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Mechanism of Cathode Process of B(Ⅲ) in LiF-NaF-KBF_4 Meltby Electrochemical Titration Technique
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作者 Qingrong Shi Xindong Wang +1 位作者 Lianyu Yuan Shuzhen Duan(Applied Science School, University of Science and Technology Beijing, Beijing 100083, China) 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 1998年第4期203-207,共5页
The mechanism of cathode process of B(Ⅲ) at molybdenum and platinum electrodes in LiF-NaF-KBF4melt was studied and the transferred electron number of the reaction was calculated by means of cyclic voltammetry.The eff... The mechanism of cathode process of B(Ⅲ) at molybdenum and platinum electrodes in LiF-NaF-KBF4melt was studied and the transferred electron number of the reaction was calculated by means of cyclic voltammetry.The effect of adsorption of electroactive component on the electrochemical response (e. g., the voltammetric i─Ecurves) was analyzed and discussed. The 'electrochemical spectra' for linear sweep voltammetry was used to elucidate the electrode reaction accompanied by a following transform process. The results show that the reduction ofB(Ⅲ) to B(0) proceeds in reversible one step three-electron reaction and the cathode process of B(Ⅲ) is affected byproduct adsorbed strongly at the electrode surface. It is assumed that the reduction and deposition of B(Ⅲ) at molybdenum and platinum electrodes proceed in two kinds of mechanism: (1) B(Ⅲ)+ 3e = Bads→ B (surface diffusiondeposition mechanism) and (2) B(Ⅲ) + 3e = B (direct deposition mechanism). 展开更多
关键词 boron ions cathode process cyclic voltammetry fluoride melt
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Identification of Complex Ions of Nb(V)in FLINAK-O^(2-)System by Infrared Spectra
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作者 王新东 段淑贞 +1 位作者 ChristensenE. BjerrumN.J. 《Rare Metals》 SCIE EI CAS CSCD 1993年第3期209-213,共5页
The FT-IR spectra for K_2NbF_7-FLINAK-O^(2-) solution were measured and compared with the spectra of crystalline K_2NbF_7 and K_2NbOF_6.The results show that the niobium fluoro-complex and/or oxyfluoro-complex ions ar... The FT-IR spectra for K_2NbF_7-FLINAK-O^(2-) solution were measured and compared with the spectra of crystalline K_2NbF_7 and K_2NbOF_6.The results show that the niobium fluoro-complex and/or oxyfluoro-complex ions are presented in these solutions.NbF_7^(2-) complex ion is the predominant species in Nb(V)-FLINAK solution(not considering oxide impurity).The influence of O^(2-) on the oxyfluoro-complex ions shows that NbOF_6^(3-) as a stable monooxyfluoro-complex anion presented in FLINAK-O^(2-) systems and the number of NbOF_6^(3-) species are increased with increasing of O^(2-) when molar ratio of O^(2-)/Nb(V) is less than 1. 展开更多
关键词 Infrared spectra NIOBIUM fluoride melt Complex ion
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