During the last decade, metal-organic frameworks(MOFs) have been applied in various fields due to their unique chemical and functional advantages. One of the widespread research hotspots is MOF-based membranes for sep...During the last decade, metal-organic frameworks(MOFs) have been applied in various fields due to their unique chemical and functional advantages. One of the widespread research hotspots is MOF-based membranes for separations, specifically continuous defect-free MOF membranes, which are usually grown on porous substrates. The substrate not only serves as the MOF layer support but also has a great influence on the membrane fabrication process and the final separation performance of the resultant membrane. In this review, we mainly introduce the progress focused on the substrates for MOF membranes fabrication. The substrate modifications and seeding methods aimed at synthesizing highquality MOF membranes are also summarized systematically.展开更多
Metal-organic frameworks(MOFs),which are self-assembled porous coordination materials,have garnered considerable attention in the fields of optoelectronics,photovoltaic,photochemistry,and photocatalysis due to their d...Metal-organic frameworks(MOFs),which are self-assembled porous coordination materials,have garnered considerable attention in the fields of optoelectronics,photovoltaic,photochemistry,and photocatalysis due to their diverse structures and excellent tunability.However,the performance of MOF-based optoelectronic applications currently falls short of the industry benchmark.To enhance the performance of MOF materials,it is imperative to undertake comprehensive investigations aimed at gaining a deeper understanding of photophysics and sequentially optimizing properties related to photocarrier transport,recombination,interaction,and transfer.By utilizing femtosecond laser pulses to excite MOFs,time-resolved optical spectroscopy offers a means to observe and characterize these ultrafast microscopic processes.This approach adds the time coordinate as a novel dimension for comprehending the interaction between light and MOFs.Accordingly,this review provides a comprehensive overview of the recent advancements in the photophysics of MOFs and additionally outlines potential avenues for exploring the time domain in the investigation of MOFs.展开更多
Purpose:This paper reports on a scientometric analysis bolstered by human-in-the-loop,domain experts,to examine the field of metal-organic frameworks(MOFs)research.Scientometric analyses reveal the intellectual landsc...Purpose:This paper reports on a scientometric analysis bolstered by human-in-the-loop,domain experts,to examine the field of metal-organic frameworks(MOFs)research.Scientometric analyses reveal the intellectual landscape of a field.The study engaged MOF scientists in the design and review of our research workflow.MOF materials are an essential component in next-generation renewable energy storage and biomedical technologies.The research approach demonstrates how engaging experts,via human-in-the-loop processes,can help develop a comprehensive view of a field’s research trends,influential works,and specialized topics.Design/methodology/approach:Ascientometric analysis was conducted,integrating natural language processing(NLP),topic modeling,and network analysis methods.The analytical approach was enhanced through a human-in-the-loop iterative process involving MOF research scientists at selected intervals.MOF researcher feedback was incorporated into our method.The data sample included 65,209 MOF research articles.Python3 and software tool VOSviewer were used to perform the analysis.Findings:The findings demonstrate the value of including domain experts in research workflows,refinement,and interpretation of results.At each stage of the analysis,the MOF researchers contributed to interpreting the results and method refinements targeting our focus Research evolution of metal organic frameworks:A scientometric approach with human-in-the-loop on MOF research.This study identified influential works and their themes.Our findings also underscore four main MOF research directions and applications.Research limitations:This study is limited by the sample(articles identified and referenced by the Cambridge Structural Database)that informed our analysis.Practical implications:Our findings contribute to addressing the current gap in fully mapping out the comprehensive landscape of MOF research.Additionally,the results will help domain scientists target future research directions.Originality/value:To the best of our knowledge,the number of publications collected for analysis exceeds those of previous studies.This enabled us to explore a more extensive body of MOF research compared to previous studies.Another contribution of our work is the iterative engagement of domain scientists,who brought in-depth,expert interpretation to the data analysis,helping hone the study.展开更多
Unsatisfactory conductivity and volume effects have hindered the commercial application of siliconbased materials as advanced anode materials for high-performance lithium-ion batteries. Herein, nitrogen doped carbon s...Unsatisfactory conductivity and volume effects have hindered the commercial application of siliconbased materials as advanced anode materials for high-performance lithium-ion batteries. Herein, nitrogen doped carbon silicon matrix composite with atomically dispersed Co sites(Si/Co-N-C) is obtained via the design of the frame structure loaded with nano-components and the multi-element hybrid strategy. Co atoms are uniformly fixed to the N-C frame and tightly packed with nanoscale silicon particles as an activation and protection building block. The mechanism of the N-C framework of loaded metal Co in the Si alloying process is revealed by electrochemical kinetic analysis and ex situ characterization tests.Impressively, the nitrogen-doped Co site activates the intercalation of the outer carbon matrix to supplement the additional capacity. The Co nanoparticles with high conductivity and support enhance the conductivity and structural stability of the composite, accelerating the Li^(+)/Na^(+) diffusion kinetics. Density functional theory(DFT) calculation confirms that the hetero-structure Si/Co-N-C adjusts the electronic structure to obtain good lithium-ion adsorption energy, reduces the Li^(+)/Na^(+) migration energy barrier.This work provides meaningful guidance for the development of high-performance metal/non-metal modified anode materials.展开更多
基金the funding from the National Natural Science Foundation of China (22078107, 22022805)the National Key Research and Development Program (2021YFB3802500)。
文摘During the last decade, metal-organic frameworks(MOFs) have been applied in various fields due to their unique chemical and functional advantages. One of the widespread research hotspots is MOF-based membranes for separations, specifically continuous defect-free MOF membranes, which are usually grown on porous substrates. The substrate not only serves as the MOF layer support but also has a great influence on the membrane fabrication process and the final separation performance of the resultant membrane. In this review, we mainly introduce the progress focused on the substrates for MOF membranes fabrication. The substrate modifications and seeding methods aimed at synthesizing highquality MOF membranes are also summarized systematically.
基金Project supported by the Science Challenge Project(Grant No.TZ2018001)the National Natural Science Foundation of China(Grant Nos.11872058 and 21802036)the Project of State Key Laboratory of Environment-friendly Energy Materials,and Southwest University of Science and Technology(Grant No.21fksy07)。
文摘Metal-organic frameworks(MOFs),which are self-assembled porous coordination materials,have garnered considerable attention in the fields of optoelectronics,photovoltaic,photochemistry,and photocatalysis due to their diverse structures and excellent tunability.However,the performance of MOF-based optoelectronic applications currently falls short of the industry benchmark.To enhance the performance of MOF materials,it is imperative to undertake comprehensive investigations aimed at gaining a deeper understanding of photophysics and sequentially optimizing properties related to photocarrier transport,recombination,interaction,and transfer.By utilizing femtosecond laser pulses to excite MOFs,time-resolved optical spectroscopy offers a means to observe and characterize these ultrafast microscopic processes.This approach adds the time coordinate as a novel dimension for comprehending the interaction between light and MOFs.Accordingly,this review provides a comprehensive overview of the recent advancements in the photophysics of MOFs and additionally outlines potential avenues for exploring the time domain in the investigation of MOFs.
文摘Purpose:This paper reports on a scientometric analysis bolstered by human-in-the-loop,domain experts,to examine the field of metal-organic frameworks(MOFs)research.Scientometric analyses reveal the intellectual landscape of a field.The study engaged MOF scientists in the design and review of our research workflow.MOF materials are an essential component in next-generation renewable energy storage and biomedical technologies.The research approach demonstrates how engaging experts,via human-in-the-loop processes,can help develop a comprehensive view of a field’s research trends,influential works,and specialized topics.Design/methodology/approach:Ascientometric analysis was conducted,integrating natural language processing(NLP),topic modeling,and network analysis methods.The analytical approach was enhanced through a human-in-the-loop iterative process involving MOF research scientists at selected intervals.MOF researcher feedback was incorporated into our method.The data sample included 65,209 MOF research articles.Python3 and software tool VOSviewer were used to perform the analysis.Findings:The findings demonstrate the value of including domain experts in research workflows,refinement,and interpretation of results.At each stage of the analysis,the MOF researchers contributed to interpreting the results and method refinements targeting our focus Research evolution of metal organic frameworks:A scientometric approach with human-in-the-loop on MOF research.This study identified influential works and their themes.Our findings also underscore four main MOF research directions and applications.Research limitations:This study is limited by the sample(articles identified and referenced by the Cambridge Structural Database)that informed our analysis.Practical implications:Our findings contribute to addressing the current gap in fully mapping out the comprehensive landscape of MOF research.Additionally,the results will help domain scientists target future research directions.Originality/value:To the best of our knowledge,the number of publications collected for analysis exceeds those of previous studies.This enabled us to explore a more extensive body of MOF research compared to previous studies.Another contribution of our work is the iterative engagement of domain scientists,who brought in-depth,expert interpretation to the data analysis,helping hone the study.
基金Research and Development Plan Project in Key Fields of Guangdong Province (2020B0101030005)Basic and Applied Basic Research Fund of Guangdong Province (2019B1515120027)+1 种基金Scientific Research Innovation Project of Graduate School of South China Normal University (2024KYLX050)Special Funds for the Cultivation of Guangdong College Students’ Scientific and Technological Innovation (“Climbing Program” Special Funds, pdjh2024a109)。
文摘Unsatisfactory conductivity and volume effects have hindered the commercial application of siliconbased materials as advanced anode materials for high-performance lithium-ion batteries. Herein, nitrogen doped carbon silicon matrix composite with atomically dispersed Co sites(Si/Co-N-C) is obtained via the design of the frame structure loaded with nano-components and the multi-element hybrid strategy. Co atoms are uniformly fixed to the N-C frame and tightly packed with nanoscale silicon particles as an activation and protection building block. The mechanism of the N-C framework of loaded metal Co in the Si alloying process is revealed by electrochemical kinetic analysis and ex situ characterization tests.Impressively, the nitrogen-doped Co site activates the intercalation of the outer carbon matrix to supplement the additional capacity. The Co nanoparticles with high conductivity and support enhance the conductivity and structural stability of the composite, accelerating the Li^(+)/Na^(+) diffusion kinetics. Density functional theory(DFT) calculation confirms that the hetero-structure Si/Co-N-C adjusts the electronic structure to obtain good lithium-ion adsorption energy, reduces the Li^(+)/Na^(+) migration energy barrier.This work provides meaningful guidance for the development of high-performance metal/non-metal modified anode materials.
