The assessment of potential risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide,for free formaldehyde is harmful to human. Some papers focus on hazard and exposure assessment,using ...The assessment of potential risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide,for free formaldehyde is harmful to human. Some papers focus on hazard and exposure assessment,using quantitative and semi-quantitative method, rather than assessment for the factors related to formaldehyde content. In order to perform early-warning research and risk management,the quantitative risk assessment is used to analyze the imported textile testing data and find the factors related to formaldehyde content. K-means algorithm is the core of the method. It can be concluded that the disqualified textiles have relations with main fiber components,fabric color,season month,and brand. Then the data in the same attribute are clustered by Kmeans algorithm. The different classes are defined as related danger level,respectively severe,moderate,and light.展开更多
With the enhancement of environmental protection consciousness,concerns have been raised about non-toxic and biodegradable leather retanning agents.According to the European standard 2002/231/EC,the free formaldehyde ...With the enhancement of environmental protection consciousness,concerns have been raised about non-toxic and biodegradable leather retanning agents.According to the European standard 2002/231/EC,the free formaldehyde content of leather products should be less than 150 mg/kg.As one of the retanning agents in the market,the content of free formaldehyde in the Multifunctional retanning agent(MTA)is 372.22 mg/kg and higher than the limit value.In this work,glutaraldehyde as an alternative of formaldehyde was used to modify acrylic polymer and an amphoteric acrylic retanning agent was prepared.Then it was used in retanning process,and its retanning and assistant-dyeing properties were investigated.The results showed that the free formaldehyde content of amphoteric acrylic retanning agent modified with glutaraldehyde was only 4.17mg/kg.Meanwhile,the presence of amino groups in the amphoteric acrylic retanning agent improved the dyeing properties of leather by electrostatic attraction.Compared with the leather treated with anionic acrylic retanning agent,the residual dye concentration of the dyeing effluent of the retanned leather with amphoteric acrylic retanning agent decreased from 17.4mg/L to 10.0mg/L,and the dyed leather had better resistances to friction and water-washing.In addition,the BOD 5/COD value of the wastewater after Mannich base polymer retanning was only 0.32,indicating that the retanning agent was biodegradable.Moreover,the leather retanned with amphoteric acrylic retanning agent had good thermal stability,fullness and physical and mechanical properties.展开更多
基金AQSIQ Science and Technology Projects,China(No.2013IK116)
文摘The assessment of potential risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide,for free formaldehyde is harmful to human. Some papers focus on hazard and exposure assessment,using quantitative and semi-quantitative method, rather than assessment for the factors related to formaldehyde content. In order to perform early-warning research and risk management,the quantitative risk assessment is used to analyze the imported textile testing data and find the factors related to formaldehyde content. K-means algorithm is the core of the method. It can be concluded that the disqualified textiles have relations with main fiber components,fabric color,season month,and brand. Then the data in the same attribute are clustered by Kmeans algorithm. The different classes are defined as related danger level,respectively severe,moderate,and light.
基金The financial support of this study was from the Key Program of National Natural Science Foundation of China(No.21838007)National Natural Science Foundation of China(No.21706151).
文摘With the enhancement of environmental protection consciousness,concerns have been raised about non-toxic and biodegradable leather retanning agents.According to the European standard 2002/231/EC,the free formaldehyde content of leather products should be less than 150 mg/kg.As one of the retanning agents in the market,the content of free formaldehyde in the Multifunctional retanning agent(MTA)is 372.22 mg/kg and higher than the limit value.In this work,glutaraldehyde as an alternative of formaldehyde was used to modify acrylic polymer and an amphoteric acrylic retanning agent was prepared.Then it was used in retanning process,and its retanning and assistant-dyeing properties were investigated.The results showed that the free formaldehyde content of amphoteric acrylic retanning agent modified with glutaraldehyde was only 4.17mg/kg.Meanwhile,the presence of amino groups in the amphoteric acrylic retanning agent improved the dyeing properties of leather by electrostatic attraction.Compared with the leather treated with anionic acrylic retanning agent,the residual dye concentration of the dyeing effluent of the retanned leather with amphoteric acrylic retanning agent decreased from 17.4mg/L to 10.0mg/L,and the dyed leather had better resistances to friction and water-washing.In addition,the BOD 5/COD value of the wastewater after Mannich base polymer retanning was only 0.32,indicating that the retanning agent was biodegradable.Moreover,the leather retanned with amphoteric acrylic retanning agent had good thermal stability,fullness and physical and mechanical properties.
