Mechanical analysis of cylinders being upset between spherical concave platen and concave supporting plate is conducted. Rigid-plastic mechanical models for cylinders are presented. When the ratio of height to diamete...Mechanical analysis of cylinders being upset between spherical concave platen and concave supporting plate is conducted. Rigid-plastic mechanical models for cylinders are presented. When the ratio of height to diameter, is larger than 1, there exists two-dimensional tensile stress in the deformed body, when the ratio is smaller than 1, there exists shear stress in static hydraulic zone. The former breaks through the theory that there is three-dimensional compressive stress irrespective of any ratio of height to diameter. The latter satisfactorily explains the mechanism of layer-like cracks in disk-shaped forgings and the flanges of forged gear axles. The representation of the two models makes the upsetting, theory into correct and perfect stage.展开更多
Large pressure equipment needs to be tested regularly to ensure safe operation;wall-climbing robots can carry the necessary tools to inspect spherical tanks,such as cameras and non-destructive testing equipment.Howeve...Large pressure equipment needs to be tested regularly to ensure safe operation;wall-climbing robots can carry the necessary tools to inspect spherical tanks,such as cameras and non-destructive testing equipment.However,a wall-climbing robot inside a spherical tank cannot be accurately positioned owing to the particularity of the spherical tank structure.This paper proposes a passive support and positioning mechanism fixed in a spherical tank to improve the adsorption capacity and positioning accuracy of the inspection robot.The main body of the mechanism was designed as a truss composed of carbon fiber telescopic rods and can work in spherical tanks with diameters of 4.6-15.7 m.The structural strength,stiffness,and stability of the mechanism are analyzed via force and deformation simulations.By constructing a mathematical model of the support and positioning mechanism,the influence of structural deformation on the supporting capacity is analyzed and calculated.The robot positioning method based on the support and positioning mechanism can effectively locate the robot inside a spherical tank.Experiments verified the support performance and robot positioning accuracy of the mechanism.This research proposes an auxiliary support and positioning mechanism for a detection robot inside a spherical tank,which can effectively improve the positioning accuracy of the robot and meet the robotic inspection requirements.展开更多
Polymerization of propylene was carried out under bulk process at 70 degrees C using the supported metallocene catalyst with four kinds of SiO2 as carrier with triethylaluminum used as cocatalyst. The morphology of th...Polymerization of propylene was carried out under bulk process at 70 degrees C using the supported metallocene catalyst with four kinds of SiO2 as carrier with triethylaluminum used as cocatalyst. The morphology of the products was studied by SEM. It was found the property of the carriers gave great effect on the fine structure of the products as well as the apperance.展开更多
Spherical pressure vessels in large sizes are generally supported on legs or columns evenly spaced around the circumference. The legs are attached at or near the equator of the sphere. This research work focussed on f...Spherical pressure vessels in large sizes are generally supported on legs or columns evenly spaced around the circumference. The legs are attached at or near the equator of the sphere. This research work focussed on flexural-torsional buckling of beam-column supports of field fabricated spherical pressure vessels using finite element analysis. Flexuraltorsional buckling is an important limit state that must be considered in structural steel design and it occurs when a structural member experiences significant out-of-plane bending and twisting. This research has therefore considered the total potential energy equation for the flexural-torsional buckling of a beam-column element. The energy equation was formulated by summing the strain energy and the potential energy of the external loads. The finite element method was applied in conjunction with the energy method to analyze the flexural-torsional buckling of beam-column supports. To apply the finite element method, the displacement functions are assumed to be cubic polynomials, and the shape functions used to derive the element stiffness and element geometric stiffness matrices. The element stiffness and geometric stiffness matrices were assembled to obtain the global stiffness matrices of the structure. The final finite element equation obtained was in the form of an eigenvalue problem. The flexural-torsional buckling loads of the structure were determined by solving for the eigenvalue of the equation. The resulting eigenvalue equation from the finite element analysis was coded using FORTRAN 90 programming language to aid in the analysis process. To validate FORTRAN 90 coding developed for the finite element analysis and the methodology, the results given by the software were compared to existing solutions and showed no significant difference P > 0.05.展开更多
The pore structure of spherical alumina supports is closely related to the dispersion of catalytically active components and the diffusion of reactants.Maintaining excellent pore structure under strict reaction condit...The pore structure of spherical alumina supports is closely related to the dispersion of catalytically active components and the diffusion of reactants.Maintaining excellent pore structure under strict reaction conditions is of utmost importance.In this work,sphericalγ-Al_(2)O_(3)support with a bimodal pore structure,composed of macropores and mesopores,was successfully synthesized using dodecane as the pore-forming agent through the oil–ammonia column-shaping method.The morphology and internal pore structure of the alumina were found to be influenced by the amount of surfactant added and ultrasound treatment conditions.Notably,when concentration of surfactant was 4‰and ultrasound voltage of 20 V was applied,the resultingγ-Al_(2)O_(3)-4‰-20 displayed a highly concentrated distribution of macropores with an average pore size of 100 nm,resulting in an impressive porosity of 69.21%.In contrast,the untreated sample ofγ-Al_(2)O_(3)-0-0 only exhibited a mesoporous distribution with a porosity of 54.03%.Moreover,after being subjected to a hydrothermal treatment in a high temperature(600°C)and high humidity(water vapor)environment for 120 h,theγ-Al_(2)O_(3)-4‰-20 sample maintained a high BET specific surface area of 170.9 m^(2)g^(−1)and mercury intrusion porosimetry specific surface area of 263.3 m^(2)g^(−1).展开更多
Spherical MgCl 2 supported metallocene catalyst was prepared by supporting MAO on carrier which was prepared from MgCl 2 ·n EtOH.Ethylene polymerization was carried out by addition of MAO/MgCl 2,different metallo...Spherical MgCl 2 supported metallocene catalyst was prepared by supporting MAO on carrier which was prepared from MgCl 2 ·n EtOH.Ethylene polymerization was carried out by addition of MAO/MgCl 2,different metallocenes and alkylaluminum,in the absence of soluble MAO.It shows high activity for ethylene polymerization at lower Al/Zr(Al/Zr=45).The effect of concentration of Al( i Bu) 3 on polymerization activities and activation of Et(Ind) 2ZrCl 2 were studied.Kinetic behavior of ethylene polymerization on spherical MgCl 2 supported metallocene catalyst was investigated,which indicated the polymers obtained by reaction could affect the diffusion of ethylene in hexane under the experiment condidtion.Different aluminium alkyls have great impact on the whole polymerization behavior,and the relative reactivity decreases in the following order:Al( i Bu) 3>AlEt 3>AlMe 3>AlEt 2Cl,in which Al( i Bu) 3 shows the highest catalytic activity (5 78×10 7 g PE/mol\|Zr·h).展开更多
基金National Natural Science Foundation of China(No.59235101)
文摘Mechanical analysis of cylinders being upset between spherical concave platen and concave supporting plate is conducted. Rigid-plastic mechanical models for cylinders are presented. When the ratio of height to diameter, is larger than 1, there exists two-dimensional tensile stress in the deformed body, when the ratio is smaller than 1, there exists shear stress in static hydraulic zone. The former breaks through the theory that there is three-dimensional compressive stress irrespective of any ratio of height to diameter. The latter satisfactorily explains the mechanism of layer-like cracks in disk-shaped forgings and the flanges of forged gear axles. The representation of the two models makes the upsetting, theory into correct and perfect stage.
基金Supported by Jiangsu Major Research and Development(Social Development)Project of China(Grant No.BE2016802).
文摘Large pressure equipment needs to be tested regularly to ensure safe operation;wall-climbing robots can carry the necessary tools to inspect spherical tanks,such as cameras and non-destructive testing equipment.However,a wall-climbing robot inside a spherical tank cannot be accurately positioned owing to the particularity of the spherical tank structure.This paper proposes a passive support and positioning mechanism fixed in a spherical tank to improve the adsorption capacity and positioning accuracy of the inspection robot.The main body of the mechanism was designed as a truss composed of carbon fiber telescopic rods and can work in spherical tanks with diameters of 4.6-15.7 m.The structural strength,stiffness,and stability of the mechanism are analyzed via force and deformation simulations.By constructing a mathematical model of the support and positioning mechanism,the influence of structural deformation on the supporting capacity is analyzed and calculated.The robot positioning method based on the support and positioning mechanism can effectively locate the robot inside a spherical tank.Experiments verified the support performance and robot positioning accuracy of the mechanism.This research proposes an auxiliary support and positioning mechanism for a detection robot inside a spherical tank,which can effectively improve the positioning accuracy of the robot and meet the robotic inspection requirements.
文摘Polymerization of propylene was carried out under bulk process at 70 degrees C using the supported metallocene catalyst with four kinds of SiO2 as carrier with triethylaluminum used as cocatalyst. The morphology of the products was studied by SEM. It was found the property of the carriers gave great effect on the fine structure of the products as well as the apperance.
文摘Spherical pressure vessels in large sizes are generally supported on legs or columns evenly spaced around the circumference. The legs are attached at or near the equator of the sphere. This research work focussed on flexural-torsional buckling of beam-column supports of field fabricated spherical pressure vessels using finite element analysis. Flexuraltorsional buckling is an important limit state that must be considered in structural steel design and it occurs when a structural member experiences significant out-of-plane bending and twisting. This research has therefore considered the total potential energy equation for the flexural-torsional buckling of a beam-column element. The energy equation was formulated by summing the strain energy and the potential energy of the external loads. The finite element method was applied in conjunction with the energy method to analyze the flexural-torsional buckling of beam-column supports. To apply the finite element method, the displacement functions are assumed to be cubic polynomials, and the shape functions used to derive the element stiffness and element geometric stiffness matrices. The element stiffness and geometric stiffness matrices were assembled to obtain the global stiffness matrices of the structure. The final finite element equation obtained was in the form of an eigenvalue problem. The flexural-torsional buckling loads of the structure were determined by solving for the eigenvalue of the equation. The resulting eigenvalue equation from the finite element analysis was coded using FORTRAN 90 programming language to aid in the analysis process. To validate FORTRAN 90 coding developed for the finite element analysis and the methodology, the results given by the software were compared to existing solutions and showed no significant difference P > 0.05.
基金National Key R&D Program of China(grant No.2022YFA1503400)Lanzhou Petrochemical Research Center project,and Programs for Foreign Talent(grant No.G2021106012L).
文摘The pore structure of spherical alumina supports is closely related to the dispersion of catalytically active components and the diffusion of reactants.Maintaining excellent pore structure under strict reaction conditions is of utmost importance.In this work,sphericalγ-Al_(2)O_(3)support with a bimodal pore structure,composed of macropores and mesopores,was successfully synthesized using dodecane as the pore-forming agent through the oil–ammonia column-shaping method.The morphology and internal pore structure of the alumina were found to be influenced by the amount of surfactant added and ultrasound treatment conditions.Notably,when concentration of surfactant was 4‰and ultrasound voltage of 20 V was applied,the resultingγ-Al_(2)O_(3)-4‰-20 displayed a highly concentrated distribution of macropores with an average pore size of 100 nm,resulting in an impressive porosity of 69.21%.In contrast,the untreated sample ofγ-Al_(2)O_(3)-0-0 only exhibited a mesoporous distribution with a porosity of 54.03%.Moreover,after being subjected to a hydrothermal treatment in a high temperature(600°C)and high humidity(water vapor)environment for 120 h,theγ-Al_(2)O_(3)-4‰-20 sample maintained a high BET specific surface area of 170.9 m^(2)g^(−1)and mercury intrusion porosimetry specific surface area of 263.3 m^(2)g^(−1).
文摘Spherical MgCl 2 supported metallocene catalyst was prepared by supporting MAO on carrier which was prepared from MgCl 2 ·n EtOH.Ethylene polymerization was carried out by addition of MAO/MgCl 2,different metallocenes and alkylaluminum,in the absence of soluble MAO.It shows high activity for ethylene polymerization at lower Al/Zr(Al/Zr=45).The effect of concentration of Al( i Bu) 3 on polymerization activities and activation of Et(Ind) 2ZrCl 2 were studied.Kinetic behavior of ethylene polymerization on spherical MgCl 2 supported metallocene catalyst was investigated,which indicated the polymers obtained by reaction could affect the diffusion of ethylene in hexane under the experiment condidtion.Different aluminium alkyls have great impact on the whole polymerization behavior,and the relative reactivity decreases in the following order:Al( i Bu) 3>AlEt 3>AlMe 3>AlEt 2Cl,in which Al( i Bu) 3 shows the highest catalytic activity (5 78×10 7 g PE/mol\|Zr·h).
