = 23.877（3）, b = 0.7483（9）, c = 1.2492（2） A, b = 92.681（2）°, V = 2230.6（4） A^3, Z = 4, Dc = 1.572 g/cm^3, m = 1.143 mm^-1, Mr = 527.85 and F（000） = 1080. The final R = 0.0581 and wR = 0.0898 with I 〉 2s（I）. 1 is a 0D motif which is connected by hydrogen bonds to form a corrugated 1D pattern. In addition, 1 shows strong photoluminescent emissions in the solid state at room temperature which can be used as potential optical materials. Theoretical calculations based on density functional theory（DFT） were employed in order to explicate the stability and chemical reactivity of 2,4＇-Hbpt with different conformations. The results indicated that conformation I is more stable and prior to coordination in the reactions.

Synthesis,Structure and Fluorescent Property of a New Isolated Zn6Co9 Heteronuclear Cluster Constructed by Four Kinds of Ligands

A novel zero-dimensional heteronuclear cluster based on N-（phosphonomethyl）imi- no-diacetic acid （H4PMIDA） and Phen （1,10-phenanthroline）, [Zn6Co9（PMIDA）6（Phen）6（NO3）4（H2O）6]·2NO3·16H2O, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectrum, thermal analysis, and single-crystal X-ray diffraction. The isolated 15- nuclearity cluster [Zn6Co9（PMIDA）6（Phen）6（NO3）4（H2O）6]^2＋ was constructed by four kinds of ligands, and its charges are balanced by NO3^–. Each isolated cluster is further extended into a 3D supramolecular network through π？？？π interaction and C–H…O hydrogen bonds. Moreover, the solid-state fluorescent property of this complex has also been investigated at room temperature.

Synthesis,Crystal Structure and Fluorescent Properties of a Cadmium(Ⅱ) Complex with 3-(Pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole

Compound [Cd_（1.5）（ppt）Br_2（H_2O）]_（2n）（1）,where Hppt = 3-（pyridin-4-yl）-5-（pyrazin-2-yl）-1H-1,2,4-triazole,has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectra,powder XRD,and X-ray diffraction.Compound 1 crystallizes in the triclinic system,space group P1 with a = 7.4402（6）,b = 8.0570（7）,c = 12.8674（11） A,α = 89.7300（10）,β = 89.8570（10）,γ = 68.3910（10）°,V = 717.13（10） A^3,Z = 1,Dc = 2.638 g/cm^3,μ = 7.824 mm^-1,F（000） = 534,the final R = 0.0324 and w R = 0.1084 for 2324 observed reflections with I 〉 2σ（I）.X-ray diffraction analyses revealed that complex 1 is a 2D layered coordination polymer constructed from the linkage of [Cd_3（μ-Br）_4] trinuclear units with ppt-spacers,and a 3D supramolecular architecture is further assembled in 1 via hydrogen-bonding contacts.Fluorescence measurements show that 1 has medium fluorescent emission at 450 nm.

Synthesis, Crystal Structure and Fluorescent Property of a Zn(Ⅱ) Complex with 1,3-Bis(imidazol-1-yl)benzene and 1,3-Benzenedicarboxylate

A novel zinc complex [Zn（BIB）（bdc）]n（1, BIB = 1,3-bis（imidazol-1-yl）benzene, bdc = 1,3-benzenedicarboxylate） has been synthesized in solvothermal conditions. The title complex was characterized by elemental analysis, IR spectra, thermal analysis, single-crystal and powder X-ray diffraction. The result proved that the alliance of BIB and aromatic carboxylic acids is good for the diversity of getatable structure. Complex 1 crystallizes in the monoclinic system of P2/c space group with a = 11.5591（10）, b = 9.6239（8）, c = 33.727（3）A, β = 103.816（3）°, V = 3643.4（5） A^3, Z = 8, μ = 1.385 mm^-1, F（000） = 1792, Dc = 1.603 g/cm^3 and Mr = 439.72 g/mol. Additionally, luminescent properties of complex 1 are also investigated and it shows good fluorescence.

Synthesis,Crystal Structure and Luminescence Study of a New Two-dimensional Mn(Ⅱ)Coordination Polymer

The coordination polymer [Mn2（cipt）2（aic）2]n （cipt = 2-（3-chlorophenyl）-1H- imidazo[4,5-f][1,10]phenanthroline, aic = 5-amino-isophthalic acid） has been obtained from hydrothermal reaction and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P , with a = 11.523（3）, b = 12.162（3）, c = 18.706（5） A^°, β = 81.789（5）°, V = 2455.2（1） A^°3, C54H32Cl2Mn2N10O8, Mr = 1129.68, Z = 2, Dc = 1.528 g/cm3, μ = 0.692 mm^-1, F（000） = 1148, R = 0.064 and wR = 0.145 for 9571 observed reflections （I 〉 2σ（I））. In this polymer, the Mn（II） atoms adopt different coordination modes. The Mn（1） atom is five-coordinated, forming a distorted tetragonal pyramidal geometry. Mn（2） atom is six-coordinated to get a distorted octahedral geometry, which is different from the Mn（1） atom. Each Mn（II） atom is linked by aic ligands with neighboring Mn（II） atoms, forming an infinite one-dimensional （1D） double-chain structure. The existence of N–H…O hydrogen bonding interactions leads the 1D chains to generate a 2D structure. Luminescent properties for the ligand cipt and compound 1 have also been discussed in detail.

Synthetic Assembly of Inorganic-organic Polyoxometalate Hybrid Structures Employing Noncovalent Interactions between 5,6-Substituted 1,10-Phenanthroline Derivative Ligands

A new strategy for the synthesis of polyoxometalate-based （POM-based） metal- organic materials was developed. The approach takes the advantage of the ability of phenanthroline derivative base to build strong noncovalent interactions. Three POM-based metal-organic com- pounds, [Mn（MOPIP）2（OH）2][Mn（MOPIP）2（OH）（SiW12O40）]·6H2O （1）, [Cu2（MOPIP）2（OH）2（H2O）]2-（SiW12O40）·5H2O （2） and [Co（Mo2O7）（MOPIP）]n （3） （MOPIP = 2-（4-methoxyphenyl）-1H-imida- zo[4,5-f][1,10]phenanthroline）, were synthesized under hydrothermal conditions. Single-crystal X-ray analysis reveals that compound 1 displays a mononuclear cluster. These clusters are intercon- nected by a framework of π…π stacking interactions to from a chain and layer structure. Compound 2 shows a multinuclear cluster with Keggin-type polyoxoanions [SiW12O40]^4- as building blocks. Strong hydrogen bonding interactions extend these multinuclear clusters into a two-dimensional layer. Compound 3 is a coordination polymer, in which [Mo2O7]^2- polyoxoanions connect the Co（II） ions running along the direction of one of the crystallographic axes to from a linear chain. Adjacent chains are further assembled into a two-dimensional network by strong hydrogen bonding interactions. The main structural traits in all of the compounds are that polyoxometalate acts as inorganic building blocks and connect metal ions to form cluster structure and coordination polymer. In addition, the photocatalytic activities and mechanism of compounds 1～3 on the degradation of Rhodamine B （RhB） under UV irradiation have been investigated in detail.

Synthesis,Fluorescence and Magnetic Properties of a New Europium(Ⅲ) Complex Eu(L)3(Phen)2

A new europium（III） complex Eu（L）3（Phen）2（1） with 2-benzoylbenzoic acid（HL） and 1,10-phenanthroline（Phen） as ligands has been synthesized. Crystal data for the complex are as follows： monoclinic, space group P21/c, a = 2.2577（4）, b = 1.23484（19）, c = 1.8789（3） nm, β = 94.918（3）o, V = 5.2189（14） nm^3, Dc = 1.512 g/cm^3, Z = 4, μ（Mo Kα） = 1.269 mm^-1, F（000） = 2408, the final R = 0.0433 and w R = 0.1038. The Eu（III） ion is coordinated by nine atoms to give a single-capped square antiprism coordination geometry. 1 shows two intense fluorescence emission bands arising from the transitions of Eu^3＋： ^5D0→^7F1（597 nm） and ^5D0→^7F2（615 nm） with an excitation wavelength of 396 nm. In addition, 1 displays antiferromagnetic property at low temperature.

Ionothermal Synthesis and Fluorescence Property of a Complex Constructed by Seven Nuclear(CH_3COO)_2Co_7(OH)_2] Clusters and 4,4＇-Oxybisbenzoic Acid Ligand

A new 3D cobalt metal-organic framework [C_7H_（13）N_2]_2[（CH_3COO）_2Co_7（oba）_5-（Hoba）_2（OH）_2]·H_2O has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, and TG. This complex crystallizes in monoclinic system, space group P21/c with a = 19.4499（4）, b = 10.8839（2）, c = 27.7796（5） ？, β = 104.467（2）o, V = 5694.22（19） ？~3, Z = 2, C_（116）H_（92）Co_7N_4O_（42）, M_r = 2626.45, D_c = 1.532 g/cm^3 , F（000） = 2682, μ = 1.085 mm-1, R = 0.0387 and wR = 0.1177. Its structure is characterized as a 3D open framework constructed by seven nuclear clusters [（CH_3COO）_Co_7（OH）_2] and the 4,4？-oxybisbenzoic acid ligand. The used ILs cations are located in the middle of the pore and compensate for the negative charges of framework. Furthermore, its fluorescence property has also been studied.

Two New Silver Coordination Polymers Constructed from 3,3-Azodibenzoic Acid and Different Pyridine Derivatives:Syntheses,Structures and Fluorescent Properties

Two coordination polymers（CPs）,{[Ag（ADA）（0.5）（DPE）]·H2O}n（1） and {[Ag（ADA）（0.5）（Bipy）（0.5）]·H2O}n（2）,（H2ADA = 3,3-azodibenzoic acid,DPE = 1,2-di（4-pyridyl）-ethylene,Bipy = 4,4？-bipyridine）,have been synthesized via solvothermal reactions of Ag＋ with ADA^2- and/or DPE,Bipy.CPs 1 and 2 were characterized by elemental analyses,IR spectra,thermal behaviors,and X-ray single-crystal diffraction.CPs 1 and 2 feature ＂Ag···Ag＂ subunits.CP 1 shows a 3D construction,in which the ＂Ag···Ag＂ subunits extend through ADA^2- and DPE ligands using μ6-kO,O;kO;kO;kO,O;kO;kO and μ2-kO;kO coordination modes,respectively.It crystallizes in triclinic system,space group P1,with a = 0.3808（18）,b = 1.2476（6）,c = 1.309（6） nm,α = 76.757（5）,β = 84.649（5）,γ = 86.809（5）o,V = 0.6024（5） nm^3,Z = 2,Mr = 351.11,C（13）H（11）AgN2O3,Dc = 1.936 g/cm3,F（000） = 348,S = 1.064,R = 0.0323 and w R = 0.0689.CP 2 exhibits a 3 D supramolecular structure,in which the ＂Ag···Ag＂ subunits are connected by ADA^2- and DPE ligands with μ6-kO;kO;kO,O;kO;kO and μ2-kO;kO coordination modes,respectively.Ultimately,through hydrogen bond and π···π interaction,the ＂Ag···Ag＂ subunits stabilize the 3D supramolecular structure of 2.It crystallizes in monoclinic,space group C2/c,with a = 25.301（15）,b = 13.197（8）,c = 6.970（4） nm,β = 102.597（7）o,V = 2.271（2） nm^3,Z = 8,C（12）H（10）AgN2O（2.50）,Mr = 330.09,Dc = 1.931 g/cm^3,F（000） = 1304,S = 1.082,R = 0.1107 and wR = 0.2984.The fluorescence properties of CPs 1 and 2 have been also investigated.

Coordination Assemblies of Cd^(Ⅱ)with 5-(Ethylthio)-1H-tetrazole and Halide Ions:Synthesis,Structure,and Luminescent Properties

Three cadmium（II）-halide complexes with 5-（ethylthio）-1H-tetrazole（Hett） as ligand, namely [Cd_7Cl_2（ett）_（12）（H_2O）_2]_n（1）, [Cd_2（OH）Br（ett）_2]_n（2） and [Cd_2（OH）I（ett）_2]_n（3）, have been hydrothermally synthesized and characterized. Complex 1 was synthesized at pH = 7 and exhibits a 3D supramolecular framework, where the adjacent Cd ions form a tetrahedron unit by ett ligands bridge and the tetrahedron units share vertices to connect each other by ett bridges to form a 2D layer architecture, which is further interlinked by μ_2-Cl to form 3D structures. Complexes 2 and 3 are isostructural, generated at pH = 8.0~9.0, displaying similar 2D networks via ett ligands and different halide ions（Br-in 2, I-in 3, respectively）. In addition, thermal stabilities and luminescent properties of new complexes 1~3 have been studied.

Structure, Growth and Characterization of Ammonium 5-Sulfosalicylic Acid Monohydrate Crystal

Ammonium 5-sulfosalicylic acid monohydrate （NH4·C7H5O6S·H2O, ASSA） was synthesized and optical grade crystal with dimensions of 45ram × 20mm × 18mm was obtained from aqueous solution by the cooling solution method. The crystal structure was confirmed by X-ray single-crystal diffraction method and the empirical composition is C7HIINO7S with formula weight 253.23. The crystal belongs to monoclinic space group P21/c with a = 1 1.884（9）, b = 7.306（5）, c = 12.152（9） A, β = 104.851（13）°, V= 1019.8（13） A3, Z = 4, Dc = 1.649 g/cm3,μ = 0.340 mm-1, F（000） =528, the final R= 0.0307 and wR= 0.0866 for 7494 observed reflections （I〉 2σ（I））, Elemental analysis, 1R and 1H-NMR spectrum were used to characterize the compound. Thermal analysis showed that one coordination water molecule was contained and dehydration temperature of ASSA crystal was 106℃. Optical transmission and fluorescence spectrum revealed that the ASSA crystal exhibited a strong absorption in ultraviolet region with the sharp absorption edge located at 340 nm and a significant blue fluorescent emission band at 442 nm.

Synthesis, Crystal Structure and Two-photon Absorption Properties of 4′-(N,N-di(4-hydroxymethyl phenyl) amino)phenyl-2,2′:6′,2''-terpyridine

A novel donor-acceptor （D-A） triphenylamino terpyridine derivative L was facilely synthesized and fully characterized, and its single crystals were obtained and determined by X-ray diffraction analysis. It crystallizes in triclinic, space group P/ with a = 11.760（5）, b =12.516（5）, c = 12.850（5） A, α = 67.141（5）, β= 65.284（5）, γ = 75.876（5）°, Mr = 621.54, F= 1575.6（11） A3, Z= 2, Dc = 1.310 g/cm3,μ = 0.245 mm-1, F（000） = 648, the final R = 0.0671 and wR = 0.1869 for 11328 observed reflections with 1〉 2σ（I）. Linear and nonlinear optical properties of terpyridine derivative L were systematically investigated. The maximum two-photon cross-section of L was 382.5 GM （Goeppert-Mayer）, measured by two-photon excited fluorescence （TPEF） method. This result demonstrates that the increase of intramolecular charge transfer （ICT） leads to enhanced two-photon absorption （2PA）, which could be achieved by introducing additional electron-donor groups to the molecular framework.

Synthesis, Crystal Structure, Fluorescent Property and DFT Study of a Novel 1D Polymer [Zn(HMICD)(bpy)]_n·2nH_2O

A new one-dimensional（1D） polymer, [Zn（HMIDC）（bpy）]n·2n H2O（1, H3MIDC = 2-methyl-imidazole-4,5-dicarboxylic acid, bpy = 2,2-bipyridine）, has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy, UV-vis spectrum and fluorescence measurements. Complex 1 crystallizes in orthorhombic system, space group Pbca with a = 14.404（3）, b = 8.6900（17）, c = 26.570（5） , V = 3325.8（11） -3, Dc = 1.700 g/cm-3, Mr = 425.70, Z = 8, F（000） = 1744, μ = 1.522 mm-（-1）, the final R = 0.0421 and w R = 0.1018. The Zn（Ⅱ） ion is six-coordinated by O and N atoms from one HMIDC ligand, two O atoms from another HMIDC ligand and two N atoms from the bpy ligand. The HMIDC anion, which acts as a tetradentate ligand, chelates two Zn ions to form a one-dimensional（1D） zigzag chain structure. We analyzed the electronic structure and orbital energies of complex 1 by DFT methods, and the results are consistent with the UV-vis spectrum. And we also discussed the luminescent mechanism of complex 1 in detail.

Crystal Structure and ESIPT Phenomena of Anionic 2H-Phenanthro[9,10-c]pyrazol-11-ols

Using 4＇-methoxy-5-hydroxyisoflavone and 4＇,5-dihydroxy-7-methoxyisoflavone as leding compounds,6-methoxy-2 H-phenanthro[9,10-c]pyrazol-11-ol（1 a） and 9-methoxy-2 Hphenanthro [9,10-c]pyrazol-6,11-diol（1 b） were synthesized by two dehydration processes in the EtOH solution.They were characterized by IR,^1H NMR and ^13C NMR.The black prism crystal of 1 a was grown by the slow solvent evaporation technique from 40：1（v/v） CHCl3/MeOH,and it was determined by single-crystal X-ray diffraction.In the crystal structure,1 a was stabilized by intramolecular（O–H···N） and intermolecular（N–H···O,O–H···O,π···π,C–H···π） interactions.In addition,the fluorescence properties of 1 a and 1 b in the base and neutral media revealed that they possessed excited state intramolecular proton transfer phenomena（ESIPT）.

Two Coordination Polymers Constructed by Cd(Ⅱ) and Zn(Ⅱ) with in situ Generated 5-(3-Pyridyl)tetrazolate Ligand：Syntheses,Crystal Structures and Luminescence Properties

Hydrothermal reactions of 3-cyanopyridine and Na N3 with Zn Cl_2 or Cd Cl_2·5/2H_2 O in the presence of 1,4-benzenedicarboxylic acid（H2bdc） yielded two new coordination polymers,{[Zn（3-ptz）（bdc）_（0.5）（H_2O）_2]n·2H_2O}_n（1） and [Cd_2（3-ptz）_2Cl_2]_n（2）,based on in situ synthesized 5-（3-pyridyl）tetrazolate（3-ptz-） organic ligand.They have been structurally characterized by elemental analysis（EA）,infrared spectroscopy（IR） and single-crystal/powder X-ray diffraction（PXRD）.In 1,two Zn（Ⅱ） ions are linked together through two μ_2-（3-ptz-） ligands to form a dimeric unit of [Zn（μ_2-3-ptz）（H_2O）_2]2^2＋,which is further connected with other equivalent units by μ_2-bdc^2-spacers,resulting in an infinite 1D polymeric chain of [Zn_2（3-ptz）_2（H_2O）_2（bdc）]_n,and then strong hydrogen bonding interactions extend these 1D chains into a 3D supramolecular structure.In 2,the Cd（Ⅱ） ions are connected through μ_4-（3-ptz-） ligands and Cl-anions,leading to infinite 2D layers of [Cd_2（3-ptz）Cl_2]_n^n＋,which are further linked by another μ_4-（3-ptz-） pillared ligand to form a 3D layered-pillared framework architecture of [Cd）2（3-ptz））2Cl）2]）n.Furthermore,thermal stability of these compounds was measured by thermogravimetric analysis（TGA） and their photoluminescent properties were also investigated in the solid state at room temperature.