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碱木质素与油页岩共热解特性及动力学分析 被引量:3
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作者 柏静儒 邵佳晔 +2 位作者 李梦迪 贾春霞 王擎 《农业工程学报》 EI CAS CSCD 北大核心 2016年第7期187-193,共7页
通过油页岩与碱木质素的热解不但可以得到丰富的轻质气体,也存在着有害的含芳环结构化合物以及酚类化合物等物质,通过二者的共热解意在减小有害物质的生成,提高气产率。选取不同工况下碱木质素与油页岩进行共热解试验,并通过2种Model f... 通过油页岩与碱木质素的热解不但可以得到丰富的轻质气体,也存在着有害的含芳环结构化合物以及酚类化合物等物质,通过二者的共热解意在减小有害物质的生成,提高气产率。选取不同工况下碱木质素与油页岩进行共热解试验,并通过2种Model free动力学分析法对该混合试样进行拟合分析。结果表明:5个试样的失质量峰整体都具有相同的规律。油页岩与碱木质素的热解峰有叠加,具备协同的条件。碱木质素添加量为80%的混合试样对气产率存在抑制作用,其余混合比都使气产率增加。基于FTIR的检测,混合比对二者的共热解产量影响的研究中表明,向油页岩中添加80%的碱性木质素,可以减少芳环结构化合物与酚类化合物的生成。但对于H2O、CO、CO2、CH4的累积产量并未产生明显的影响。不同升温速率的试样中,芳环结构化合物、CO2、CH4的累积产量与升温速率和温度成正比,H2O、CO、苯酚类化合物则不同。通过2种Model free法对该试验数据进行拟合且效果较好,证明了该反应机理的复杂性。 展开更多
关键词 油页岩 热解 生物质 TG-FTIR Model free法 碱木质素
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Improved hybrid iterative optimization method for seismic full waveform inversion
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作者 王义 董良国 刘玉柱 《Applied Geophysics》 SCIE CSCD 2013年第3期265-277,357,358,共15页
In full waveform inversion (FWI), Hessian information of the misfit function is of vital importance for accelerating the convergence of the inversion; however, it usually is not feasible to directly calculate the He... In full waveform inversion (FWI), Hessian information of the misfit function is of vital importance for accelerating the convergence of the inversion; however, it usually is not feasible to directly calculate the Hessian matrix and its inverse. Although the limited memory Broyden-Fletcher-Goldfarb-Shanno (L-BFGS) or Hessian-free inexact Newton (HFN) methods are able to use approximate Hessian information, the information they collect is limited. The two methods can be interlaced because they are able to provide Hessian information for each other; however, the performance of the hybrid iterative method is dependent on the effective switch between the two methods. We have designed a new scheme to realize the dynamic switch between the two methods based on the decrease ratio (DR) of the misfit function (objective function), and we propose a modified hybrid iterative optimization method. In the new scheme, we compare the DR of the two methods for a given computational cost, and choose the method with a faster DR. Using these steps, the modified method always implements the most efficient method. The results of Marmousi and overthrust model testings indicate that the convergence with our modified method is significantly faster than that in the L-BFGS method with no loss of inversion quality. Moreover, our modified outperforms the enriched method by a little speedup of the convergence. It also exhibits better efficiency than the HFN method. 展开更多
关键词 Full waveform inversion Hessian information limited memory BFGS method Hessian-free inexact Newton method decrease ratio
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Shape-free finite element method:The plane hybrid stress-function (HS-F) element method for anisotropic materials 被引量:9
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作者 CEN Song FU XiangRong +2 位作者 ZHOU GuoHua ZHOU MingJue LI ChenFeng 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第4期653-665,共13页
The sensitivity problem to mesh distortion and the low accuracy problem of the stress solutions are two inherent difficulties in the finite element method.By applying the fundamental analytical solutions (in global Ca... The sensitivity problem to mesh distortion and the low accuracy problem of the stress solutions are two inherent difficulties in the finite element method.By applying the fundamental analytical solutions (in global Cartesian coordinates) to the Airy stress function of the anisotropic materials,8-and 12-node plane quadrilateral hybrid stress-function (HS-F) elements are successfully developed based on the principle of the minimum complementary energy.Numerical results show that the present new elements exhibit much better and more robust performance in both displacement and stress solutions than those obtained from other models.They can still perform very well even when the element shapes degenerate into a triangle and a concave quadrangle.It is also demonstrated that the proposed construction procedure is an effective way for developing shape-free finite element models which can completely overcome the sensitivity problem to mesh distortion and can produce highly accurate stress solutions. 展开更多
关键词 finite element hybrid stress-function (HS-F) element shape-free stress function the principle of minimum complementary energy fundamental analytical solutions anisotropic materials
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