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Free Vibration Analysis of Symmetrically Laminated Composite Plates on Elastic Foundation and Coupled with Stationary Fluid 被引量:1
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作者 Arash SHAHBAZTABAR Ahmad RAHBAR-RANJI 《China Ocean Engineering》 SCIE EI CSCD 2018年第3期266-277,共12页
Free vibration analysis of symmetrically laminated composite plates resting on Pasternak elastic support and coupled with an ideal, incompressible and inviscid fluid is the objective of the present work. The fluid dom... Free vibration analysis of symmetrically laminated composite plates resting on Pasternak elastic support and coupled with an ideal, incompressible and inviscid fluid is the objective of the present work. The fluid domain is considered to be infinite in the length direction but bounded in the depth and width directions. In order to derive the eigenvalue equation, Rayleigh-Ritz method is applied for the fluid-plate-foundation system. The efficiency of the method is proved by comparison studies with those reported in the open literature. At the end, parametric studies are carried out to examine the impact of different parameters on the natural frequencies. 展开更多
关键词 free vibration analysis laminated composite plate fluid-plate-foundation interaction Rayleigh-Ritz method Pasternak foundation
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Static and free vibration analysis of four-parameter continuous grading elliptical sandwich plates
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作者 M.H.YAS F.AKHLAGHI +1 位作者 S.KAMARIAN A.H.YAS 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第4期523-536,共14页
In the present study,the static and dynamic analyses of elliptical functionally graded sandwich(FGS)plates are investigated.The constituent materials of the sandwich plates are ceramic and metal so that the core is ma... In the present study,the static and dynamic analyses of elliptical functionally graded sandwich(FGS)plates are investigated.The constituent materials of the sandwich plates are ceramic and metal so that the core is made of pure metal,while the face sheets consist of a combination of metal and ceramic according to a four-parameter power-law distribution.Different material profiles such as classic,symmetric,and asymmetric can be obtained using the applied generalized power-law distribution relation.The analysis is performed based on the classical laminated plate theory(CLPT)and the Ritz method.The effects of four parameters in the material distribution relation as well as different geometric parameters on the deflection and natural frequencies of elliptical FGS plates are studied.The results of this study show that with a proper distribution of materials,the optimal static and dynamic behavior can be achieved.The results also indicate that the generalized power-law distribution has significant effects on the natural frequencies of elliptical FGS plates.For example,although the frequency parameter of a plate with ceramic face sheets is more than the one with metal face sheets,the use of larger amounts of ceramic does not necessarily increase the natural frequency of the structure. 展开更多
关键词 elliptical plate sandwich plate four-parameter power-law distribution static analysis free vibration analysis Ritz method
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Nonlinear free vibration analysis of piezoelastic laminated plates with interface damage
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作者 傅衣铭 李升 姜叶洁 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第2期129-144,共16页
This paper presents a nonlinear model for piezoelastic laminated plates with damage effect of the intra-layers and inter-laminar interfaces. Discontinuity of displacement and electric potential on the interfaces are d... This paper presents a nonlinear model for piezoelastic laminated plates with damage effect of the intra-layers and inter-laminar interfaces. Discontinuity of displacement and electric potential on the interfaces are depicted by three shape functions. By using the Hamilton variation principle, the three-dimensional nonlinear dynamic equations of piezoelastic laminated plates with damage effect are derived. Then, by using the Galerkin method, a mathematical solution is presented. In the numerical studies, effects of various factors on the natural frequencies and nonlinear amplitude-frequency response of the simply-supported peizoelastic laminated plates with interfacial imperfections are discussed. These factors include different damage models, thickness of the piezoelectric layer, side-to-thickness ratio, and length-to-width ratio. 展开更多
关键词 piezoelastic laminated plates nonlinear free vibration analysis interfacial damage damage evolution the Galerkin method
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Free Vibration Analysis of Rectangular Plate with Cutouts under Elastic Boundary Conditions in Independent Coordinate Coupling Method
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作者 Qiuhong Li Wenhao Huang +3 位作者 Joey Sanchez Ping Wang Qiang Ding Jiufa Wang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第3期2093-2121,共29页
Based on Kirchhoff plate theory and the Rayleigh-Ritz method,the model for free vibration of rectangular plate with rectangular cutouts under arbitrary elastic boundary conditions is established by using the improved ... Based on Kirchhoff plate theory and the Rayleigh-Ritz method,the model for free vibration of rectangular plate with rectangular cutouts under arbitrary elastic boundary conditions is established by using the improved Fourier series in combination with the independent coordinate coupling method(ICCM).The effect of the cutout is taken into account by subtracting the energies of the cutouts from the total energies of the whole plate.The vibration displacement function of the hole domain is based on the coordinate system of the hole domain in this method.From the continuity condition of the vibration displacement function at the cutout,the transition matrix between the two coordinate systems is constructed,and the mass and stiffness matrices are completely obtained.As a result,the calculation is simplified and the computational efficiency of the solution is improved.In this paper,numerical examples and modal experiments are presented to validate the effectiveness of the modeling methods,and parameters related to influencing factors of the rectangular plate are analyzed to study the vibration characteristics. 展开更多
关键词 Rectangular plate with cutouts the independent coordinate coupling method elastic boundary conditions free vibration analysis
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Finite element analysis of functionally graded sandwich plates with porosity via a new hyperbolic shear deformation theory 被引量:2
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作者 Pham Van Vinh Le Quang Huy 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第3期490-508,共19页
This study focusses on establishing the finite element model based on a new hyperbolic sheareformation theory to investigate the static bending,free vibration,and buckling of the functionally graded sandwich plates wi... This study focusses on establishing the finite element model based on a new hyperbolic sheareformation theory to investigate the static bending,free vibration,and buckling of the functionally graded sandwich plates with porosity.The novel sandwich plate consists of one homogenous ceramic core and two different functionally graded face sheets which can be widely applied in many fields of engineering and defence technology.The discrete governing equations of motion are carried out via Hamilton’s principle and finite element method.The computation program is coded in MATLAB software and used to study the mechanical behavior of the functionally graded sandwich plate with porosity.The present finite element algorithm can be employed to study the plates with arbitrary shape and boundary conditions.The obtained results are compared with available results in the literature to confirm the reliability of the present algorithm.Also,a comprehensive investigation of the effects of several parameters on the bending,free vibration,and buckling response of functionally graded sandwich plates is presented.The numerical results shows that the distribution of porosity plays significant role on the mechanical behavior of the functionally graded sandwich plates。 展开更多
关键词 Functionally graded sandwich plates Porous plates Hyperbolic shear deformation theory Bending analysis free vibration analysis Buckling analysis
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Computational mission analysis and conceptual system design for super low altitude satellite 被引量:1
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作者 Ming Xu Jinlong Wang Nan Zhou 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2014年第1期43-58,共16页
This paper deals with system engineering and design methodology for super low altitude satel ites in the view of the com-putational mission analysis. Due to the slight advance of imaging instruments, such as the focus... This paper deals with system engineering and design methodology for super low altitude satel ites in the view of the com-putational mission analysis. Due to the slight advance of imaging instruments, such as the focus of camera and the image element of charge coupled device (CCD), it is an innovative and economical way to improve the camera’s resolution to enforce the satel ite to fly on the lower altitude orbit. DFH-3, the mature satel ite bus de-veloped by Chinese Academy of Space Technology, is employed to define the mass and power budgets for the computational mis-sion analysis and the detailed engineering design for super low altitude satel ites. An effective iterative algorithm is proposed to solve the ergodic representation of feasible mass and power bud-gets at the flight altitude under constraints. Besides, boundaries of mass or power exist for every altitude, where the upper boundary is derived from the maximum power, while the minimum thrust force holds the lower boundary before the power reaching the initial value. What’s more, an analytical algorithm is employed to numerical y investigate the coverage percentage over the altitude, so that the nominal altitude could be selected from al the feasi-ble altitudes based on both the mass and power budgets and the repetitive ground traces. The local time at the descending node is chosen for the nominal sun-synchronous orbit based on the average evaluation function. After determining the key orbital ele-ments based on the computational mission analysis, the detailed engineering design on the configuration and other subsystems, like power, telemetry telecontrol and communication (TT&amp;C), and attitude determination and control system (ADCS), is performed based on the benchmark bus, besides, some improvements to the bus are also implemented to accommodate the flight at a super low altitude. Two operation strategies, drag-free closed-loop mode and on/off open-loop mode, are presented to maintain the satel-lite’s altitude. Final y, a flight planning schedule for the satel ite is demonstrated from its launch into the initial altitude at the very beginning to its decay to death in the end. 展开更多
关键词 super low altitude computational mission analysis drag free control mass and power budget.
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Historical relationships of the Mesoamerican highlands,with emphasis on tropical montane cloud forests:a temporal cladistic biogeographical analysis
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作者 CASTRO-TORREBLANCA Marisol ESPINOSA David +1 位作者 BUENO-HERNANDEZ Alfredo LUNA-VEGA Isolda 《Journal of Mountain Science》 SCIE CSCD 2023年第1期129-140,共12页
The historical relationships of nine areas of endemism of the tropical montane cloud forests(TMCFs)were analysed based on a temporal cladistic biogeographical approach.Three cladistic biogeographical analyses were con... The historical relationships of nine areas of endemism of the tropical montane cloud forests(TMCFs)were analysed based on a temporal cladistic biogeographical approach.Three cladistic biogeographical analyses were conducted based on 29cladograms of terrestrial taxa by partitioning them into three time-slices,namely,Miocene,Pliocene,and Pleistocene.The results showed different area relationships over time.For the Miocene and Pliocene time slices,the Isthmus of Tehuantepec acted as a geographic barrier that fragmented the TMCFs into two portions:west of the Isthmus and east of the Isthmus.In the case of the Pleistocene,the TMCFs were broken into two portions,one related to the Neotropical region and the other to the Nearctic region.Furthermore,the analyses allowed us to detect the influences of different geological and paleoclimatological events on the distribution of the TMCFs over time.Therefore,the TMCFs current distribution might have been driven by geological events during the Miocene-Pliocene,whereas climatic fluctuations have the highest impact during the Pleistocene. 展开更多
关键词 Dispersal Evolutionary biogeography Paralogy free subtree analysis VICARIANCE
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AN EXACT SYMPLECTIC SOLUTION FOR THE DYNAMIC ANALYSIS OF SHEAR DEFORMABLE ANTISYMMETRIC ANGLE-PLY LAMINATED PLATES
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作者 Zou Guiping (Department of Engineering Mechanics,Tongji University,Shanghai 200092) 《Acta Mechanica Solida Sinica》 SCIE EI 1996年第3期263-273,共11页
From the mixed variational principle, by the selection of the state variables and its dual variables, the Hamiltonian canonical equation for the dynamic analysis of shear deformable antisymmetric angle-ply laminated p... From the mixed variational principle, by the selection of the state variables and its dual variables, the Hamiltonian canonical equation for the dynamic analysis of shear deformable antisymmetric angle-ply laminated plates is derived, leading to the mathematical frame of symplectic geometry and algorithms, and the exact solution for the arbitrary boundary conditions is also derived by the adjoint orthonormalized symplectic expansion method. Numerical results are presented with the emphasis on the effects of length/thickness ratio, arbitrary boundary conditions, degrees of anisotropy, number of layers, ply-angles and the corrected coefficients of transverse shear. 展开更多
关键词 Hamilton canonical equation SYMPLECTIC free vibration analysis antisymmetric angle-ply laminated plates
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Comparison of methods for vibration analysis of electrostatic precipitators
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作者 Iwona Adamiec-Wójcik Andrzej Nowak Stanisaw Wojciech 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第1期72-79,共8页
The paper presents two methods for the formulation of free vibration analysis of collecting electrodes of precipitators.The first,called the hybrid finite element method, combines the finit element method used for cal... The paper presents two methods for the formulation of free vibration analysis of collecting electrodes of precipitators.The first,called the hybrid finite element method, combines the finit element method used for calculations of spring deformations with the rigid finite element method used to reflect mass and geometrical features,which is called the hybrid finite element method.As a result,a model with a diagonal mass matrix is obtained.Due to a specific geometry of the electrodes,which are long plates of complicated shapes,the second method proposed is the strip method which is a semi-analytical method.The strip method allows us to formulate the equations of motion with a considerably smaller number of generalized coordinates.Results of numerical calculations obtained by both methods are compared with those obtained using commercial software like ANSYS and ABAQUS.Good compatibility of results is achieved. 展开更多
关键词 Finite element method · Rigid finite element method · Strip method · free vibration analysis · Electrostatic precipitators
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Dynamic Response Analysis of A 5 MW NREL Wind Turbine Blade under Flap-Wise and Edge-Wise Vibrations
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作者 Amna Algolfat Weizhuo Wang Alhussein Albarbar 《Journal of Dynamics, Monitoring and Diagnostics》 2022年第4期208-222,共15页
A wind turbine is subjected to a regime of varying loads.For example,each rotor revolution causes a complete gravity stress reversal in the low-speed shaft,and there are varying stresses from the out-of-plane loading ... A wind turbine is subjected to a regime of varying loads.For example,each rotor revolution causes a complete gravity stress reversal in the low-speed shaft,and there are varying stresses from the out-of-plane loading cycle due to fluctuating wind load.Consequently,wind turbine blade design is governed by fatigue rather than ultimate load considerations.Previous studies have adopted many different beam theories,using different techniques and codes,to model the National Renewable Energy Laboratory(NREL)5MWoffshore wind turbine blade.There are differences,from study to study,in the free vibration results and the dynamic response.The contribution of this study is to apply the code written by the authors to the different beam theories used with the aim of comparing the different beam theories presented in the literature and that developed by the authors.This paper reports the investigation of the effects of deformation parameters on the dynamic characteristics of the NREL 5 MW offshore wind turbine blades predicted by the different beam theories.The investigation of free vibrations is a fundamental step in the analysis of structural dynamics,and this study compares different computational structural methods and investigates their effect on the predicted dynamic response.The modal characteristics of every model examined have been combined with strip theory to determine the dynamic response of the blade. 展开更多
关键词 blade dynamic response edge-wise vibration free vibration analysis flap-wise vibration wind turbine vibration
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FINITE STRIP DYNAMIC ANALYSIS OF CYLINDRICAL SHELL SANDWICH STRUCTURES 被引量:1
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作者 Hu Xuanli, Chen Hualing Xi’ an Jiaotong University Wauer J . Institut fur Technische Mechanik, Universitat Karlsrube , Germany 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 1997年第2期141-147,共3页
A rectangular, singly curved and finite strip element for curved sandwich dynamic analysis is developed. The convergence and speed of the method, the strip element density and the reduction of the degrees of freedom e... A rectangular, singly curved and finite strip element for curved sandwich dynamic analysis is developed. The convergence and speed of the method, the strip element density and the reduction of the degrees of freedom etc . are discussed through free vibration analysis of a honeycomb cylindrical shell pan-el. The results show that the frequencies and modal shapes obtained agree very well with the analytical solutions for the symmetrical honeycomb sandwich under the simply supported end conditions. 展开更多
关键词 Sandwich honeycomb Cylindrical shell Finite strip analysis free vibration
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Exact free vibration analysis of open circular cylindrical shells by the method of reverberation-ray matrix 被引量:2
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作者 Xiong-liang YAO Dong TANG +1 位作者 Fu-zhen PANG Shuo LI 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2016年第4期295-316,共22页
This paper is concerned with the free vibration analysis of open circular cylindrical shells with either the two straight edges or the two curved edges simply supported and the remaining two edges supported by arbitra... This paper is concerned with the free vibration analysis of open circular cylindrical shells with either the two straight edges or the two curved edges simply supported and the remaining two edges supported by arbitrary classical boundary conditions. Based on the Donnell-Mushtari-Vlasov thin shell theory, an analytical solution of the traveling wave form along the simply supported edges and the modal wave form along the remaining two edges is obtained. With such a unidirectional traveling wave form solution, the method of the reverberation-ray matrix is introduced to derive the equation of natural frequencies of the shell with different classical boundary conditions. The exact solutions for natural frequencies of the open circular cylindrical shell are obtained with the employment of a golden section search algorithm. The calculation results are compared with those obtained by the finite element method and the methods in the available literature. The influence of length, thickness, radius, included angle, and the boundary conditions of the open circular cylindrical shell on the natural frequencies is investigated. The exact calculation results can be used as benchmark values for researchers to check their numerical methods and for engineers to design structures with thin shell components. 展开更多
关键词 Open circular cylindrical shell Method of reverberation-ray matrix free vibration analysis Donnell-Mushtari- Vlasov thin shell theory Analytical wave form solution
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Numerical study of mono-crystalline silicon solar cells with passivated emitter and rear contact configuration for the efficiency beyond 24% based on mass production technology 被引量:2
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作者 Peng Wang Gaofei Li +6 位作者 Miao Wang Hong Li Jing Zheng Liyou Yang Yigang Chen Dongdong Li Linfeng Lu 《Journal of Semiconductors》 EI CAS CSCD 2020年第6期78-84,共7页
Mono-crystalline silicon solar cells with a passivated emitter rear contact(PERC)configuration have attracted extensive attention from both industry and scientific communities.A record efficiency of 24.06%on p-type si... Mono-crystalline silicon solar cells with a passivated emitter rear contact(PERC)configuration have attracted extensive attention from both industry and scientific communities.A record efficiency of 24.06%on p-type silicon wafer and mass production efficiency around 22%have been demonstrated,mainly due to its superior rear side passivation.In this work,the PERC solar cells with a p-type silicon wafer were numerically studied in terms of the surface passivation,quality of silicon wafer and metal electrodes.A rational way to achieve a 24%mass-production efficiency was proposed.Free energy loss analyses were adopted to address the loss sources with respect to the limit efficiency of 29%,which provides a guideline for the design and manufacture of a high-efficiency PERC solar cell. 展开更多
关键词 monocrystalline silicon solar cell passivated emitter rear contact numerical simulation free energy loss analysis
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Surrogate potency assays:Comparison of binding profiles complements dose response curves for unambiguous assessment of relative potencies 被引量:1
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作者 Robert Karlsson Veronica Fridh Asa Frostell 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2018年第2期138-146,共9页
Surface plasmon resonance(SPR) systems are widely used for detailed characterization of antibody activities including antigen and Fc-receptor binding. During the later stages of development, where the focus is to ensu... Surface plasmon resonance(SPR) systems are widely used for detailed characterization of antibody activities including antigen and Fc-receptor binding. During the later stages of development, where the focus is to ensure that established critical quality attributes(CQAs) are maintained during cell culture,purification and formulation processes, analysis is simplified, and relative potencies are often determined. Here, simulation of binding data revealed that relative potency values, determined via parallel line analysis(PLA) and half maximal effective concentration(EC50) analysis accurately reflect changes in active concentration only if binding kinetics remain unchanged. Changes in the association rate constant shifted dose response curves, and therefore relative potencies, in the same way as changes in analyte concentration do. However, for interactions characterized by stable binding, changes in the dissociation rate constant did not result in any shift, suggesting that this type of change may go unnoticed in the dose response curve. Thus, EC50 and PLA analyses of dose response curves obtained with an anti-TNF-α antibody were complemented with the Biacore functionality for sensorgram comparison analysis, whereby changes in antigen and Fc-receptor binding profiles could be detected. Next, analysis of temperature stressed TNF-α antibody revealed that calibration free concentration analysis(CFCA) data correlated perfectly with relative potency values. Together, these results demonstrate that combinations of SPR based dose response curves, sensorgram comparison and CFCA can be used to strengthen the confidence in relative potency assessments, and suggest that SPR can potentially be used as a surrogate potency assay in the quality control of biotherapeutic medicines. 展开更多
关键词 Surface plasmon resonance EC50 Sensorgram comparison Calibration free concentration analysis Surrogate potency assay TNF-A
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Correlation analysis of three influencing factors and the dust production rate for a free-falling particle stream 被引量:1
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作者 Mengjie Duan Yi Wang +4 位作者 Xiaofen Ren Xinrui Qu Yingxue Cao Yang Yang Lun Nian 《Particuology》 SCIE EI CAS CSCD 2017年第5期126-133,共8页
The effects of three factors (i.e., drop height h, hopper outlet diameter do, and material temperature T] on the dust generation rate derived from a free falling particle stream were investigated via filll factorial ... The effects of three factors (i.e., drop height h, hopper outlet diameter do, and material temperature T] on the dust generation rate derived from a free falling particle stream were investigated via filll factorial experiments. The correlation between the three factors and dust generation rate was also analysed. Results show that Tand h affect the first fugitive dust rate largely, whereas the second fugitive dust rate is mainly dominated by h and do. Through analysing the first fugitive dust percentage data, it is found that h and T should be considered first for higher temperatures and lower flow rates, whereas h and do can be considered under contrasting conditions, and h should be controlled in the remaining two sets of conditions. Relationships between the influencing factors and total and first fugitive dust rates were developed via multiple regression to quantify the dust emission rates for different contact surfaces (rigid or water). 展开更多
关键词 Particle stream free falling Multiple factors Correlation Regression analysis
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Sensitivity analysis of an HgCdTe based photovoltaic receiver for long-wavelength free space optical communication systems 被引量:1
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作者 A.D.D.Dwivedi P.Chakrabarti 《Optoelectronics Letters》 EI 2009年第1期21-25,共5页
We examine theoretically the performance of an Hg0.77Cd0.23Te based p-n photodetector/HFET optical receiver due to its possible application at 10.6 μm free space optical communication system at high bit rate.A rigoro... We examine theoretically the performance of an Hg0.77Cd0.23Te based p-n photodetector/HFET optical receiver due to its possible application at 10.6 μm free space optical communication system at high bit rate.A rigorous noise model of the receiver has been developed for this purpose.We calculate the total noise and sensitivity of the receiver.The front-end of the receiver exhibits a sensitivity of -45 dBm at a bit rate of 1 Gb/s and -30 dBm at a bit rate of 10 Gb/s,and the total mean-square noise curren t〈i2n〉=5×10-15 A2 at a bit rate of 1 Gb/s an d〈i2n〉 =10-12 A2 at a bit rate of 10 Gb/s,and a 3-dB bandwidth of 10 GHz. 展开更多
关键词 Hg HFET Sensitivity analysis of an HgCdTe based photovoltaic receiver for long-wavelength free space optical communication systems free
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免费师范生政策的风险分析及在地方师范大学推广的制度设计 被引量:12
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作者 申卫革 《中国高教研究》 CSSCI 北大核心 2013年第11期42-45,共4页
免费师范生教育政策作为政府改善和补偿农村地区师资的政策,正在由部属师范大学向地方师范大学推广。该政策在执行的过程中在招生、契约履行的可能性、对个人发展钳制的伦理困境、对农村师资补偿机制的有效性等方面存在着一些风险,只有... 免费师范生教育政策作为政府改善和补偿农村地区师资的政策,正在由部属师范大学向地方师范大学推广。该政策在执行的过程中在招生、契约履行的可能性、对个人发展钳制的伦理困境、对农村师资补偿机制的有效性等方面存在着一些风险,只有通过恰切的制度设计才能实现该政策推广的价值目标。 展开更多
关键词 免费师范生 地方师范大学 风险分析 制度设计
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Synergistic effects of zeolitic imidazolate frameworks(ZIFs)with different transition metals on intumescent flame-retarded polypropylene composites:A comparative study
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作者 Yufeng Quan Ruiqing Shen +4 位作者 Christian Schweizer Pradeep Parajuli Zhuoran Zhang Waruna Kulatilaka Qingsheng Wang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第24期102-110,共9页
The use of intumescent flame retardants(IFRs)is considered an environmentally friendly and cost-effective strategy to suppress potential fire hazards from synthetic polymers.However,some conventional IFRs are neither ... The use of intumescent flame retardants(IFRs)is considered an environmentally friendly and cost-effective strategy to suppress potential fire hazards from synthetic polymers.However,some conventional IFRs are neither efficient in developing a thermally stable char layer nor reducing the release of toxic byproducts during polymer combustion.In this work,we aim to discuss the effects of zeolitic imidazolate frameworks(ZIFs)on synergistically improving the flame retardancy behaviors in polypropylene(PP)composites,including thermal degradation(evolved gas analysis),free radical reactions in the gaseous phase(in-situ chemiluminescent image analysis),and carbonaceous structure in the condensed phase(micro-morphology and composition analysis).It is found that the transition metals in ZIFs can catalytically accelerate the crosslinking reaction at a lower initial temperature and decrease the amount of hydrocarbon volatiles in the gaseous phase.Once ignited,the embedded ZIFs can firstly bridge adjacent phosphorus chains in the polymer matrix to expand crosslinking degrees and then they are anchored in the developed N-doped phospho-carbonaceous networks after pyrolysis.As a result,more compact char residue structures are observed in the condensed phase for ZIF-reinforced composites.For example,by replacing 2 wt%of IFR with ZIF-67,the peak heat release rate,peak smoke production rate,and peak CO production rate are reduced by 69%,80%,and 72%,respectively,when compared to the conventional composite.These results indicate an excellent solution to resolve inherent fire hazards associated with IFRs in polymers and achieve necessary efficiency for industrial applications.It also provides a new strategy for determining flammability characteristics and combustion mechanisms of polymer composites using in-situ chemiluminescence analysis. 展开更多
关键词 Polymer flammability Intumescent flame retardants Zeolitic imidazolate frameworks Thermal degradation free radical analysis Flame retardant mechanism
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