Although two moulds for methane gas in coal with the free state and adsorption state have been popularly considered, the derivation between the real methane gas state equation in coal and the perfect gas state equatio...Although two moulds for methane gas in coal with the free state and adsorption state have been popularly considered, the derivation between the real methane gas state equation in coal and the perfect gas state equation has been fuzzily considered and the mechanism of interaction for coal aromatics and methane gas molecules has not been understood. Then these problems have been discussed in this paper applied the principle of statistical thermo mechanics and quantum chemistry as well as based on the numerical calculating of experiential data in quantum chemistry. Therefore, it is revealed by research results that the experience state equation for real methane gas in coal, which is put forward in this paper, is closer to actual situation and the interaction process for methane gas adsorption on the surface of coal aromatics can be formulated by Morse potential function. Furthermore it is most stable through this research that the structural mould for methane gas molecule adsorption on the surface of coal nuclear with one gas molecule on top of another aromatics in regular triangle cone has been understood, and it is a physical adsorption for methane gas adsorption with single layer molecule on the surface of coal nuclear.展开更多
Objective Despite the adoption of various permeability enhancement technologies,the low permeability of coal reservoir has not been fundamentally improved for the development of coalbed methane(CBM)on the ground or ...Objective Despite the adoption of various permeability enhancement technologies,the low permeability of coal reservoir has not been fundamentally improved for the development of coalbed methane(CBM)on the ground or the control of gas underground.展开更多
A research on the application of a TG-DTA(thermal gravimetry aifferential thermal analysis)to the quick determination of moisture,organic volatile fixed carbon,ash and caloric value for coal is described.
In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/...In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal.展开更多
Streamflow in the Kuye River basin has been sharply reduced by the effects of climate change and human activities.Since 1997,the intensification of coal mining has resulted in substantial reductions to streamflow alon...Streamflow in the Kuye River basin has been sharply reduced by the effects of climate change and human activities.Since 1997,the intensification of coal mining has resulted in substantial reductions to streamflow alongside an ever-increasing demand for water.In this study,we present a derived statistical method,incorporating the Mann-Kendall and Pettitt method(MK-P) and the Soil and Water Assessment Tool(SWAT),and apply it to estimating the streamflow reductions caused by underground mining for coal in the Kuye River basin.The results show that underground mining is an important cause of the streamflow reductions observed since1997,being responsible for reductions of 21.15 mm/yr(~56%of the total) during 1997-2009.The results of the SWAT simulation were assessed by several performance criteria:Nash-Suttcliffe Efficiency(Nse),correlation coefficient(R^2),relative error(RE),P-factor and Pv-factor.The close match between the simulations and observed data supports the reasonability of our findings.We suggest that engineering strategies be adopted to limit streamflow loss into goafs via fractured zones in the coalfield.展开更多
文摘Although two moulds for methane gas in coal with the free state and adsorption state have been popularly considered, the derivation between the real methane gas state equation in coal and the perfect gas state equation has been fuzzily considered and the mechanism of interaction for coal aromatics and methane gas molecules has not been understood. Then these problems have been discussed in this paper applied the principle of statistical thermo mechanics and quantum chemistry as well as based on the numerical calculating of experiential data in quantum chemistry. Therefore, it is revealed by research results that the experience state equation for real methane gas in coal, which is put forward in this paper, is closer to actual situation and the interaction process for methane gas adsorption on the surface of coal aromatics can be formulated by Morse potential function. Furthermore it is most stable through this research that the structural mould for methane gas molecule adsorption on the surface of coal nuclear with one gas molecule on top of another aromatics in regular triangle cone has been understood, and it is a physical adsorption for methane gas adsorption with single layer molecule on the surface of coal nuclear.
基金financially supported by the National Natural Sciences Foundation of China(grant No.NSFC 41472127)
文摘Objective Despite the adoption of various permeability enhancement technologies,the low permeability of coal reservoir has not been fundamentally improved for the development of coalbed methane(CBM)on the ground or the control of gas underground.
文摘A research on the application of a TG-DTA(thermal gravimetry aifferential thermal analysis)to the quick determination of moisture,organic volatile fixed carbon,ash and caloric value for coal is described.
基金National Natural Science Foundation of China(4 9672 13 1)
文摘In accordance with the confusion on classification of source rocks, the authors raised a source rock classification for its enriched and dispersed organic matter types based on both Alpern’s idea and maceral genesis/composition. The determined rock type is roughly similar to palynofacies of Combaz , whereas it is "rock maceral facies (for coal viz. coal facies)" in strictly speaking. Therefore, it is necessary to use the organic ingredients classification proposed by the authors so that it can be used for both maceral analysis and environment research . This source rock classification not only shows sedimentology and diagenetic changes but also acquires organic matter type even if hydrocarbon potential derived from maceral’s geochemical parameters. So, it is considered as genetic classification. The "rock maceral facies" may be transformed to sedimentary organic facies , which is used as quantitative evaluation means if research being perfect.Now, there are many models in terms of structure either for coal or for kerogen. In our opinion, whatever coal or kerogen ought be polymer, then we follow Combaz’s thought and study structure of amorphous kerogens which are accordance with genetic mechanism showing biochemical and geochemical process perfectly. Here, we use the time of flight secondary ion mass spectrometry (TOFSIMS) to expand Combaz’s models from three to five. They are also models for coal.
基金supported by the National Natural Science Foundation of China(Grant Nos.51309107,E090105,41130639 and 51179045)the Public Welfare Program(Grant Nos.201501022 and 201301068)+1 种基金the Fundamental Research Funds for the Central Public Welfare Research Institutes(Grant No.HKY-JBYW-2013-19)the Fundamental Research Funds for the Central Universities(Grant Nos.2014B34914 and 2015B28514)
文摘Streamflow in the Kuye River basin has been sharply reduced by the effects of climate change and human activities.Since 1997,the intensification of coal mining has resulted in substantial reductions to streamflow alongside an ever-increasing demand for water.In this study,we present a derived statistical method,incorporating the Mann-Kendall and Pettitt method(MK-P) and the Soil and Water Assessment Tool(SWAT),and apply it to estimating the streamflow reductions caused by underground mining for coal in the Kuye River basin.The results show that underground mining is an important cause of the streamflow reductions observed since1997,being responsible for reductions of 21.15 mm/yr(~56%of the total) during 1997-2009.The results of the SWAT simulation were assessed by several performance criteria:Nash-Suttcliffe Efficiency(Nse),correlation coefficient(R^2),relative error(RE),P-factor and Pv-factor.The close match between the simulations and observed data supports the reasonability of our findings.We suggest that engineering strategies be adopted to limit streamflow loss into goafs via fractured zones in the coalfield.