1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid v...1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...展开更多
A new porous Cd（Ⅱ） coordination compound, namely, [Cd（bpdc）（L）2]·3H2O（1, L = 11-fluoro-dipyrido[3,2-a：2,3-c]phenazine and bpdc = 1,1-biphenyl-2,2-dicarboxylate） was synthesized under hydrothermal condit...A new porous Cd（Ⅱ） coordination compound, namely, [Cd（bpdc）（L）2]·3H2O（1, L = 11-fluoro-dipyrido[3,2-a：2,3-c]phenazine and bpdc = 1,1-biphenyl-2,2-dicarboxylate） was synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffraction. It crystallizes in tetragonal, space group P4122 with a = 9.8486（4）, b = 9.8486（4）, c = 45.925（4）A, V = 4454.5（5） 3, Z = 4, C50H29 Cd F2N8O7, Mr = 1004.21, Dc = 1.497 g/cm^3, F（000） = 2028, μ（Mo Ka） = 0.562 mm^-1, R = 0.0566 and w R = 0.1585. Each Cd（Ⅱ） atom is coordinated by one bpdc anion and two L ligands to give a discrete molecule. Neighboring discrete molecules are stacked by π-π interactions among L ligands, resulting in an interesting 1D supramolecular chain. Moreover, the 1D supramolecular chains are packed with each other to give a porous structure, in which an infinite channel is filled with water molecules. In addition, the thermal behavior and luminescent property of 1 have also been studied.展开更多
文摘1 Results Electrochemical energy storage devices such as lithium-ion batteries[1-2] and double-layer capacitors[3-4] have attracted a great deal of attention because of their potential application to electric hybrid vehicles. They utilize nonaqueous electrolyte solutions comprising from organic solvents and lithium or quaternary ammonium salts with fluorine-containing anions. This is because the relatively large anions with electron-withdrawing atoms enable ionic dissociation in dipolar aprotic solvents...
基金Supported by the Science and Technology Research Projects of the Education Committee of Jilin Province(No.2013206)
文摘A new porous Cd（Ⅱ） coordination compound, namely, [Cd（bpdc）（L）2]·3H2O（1, L = 11-fluoro-dipyrido[3,2-a：2,3-c]phenazine and bpdc = 1,1-biphenyl-2,2-dicarboxylate） was synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffraction. It crystallizes in tetragonal, space group P4122 with a = 9.8486（4）, b = 9.8486（4）, c = 45.925（4）A, V = 4454.5（5） 3, Z = 4, C50H29 Cd F2N8O7, Mr = 1004.21, Dc = 1.497 g/cm^3, F（000） = 2028, μ（Mo Ka） = 0.562 mm^-1, R = 0.0566 and w R = 0.1585. Each Cd（Ⅱ） atom is coordinated by one bpdc anion and two L ligands to give a discrete molecule. Neighboring discrete molecules are stacked by π-π interactions among L ligands, resulting in an interesting 1D supramolecular chain. Moreover, the 1D supramolecular chains are packed with each other to give a porous structure, in which an infinite channel is filled with water molecules. In addition, the thermal behavior and luminescent property of 1 have also been studied.
