Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ig...Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.展开更多
Magnesium and magnesium alloy foils have great potential for application in battery anodes,electromagnetic shielding,optics and acoustics,and biology because of their excellent specific damping,internal dissipation co...Magnesium and magnesium alloy foils have great potential for application in battery anodes,electromagnetic shielding,optics and acoustics,and biology because of their excellent specific damping,internal dissipation coefficients,magnetic and electrical conductivities,as well as high theoretical specific capacity.However,magnesium alloys exhibit poor deformation ability due to their hexagonal close-packed crystal structure.Preparing magnesium and magnesium alloy foils with thicknesses of less than 0.1 mm is difficult because of surface oxidation and grain growth at high temperatures or severe anisotropy after cold rolling that leads to cracks.Numerous methods have been applied to prepare magnesium alloy foils.They include warm rolling,cold rolling,accumulative roll bonding,electric plastic rolling,and on-line heating rolling.Defects of magnesium and magnesium alloy foils during preparation,such as edge cracks and breakage,are important factors for consideration.Herein,the current status of the research on magnesium and magnesium alloy foils is summarized from the aspects of foil preparation,defect control,performance characterization,and application prospects.The advantages and disadvantages of different preparation methods and defect(edge cracks and breakage)mechanisms in the preparation of foils are identified.展开更多
High-purity copper(Cu) with excellent thermal and electrical conductivity, is crucial in modern technological applications, including heat exchangers, integrated circuits, and superconducting magnets. The current puri...High-purity copper(Cu) with excellent thermal and electrical conductivity, is crucial in modern technological applications, including heat exchangers, integrated circuits, and superconducting magnets. The current purification process is mainly based on the zone/electrolytic refining or anion exchange, however, which excessively relies on specific integrated equipment with ultra-high vacuum or chemical solution environment, and is also bothered by external contaminants and energy consumption. Here we report a simple approach to purify the Cu foils from 99.9%(3N) to 99.99%(4N) by a temperature-gradient thermal annealing technique, accompanied by the kinetic evolution of single crystallization of Cu.The success of purification mainly relies on(i) the segregation of elements with low effective distribution coefficient driven by grain-boundary movements and(ii) the high-temperature evaporation of elements with high saturated vapor pressure.The purified Cu foils display higher flexibility(elongation of 70%) and electrical conductivity(104% IACS) than that of the original commercial rolled Cu foils(elongation of 10%, electrical conductivity of ~ 100% IACS). Our results provide an effective strategy to optimize the as-produced metal medium, and therefore will facilitate the potential applications of Cu foils in precision electronic products and high-frequency printed circuit boards.展开更多
Al/Ni reactive multilayer foil(RMF)possesses excellent comprehensive properties as a promising substitute for traditional Cu bridge.A theoretical resistivity model of Al/Ni RMF was developed to guide the optimization ...Al/Ni reactive multilayer foil(RMF)possesses excellent comprehensive properties as a promising substitute for traditional Cu bridge.A theoretical resistivity model of Al/Ni RMF was developed to guide the optimization of EFIs.Al/Ni RMF with different bilayer thicknesses and bridge dimensions were prepared by MEMS technology and electrical explosion tests were carried out.According to physical and chemical reactions in bridge,the electrical explosion process was divided into 5 stages:heating of condensed bridge,vaporization and diffusion of Al layers,intermetallic combination reaction,intrinsic explosion,ionization of metal gases,which are obviously shown in measured voltage curve.Effects of interface and grain boundary scattering on the resistivity of film metal were considered.Focusing on variations of substance and state,the resistivity was developed as a function of temperature at each stage.Electrical explosion curves were calculated by this model at different bilayer thicknesses,bridge dimensions and capacitor voltages,which showed an excellent agreement with experimental ones.展开更多
Ultrasonic baths and sonochemical reactors are widely used in industrial applications dealing with surface cleaningand chemical synthesis. The processes of erosion, cleaning and structuring of the surface can be typic...Ultrasonic baths and sonochemical reactors are widely used in industrial applications dealing with surface cleaningand chemical synthesis. The processes of erosion, cleaning and structuring of the surface can be typically controlledby changing relevant influential parameters. In particular, in this work, we experimentally investigate theeffect of NaCl concentration (0–5.5 mol/L) on the erosion of an aluminum foil under ultrasonic exposure at afrequency of 28 kHz. Special attention is paid to the determination of cavitation zones and their visualizationusing heat maps. It is found that at low NaCl concentration (0.3 mol/L), the foil destruction rate is higher thanin distilled water. At higher concentrations of salt, cavitation takes place mainly in the upper part of the container.展开更多
Taking bump-type gas foil bearings as the research object,a deformation model of bump foil and a thin-plate finite element model of top foil were proposed.By solving Reynolds equation and energy equation,the pressure ...Taking bump-type gas foil bearings as the research object,a deformation model of bump foil and a thin-plate finite element model of top foil were proposed.By solving Reynolds equation and energy equation,the pressure distribution and the temperature distribution of gas films in foil bearings were obtained.Further,a numerical method for calculating the lubrication performance of gas foil bearings with considering the surface roughness was proposed.With a specific example,effects of the surface roughness on the bearing lubrication performance were parametrically studied.The results indicate that rougher journal surface can lead to larger fluctuation of the lubrication performance,while surface roughness of top foil has few effects on the fluctuation.Moreover,the mean values of performance parameters almost remain constant at different values of surface roughness.展开更多
Ti/Fe clad plate had attracted extensive attention because of its important application. In order to reduce the titanium layer thickness, the explosive welding of TA1 titanium foil to Q235 steel plate was carried out....Ti/Fe clad plate had attracted extensive attention because of its important application. In order to reduce the titanium layer thickness, the explosive welding of TA1 titanium foil to Q235 steel plate was carried out. The interfacial bonding performance was analyzed by micromorphology analysis and mechanical property test, and the formation process of interfacial wave and molten block in the vortex was simulated by smoothed particle hydrodynamics(SPH) method. The results showed that salt as pressure transfer layer used in explosive welding could play a good buffer effect on the collision between flyer and base layers. Regular waveforms were formed on the bonding interface, and the titanium foil/steel clad plate exhibited good welding quality and bonding property. The crest of the observed interfacial wave moved 200 μm from the beginning to the final formation, and it was important of jet on the formation of interfacial waveform. The interface was mainly bonded in the form of molten layer, and the grains near the interface were streamlined. Molten block containing intermetallic compounds and metal oxides appeared in the vortex of wave crest.展开更多
The results of a study of the electrical explosion of aluminum foils with an artificial periodic surface structure created by laser engraving are presented.Experiments were carried out on pulsed high-current generator...The results of a study of the electrical explosion of aluminum foils with an artificial periodic surface structure created by laser engraving are presented.Experiments were carried out on pulsed high-current generators BIN(270 kA,300 kV,100 ns)and KING(200 kA,40 kV,200 ns)with Al foil of thicknesses 16 and 4μm,respectively.Images of the exploded foils were recorded by point projection radiography in the radiation from hybrid X-pinches.It is found that the application of an artificial periodic structure to the foil leads to a much more uniform and well-defined periodic structure of the exploded foil.Images recorded in the UV range using a microchannel-plate-intensified detector show that the radiation from a surface-modified foil is more uniform along the entire length and width of the foil than that from a foil without modification.展开更多
The aluminum foil for high voltage aluminum electrolytic capacitor was immersed in 0.5 mol/L H3PO4 or 0.125 mol/L NaOH solution at 40 ℃ for different time and then DC electro-etched in 1 mol/L HC1+2.5 mol/L H2SO4 el...The aluminum foil for high voltage aluminum electrolytic capacitor was immersed in 0.5 mol/L H3PO4 or 0.125 mol/L NaOH solution at 40 ℃ for different time and then DC electro-etched in 1 mol/L HC1+2.5 mol/L H2SO4 electrolyte at 80 ℃. The pitting potential and self corrosion potential of A1 foil were measured with polarization curves (PC). The potentiostatic current--time curve was recorded and the surface and cross section images of etched A1 foil were observed with SEM. The electrochemical impedance spectroscopy (EIS) of etched A1 foil and potential transient curves (PTC) during initial etching stage were measured. The results show the chemical pretreatments can activate A1 foil surface, facilitate the absorption, diffusion and migration of C1- onto the A1 foil during etching, and improve the initiation rate of meta-stable pits and density of stable pits and tunnels, leading to much increase in the real surface area and special capacitance of etched A1 foil.展开更多
The Al foil for high voltage Al electrolytic capacitor usage was immersed in 5.0%NaOH solution containing trace amount of Zn2+and Zn was chemically plated on its surface through an immersion-reduction reaction. Such ...The Al foil for high voltage Al electrolytic capacitor usage was immersed in 5.0%NaOH solution containing trace amount of Zn2+and Zn was chemically plated on its surface through an immersion-reduction reaction. Such Zn-deposited Al foil was quickly transferred into HCl-H 2 SO 4 solution for DC-etching. The effects of Zn impurity on the surface and cross-section etching morphologies and electrochemical behavior of Al foil were investigated by SEM, polarization curve (PC) and electrochemical impedance spectroscopy (EIS). The special capacitance of 100 V formation voltage of etched foil was measured. The results show that the chemical plating Zn on Al substrate in alkali solution can reduce the pitting corrosion resistance, enhance the pitting current density and improve the density and uniform distribution of pits and tunnels due to formation of the micro Zn-Al galvanic local cells. The special capacitance of etched foil grows with the increase of Zn2+concentration.展开更多
The grain statistics effect was investigated through asymmetric rolling of pure copper foil by a realistic polycrystalline aggregates model and crystal plasticity element finite model.A polycrystalline aggregate model...The grain statistics effect was investigated through asymmetric rolling of pure copper foil by a realistic polycrystalline aggregates model and crystal plasticity element finite model.A polycrystalline aggregate model was generated and a crystal plasticity-based finite element model was developed for each grain and the specimen as a whole.The crystal plasticity model itself is rate dependent and accounts for local dissipative hardening effects and the original orientation of each grain was generated based on the orientation distribution function(ODF).The deformation behaviors,including inhomogeneous material flow,decrease of contact press and roll force with the increase of grain size for the constant size of specimens,were studied.It is revealed that when the specimens are composed of only a few grains across thickness,the grains with different sizes,shapes and orientations are unevenly distributed in the specimen and each grain plays a significant role in micro-scale plastic deformation and leads to inhomogeneous deformation and the scatter of experimental and simulation results.The slip system activity was examined and the predicted results are consistent with the surface layer model.The slip band is strictly influenced by the misorientation of neighbor grain with consideration of slip system activity.Furthermore,it is found that the decrease of roll force and the most active of slip system in surface grains are caused by the increase of free surface grain effect when the grain size is increased.The results of the physical experiment and simulation provide a basic understanding of micro-scaled plastic deformation behavior in asymmetric foil rolling.展开更多
Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of...Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of the resulting anodized film were examined by TEM and XRD.The special capacitance,resistance and withstanding voltage of the film were explored with electrochemical impedance spectroscopy(EIS),LCR meter and small-current charging.The results show that the high voltage anodized oxide film consists of an inner layer with high crystallinity and an outer layer with low crystallinity.However,the crystallinity of the film formed in boric acid+citric acid mixed solution is higher than that of the film formed in only boric acid solution,leading to an increase in film's field strength and special capacitance.Meanwhile,there are more defects from phase transformation in the out layer of the film formed in boric acid+citric acid mixed solution than in that of film formed in only boric acid solution,leading to a decrease in film's resistance and withstanding voltage.展开更多
A novel approach is proposed for computing the minimum thickness of a metal foil that can be achieved by asymmetric rolling using rolls with identical diameter. This approach is based on simultaneously solving Tseliko...A novel approach is proposed for computing the minimum thickness of a metal foil that can be achieved by asymmetric rolling using rolls with identical diameter. This approach is based on simultaneously solving Tselikov equation for the rolling pressure and the modified Hitchcock equation for the roller flattening. To minimize the effect of the elastic deformation on the equal flow per second during the ultrathin foil rolling process, the law of conservation of mass was employed to compute the proportions of the forward slip, backward slip, and the cross shear zones in the contact arc, and then a formula was derived for computing the minimum thickness for asymmetric rolling. Experiment was conducted to find the foil minimum thickness for 304 steel by asymmetric rolling under the asymmetry ratios of 1.05, 1.15 and 1.30. The experimental results are in good agreement with the calculated ones. It was validated that the proposed formula can be used to calculate the foil minimum thickness under the asymmetric rolling condition.展开更多
Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were inve...Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were investigated by using a foil with roughened surface by chemical etching and a plain foil with smooth surface on both sides. For high-conductivity LiCoO2 active materials with large particle size, there are no significant differences in battery performance between the two types of foils. But for low-conductivity LiFePO4 active materials with small particle size, high-rate discharge properties are significantly different. The possibility shows that optimizing both the surface morphology of the aluminum foil and particle size of active material leads to improvement of the battery performance.展开更多
Mo foil (10 -20 μm in thickness) and Al foil (20 -60 μLm in thickness) were vacuum diffusion bonded at 600 - 640 ~C under 20 MPa for 54 min - 6 h. The joints were examined by scanning electron microscopy (SEM)...Mo foil (10 -20 μm in thickness) and Al foil (20 -60 μLm in thickness) were vacuum diffusion bonded at 600 - 640 ~C under 20 MPa for 54 min - 6 h. The joints were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) to study the evolution mechanism of the reaction layers. The results show that Al atoms diffuse into Mo grain boundaries and form reaction products as Mo3Al8, MoAl4 , MoAl5 and MoAl12. The surface oxide film is eroded by the growths of the reaction products that plow into the lamellar texture of Mo grain boundaries. Mo3Al8 layer grows by "taking root" downwards and transforms into MoAl4 and MoAl5 phases upwards by absorbing Al atoms. MoAl12 layer grows up from MoAl5 layer in the same way. When the supplement of Al atoms ceases, MoAl12 transforms reversely into MoAl5 and MoAl5 into MoAl4 via the loss of Al atoms. However, MoAl4 continues to precipitate from Mo3Als layer. At last, there are MoAl4 and Mo3Al8 remained on the joint interface.展开更多
Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite...Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite element modeling shows that these clusters of hard particles induce the fracture of the nano-scale lubricant oil film at first and further lead to severe deformation in the nearby aluminum foil substrate along the rolling direction. Consequently, the optical property in this region differs from that in the surroundings, resulting in surface defects.展开更多
Centrifugal forces are commonly created when ships turn, which may cause a ship to capsize in a critical situation. A mathematical model has been developed to optimize the stability coefficients for ship, with the aim...Centrifugal forces are commonly created when ships turn, which may cause a ship to capsize in a critical situation. A mathematical model has been developed to optimize the stability coefficients for ship, with the aim to prevent capsizing and to increase ship maneuverability in high-speed water craft. This model can be used to develop algorithms for control system improvement. The mathematical model presented in this paper optimized the use of multipurpose hydrofoils to reduce heeling and the trimming moment, maintaining an upright ship’s position and lessening the resistance via transverse force. Conventionally, the trimming and heeling of a ship are controlled using ballast water;however, under variable sea conditions it is sometimes difficult to control a ship’s motion using ballast water. In this case, a hydrofoil would be more stable and maneuverable than a ballast tank controlled vessel. A movable hydrofoil could theoretically be adapted from moveable aerofoil technology. This study proves the merit of further investigation into this possibility.展开更多
文摘Exploding foil initiator(EFI)is a kind of advanced device for initiating explosives,but its function is unstable when it comes to directly igniting pyrotechnics.To solve the problem,this research aims to reveal the ignition mechanism of EFIs directly igniting pyrotechnics.An oscilloscope,a photon Doppler velocimetry,and a plasma spectrum measurement system were employed to obtain information of electric characteristics,impact pressure,and plasma temperature.The results of the electric characteristics and the impact pressure were inconsistent with ignition results.The only thing that the ignition success tests had in common was that their plasma all had a relatively long period of high-temperature duration(HTD).It eventually concludes that the ignition mechanism in this research is the microconvection heat transfer rather than the shock initiation,which differs from that of exploding foil initiators detonating explosives.Furthermore,the methods for evaluating the ignition success of semiconductor bridge initiators are not entirely applicable to the tests mentioned in this paper.The HTD is the critical parameter for judging the ignition success,and it is influenced by two factors:the late time discharge and the energy of the electric explosion.The longer time of the late time discharge and the more energy of the electric explosion,the easier it is to expand the HTD,which improves the probability of the ignition success.
基金financially supported by the National Key Research and Development Program of China(Nos.2022 YFB3709300 and 2021YFB3701000)the National Natural Science Foundation of China(Nos.52271090 and 52071036)+1 种基金the Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030006)the Independent Research Project of State Key Laboratory of Mechanical Transmissions(Nos.SKLMT-ZZKT-2022Z01 and S KLMT-ZZKT-2022M12)。
文摘Magnesium and magnesium alloy foils have great potential for application in battery anodes,electromagnetic shielding,optics and acoustics,and biology because of their excellent specific damping,internal dissipation coefficients,magnetic and electrical conductivities,as well as high theoretical specific capacity.However,magnesium alloys exhibit poor deformation ability due to their hexagonal close-packed crystal structure.Preparing magnesium and magnesium alloy foils with thicknesses of less than 0.1 mm is difficult because of surface oxidation and grain growth at high temperatures or severe anisotropy after cold rolling that leads to cracks.Numerous methods have been applied to prepare magnesium alloy foils.They include warm rolling,cold rolling,accumulative roll bonding,electric plastic rolling,and on-line heating rolling.Defects of magnesium and magnesium alloy foils during preparation,such as edge cracks and breakage,are important factors for consideration.Herein,the current status of the research on magnesium and magnesium alloy foils is summarized from the aspects of foil preparation,defect control,performance characterization,and application prospects.The advantages and disadvantages of different preparation methods and defect(edge cracks and breakage)mechanisms in the preparation of foils are identified.
基金Project supported by the Basic and Applied Basic Research Foundation of Guangdong Province,China(Grant Nos.2019A1515110302 and 2022A1515140003)the Key Research and Development Program of Guangdong Province,China(Grant Nos.2020B010189001,2021B0301030002,2019B010931001,and 2018B030327001)+5 种基金the National Natural Science Foundation of China(Grant Nos.52172035,52025023,52322205,51991342,52021006,51991344,52100115,11888101,92163206,12104018,and 12274456)the National Key Research and Development Program of China(Grant Nos.2021YFB3200303,2022YFA1405600,2018YFA0703700,2021YFA1400201,and 2021YFA1400502)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB33000000)the Pearl River Talent Recruitment Program of Guangdong Province,China(Grant No.2019ZT08C321)China Postdoctoral Science Foundation(Grant Nos.2020T130022 and 2020M680178)the Science and Technology Plan Project of Liaoning Province,China(Grant No.2021JH2/10100012).
文摘High-purity copper(Cu) with excellent thermal and electrical conductivity, is crucial in modern technological applications, including heat exchangers, integrated circuits, and superconducting magnets. The current purification process is mainly based on the zone/electrolytic refining or anion exchange, however, which excessively relies on specific integrated equipment with ultra-high vacuum or chemical solution environment, and is also bothered by external contaminants and energy consumption. Here we report a simple approach to purify the Cu foils from 99.9%(3N) to 99.99%(4N) by a temperature-gradient thermal annealing technique, accompanied by the kinetic evolution of single crystallization of Cu.The success of purification mainly relies on(i) the segregation of elements with low effective distribution coefficient driven by grain-boundary movements and(ii) the high-temperature evaporation of elements with high saturated vapor pressure.The purified Cu foils display higher flexibility(elongation of 70%) and electrical conductivity(104% IACS) than that of the original commercial rolled Cu foils(elongation of 10%, electrical conductivity of ~ 100% IACS). Our results provide an effective strategy to optimize the as-produced metal medium, and therefore will facilitate the potential applications of Cu foils in precision electronic products and high-frequency printed circuit boards.
基金National Natural Science Foundation of China(Grant No.11872013)for supporting this project.
文摘Al/Ni reactive multilayer foil(RMF)possesses excellent comprehensive properties as a promising substitute for traditional Cu bridge.A theoretical resistivity model of Al/Ni RMF was developed to guide the optimization of EFIs.Al/Ni RMF with different bilayer thicknesses and bridge dimensions were prepared by MEMS technology and electrical explosion tests were carried out.According to physical and chemical reactions in bridge,the electrical explosion process was divided into 5 stages:heating of condensed bridge,vaporization and diffusion of Al layers,intermetallic combination reaction,intrinsic explosion,ionization of metal gases,which are obviously shown in measured voltage curve.Effects of interface and grain boundary scattering on the resistivity of film metal were considered.Focusing on variations of substance and state,the resistivity was developed as a function of temperature at each stage.Electrical explosion curves were calculated by this model at different bilayer thicknesses,bridge dimensions and capacitor voltages,which showed an excellent agreement with experimental ones.
文摘Ultrasonic baths and sonochemical reactors are widely used in industrial applications dealing with surface cleaningand chemical synthesis. The processes of erosion, cleaning and structuring of the surface can be typically controlledby changing relevant influential parameters. In particular, in this work, we experimentally investigate theeffect of NaCl concentration (0–5.5 mol/L) on the erosion of an aluminum foil under ultrasonic exposure at afrequency of 28 kHz. Special attention is paid to the determination of cavitation zones and their visualizationusing heat maps. It is found that at low NaCl concentration (0.3 mol/L), the foil destruction rate is higher thanin distilled water. At higher concentrations of salt, cavitation takes place mainly in the upper part of the container.
文摘Taking bump-type gas foil bearings as the research object,a deformation model of bump foil and a thin-plate finite element model of top foil were proposed.By solving Reynolds equation and energy equation,the pressure distribution and the temperature distribution of gas films in foil bearings were obtained.Further,a numerical method for calculating the lubrication performance of gas foil bearings with considering the surface roughness was proposed.With a specific example,effects of the surface roughness on the bearing lubrication performance were parametrically studied.The results indicate that rougher journal surface can lead to larger fluctuation of the lubrication performance,while surface roughness of top foil has few effects on the fluctuation.Moreover,the mean values of performance parameters almost remain constant at different values of surface roughness.
文摘Ti/Fe clad plate had attracted extensive attention because of its important application. In order to reduce the titanium layer thickness, the explosive welding of TA1 titanium foil to Q235 steel plate was carried out. The interfacial bonding performance was analyzed by micromorphology analysis and mechanical property test, and the formation process of interfacial wave and molten block in the vortex was simulated by smoothed particle hydrodynamics(SPH) method. The results showed that salt as pressure transfer layer used in explosive welding could play a good buffer effect on the collision between flyer and base layers. Regular waveforms were formed on the bonding interface, and the titanium foil/steel clad plate exhibited good welding quality and bonding property. The crest of the observed interfacial wave moved 200 μm from the beginning to the final formation, and it was important of jet on the formation of interfacial waveform. The interface was mainly bonded in the form of molten layer, and the grains near the interface were streamlined. Molten block containing intermetallic compounds and metal oxides appeared in the vortex of wave crest.
基金supported by the Russian Science Foundation,Project No.19-79-30086-P.
文摘The results of a study of the electrical explosion of aluminum foils with an artificial periodic surface structure created by laser engraving are presented.Experiments were carried out on pulsed high-current generators BIN(270 kA,300 kV,100 ns)and KING(200 kA,40 kV,200 ns)with Al foil of thicknesses 16 and 4μm,respectively.Images of the exploded foils were recorded by point projection radiography in the radiation from hybrid X-pinches.It is found that the application of an artificial periodic structure to the foil leads to a much more uniform and well-defined periodic structure of the exploded foil.Images recorded in the UV range using a microchannel-plate-intensified detector show that the radiation from a surface-modified foil is more uniform along the entire length and width of the foil than that from a foil without modification.
基金Project supported by University New Materials Disciplines Constructions Program of Beijing Region,ChinaProject(51172102/E020801) supported by the National Natural Science Foundation of China
文摘The aluminum foil for high voltage aluminum electrolytic capacitor was immersed in 0.5 mol/L H3PO4 or 0.125 mol/L NaOH solution at 40 ℃ for different time and then DC electro-etched in 1 mol/L HC1+2.5 mol/L H2SO4 electrolyte at 80 ℃. The pitting potential and self corrosion potential of A1 foil were measured with polarization curves (PC). The potentiostatic current--time curve was recorded and the surface and cross section images of etched A1 foil were observed with SEM. The electrochemical impedance spectroscopy (EIS) of etched A1 foil and potential transient curves (PTC) during initial etching stage were measured. The results show the chemical pretreatments can activate A1 foil surface, facilitate the absorption, diffusion and migration of C1- onto the A1 foil during etching, and improve the initiation rate of meta-stable pits and density of stable pits and tunnels, leading to much increase in the real surface area and special capacitance of etched A1 foil.
基金Project (51172102) supported by the National Natural Science Foundation of ChinaProject (BS2011CL011) supported by Promotive Research Fund for Young and Middle-aged Scientists of Shandong Province(doctor fund),China
文摘The Al foil for high voltage Al electrolytic capacitor usage was immersed in 5.0%NaOH solution containing trace amount of Zn2+and Zn was chemically plated on its surface through an immersion-reduction reaction. Such Zn-deposited Al foil was quickly transferred into HCl-H 2 SO 4 solution for DC-etching. The effects of Zn impurity on the surface and cross-section etching morphologies and electrochemical behavior of Al foil were investigated by SEM, polarization curve (PC) and electrochemical impedance spectroscopy (EIS). The special capacitance of 100 V formation voltage of etched foil was measured. The results show that the chemical plating Zn on Al substrate in alkali solution can reduce the pitting corrosion resistance, enhance the pitting current density and improve the density and uniform distribution of pits and tunnels due to formation of the micro Zn-Al galvanic local cells. The special capacitance of etched foil grows with the increase of Zn2+concentration.
基金Project(51374069)supported by the National Natural Science Foundation of ChinaProject(U1460107)supported by the Joint Fund of the National Natural Science Foundation of China
文摘The grain statistics effect was investigated through asymmetric rolling of pure copper foil by a realistic polycrystalline aggregates model and crystal plasticity element finite model.A polycrystalline aggregate model was generated and a crystal plasticity-based finite element model was developed for each grain and the specimen as a whole.The crystal plasticity model itself is rate dependent and accounts for local dissipative hardening effects and the original orientation of each grain was generated based on the orientation distribution function(ODF).The deformation behaviors,including inhomogeneous material flow,decrease of contact press and roll force with the increase of grain size for the constant size of specimens,were studied.It is revealed that when the specimens are composed of only a few grains across thickness,the grains with different sizes,shapes and orientations are unevenly distributed in the specimen and each grain plays a significant role in micro-scale plastic deformation and leads to inhomogeneous deformation and the scatter of experimental and simulation results.The slip system activity was examined and the predicted results are consistent with the surface layer model.The slip band is strictly influenced by the misorientation of neighbor grain with consideration of slip system activity.Furthermore,it is found that the decrease of roll force and the most active of slip system in surface grains are caused by the increase of free surface grain effect when the grain size is increased.The results of the physical experiment and simulation provide a basic understanding of micro-scaled plastic deformation behavior in asymmetric foil rolling.
基金Project supported by University New Materials Disciplines Construction Program of Beijing Region
文摘Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of the resulting anodized film were examined by TEM and XRD.The special capacitance,resistance and withstanding voltage of the film were explored with electrochemical impedance spectroscopy(EIS),LCR meter and small-current charging.The results show that the high voltage anodized oxide film consists of an inner layer with high crystallinity and an outer layer with low crystallinity.However,the crystallinity of the film formed in boric acid+citric acid mixed solution is higher than that of the film formed in only boric acid solution,leading to an increase in film's field strength and special capacitance.Meanwhile,there are more defects from phase transformation in the out layer of the film formed in boric acid+citric acid mixed solution than in that of film formed in only boric acid solution,leading to a decrease in film's resistance and withstanding voltage.
基金Projects(51374069U1460107)supported by the National Natural Science Foundation of China
文摘A novel approach is proposed for computing the minimum thickness of a metal foil that can be achieved by asymmetric rolling using rolls with identical diameter. This approach is based on simultaneously solving Tselikov equation for the rolling pressure and the modified Hitchcock equation for the roller flattening. To minimize the effect of the elastic deformation on the equal flow per second during the ultrathin foil rolling process, the law of conservation of mass was employed to compute the proportions of the forward slip, backward slip, and the cross shear zones in the contact arc, and then a formula was derived for computing the minimum thickness for asymmetric rolling. Experiment was conducted to find the foil minimum thickness for 304 steel by asymmetric rolling under the asymmetry ratios of 1.05, 1.15 and 1.30. The experimental results are in good agreement with the calculated ones. It was validated that the proposed formula can be used to calculate the foil minimum thickness under the asymmetric rolling condition.
文摘Aluminum foils having thicknesses of 10-20 μm are commonly employed as current collectors for cathode electrodes in Li-ion batteries. The effects of the surface morphology of the foil on battery performance were investigated by using a foil with roughened surface by chemical etching and a plain foil with smooth surface on both sides. For high-conductivity LiCoO2 active materials with large particle size, there are no significant differences in battery performance between the two types of foils. But for low-conductivity LiFePO4 active materials with small particle size, high-rate discharge properties are significantly different. The possibility shows that optimizing both the surface morphology of the aluminum foil and particle size of active material leads to improvement of the battery performance.
基金This work is supported by National Natural Science Foundation of China (10676027).
文摘Mo foil (10 -20 μm in thickness) and Al foil (20 -60 μLm in thickness) were vacuum diffusion bonded at 600 - 640 ~C under 20 MPa for 54 min - 6 h. The joints were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) to study the evolution mechanism of the reaction layers. The results show that Al atoms diffuse into Mo grain boundaries and form reaction products as Mo3Al8, MoAl4 , MoAl5 and MoAl12. The surface oxide film is eroded by the growths of the reaction products that plow into the lamellar texture of Mo grain boundaries. Mo3Al8 layer grows by "taking root" downwards and transforms into MoAl4 and MoAl5 phases upwards by absorbing Al atoms. MoAl12 layer grows up from MoAl5 layer in the same way. When the supplement of Al atoms ceases, MoAl12 transforms reversely into MoAl5 and MoAl5 into MoAl4 via the loss of Al atoms. However, MoAl4 continues to precipitate from Mo3Als layer. At last, there are MoAl4 and Mo3Al8 remained on the joint interface.
基金Project(51074117)supported by the National Natural Science Foundation of ChinaProject(2009CDA044)supported by the Foundation for Distinguished Young Scientists of Hubei Province,ChinaProjects(201104493,20100471161)supported by the China Postdoctoral Science Foundation
文摘Scanning electron microscopy and X-ray energy dispersive spectrum analysis show that the clusters of intermetallic AlFeSi particle are distributed on or near the aluminum foil stock surfaces heterogeneously. 3D finite element modeling shows that these clusters of hard particles induce the fracture of the nano-scale lubricant oil film at first and further lead to severe deformation in the nearby aluminum foil substrate along the rolling direction. Consequently, the optical property in this region differs from that in the surroundings, resulting in surface defects.
文摘Centrifugal forces are commonly created when ships turn, which may cause a ship to capsize in a critical situation. A mathematical model has been developed to optimize the stability coefficients for ship, with the aim to prevent capsizing and to increase ship maneuverability in high-speed water craft. This model can be used to develop algorithms for control system improvement. The mathematical model presented in this paper optimized the use of multipurpose hydrofoils to reduce heeling and the trimming moment, maintaining an upright ship’s position and lessening the resistance via transverse force. Conventionally, the trimming and heeling of a ship are controlled using ballast water;however, under variable sea conditions it is sometimes difficult to control a ship’s motion using ballast water. In this case, a hydrofoil would be more stable and maneuverable than a ballast tank controlled vessel. A movable hydrofoil could theoretically be adapted from moveable aerofoil technology. This study proves the merit of further investigation into this possibility.