The recovery of heavy oil by water flooding is 10% lower than that of conventional crude oil, so enhanced oil recovery （EOR） is of great significance for heavy oil. In this paper, foam flooding with a gas-liquid rat...The recovery of heavy oil by water flooding is 10% lower than that of conventional crude oil, so enhanced oil recovery （EOR） is of great significance for heavy oil. In this paper, foam flooding with a gas-liquid ratio （GLR） of 0.2：1 for the Zhuangxi heavy oil （325 mPa.s at 55 ℃） was performed on cores, sand packs and plate model. In sand pack tests, polymer enhanced foam flooding increased oil recovery by 39.8%, which was 11.4% higher than that for alkali/surfactant/polymer （ASP） flooding under the same conditions. Polymer enhanced foam flooding in plate models shows that the low GLR foam flooding increased oil recovery by about 30%, even when the extended water flooding was finished at 90% water cut. Moreover, it was discovered by microscopy that foam was more stable in heavy oil than in light oil. These results confirm that low GLR foam flooding is a promising technology for displacing conventional heavy oil.展开更多
The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated fro...The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media.展开更多
Surfactants for enhanced oil recovery are important to study due to their special characteristics like foam generation,lowering interfacial tension between oleic and aqueous phases,and wettability alteration of reserv...Surfactants for enhanced oil recovery are important to study due to their special characteristics like foam generation,lowering interfacial tension between oleic and aqueous phases,and wettability alteration of reservoir rock surfaces.Foam is a good mobility control agent in enhanced oil recovery for improving the mobility ratio.In the present work,the foaming behavior of three nonionic ethoxylated surfactants,namely Tergitol 15-S-7,Tergitol 15-S-9,and Tergitol 15-S-12,was studied experimentally.Among the surfactants,Tergitol 15-S-12 shows the highest foamability.The effect of Na Cl concentration and synthetic seawater on foaming behavior of the surfactants was investigated by the test-tube shaking method.The critical micelle concentrations of aqueous solutions of the different nonionic surfactants were measured at 300 K.It was found that the critical micelle concentrations of all surfactants also increased with increasing ethylene oxide number.Dynamic light scattering experiments were performed to investigate the micelle sizes of the surfactants at their respective critical micelle concentrations.Core flooding experiments were carried out in sand packs using the surfactant solutions.It was found tha t22% additional oil was recovered in the case of all the surfactants over secondary water flooding.Tergitol 15-S-12exhibited the maximum additional oil recovery which is more than 26%after water injection.展开更多
The origins and logging responses of flushed zones in some blocks of Orinoco heavy oil belt, Venezuela are still unclear. To solve this issue, we examined the conventional logging, nuclear magnetic resonance logging, ...The origins and logging responses of flushed zones in some blocks of Orinoco heavy oil belt, Venezuela are still unclear. To solve this issue, we examined the conventional logging, nuclear magnetic resonance logging, fluid viscosity, core analysis and oil field production data comprehensively to find out the logging responses and origins of the flushed zones. The results show that the main reason for the formation of flushed zone is surface water invasion, which leads to crude oil densification. The crude oil densification produces asphalt membrane(asphalt crust) which wraps up free water, causing special logging responses of the flushed zones. According to the different logging responses, we classified the flushed zones into two types and analyzed the formation processes of the two types of flushed zones. According to the characteristics of logging curves after water flush, we confirmed that the water flush began earlier than the reservoir accumulation.展开更多
基金support from the Innovation Team Program and New Century Excellent Talents Awards Program,the Ministry of Education of ChinaFok Ying Tung Education Foundation
文摘The recovery of heavy oil by water flooding is 10% lower than that of conventional crude oil, so enhanced oil recovery （EOR） is of great significance for heavy oil. In this paper, foam flooding with a gas-liquid ratio （GLR） of 0.2：1 for the Zhuangxi heavy oil （325 mPa.s at 55 ℃） was performed on cores, sand packs and plate model. In sand pack tests, polymer enhanced foam flooding increased oil recovery by 39.8%, which was 11.4% higher than that for alkali/surfactant/polymer （ASP） flooding under the same conditions. Polymer enhanced foam flooding in plate models shows that the low GLR foam flooding increased oil recovery by about 30%, even when the extended water flooding was finished at 90% water cut. Moreover, it was discovered by microscopy that foam was more stable in heavy oil than in light oil. These results confirm that low GLR foam flooding is a promising technology for displacing conventional heavy oil.
基金Ministry of Higher Education (Vot No. Q.J130000.2542.08H61)Universiti Teknologi (UTM) Malaysia for supporting this research
文摘The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media.
基金the financial support provided by Council for Scientific and Industrial Research [22(0649)/13/EMR-II], New Delhi, to the Department of Petroleum Engineering, Indian Institute of Technology (Indian School of Mines), Dhanbad, India
文摘Surfactants for enhanced oil recovery are important to study due to their special characteristics like foam generation,lowering interfacial tension between oleic and aqueous phases,and wettability alteration of reservoir rock surfaces.Foam is a good mobility control agent in enhanced oil recovery for improving the mobility ratio.In the present work,the foaming behavior of three nonionic ethoxylated surfactants,namely Tergitol 15-S-7,Tergitol 15-S-9,and Tergitol 15-S-12,was studied experimentally.Among the surfactants,Tergitol 15-S-12 shows the highest foamability.The effect of Na Cl concentration and synthetic seawater on foaming behavior of the surfactants was investigated by the test-tube shaking method.The critical micelle concentrations of aqueous solutions of the different nonionic surfactants were measured at 300 K.It was found that the critical micelle concentrations of all surfactants also increased with increasing ethylene oxide number.Dynamic light scattering experiments were performed to investigate the micelle sizes of the surfactants at their respective critical micelle concentrations.Core flooding experiments were carried out in sand packs using the surfactant solutions.It was found tha t22% additional oil was recovered in the case of all the surfactants over secondary water flooding.Tergitol 15-S-12exhibited the maximum additional oil recovery which is more than 26%after water injection.
基金Supported by the China Major National Oil&Gas Project(2016ZX05031-001)
文摘The origins and logging responses of flushed zones in some blocks of Orinoco heavy oil belt, Venezuela are still unclear. To solve this issue, we examined the conventional logging, nuclear magnetic resonance logging, fluid viscosity, core analysis and oil field production data comprehensively to find out the logging responses and origins of the flushed zones. The results show that the main reason for the formation of flushed zone is surface water invasion, which leads to crude oil densification. The crude oil densification produces asphalt membrane(asphalt crust) which wraps up free water, causing special logging responses of the flushed zones. According to the different logging responses, we classified the flushed zones into two types and analyzed the formation processes of the two types of flushed zones. According to the characteristics of logging curves after water flush, we confirmed that the water flush began earlier than the reservoir accumulation.
