Engineering of Self-Supported Electrocatalysts on a Three-Dimensional Nickel Foam Platform for Efficient Water Electrolysis

Economical water electrolysis requires highly active non-noble electrocatalysts to overcome the sluggish kinetics of the two half-cell reactions,oxygen evolution reaction,and hydrogen evolution reaction.Although intensive efforts have been committed to achieve a hydrogen economy,the expensive noble metal-based catalysts remain under consideration.Therefore,the engineering of self-supported electrocatalysts prepared using a direct growth strategy on three-dimensional(3D)nickel foam(NF)as a conductive substrate has garnered significant interest.This is due to the large active surface area and 3D porous network offered by these electrocatalysts,which can enhance the synergistic eff ect between the catalyst and the substrate,as well as improve electrocatalytic performance.Hydrothermal-assisted growth,microwave heating,electrodeposition,and other physical methods(i.e.,chemical vapor deposition and plasma treatment)have been applied to NF to fabricate competitive electrocatalysts with low overpotential and high stability.In this review,recent advancements in the development of self-supported electrocatalysts on 3D NF are described.Finally,we provide future perspectives of self-supported electrode platforms in electrochemical water splitting.

Electrokinetic-mechanism of water and furfural oxidation on pulsed laser-interlaced Cu_(2)O and CoO on nickel foam

The electrocatalytic oxidation of biomass-derived furfural(FF)feedstocks into 2-furoic acid(FA)holds immense industrial potential in optics,cosmetics,polymers,and food.Herein,we fabricated Co O/Ni O/nickel foam(NF)and Cu_(2)O/Ni O/NF electrodes via in situ pulsed laser irradiation in liquids(PLIL)for the bifunctional electrocatalysis of oxygen evolution reaction(OER)and furfural oxidation reaction(FOR),respectively.Simultaneous oxidation of NF surface to NiO and deposition of CoO and/or Cu_(2)O on NF during PLIL offer distinct advantages for enhancing both the OER and FOR.CoO/NiO/NF electrocatalyst provides a consistently low overpotential of~359 m V(OER)at 10 m A/cm^(2),achieving the maximum FA yield(~16.37 m M)with 61.5%selectivity,79.5%carbon balance,and a remarkable Faradaic efficiency of~90.1%during 2 h of FOR at 1.43 V(vs.reversible hydrogen electrode).Mechanistic pathway via in situ electrochemical-Raman spectroscopy on CoO/NiO/NF reveals the involvement of phase transition intermediates(NiOOH and CoOOH)as surface-active centers during electrochemical oxidation.The carbonyl carbon in FF is attacked by hydroxyl groups to form unstable hydrates that subsequently undergo further oxidation to yield FA products.This method holds promise for large-scale applications,enabling simultaneous production of renewable building materials and fuel.

Buckling Properties of Water-Drop-Shaped Pressure Hulls with Various Shape Indices Under Hydrostatic External Pressure

The water-drop-shaped pressure hull has a good streamline,which has good application prospect in the underwater observatory.Therefore,this study conducted analytical,experimental and numerical investigation of the buckling properties of water-drop-shaped pressure hulls under hydrostatic pressure.A water-drop experiment was conducted to design water-drop-shaped pressure hulls with various shape indices.The critical loads for the water-drop-shaped pressure hulls were resolved by using Mushtari’s formula.Several numerical simulations including linear buckling analysis and nonlinear buckling analysis including eigenmode imperfections were performed.The results indicated that the critical loads resolved by Mushtari's formula were in good agreement with the linear buckling loads from the numerical simulations.This formula can be extended to estimate the buckling capacity of water-drop-shaped pressure hulls.In addition,three groups of pressure hulls were fabricated by using stereolithography,a rapid prototyping technique.Subsequently,three groups of the pressure hulls were subjected to ultrasonic measurements,optical scanning,hydrostatic testing and numerical analysis.The experimental results were consistent with the numerical results.The results indicate that the sharp end of the water-drop-shaped pressure hulls exhibited instability compared with the blunt end.This paper provides a new solution to the limitations of experimental studies on the water-drop-shaped pressure hulls as well as a new configuration and evaluation method for underwater observatories.

Self-supported Ni2P nanosheets on low-cost three-dimensional Fe foam as a novel electrocatalyst for efficient water oxidation

Electrochemical water splitting into hydrogen and oxygen is a promising strategy for future renewable energy conversion devices.The oxygen evolution reaction(OER)is considered as the bottleneck reaction in an overall water splitting system because it involves 4e- and 4H+ transfer processes.Currently,it is highly desirable to explore low-cost alternative catalysts for OER at ambient conditions.Herein,we report for the first time that nickel phosphide(Ni2P)nanosheets can be facilely grown on Fe foam(FF)as an efficient electrocatalyst for OER with excellent durability and catalytic activity under alkaline conditions.To reach a current density of 10 m A/cm2,the Ni2P-FF catalyst required a low overpotential of only 198 mV for OER.The catalyst’s high OER activity and durability were well maintained at a high current density.The required overpotentials were only 267 and 313 mV to achieve the current densities of 100 and 300 m A/cm2,respectively.The combination of low-cost Fe foam with Ni2P provides a promising low-cost catalyst for large-scale application of electrocatalytic water splitting.

Evolution of a Water Pendant Droplet: Effect of Temperature and Relative Humidity

As part of a better understanding of drying liquids within porous materials, measurements from 293 to 343 K of deionized water surface tension in air as a function of relative humidity are exposed. Experimental work was carried out using the pendant drop method coupled with image analysis within an adapted instrumented climatic chamber. Results show that surface tension linearly decreases when relative humidity increases. Although the effect of humidity is less compared to that of the temperature and even less compared to a surfactant impact, it must not be neglected and values have to be mentioned when dealing with water evaporation. Modifying surface tension also affects the pendant drop shape. The drying kinetics of the pendant drop volume and its outer shell are connected to this change of shape. Steam in the air can be assimilated to a wetting agent, hence a surfactant, and can be used in an environmental-friendly way to ease the drying stage. Indeed, the challenge is to limit the risk of cracking and damaging pieces during this crucial step in material processing.

Copper foam-derived electrodes as efficient electrocatalysts for conventional and hybrid water electrolysis

Electrochemical water splitting has been demonstrated as a promising technology for the renewable generation of green hydrogen from water.Despite the extensive progress in materials science,one particular challenge for further development towards industrial application lies in the rational design and exploitation of efficient and cost-effective materials,especially oxygen evolution reaction(OER)electrocatalysts at the anode.In addition,attempts to replace the OER with other more oxidizable anode reactions are being evaluated as a groundbreaking strategy for generating hydrogen at lower potentials and reducing overall energy costs while producing valuable chemicals simultaneously.Compared with Fe/Co/Ni-based compounds,Cu-based materials have not received extensive research attention for electrode designs despite their high conductivity and abundant earth reserves.In this review,combining with the advantages of a three-dimensional network structure of metal foams,we summarize recent progress on Cu foam(CF)-derived materials as efficient electrocatalysts towards pure water electrolysis and hybrid water electrolysis.The advantages of CF and design strategies to enhance the electrocatalytic activity and operational durability are presented first.Catalyst design and fabrication strategies are then highlighted and the structure-activity relationship is also discussed.Finally,we propose challenges and perspectives on self-supported electrodes beyond CF-derived materials.

Development and Performance Evaluation of Self-Generating Enhanced Foam Water Plugging System

For the waterflooding of late development on an offshore oilfield has become worse, and some wells group has entered into high water cut-off period, water plugging work becomes particularly important. Due to the limited construction of offshore oilfield, space water supply difficulties, and stability of plugging agent, self-generating enhanced foam has been designed as the aimed block plugging system. The formula is determined as: 23.25% of NH4Cl + 30% of NaNO2 + 0.1% of catalyst + 0.6% of COSL-3 foaming agent + 0.25% of HS-type HPAM foam stabilizer. Measurement point of pipe with permeability of 0.5 μm2 and 2 μm2 has been used in the plugging and EOR experiments. The experiments show that this system has the selective plugging effect for the heterogeneous formation, especially for middle and posterior part of high permeability formation, and the recovery rate of low permeability pipe is enhanced up to 32.15%.

Tests on Alkali-Activated Slag Foamed Concrete with Various Water-Binder Ratios and Substitution Levels of Fly Ash

To provide basic data for the reasonable mixing design of the alkali-activated (AA) foamed concrete as a thermal insulation material for a floor heating system, 9 concrete mixes with a targeted dry density less than 400 kg/m3 were tested. Ground granulated blast-furnace slag (GGBS) as a source material was activated by the following two types of alkali activators: 10% Ca(OH)2 and 4% Mg(NO3)2, and 2.5% Ca(OH)2 and 6.5% Na2SiO3. The main test parameters were water-to-binder (W/B) ratio and the substitution level (RFA) of fly ash (FA) for GGBS. Test results revealed that the dry density of AA GGBS foamed concrete was independent of the W/B ratio an RFA, whereas the compressive strength increased with the decrease in W/B ratio and with the increase in RFA up to 15%, beyond which it decreased. With the increase in the W/B ratio, the amount of macro capillaries and artificial air pores increased, which resulted in the decrease of compressive strength. The magnitude of the environmental loads of the AA GGBS foamed concrete is independent of the W/B ratio and RFA. The largest reduction percentage was found in the photochemical oxidation potential, being more than 99%. The reduction percentage was 87% - 93% for the global warming potential, 81% - 84% for abiotic depletion, 79% - 84% for acidification potential, 77% - 85% for eutrophication potential, and 73% - 83% for human toxicity potential. Ultimately, this study proved that the developed AA GGBS foamed concrete has a considerable promise as a sustainable construction material for nonstructural element.

The corrosive behaviors of GI and IF steel sheets in salt water drops

The corrosive behaviors of hot-dip galvanized steel （G I） sheets and the corresponding interstitial free （IF） steel base sheets for use in automobiles were investigated by the classical salt water drop （SWD） test at room temperature. The corrosive processes and products were observed and analyzed through morphological observation, a scanning electronic microscope （SEM） and an energy dispersive spectrum （EDS）. The results show that the anodic and cathode sites can be distinguished clearly during and after the test. The propagation of rusting, and the color, distribution and composition of the final corrosive products of the two kinds of materials are quite different. The SWD corrosive mechanisms of steel with and without galvanized coating are both discussed in this paper.

Drying Characteristics of Microwave-assisted Foam Drying of Corn Soaking Water

To improve the industrial utilization of corn soaking water, the yeast protein powder was produced by microwave-assisted foam drying. Firstly, preparation experiments were carded out, which included the foaming characteristic experiments of fermentation broth and that about the effects of carbon and nitrogen ratio on solid content in the fermentation broth. Secondly, the drying characteristics experiment of corn soaking water was studied, which selected the microwave power, material amount and thickness as the influencing factors for the single experiment. The results showed that the final moisture content （d.b.） and drying rate were significantly affected by those factors.

A Theoretical Model of the Water Vapor Diffusion through the Surface of Cloud Droplets

In order to understand better the dynamics of formation, growth and evaporation process of the cloud drops, it had developed a mathematical and physics model, using the equation of the vapor diffusion law get cross its surface, taken into consideration that it has a spherical form. When the spherical drop is formed, its time of live will depend on its radio value a; so, on the one hand, if the a value is bigger than critical radio value, then the drop growth because the condensation process win to the evaporation process, on the other hand, if the a value is less than critical radio value, then the cloud drop will be evaporated. To case the drop growth, the condensation process to the vapor diffusion gets cross its surface government the phenomenal dynamical. This important process is theoretically modeling in order to get a bigger understanding to design more efficient method of modifying them in a benefit way.

Analysis of Water Mist Suppression with Foam Additive in Wind Generator

The study adopted a 20-foot long container to simulate the situation inside a turbine cabin. Water mist sprays were installed internally and used to perform fire extinguishing tests. Under these different scenarios, several operating factors were adjusted with the results of each adjustment subsequently measured. The operating factors studied included： operating pressures, foam concentrations, cabin opening issues, and obstacles. Each of the factors was compared with the others so as to find out which combinations would be most suitable for a water mist spray system installed inside a wind turbine cabin. The presence of obstructions hinders the direct impact of the mist spray on the fire source and in average an additional 2 to 3 minutes is required to put out the fire. This study found that the effect of the foam-water ratio is linear. Regardless of the scenario, the optimum mixture ratio is 3%. The line graph shows that the most unsuitable aqueous film-forming mixture ratio is 6%. This experiment found that the main fire extinguishing mechanism of water mist spray is the cooling of a large area via water droplets. This system is very effective in bringing down the temperature. The addition of foam in water mist spray, however, impaired the effectiveness of the cooling effect although the fire control mechanism via emulsification markedly reduced the time required to put out the fire. The increase in foam magnification will considerably enhance the fire extinguishing efficiency.

Rear-Surface Deformation of a Water Drop in Aero-Breakup of Shear Mode

Deformation of water drops in shock-induced high-speed flows is investigated with a focus to the influence of primitive flow parameters on the rear-surface deformation features. Two typical deformation patterns are discovered through high-speed photography. A simple equation to evaluate the radial acceleration of the drop surface is derived. The combined use of this equation and outer flow simulation makes it possible for us to reconstruct the profiles of the early deformed drops. The results agree well with the experiments. Further analysis shows that the duration of flow establishment with respect to the overall breakup time shapes the rear side profile of the drop. Thereby the ratio of the two times, expressed as the square root of the density ratio, appears to be an effective indicator of the deformation features.

A Comparative Study of Water Imagery in the Chinese Poem Happy Rain on a Spring Night and American Poem A Drop Fell on the Apple Tree

This essay directs at the water imagery of two poems Happy Rain on a Spring Night and A Drop Fell on the Apple Tree.Although living in different time and place, Chinese poet Du Fu and American poetess Emily Dickinson share some deep understanding of the water. This secret of water imagery is unveiled in this essay with the help of Archetypal Criticism, revealing its significance to the human beings as a race.

Pressure drop of the film-enlarged tube bundles in air-water two-phase cross flow in evaporative air cooler

An experiment was carried out to investigate the relation of the maximum velocity of air passing through narrowest passage, mass flux of spray water in one square meter in one hour and the pressure drop of tube bundles. Twelve equations were obtained for the relation. The results show that the pressure drop of the tube bundles increases with increase of the maximum velocity of air and the mass flux of spray water. Comparing the pressure drop of the bare tube bundles with that of the film-enhanced tube bundles, it is found that the pressure drop of the film-enhanced tube bundles is lower about 11% and the surface roughness of the film-enhanced plates is a main factor that influences the pressure drop. The data and method obtained in the paper can be used to compute the pressure drop of the film-enhanced tube bundles and is helpful for selection of fan.

Experimental study on steam-water two-phase flow frictional pressure drops in helical coils

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Study on Pre-treatment of the Domestic Sewage by Water-dropping Aeration Zeolite Bed Technology

[ Objective] The research aimed to study pre-treatment effect of the domestic sewage by water-dropping aeration zeolite bed technology. [ Method] By water-dropping aeration manner, we conducted sewage reoxygenation. Zeolite was used to replace traditional contact oxidization fill- er. We inspected oxygenation effect of the water-dropping aeration manner and removal efficiency of the pollutant in sewage after biological contact oxidation. [ Result] Under the experimental condition with water-dropping heights of 0.30, 0.45 and 0.60 m, average added values of the dissolved oxygen for raw water were respectively 2.4, 3.6 and 4.2 rag/l_ after water-dropping aeration. Under the situation with average HRT of 2 h, when COD, TN and TP of the influent were respectively 309.0 -464.0, 33.3 -95.0 and 4.0 -7.5 mg/L, their corresponding average removal rates were 47.25%, 46.39% and 40.75%. [ Conclusion] The research conducted useful attempt for high-efficiency and low-cost treatment of the domestic sewaqe in rural area.

聚乙烯醇对泡沫混凝土性能及孔结构的影响

以聚乙烯醇和普通硅酸盐水泥为主要原料,制备泡沫混凝土。研究了聚乙烯醇对泡沫混凝土力学性能、吸水率、干密度和孔结构的影响。结果表明,掺入适量聚乙烯醇可显著减小气孔的尺寸,优化孔径分布;掺入适量聚乙烯醇可以提高泡沫混凝土的抗压和抗折强度;聚乙烯醇可以降低泡沫混凝土的吸水率,并在一定程度上减小了泡沫混凝土的干密度。

高滴点低水淋流失量的锂基润滑脂的制备及影响因素研究

本文采用预制皂生产工艺制备锂基润滑脂。以聚α烯烃、烷基萘及多元醇酯作为基础油,通过调整基础油的比例和试验条件,制得了具有较高滴点、低水淋流失量的锂基润滑脂。研究了稠化剂的类型及添加量、基础油的种类及极性、二烷基二硫代磷酸锌(ZDDP)的添加时机、炼制时间对润滑脂的滴点和水淋流失量的影响。研究结果表明:采用预制皂生产工艺,使用聚α烯烃、烷基萘和多元醇酯三种基础油复配,锂皂含量(质量分数)约为36.8%,在180~190℃的温度下炼制40~50 min,可制得滴点达到269℃、水淋流失量<1.0%的润滑脂。该工艺的特点是工艺过程简单,易操作,皂含量控制准确,产品质量稳定性好。

基于进排气装置填充泡沫应用性能研究

分析了进排气装置的结构组成和填充泡沫成型工艺,运用ANSYS Workbench中的热力学模块对进排气装置填充泡沫隔热性能进行了仿真计算,并开展了填充泡沫样件隔热和吸水率试验。仿真和实测结果表明:填充泡沫隔热性能显著,能够减少排气管内180℃高温废气所含热量传导至进气管表面,使进气管表面的温度降至61℃,且在0.15 MPa压力保压24 h后最大吸水率为0.72%,满足隔热和吸水率使用要求,释放了风险,为其应用提供了坚实的理论支持。