Synthesis of novel chiral fluorinating agents,(+)-and(-)-N-fluoro-3-methyl-3-(4-methylphenyl)-2H-benzo[e][1,2]thiazine-1,1,4-triones

Treatment of N-t-butylbenzenesulfonamide with an excess of BuLi, followed by the reaction with methyl 2-（4-methylphenyl）propanoate, gave the corresponding 2-carboxybenzenesulfonamide, which underwent a sequence of consecutive N-deprotective cyclization process mediated by TMSCI-NaI-MeCN reagent to afford the N-sulfonylimine. Following the bromination and ring expansion, 3-methyl-3-（4-methylphenyl）-2H-benzo[e][1,2]thiazine-l,l,4-trione was obtained. Optical resolution of the racemic benzosultam using （-）-menthoxyacetyl chloride, furnished the optically p.ure （＋）- and （-）-3-methyl-3-（4-methylphenyl）-2H- benzo[e][1,2]thiazine-1,1,4-triones, which were fluorinated with FC103 to produce the corresponding chiral N-F agents.

Experimental research on combustion fluorine retention using calcium-based sorbets during coal combustion(Ⅱ)

During the fixed bed tube furnace combustion experimental study,stimulated the calcium-based sorbent grain size and microstructured influencing factors to explain the fluorine retention effect influence law,and expounded the combustion fluorine retention agent developing principle,and probed into the high-temperature fluorine retention agent technical approach.The results show that the calcium-based sorbent particle grain size and pore structure also have the bigger influence on the combustion fluorine retention ef- fect,and reducing the calcium-based sorbent particle grain size and improving the calcium sorbent structure characteristics at very high temperature to enhance the fluorine retention effect is the important approach to the fluorine retention agent development.

Experimental research on combustion fluorine retention using calcium-based sorbets during coal combustion(Ⅰ)

In order to provide experimental guide to commercial use of fluorine pollution control during coal combustion, with fluorine pollution control during coal combustion in mind, this paper proposed the theory of combustion fluorine retention technology. Feasibility of fluorine retention reaction with calcium-based fluorine retention agent was analyzed through thermo-dynamic calculation during coal combustion. By simulating the restraining and retention effects and influential factors of calcium-based sorbets on vaporized fluoride during experimental combustion using fixed bed tube furnace, the paper systematically explored the influential law of such factors as combustion temperature, retention time, and added quantities of calcium-based sorbets on effects of fluorine retention. The research result shows that adding calcium-based fluorine retention agent in coal combustion has double effects of fluorine retention and sulfur retention, it lays an experimental foundation for commercial test of combustion fluorine retention.