A mechanochemical method was employed to prepare modified iron molybdate catalysts with various metal salts as precursors.The physicochemical properties of the iron molybdate catalysts were characterized,and their per...A mechanochemical method was employed to prepare modified iron molybdate catalysts with various metal salts as precursors.The physicochemical properties of the iron molybdate catalysts were characterized,and their performances in catalyzing the reaction from methanol to formaldehyde(HCHO)were evaluated.Iron molybdate catalysts doped with Co(NO_(3))_(2)·6H_(2)Oand Al(NO_(3))_(3)·9H_(2)O resulted in high HCHO yields.Compared with a commercial catalyst,the HCHO yields in the reaction with the modified catalyst at an optimal Co/Mo molar ratio reached 97.37%.According to chemical state analysis,the formation of CoO and the efficient decrease in the MoO_(3)sublimation rate could be important factors enhancing the HCHO yield in reactions catalyzed with iron molybdate doped with different Co/Mo mole ratios.展开更多
基金the Natural Science Foundation Project of Xinjiang Uygur Autonomous(Grant No.2019D01C084)for financial support.
文摘A mechanochemical method was employed to prepare modified iron molybdate catalysts with various metal salts as precursors.The physicochemical properties of the iron molybdate catalysts were characterized,and their performances in catalyzing the reaction from methanol to formaldehyde(HCHO)were evaluated.Iron molybdate catalysts doped with Co(NO_(3))_(2)·6H_(2)Oand Al(NO_(3))_(3)·9H_(2)O resulted in high HCHO yields.Compared with a commercial catalyst,the HCHO yields in the reaction with the modified catalyst at an optimal Co/Mo molar ratio reached 97.37%.According to chemical state analysis,the formation of CoO and the efficient decrease in the MoO_(3)sublimation rate could be important factors enhancing the HCHO yield in reactions catalyzed with iron molybdate doped with different Co/Mo mole ratios.
