Nuclear ?eld shift effects on stable isotope fractionation: a review

An anomalous isotope effect exists in many heavy element isotope systems （e.g., Sr, Gd, Zn, U）. This effect used to be called the ＂odd--even isotope effect＂ because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-indepen- dent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is cur- rently denoted as the nuclear field shift effect （NFSE）. It is found that the NFSE can drive isotope fractionation of some heavy elements （e.g., Hg, T1, U） to an astonishing degree, far more than the magnitude caused by the con- ventional mass-dependent effect （MDE）. For light ele- ments, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T2, while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect （KIE） and heavy isotope geochronology.

Experimental study of the effect of adipose stromal vascular fraction cells on the survival rate of fat transplantation

Objective To investigate the effect of adipose stromal vascular fraction cells(SVFs)on the survival rate of fat ransplantation.Methods 0.5mL autologous fat tissue was mixed with: ① DiI-labeled autologous SVFs (Group A);②

Phase transition in bilayer quantum Hall system with opposite magnetic field

We construct a mapped bilayer quantum Hall system to realize the proposal that two nearly flatbands have opposite Chern numbers.For the C=±1 case,the two Landau levels of the bilayer experience opposite magnetic fields.We consider a mapped bilayer quantum Hall system at total fillingν_(t)=1/2+1/2where the intralayer interaction is repulsive and the interlayer interaction is attractive.We take exact diagonalization(ED)calculations on a torus to study the phase transition when the separation distance d/l_(B)is driven.The critical point at d_(c)/l_(B)=0.68 is characterized by a collapse of degeneracy and a crossing of energy levels.In the region d/l_(B)<d_(c)/l_(B),the states of each level are highly degenerate.The pair-correlation function indicates electrons with opposite pseudo-spins are strong correlated at r=0.We find an exciton stripe phase composed of bound pairs.The ferromagnetic ground state is destroyed by the strong effective attractive potential.An electron composite-Fermion(eCF)and a hole composite Fermion(hCF)are tightly bound.In the region d/lB>d_(c)/l_(B),a crossover from the d→d_(c)limit to the large d limit is observed.The electron and hole composite Fermion liquids(CFL)are realized by composite Fermions(CF)which attach opposite fluxes,respectively.

Quark confinement and the fractional quantum Hall effect

Working in the physics of Wilson factor and Aharonov-Bohm effect, we find in the fluxtubequark system the topology of a baryon consisting of three heavy flavor quarks resembles that of the fractional quantum Hall effect （FQHE） in condensed matter. This similarity yields the result that the constituent quarks of baryon have the ＂filling factor＂ 1/3, thus the previous conjecture that quark confinement is a correlation effect is confirmed. Moreover, by deriving a Hamiltonian of the system analogous to that of FQHE, we predict an energy gap for the ground state of a heavy three-quark system.

Equilibrium and kinetic Si isotope fractionation factors and their implications for Si isotope distributions in the Earth's surface environments

Several important equilibrium Si isotope fractionation factors among minerals,organic molecules and the H_4SiO_4 solution are complemented to facilitate the explanation of the distributions of Si isotopes in Earth's surface environments.The results reveal that,in comparison to aqueous H_4SiO_4,heavy Si isotopes will be significantly enriched in secondary silicate minerals.On the contrary,quadra-coordinated organosilicon complexes are enriched in light silicon isotope relative to the solution.The extent of ^(28)Si-enrichment in hyper-coordinated organosilicon complexes was found to be the largest.In addition,the large kinetic isotope effect associated with the polymerization of monosilicic acid and dimer was calculated,and the results support the previous statement that highly ^(28)Sienrichment in the formation of amorphous quartz precursor contributes to the discrepancy between theoretical calculations and field observations.With the equilibrium Si isotope fractionation factors provided here,Si isotope distributions in many of Earth's surface systems can be explained.For example,the change of bulk soil δ^(30)Si can be predicted as a concave pattern with respect to the weathering degree,with the minimum value where allophane completely dissolves and the total amount of sesquioxides and poorly crystalline minerals reaches their maximum.When,under equilibrium conditions,the well-crystallized clays start to precipitate from the pore solutions,the bulk soil δ^(30)Si will increase again and reach a constant value.Similarly,the precipitation of crystalline smectite and the dissolution of poorly crystalline kaolinite may explain the δ^(30)Si variations in the ground water profile.The equilibrium Si isotope fractionations among the quadracoordinated organosilicon complexes and the H_4SiO_4solution may also shed light on the Si isotope distributions in the Si-accumulating plants.

Entanglement spectrum of non-Abelian anyons

Non-Abelian anyons can emerge as fractionalized excitations in two-dimensional systems with topological order. One important example is the Moore–Read fractional quantum Hall state. Its quasihole states are zero-energy eigenstates of a parent Hamiltonian, but its quasiparticle states are not. Both of them can be modeled on an equal footing using the bipartite composite fermion method. We study the entanglement spectrum of the cases with two or four non-Abelian anyons. The counting of levels in the entanglement spectrum can be understood using the edge theory of the Moore–Read state, which reflects the topological order of the system. It is shown that the fusion results of two non-Abelian anyons is determined by their distributions in the bipartite construction.

Sub-millikelvin station at Synergetic Extreme Condition User Facility

The Institute of Physics, Chinese Academy of Sciences, is in charge of the construction of the Synergetic Extreme Condition User Facility （SECUF） in Huairou, Beijing. The SECUF is a comprehensive facility focused on providing extreme physical conditions for scientific research, including an ultralow temperature, ultrahigh pressure, ultrahigh magnetic field, and ultrafast laser. The ultralow temperature will be realized by the sub-millikelvin （sub-mK） station, whose main component is an adiabatic nuclear demagnetization refrigerator （ANDR）. The refrigerator is designed to have a base temperature below 1 mK and a magnetic field up to 16 T for experiments, as well as a characteristic parameter of B/T ≥-104 T/K. In this review, we introduce adiabatic nuclear demagnetization refrigeration, thermometry from 10 mK to sub-mK, the properties and parameters of the ANDR of the SECUF, and related prospective research topics.

The Integer-Fraction Principle of the Digital Electric Charge for Quarks and Quasiparticles

In the integer-fraction principle of the digital electric charge, individual integral charge and individual fractional charge are the digital representations of the allowance and the disallowance of irreversible kinetic energy, respectively. The disallowance of irreversible kinetic energy for individual fractional charge brings about the confinement of individual fractional charges to restrict irreversible movement resulted from irreversible kinetic energy. Collective fractional charges are confined by the short-distance confinement force field where the sum of the collective fractional charges is integer. As a result, fractional charges are confined and collective. The confinement force field includes gluons in QCD (quantum chromodynamics) for collective fractional charge quarks in hadrons and the magnetic flux quanta for collective fractional charge quasiparticles in the fractional quantum Hall effect (FQHE). The collectivity of fractional charges requires the attachment of energy as flux quanta to bind collective fractional charges. The integer-fraction transformation from integral charges to fractional charges consists of the three steps: 1) the attachment of an even number of flux quanta to individual integral charge fermions to form individual integral charge composite fermions, 2) the attachment of an odd number of flux quanta to individual integral charge composite fermions to form transitional collective integral charge composite bosons, and 3) the conversion of flux quanta into the confinement force field to confine collective fractional charge composite fermions converted from composite bosons. The charges of quarks are fractional, because QCD (the strong force) emerges in the universe that has no irreversible kinetic energy. Kinetic energy emerged in the universe after the emergence of the strong force. The charges of the quasiparticles in the FQHE are fractional because of the confinement by a two-dimensional system, the Landau levels, and an extremely low temperature and the collectivity by high energy magnetic flux quanta. From the integer-fraction transformation from integral charge electrons to fractional charge quarks, the calculated masses of pion, muon and constituent quarks are in excellent agreement with the observed values.

Simultaneous determination of seven active components in n-butanol effective fraction of Xiao Chai Hu Tang by HPLC-DAD-ELSD

An HPLC-DAD-ELSD method was developed and validated for the simultaneous quantitation of seven active components（liquiritin, baicalin, wogonoside, baicalein, wogonin, ginsenosides Re and ginsenosides Rb1） in n-butanol effective fraction of Xiao Chai Hu Tang. A Diamonsil C18（2） column（4.6 mm × 250 mm, 5 μm） was used as the stationary phase and the mobile phase was consisted of acetonitrile and aqueous phosphate acid（0.05%, v/v）. Gradient elution was carried out at the flow rate of 1 m L/min. The detection wavelength was set at 276 nm and an evaporative light scattering detector was also used. Good linearity for all the seven active components was observed. The established method is simple, fast, reliable, and suitable for the quality control of n-butanol effective fraction of Xiao Chai Hu Tang.

Biomechanical Experimental Study on Effective Fraction of Radix Salviae Miltiorrhizae on Healing of Bone Fracture

Objective: To assess the effect of Danshen 9403 (DS 9403), an effective fraction of Radix Salviae miltiorrhizae (RSM) on healing of bone fracture. Methods: Standardized radial fracture was performed in 120 Wistar rats. The model rats were randomized into four groups: Group A was fed with DS 9403, group B injected with Staphylococcus aureus , group C with normal saline administration, and group D with RSM injection. The treatment began at the first day of fracture. The rats were sacrificed on the day 25, 39 and 50 separately in batches and their intact radii were removed by dissection for detecting load and stress of three point bending test with autograph universal material testing machine (Shimazu, Japan). Results: The parameters of load in DS 9403 treated group on the 39th day and that of stress at 25th, 39th and 50th day were (6.20±1.32)N, (5.71±3.58)N/mm 2, (8.27±2.42)N/mm 2 and (66.25±26.21)N/mm 2 respectively, which were significantly higher than those in other groups, P <0.05. Conclusion: DS 9403 has the action of increasing the strength of fracture broken end.

Measurements of effective delayed neutron fraction in a fast neutron reactor using the perturbation method

A perturbation method is proposed to obtain the effective delayed neutron fraction βeff of a cylindrical highly enriched uranium reactor. Based on reactivity measurements with and without a sample at a specified position using the positive period technique, the reactor reactivity perturbation Ap of the sample in βeff units is measured. Simulations of the perturbation experiments are performed using the MCNP program. The PERT card is used to provide the difference dk of effective neutron multiplication factors with and without the sample inside the reactor. Based on the relationship between the effective multiplication factor and the reactivity, the equation βeff=dk/△ρ is derived. In this paper, the reactivity perturbations of 13 metal samples at the designable position of the reactor are measured and calculated. The average βeff value of the reactor is given as 0.00645, and the standard uncertainty is 3.0%. Additionally, the perturbation experiments for fleer can be used to evaluate the reliabilities of the delayed neutron parameters. This work shows that the delayed neutron data of 235U and 23SU froin G.R. Keepin＇s publication are more reliable than those from ENDF-B6.0, ENDF-B7.0, JENDL3.3 and CENDL2.2.

THE EFFECTS OF THE ETHANOLIC FRACTION OF CORIOLUS VERSICOLOR ON THE A549 NON-SMALL-CELL LUNG CANCER CELL LINE

Coriolus versicolor has demonstrated anti-cancer effects via polysaccharide-peptides(PSP)and polysaccharide Krestin(PSK).However,many other bioactive compounds within Coriolus versicolor(CV)may not have been identified.Our primary focus was to determine whether the ethanolic extract of Coriolus versicolor demonstrated any anti-cancer effects.The crude ethanolic extract was utilized,as was

Improvement of in situ LA-ICP-MS U-Pb dating method for carbonate minerals and its application in petroleum geology

In situ carbonate U-Pb dating is gaining popularity,and it has great potential for application in petroleum geology.However,the low U content(<10μg/g)and high common Pb content of carbonate minerals,along with the uneven distribution of U and Pb and the lack of matrix-matched reference material make carbonate U-Pb dating inaccurate and less successful,which limits the widespread application in geosciences.This study evaluated the limitations of in situ carbonate U-Pb dating and proposed a method to rationally determine the laser ablation parameters of samples by improving the experimental approach based on the laser ablation sector field inductively coupled plasma mass spectrometry(LA-SF-ICP-MS).By setting a different spot size and laser frequency for the reference material and unknown samples in the same session based on the U content of the sample,the ablation craters of the reference material and unknown samples were given the same depth/width ratio,avoiding systematic offset caused by differences in down-hole element fractionation and reducing the consume of reference material.Depending on the heterogeneous distribution of U and Pb contents in carbonate minerals,the method of grid screening and setting ablation spots during screening were used to quickly select domains with high U and low common Pb,which improves the efficiency of setting laser spots and the success rate of dating,as well as reduces the experimental time and economic cost.The accuracy and success rate of carbonate U-Pb dating were effectively improved by improving the experimental method,and the technique was applied to two carbonate samples with low U and high common Pb contents that were difficult to date by traditional methods.The two samples are the saddle dolomite in the central Sichuan Basin and the calcite cement in the sandstone reservoir of the Cretaceous Qingshuihe Formation in the South Junggar Basin.The robust ages have been obtained,which constrains the timing of the diagenetic and hydrocarbon accumulation process in the studied area.